CN113200600B - Device and method for treating high-ammonia-nitrogen organic matter wastewater by semi-shortcut nitrification anaerobic ammonia oxidation and serial shortcut denitrification anaerobic ammonia oxidation - Google Patents
Device and method for treating high-ammonia-nitrogen organic matter wastewater by semi-shortcut nitrification anaerobic ammonia oxidation and serial shortcut denitrification anaerobic ammonia oxidation Download PDFInfo
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- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 72
- 230000003647 oxidation Effects 0.000 title claims abstract description 67
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 29
- 239000002351 wastewater Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000005416 organic matter Substances 0.000 title claims abstract description 9
- 239000010802 sludge Substances 0.000 claims abstract description 52
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 43
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000010865 sewage Substances 0.000 claims abstract description 17
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 claims abstract description 13
- 241000894006 Bacteria Species 0.000 claims abstract description 10
- 238000009280 upflow anaerobic sludge blanket technology Methods 0.000 claims abstract 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 138
- 230000002572 peristaltic effect Effects 0.000 claims description 61
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 42
- 230000014759 maintenance of location Effects 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- 238000005273 aeration Methods 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
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- 230000003203 everyday effect Effects 0.000 claims 1
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- 238000005265 energy consumption Methods 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000010815 organic waste Substances 0.000 description 17
- 238000011081 inoculation Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
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- 239000006227 byproduct Substances 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
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- 238000004886 process control Methods 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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Abstract
Description
技术领域technical field
本发明涉及一种半短程硝化厌氧氨氧化串联短程反硝化厌氧氨氧化处理高氨氮有机物废水的装置与方法,属于污水生物处理领域。The invention relates to a semi-short-range nitrification anammox series short-range denitrification anammox device and method for treating high-ammonia-nitrogen organic waste water, belonging to the field of sewage biological treatment.
背景技术Background technique
随着我国经济的快速发展以及对可持续发展理念的提倡,水资源的日益紧缺问题逐渐受到关注。然而,大量的水资源被利用后因其处理或排放不当而污染水体,其中水体富营养化现象最为常见。在化肥、石油产业日益壮大的今天,其排放的高氨氮有机物废水以其高氨氮、危害性强、处理困难等特点得到业内人士的高度重视。而随着日益严格的污水排放标准和持续恶化的水质情况,传统硝化反硝化工艺已经不能满足节能高效、脱氮效率高等要求,开发新的可持续与提质增效的脱氮工艺迫在眉睫。With the rapid development of my country's economy and the promotion of the concept of sustainable development, the increasing shortage of water resources has gradually attracted attention. However, a large amount of water resources are polluted due to improper treatment or discharge after being used, among which eutrophication is the most common phenomenon. Today, with the growing chemical fertilizer and petroleum industries, the discharged high-ammonia-nitrogen organic waste water has been highly valued by people in the industry due to its high ammonia-nitrogen content, strong hazards, and difficult treatment. With increasingly stringent sewage discharge standards and deteriorating water quality, the traditional nitrification and denitrification process can no longer meet the requirements of energy saving, high efficiency and high denitrification efficiency. It is imminent to develop a new sustainable denitrification process with improved quality and efficiency.
在污水生物脱氮领域,厌氧氨氧化菌以亚硝酸根为电子受体氧化氨而生成氮气,从而达到对水中氮素污染去除的目的。厌氧氨氧化的提出与应用推动了污水处理厂由高能耗的末端处理向零能耗或产能单元的功能转变,而厌氧氨氧化工艺与其他新型脱氮工艺的组合工艺更是可以实现废水的深度脱氮,且上流式厌氧污泥床反应器(UASB)有利于厌氧氨氧化菌的有效持留。目前,短程硝化工艺控制硝化反应只进行到亚硝态氮阶段,大大降低了曝气能耗。而半短程硝化则是在氨谷点前停止曝气从而控制氨氮与亚硝态氮的比例达到1~1.32,为厌氧氨氧化提供了稳定的底物获取。In the field of sewage biological denitrification, anammox bacteria use nitrite as the electron acceptor to oxidize ammonia to generate nitrogen, so as to achieve the purpose of removing nitrogen pollution in water. The proposal and application of anaerobic ammonium oxidation has promoted the functional transformation of sewage treatment plants from high-energy-consuming terminal treatment to zero-energy or production capacity units, and the combination of anaerobic ammonium oxidation process and other new nitrogen removal processes can even realize wastewater treatment. The deep denitrification, and the upflow anaerobic sludge bed reactor (UASB) is conducive to the effective retention of anammox bacteria. At present, the short-range nitrification process controls the nitrification reaction only to the nitrite nitrogen stage, which greatly reduces the energy consumption of aeration. The semi-short-cut nitrification is to stop aeration before the ammonia valley point to control the ratio of ammonia nitrogen to nitrite nitrogen to 1-1.32, which provides a stable substrate for anaerobic ammonium oxidation.
