CN109761454A - A method for realizing deep denitrification by denitrifying ammonia oxidation MBBR process - Google Patents
A method for realizing deep denitrification by denitrifying ammonia oxidation MBBR process Download PDFInfo
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- CN109761454A CN109761454A CN201910213091.XA CN201910213091A CN109761454A CN 109761454 A CN109761454 A CN 109761454A CN 201910213091 A CN201910213091 A CN 201910213091A CN 109761454 A CN109761454 A CN 109761454A
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- zone
- nitrogen
- aerobic
- anoxic
- mbbr
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- 238000000034 method Methods 0.000 title claims abstract description 34
- AHEWZZJEDQVLOP-UHFFFAOYSA-N monobromobimane Chemical compound BrCC1=C(C)C(=O)N2N1C(C)=C(C)C2=O AHEWZZJEDQVLOP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 230000003647 oxidation Effects 0.000 title description 4
- 238000007254 oxidation reaction Methods 0.000 title description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title description 3
- 229910021529 ammonia Inorganic materials 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 22
- 239000010865 sewage Substances 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 9
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 8
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010802 sludge Substances 0.000 claims description 14
- 238000010992 reflux Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 238000006396 nitration reaction Methods 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 238000004062 sedimentation Methods 0.000 claims description 5
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000005276 aerator Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 241001453382 Nitrosomonadales Species 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 241000894006 Bacteria Species 0.000 abstract 1
- 230000009615 deamination Effects 0.000 abstract 1
- 238000006481 deamination reaction Methods 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
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- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
A method of advanced nitrogen is realized by denitrifying ammoxidation MBBR technique, belongs to technical field of sewage.MBBR filler is added to anaerobism and anoxic zone, by denitrification reduction control in the nitrous stage, the nitrous of generation occurs Anammox with the ammonia nitrogen in raw sewage and reacts, and realizes denitrifying ammoxidation approach deamination.Denitrifying bacterium and anaerobic ammonia oxidizing bacteria are applied to sewage treatment by the present invention, can be saved carbon source and the energy by denitrifying ammoxidation approach, be realized sewage deep denitrogenation.
Description
Technical field
The present invention relates to a kind of methods for realizing advanced nitrogen by denitrifying ammoxidation MBBR technique, belong to sewage treatment
Technical field is suitable for sanitary sewage disposal and handles containing nitrate wastewater, improves nitrogen removal efficiency, solve nitrogen and phosphorus pollution, protect
Protect water environment.
Background technique
Eutrophication caused by China's water body nitrogen and phosphorus pollution is serious.
Common sanitary sewage belongs to the low ammonia nitrogen concentration waste water of low temperature, and conventional short distance nitration+Anammox technology exists
Bottleneck, short distance nitration are difficult to realize and maintain, anaerobic ammonia oxidizing bacteria slow growth, and the generation cycle is long.
Denitrifying ammoxidation carries out part anti-nitration reaction (NO3- NO2-) and anaerobism i.e. in single-reactor
Ammoxidation reaction, electron acceptor NO2--N in anaerobic ammonium oxidation process from denitrification process NO3--N reduction,
It can be difficult to the problem of obtaining with effective solution anaerobic ammonium oxidation process NO2--N, and can be by anaerobic ammonium oxidation process
The NO3--N of generation is removed in situ, thus TN removal rate is higher, while being coupled Anammox reaction and being enabled this technique
Carbon source and aeration energy consumption are further saved, can be used for strengthening the nitrogen phosphorus ligands effect of conventional activated sludge process.
Summary of the invention
The present invention is to provide a kind of methods for realizing advanced nitrogen by denitrifying ammoxidation MBBR technique, strengthen common
The total nitrogen removal effect of activated sludge process improves nitrogen removal rate.
A method of realizing that advanced nitrogen, device composition mainly include (1) by denitrifying ammoxidation MBBR technique
Intake pump, (2) MBBR filler, (3) anaerobic zone, (4) anoxic zone, (5) anoxic zone, (6) aerobic zone, (7) aerobic zone, (8) are aerobic
Area, (9) aerobic zone, (10) sedimentation basin, (11) water outlet, (12) blender, (13) aerator, (14) sludge reflux pump, (15)
Nitrification liquid reflux pump.
A method of pass through denitrifying ammoxidation MBBR technique realize advanced nitrogen, which is characterized in that (3) anaerobic zone,
(4) anoxic zone, (5) anoxic zone etc. area fillings (2) MBBR filler.
A method of advanced nitrogen being realized by denitrifying ammoxidation MBBR technique, which is characterized in that including following step
It is rapid:
1) sewage passes through (1) intake pump into (3) anaerobic zone first, while activated sludge is also entered by (14) sludge reflux pump
(3) anaerobic zone, nitrification liquid enter (4) anoxic zone, (5) anoxic zone by (15) nitrification liquid reflux pump, lack in (3) anaerobic zone, (4)
Part anti-nitration reaction occurs in the activated Sludge Systems in regions such as oxygen area, (5) anoxic zone, nitrate nitrogen is reduced to nitrous state
Nitrogen, occurs Anammox reaction on (2) the MBBR filler in this region, and nitrous and ammonia nitrogen reaction generate nitrogen, occur simultaneously
Anaerobic phosphorus release reaction；
2) anoxic end residual mixed liquor continues to flow into (6) aerobic zone, (7) aerobic zone, (8) aerobic zone, (9) aerobic zone, remaining
Ammonia nitrogen occurs nitration reaction and is removed, while aerobic phosphorus absorption reaction occurs, and by (10) sedimentation basin mud-water separation, (11) water outlet reaches
Mark discharge.
Detailed description of the invention
Fig. 1 is a kind of method for realizing advanced nitrogen by denitrifying ammoxidation MBBR technique, in Fig. 1: 1- intake pump, 2-
MBBR filler, the anaerobic zone 3-, the anoxic zone 4-, the anoxic zone 5-, the aerobic zone 6-, the aerobic zone 7-, the aerobic zone 8-, the aerobic zone 9-, 10- are heavy
Shallow lake pond, 11- water outlet, 12- blender, 13- aerator, 14- sludge reflux pump, 15- nitrification liquid reflux pump.
Specific embodiment
In conjunction with Fig. 1 embodiment that the present invention will be described in detail:
1) sewage passes through (1) intake pump into (3) anaerobic zone first, while activated sludge is also entered by (14) sludge reflux pump
(3) anaerobic zone, nitrification liquid enter (4) anoxic zone, (5) anoxic zone by (15) nitrification liquid reflux pump, lack in (3) anaerobic zone, (4)
Part anti-nitration reaction occurs in the activated Sludge Systems in regions such as oxygen area, (5) anoxic zone, nitrate nitrogen is reduced to nitrous state
Nitrogen, occurs Anammox reaction on (2) the MBBR filler in this region, and nitrous and ammonia nitrogen reaction generate nitrogen, occur simultaneously
Anaerobic phosphorus release reaction；
2) anoxic end residual mixed liquor continues to flow into (6) aerobic zone, (7) aerobic zone, (8) aerobic zone, (9) aerobic zone, remaining
Ammonia nitrogen occurs nitration reaction and is removed, while aerobic phosphorus absorption reaction occurs, and by (10) sedimentation basin mud-water separation, (11) water outlet reaches
Mark discharge.
Using certain School Wastewater as subjects, the contaminant removal capacity of this method is investigated, data target is shown, system
After stable: effluent COD concentration is≤50 mg/L, BOD≤10 mg/L, NH4 +- N concentration≤1 mg/L, NO3 -- N concentration is
≤ 5 mg/L, TN concentration≤10 mg/L, the mg/L of TP≤0.5.
The above content is combining specific test embodiment to illustrate to what the present invention was done, so that the relevant personnel are more preferable
Ground understands, must not believe that specific implementation of the invention is confined to these, therefore field technical staff is made based on the method
Simple modifications are all within that scope of the present invention.
Claims (3)
1. it is a kind of by denitrifying ammoxidation MBBR technique realize advanced nitrogen method, device composition mainly include (1) into
Water pump, (2) MBBR filler, (3) anaerobic zone, (4) anoxic zone, (5) anoxic zone, (6) aerobic zone, (7) aerobic zone, (8) aerobic zone,
(9) aerobic zone, (10) sedimentation basin, (11) water outlet, (12) blender, (13) aerator, (14) sludge reflux pump, (15) nitrification
Liquid reflux pump.
2. a kind of method for realizing advanced nitrogen by denitrifying ammoxidation MBBR technique, which is characterized in that (3) anaerobic zone, (4)
Anoxic zone, (5) anoxic zone etc. area fillings (2) MBBR filler.