短程反硝化使反硝化停留在中间产物亚硝态氮从而获得高且稳定的亚硝积累,供氧氨氧化反应利用。半短程硝化厌氧氨氧化的出水中势必会含有大量硝态氮,为了进一步降低总氮和提高脱氮效率,可以串联一个短程反硝化厌氧氨氧化 UASB反应器,利用上流式反应器的优势,促进菌群的持留和协作,从而实现高氨氮有机物废水的深度脱氮。The short-cut denitrification makes the denitrification stay in the intermediate product nitrite nitrogen to obtain high and stable nitrite accumulation, which can be used for the oxygen ammonium oxidation reaction. The effluent of semi-short-path nitrification anammox will inevitably contain a large amount of nitrate nitrogen. In order to further reduce total nitrogen and improve nitrogen removal efficiency, a short-path denitrification anammox UASB reactor can be connected in series to take advantage of the upflow reactor , to promote the persistence and cooperation of the bacterial flora, so as to realize the deep denitrification of wastewater with high ammonia nitrogen organic matter.
发明内容Contents of the invention
本发明提出了半短程硝化厌氧氨氧化串联短程反硝化厌氧氨氧化处理高氨氮有机物废水的装置与方法。高氨氮有机物废水通过半短程硝化将其中的一半氨氮转化为亚硝态氮,之后氨氮与亚硝态氮的质量浓度比为1~1.32的出水在UASB 颗粒污泥系统中发生厌氧氨氧化反应,将氨氮与亚硝态氮同步去除;含有硝态氮的厌氧氨氧化出水和并联进入的高氨氮有机物废水在短程反硝化厌氧氨氧化一体化UASB反应器中发生反应,硝态氮在短程反硝化菌的作用下转化为亚硝态氮,之后再与高氨氮有机物废水中的氨氮发生厌氧氨氧化反应,进一步提高系统的脱氮率。该方法为高氨氮有机物废水的处理提供了新的思路,解决了其耗能大、脱氮效率低等问题,提高了出水水质。The invention proposes a semi-short-path nitrification anaerobic ammonium oxidation device and a method for treating high-ammonia-nitrogen organic waste water in series with short-range denitrification anammox oxidation. Half of the ammonia nitrogen in the high ammonia nitrogen organic wastewater is converted into nitrite nitrogen through semi-short-path nitrification, and then the effluent with a mass concentration ratio of ammonia nitrogen to nitrite nitrogen of 1 to 1.32 undergoes anaerobic ammonium oxidation reaction in the UASB granular sludge system , remove ammonia nitrogen and nitrite nitrogen synchronously; the anammox effluent containing nitrate nitrogen and the high ammonia nitrogen organic wastewater entering in parallel react in the short-range denitrification anammox integrated UASB reactor, and the nitrate nitrogen is Under the action of short-range denitrifying bacteria, it is converted into nitrite nitrogen, and then undergoes anaerobic ammonium oxidation reaction with ammonia nitrogen in high-ammonia nitrogen organic wastewater to further improve the denitrification rate of the system. This method provides a new idea for the treatment of high-ammonia-nitrogen organic waste water, solves the problems of high energy consumption and low denitrification efficiency, and improves the quality of effluent.