3. a kind of method for realizing advanced nitrogen by denitrifying ammoxidation MBBR technique, which comprises the following steps:
1) sewage passes through (1) intake pump into (3) anaerobic zone first, while activated sludge is also entered by (14) sludge reflux pump
(3) anaerobic zone, nitrification liquid enter (4) anoxic zone, (5) anoxic zone by (15) nitrification liquid reflux pump, lack in (3) anaerobic zone, (4)
Part anti-nitration reaction occurs in the activated Sludge Systems in regions such as oxygen area, (5) anoxic zone, nitrate nitrogen is reduced to nitrous state
Nitrogen, occurs Anammox reaction on (2) the MBBR filler in this region, and nitrous and ammonia nitrogen reaction generate nitrogen, occur simultaneously
Anaerobic phosphorus release reaction；
2) anoxic end residual mixed liquor continues to flow into (6) aerobic zone, (7) aerobic zone, (8) aerobic zone, (9) aerobic zone, remaining
Ammonia nitrogen occurs nitration reaction and is removed, while aerobic phosphorus absorption reaction occurs, and by (10) sedimentation basin mud-water separation, (11) water outlet reaches
Mark discharge.
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| CN201910213091.XA CN109761454A (en) | 2019-03-20 | 2019-03-20 | A method for realizing deep denitrification by denitrifying ammonia oxidation MBBR process |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113072075A (en) * | 2021-03-30 | 2021-07-06 | 湖南三友环保科技有限公司 | Preparation method and application of sulfur-based diatomite powder material |
| CN113772880A (en) * | 2021-08-24 | 2021-12-10 | 北京工业大学 | A strengthening method for realizing phosphorus recovery based on DEAMOX2Device and method for nitrogen and phosphorus removal by adopting/O-BCO (anoxic-oxic) process |
| CN113955851A (en) * | 2021-08-18 | 2022-01-21 | 北京工业大学 | Post-selection anoxic/aerobic internal carbon source reinforced municipal sewage deep denitrification device and method |
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| CA2852492A1 (en) * | 2013-05-23 | 2014-11-23 | Manuel Alvarez-Cuenca | Nutrients removal from water/wastewater using simultaneous treatment by an anammox/pao reactor (star) |
| CN104556376A (en) * | 2014-11-29 | 2015-04-29 | 北京工业大学 | Autotrophic nitrogen removal method for biological phosphorus removal of urban sewage based on short-cut denitrification for providing nitrite |
| CN108439599A (en) * | 2018-05-04 | 2018-08-24 | 北京工业大学 | A kind of apparatus and method of the endogenous short-cut denitrification coupling ANAMMOX advanced nitrogen dephosphorization of city domestic sewage |
| US20180257966A1 (en) * | 2015-09-23 | 2018-09-13 | Bkt Co., Ltd. | Wastewater treatment apparatus adopting biofiltration process for pretreatment of shortened nitrogen removal process |
| CN109368928A (en) * | 2018-11-21 | 2019-02-22 | 杭州宸祥环境工程有限公司 | A kind of dephosphorization denitrogenation devices and methods therefor based on short-cut denitrification reaction |
| CN109485152A (en) * | 2018-12-19 | 2019-03-19 | 北京工业大学 | A kind of apparatus and method of continuous flow municipal sewage short-cut denitrification part ANAMMOX advanced nitrogen dephosphorization |
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2019
- 2019-03-20 CN CN201910213091.XA patent/CN109761454A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2852492A1 (en) * | 2013-05-23 | 2014-11-23 | Manuel Alvarez-Cuenca | Nutrients removal from water/wastewater using simultaneous treatment by an anammox/pao reactor (star) |
| CN104556376A (en) * | 2014-11-29 | 2015-04-29 | 北京工业大学 | Autotrophic nitrogen removal method for biological phosphorus removal of urban sewage based on short-cut denitrification for providing nitrite |
| US20180257966A1 (en) * | 2015-09-23 | 2018-09-13 | Bkt Co., Ltd. | Wastewater treatment apparatus adopting biofiltration process for pretreatment of shortened nitrogen removal process |
| CN108439599A (en) * | 2018-05-04 | 2018-08-24 | 北京工业大学 | A kind of apparatus and method of the endogenous short-cut denitrification coupling ANAMMOX advanced nitrogen dephosphorization of city domestic sewage |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113072075A (en) * | 2021-03-30 | 2021-07-06 | 湖南三友环保科技有限公司 | Preparation method and application of sulfur-based diatomite powder material |
| CN113955851A (en) * | 2021-08-18 | 2022-01-21 | 北京工业大学 | Post-selection anoxic/aerobic internal carbon source reinforced municipal sewage deep denitrification device and method |
| CN113772880A (en) * | 2021-08-24 | 2021-12-10 | 北京工业大学 | A strengthening method for realizing phosphorus recovery based on DEAMOX2Device and method for nitrogen and phosphorus removal by adopting/O-BCO (anoxic-oxic) process |
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