本发明的目的是通过以下技术方案来解决的:半短程硝化厌氧氨氧化串联短程反硝化厌氧氨氧化处理高氨氮有机物废水的装置与方法,其特征在于:The object of the present invention is solved by the following technical scheme: semi-short-path nitrification anammox series short-range denitrification anammox device and method for treating high-ammonia-nitrogen organic waste water, characterized in that:
所用装置包括:进水水箱(1)、半短程硝化SBR反应器(2)、第一中间水箱(3)、厌氧氨氧化UASB反应器(4)、第二中间水箱(5)、短程反硝化厌氧氨氧化UASB反应器(6);The devices used include: water inlet tank (1), semi-short-path nitrification SBR reactor (2), first intermediate water tank (3), anaerobic ammonium oxidation UASB reactor (4), second intermediate water tank (5), short-range reaction Nitrification anaerobic ammonium oxidation UASB reactor (6);
所述半短程硝化SBR反应器(2)包括第一蠕动泵(2.1)、第一进水口(2.2)、曝气盘(2.3)、第一出水口(2.4)、气体流量计(2.5)、气泵(2.6)、搅拌器(2.7)、第一pH/DO测定仪(2.8);所述厌氧氨氧化UASB反应器(4)包括第二蠕动泵(4.1)、第二进水口(4.2)、第二pH/DO测定仪(4.3)、温控装置(4.4)、第二出水口(4.5);所述短程反硝化厌氧氨氧化UASB反应器(6)包括第三蠕动泵(6.1)、第三进水口(6.2)、第四蠕动泵(6.3)、第三pH/DO测定仪(6.4)、回流口(6.5)、第三出水口(6.6)、第五蠕动泵(6.7);The semi-short-path nitrification SBR reactor (2) includes a first peristaltic pump (2.1), a first water inlet (2.2), an aeration tray (2.3), a first water outlet (2.4), a gas flow meter (2.5), Air pump (2.6), agitator (2.7), first pH/DO measuring instrument (2.8); described anaerobic ammonium oxidation UASB reactor (4) comprises second peristaltic pump (4.1), second water inlet (4.2) , a second pH/DO measuring instrument (4.3), a temperature control device (4.4), a second water outlet (4.5); the short-range denitrification anammox UASB reactor (6) includes a third peristaltic pump (6.1) , the third water inlet (6.2), the fourth peristaltic pump (6.3), the third pH/DO measuring instrument (6.4), the return port (6.5), the third water outlet (6.6), the fifth peristaltic pump (6.7);
所述进水水箱(1)中的高氨氮有机物废水通过第一蠕动泵(2.1)从第一进水口(2.2)泵入半短程硝化SBR反应器(2),出水通过第一出水口(2.4)排入第一中间水箱(3);第一中间水箱(3)通过第二蠕动泵(4.1)与厌氧氨氧化 UASB反应器(4)的第二进水口(4.2)相连,出水通过第二出水口(4.5)排入第二中间水箱(5);进水水箱(1)与第二中间水箱(5)分别通过第五蠕动泵(6.7) 和第三蠕动泵(6.1)与短程反硝化厌氧氨氧化UASB反应器(6)的第三进水口 (6.2)相连,回流口(6.5)通过第四蠕动泵(6.3)与第三进水口(6.2)相连并进行污泥回流。The high-ammonia-nitrogen organic waste water in the water inlet tank (1) is pumped into the semi-short-path nitrification SBR reactor (2) from the first water inlet (2.2) through the first peristaltic pump (2.1), and the effluent passes through the first water outlet (2.4 ) into the first intermediate water tank (3); the first intermediate water tank (3) is connected to the second water inlet (4.2) of the anaerobic ammonium oxidation UASB reactor (4) through the second peristaltic pump (4.1), and the outlet water passes through the second The second water outlet (4.5) is discharged into the second intermediate water tank (5); the water inlet water tank (1) and the second intermediate water tank (5) are respectively connected to the short-range reverse flow through the fifth peristaltic pump (6.7) and the third peristaltic pump (6.1). The third water inlet (6.2) of the nitrification anaerobic ammonium oxidation UASB reactor (6) is connected, and the return port (6.5) is connected with the third water inlet (6.2) through the fourth peristaltic pump (6.3) to perform sludge return.
应用所述装置的方法,其特征在于,包括以下步骤:The method for using said device is characterized in that it comprises the following steps:
(1)系统的启动:(1) System startup:
(1.1)半短程硝化SBR反应器的启动:接种污泥为短程硝化污泥,接种后污泥浓度保持在3000-3500mg/L,污泥停留时间为25天,水力停留时间为3-4h,室温下运行;在每个周期内,将进水水箱(1)中的NH4 +-N为200~250mg/L,COD 为650~1300mg/L的高氨氮有机物废水通过第一蠕动泵(2.1)泵入半短程硝化 SBR反应器(2)中,溶解氧保持在2~2.5mg/L,曝气搅拌3h,沉淀1h后排水,排水比60%;当出水中氨氮与亚硝态氮的质量浓度比为1~1.32时且稳定运行15d 及以上认为半短程硝化反应器启动成功。(1.1) Start-up of the semi-short-path nitrification SBR reactor: the inoculation sludge is short-path nitrification sludge, the sludge concentration after inoculation is maintained at 3000-3500mg/L, the sludge residence time is 25 days, and the hydraulic retention time is 3-4h. It operates at room temperature; in each cycle, the high ammonia nitrogen organic waste water with NH 4 + -N of 200-250 mg/L and COD of 650-1300 mg/L in the water inlet tank (1) is passed through the first peristaltic pump (2.1 ) is pumped into the semi-short-path nitrification SBR reactor (2), the dissolved oxygen is maintained at 2-2.5 mg/L, aerated and stirred for 3 hours, and drained after 1 hour of precipitation, with a drainage ratio of 60%; when the amount of ammonia nitrogen and nitrite nitrogen in the effluent When the mass concentration ratio is 1-1.32 and the stable operation time is 15 days or more, it is considered that the semi-short-path nitrification reactor starts up successfully.
(1.2)厌氧氨氧化UASB反应器的启动:接种污泥为厌氧氨氧化颗粒污泥,接种后污泥浓度保持在4500-5000mg/L,水力停留时间为4h,不主动排泥,通过温度控制装置保持温度在30±2℃;第一中间水箱(3)中的半短程硝化SBR反应器(2)出水通过第二蠕动泵(4.1)连续泵入厌氧氨氧化UASB反应器(4) 中;当出水中氨氮与亚硝态氮浓度均<1mg/L时且稳定运行15d及以上认为厌氧氨氧化UASB反应器启动成功。(1.2) Start-up of the anammox UASB reactor: the inoculated sludge is anaerobic ammonium oxidation granular sludge, the sludge concentration after inoculation is maintained at 4500-5000mg/L, the hydraulic retention time is 4h, and the sludge is not actively discharged. The temperature control device keeps the temperature at 30±2°C; the semi-short-path nitrification SBR reactor (2) effluent in the first intermediate water tank (3) is continuously pumped into the anaerobic ammonium oxidation UASB reactor (4) through the second peristaltic pump (4.1) ); when the concentrations of ammonia nitrogen and nitrite nitrogen in the effluent are both less than 1 mg/L and have been in stable operation for 15 days or more, the anaerobic ammonium oxidation UASB reactor is considered to be successfully started.
(1.3)短程反硝化厌氧氨氧化UASB反应器的启动:接种污泥为实验室稳定运行的短程反硝化厌氧氨氧化一体化反应器内污泥,接种后污泥浓度保持在 5000-5500mg/L,水力停留时间为4h,常温下运行,反应器设有回流,回流比为 3.0;第二中间水箱(5)中的厌氧氨氧化UASB反应器(4)出水与进水水箱(1) 中的高氨氮有机物废水混合后通过第三蠕动泵(6.1)连续泵入短程反硝化厌氧氨氧化UASB反应器(6)中,通过调整进水比例控制混合液中的NOX --N与 NH4 +-N质量浓度比为1-1.32;当出水中氨氮与硝态氮浓度均<1mg/L时且稳定运行15d及以上认为短程反硝化厌氧氨氧化UASB反应器启动成功。(1.3) Start-up of short-range denitrification anaerobic ammonium oxidation UASB reactor: the inoculated sludge is the sludge in the short-range denitrification anaerobic ammonium oxidation integrated reactor operated stably in the laboratory, and the sludge concentration after inoculation is maintained at 5000-5500mg /L, the hydraulic retention time is 4h, and it operates at normal temperature. The reactor is provided with reflux, and the reflux ratio is 3.0; the anaerobic ammonium oxidation UASB reactor (4) in the second intermediate water tank (5) has water outlet and water inlet water tank (1 ) mixed with high-ammonia-nitrogen organic waste water through the third peristaltic pump (6.1) and continuously pumped into the short-path denitrification anaerobic ammonium oxidation UASB reactor (6), and the NO X in the mixed solution is controlled by adjusting the ratio of influent - -N The mass concentration ratio of NH 4 + -N is 1-1.32; when the concentrations of ammonia nitrogen and nitrate nitrogen in the effluent are both less than 1 mg/L and have been in stable operation for 15 days or more, the short-range denitrification anaerobic ammonium oxidation UASB reactor is considered to be successfully started.
(2)系统的运行:(2) System operation:
(2.1)半短程硝化SBR反应器的运行:NH4 +-N为200~250mg/L,COD为 650~1300mg/L的高氨氮有机物废水由进水水箱(1)通过第一蠕动泵(2.1)泵入半短程硝化SBR反应器中,AO运行,好氧段通过气体流量计将溶解氧控制在 2~2.5mg/L,定期排泥控制泥龄为25d;每天运行3个周期,每周期8h,包括进水10min、厌氧搅拌30~60min、曝气3~3.5h、沉淀1h、排水10min、闲置130~190min;排水比为60%,NH4 +-N与NO2 --N的质量浓度比为1~1.32的出水排入第一中间水箱(3)。(2.1) Operation of the semi-short-path nitrification SBR reactor: NH 4 + -N is 200 ~ 250mg/L, COD is 650 ~ 1300mg/L of high ammonia nitrogen organic waste water from the water inlet tank (1) through the first peristaltic pump (2.1 ) is pumped into the semi-short-path nitrification SBR reactor, AO is running, the dissolved oxygen in the aerobic section is controlled at 2-2.5 mg/L through the gas flow meter, and the sludge age is controlled by regular sludge discharge to 25 days; 3 cycles per day, each cycle 8 hours, including 10 minutes of water inflow, 30 to 60 minutes of anaerobic stirring, 3 to 3.5 hours of aeration, 1 hour of sedimentation, 10 minutes of drainage, and 130 to 190 minutes of idle time; the drainage ratio is 60%, and the mixture of NH 4 + -N and NO 2 - -N The effluent with a mass concentration ratio of 1-1.32 is discharged into the first intermediate water tank (3).
(2.2)厌氧氨氧化UASB反应器的运行:第一中间水箱(3)的污水通过第二蠕动泵(4.1)进入厌氧氨氧化UASB反应器中,污水流量为0.75L/h,水力停留时间为4h,不主动排泥,温度控制在30±2℃;厌氧氨氧化菌将进水中的NH4 +-N 和NO2 --N去除转化为N2,含有硝态氮的出水排入第二中间水箱(5)。(2.2) Operation of the anaerobic ammonium oxidation UASB reactor: the sewage of the first intermediate water tank (3) enters the anaerobic ammonium oxidation UASB reactor through the second peristaltic pump (4.1), and the sewage flow rate is 0.75L/h, hydraulic retention The time is 4 hours, without active sludge discharge, and the temperature is controlled at 30±2°C; the anammox bacteria remove NH 4 + -N and NO 2 - -N in the influent and convert them into N 2 , and the effluent containing nitrate nitrogen Drains into the second intermediate tank (5).
(2.3)短程反硝化厌氧氨氧化UASB反应器的运行:第二中间水箱(5)的污水和进水水箱(1)中的高氨氮有机物废水分别通过第三蠕动泵(6.1)和第五蠕动泵(6.7)进入短程反硝化厌氧氨氧化UASB反应器中,通过第三蠕动泵(6.1) 和第五蠕动泵(6.7)的污水流量分别为0.75L/h和0.125L/h,反应器上部的回流口(6.5)通过第四蠕动泵(6.3)与第三进水口(6.2)相连进行回流,回流量为 2.625L/h,回流比为3.0,出水通过U型管排出。(2.3) Operation of short-range denitrification anaerobic ammonium oxidation UASB reactor: the sewage in the second intermediate water tank (5) and the high-ammonia nitrogen organic waste water in the water inlet tank (1) pass through the third peristaltic pump (6.1) and the fifth respectively The peristaltic pump (6.7) enters the short-path denitrification anaerobic ammonium oxidation UASB reactor, and the sewage flows through the third peristaltic pump (6.1) and the fifth peristaltic pump (6.7) are respectively 0.75L/h and 0.125L/h, and the reaction The return port (6.5) on the upper part of the device is connected to the third water inlet (6.2) through the fourth peristaltic pump (6.3) for return flow, the return flow rate is 2.625L/h, the return flow ratio is 3.0, and the outlet water is discharged through the U-shaped pipe.
本发明专利具有以下优势:The invention patent has the following advantages:
1)通过半短程硝化反应,不仅可以为后续厌氧氨氧化提供合适的氨氮和亚硝态氮比例,而且可以节省曝气能耗,经济有效。1) Through the semi-short-range nitrification reaction, it can not only provide a suitable ratio of ammonia nitrogen and nitrite nitrogen for the subsequent anammox oxidation, but also save aeration energy consumption, which is economical and effective.
2)上流式厌氧污泥床反应器有利于颗粒厌氧氨氧化菌的持留,更大程度地实现氨氮和亚硝态氮的同步去除。2) The upflow anaerobic sludge bed reactor is conducive to the retention of granular anammox bacteria, and realizes the simultaneous removal of ammonia nitrogen and nitrite nitrogen to a greater extent.
3)短程反硝化菌与厌氧氨氧化菌在上流式厌氧污泥床反应器内实现协同脱氮,处理了上一厌氧氨氧化反应器的副产物硝态氮,总氮进一步降低。3) Short-range denitrifying bacteria and anammox bacteria achieve synergistic denitrification in the upflow anaerobic sludge bed reactor, and the by-product nitrate nitrogen of the previous anammox reactor is processed, and the total nitrogen is further reduced.
4)短程反硝化厌氧氨氧化过程减少了曝气能耗和碳源需求,且污泥产量远小于传统硝化反硝化过程,降低了后续污泥处理成本。4) The short-range denitrification anammox process reduces aeration energy consumption and carbon source requirements, and the sludge output is much smaller than the traditional nitrification and denitrification process, which reduces the subsequent sludge treatment cost.
综上所述,利用本发明处理高氨氮有机物废水,具有节省曝气能耗、提高脱氮率、减少碳源需求等优点。To sum up, using the present invention to treat high-ammonia-nitrogen organic waste water has the advantages of saving aeration energy consumption, improving denitrification rate, and reducing carbon source demand.
附图说明Description of drawings
图1是:半短程硝化厌氧氨氧化串联短程反硝化厌氧氨氧化处理高氨氮有机物废水的装置与方法。Fig. 1 is a device and method for treating waste water with high ammonia nitrogen organic matter by semi-short-path nitrification anammox in series with short-path denitrification anammox.
图1中:1-进水水箱、2-半短程硝化SBR反应器、3-第一中间水箱、4-厌氧氨氧化UASB反应器、5-第二中间水箱、6-短程反硝化厌氧氨氧化UASB反应器;2.1-第一蠕动泵、2.2-第一进水口、2.3-曝气盘、2.4-第一出水口、2.5-气体流量计、2.6-气泵、2.7-搅拌器、2.8-第一pH/DO测定仪;4.1-第二蠕动泵、4.2-第二进水口、4.3- 第二pH/DO测定仪、4.4-温控装置、4.5-第二出水口、6.1-第三蠕动泵;6.2-第三进水口、6.3-第四蠕动泵、6.4-第三pH/DO测定仪、6.5- 回流口、6.6-第三出水口、6.7-第五蠕动泵。In Figure 1: 1-influent water tank, 2-semi-short-path nitrification SBR reactor, 3-first intermediate water tank, 4-anaerobic ammonium oxidation UASB reactor, 5-second intermediate water tank, 6-short-path denitrification anaerobic Ammoxidation UASB reactor; 2.1-first peristaltic pump, 2.2-first water inlet, 2.3-aeration plate, 2.4-first water outlet, 2.5-gas flow meter, 2.6-air pump, 2.7-stirrer, 2.8- 1st pH/DO measuring instrument; 4.1-Second peristaltic pump, 4.2-Second water inlet, 4.3-Second pH/DO measuring instrument, 4.4-Temperature control device, 4.5-Second water outlet, 6.1-Third peristaltic Pump; 6.2-third water inlet, 6.3-fourth peristaltic pump, 6.4-third pH/DO measuring instrument, 6.5-reflux port, 6.6-third water outlet, 6.7-fifth peristaltic pump.
具体实施方式Detailed ways
下面结合附图和实施例详细说明本发明的实施方案:Embodiments of the present invention are described in detail below in conjunction with accompanying drawings and examples:
如图1所示,半短程硝化厌氧氨氧化串联短程反硝化厌氧氨氧化处理高氨氮有机物废水的装置与方法,所用装置包括:进水水箱(1)、半短程硝化SBR反应器(2)、第一中间水箱(3)、厌氧氨氧化UASB反应器(4)、第二中间水箱 (5)、短程反硝化厌氧氨氧化UASB反应器(6);其特征在于所述进水水箱(1) 中的高氨氮有机物废水通过第一蠕动泵(2.1)从第一进水口(2.2)泵入半短程硝化SBR反应器(2),出水通过第一出水口(2.4)排入第一中间水箱(3);第一中间水箱(3)通过第二蠕动泵(4.1)与厌氧氨氧化UASB反应器(4)的第二进水口(4.2)相连,出水通过第二出水口(4.5)排入第二中间水箱(5);进水水箱(1)与第二中间水箱(5)分别通过第五蠕动泵(6.7)和第三蠕动泵(6.1) 与短程反硝化厌氧氨氧化UASB反应器(6)的第三进水口(6.2)相连,回流口 (6.5)通过第四蠕动泵(6.3)与第三进水口(6.2)相连并进行污泥回流。As shown in Figure 1, the semi-short-path nitrification anammox series short-path denitrification anammox device and method for treating high-ammonia nitrogen organic waste water, the devices used include: water inlet tank (1), semi-short-path nitrification SBR reactor (2 ), the first intermediate water tank (3), the anammox UASB reactor (4), the second intermediate water tank (5), the short-range denitrification anammox UASB reactor (6); it is characterized in that the influent The high ammonia nitrogen organic waste water in the water tank (1) is pumped into the semi-short-path nitrification SBR reactor (2) from the first water inlet (2.2) through the first peristaltic pump (2.1), and the effluent is discharged into the second water outlet (2.4) through the first water outlet (2.4). An intermediate water tank (3); the first intermediate water tank (3) is connected to the second water inlet (4.2) of the anaerobic ammonium oxidation UASB reactor (4) by the second peristaltic pump (4.1), and the water outlet is passed through the second water outlet ( 4.5) Discharge into the second intermediate water tank (5); the water inlet tank (1) and the second intermediate water tank (5) pass through the fifth peristaltic pump (6.7) and the third peristaltic pump (6.1) and short-range denitrification anaerobic ammonia respectively The third water inlet (6.2) of the oxidation UASB reactor (6) is connected, and the return port (6.5) is connected with the third water inlet (6.2) through the fourth peristaltic pump (6.3) to perform sludge return.
实验系统如图1所示,各反应器均采用有机玻璃制成,半短程硝化SBR反应器(2)总体积11L,有效体积为10L;厌氧氨氧化UASB反应器(4)5L,有效体积3L;短程反硝化厌氧氨氧化UASB反应器(6)总体积5L,有效体积3L。The experimental system is shown in Figure 1. Each reactor is made of plexiglass. The semi-short-path nitrification SBR reactor (2) has a total volume of 11L and an effective volume of 10L; the anammox UASB reactor (4) has an effective volume of 5L. 3L; the short-range denitrification anaerobic ammonium oxidation UASB reactor (6) has a total volume of 5L and an effective volume of 3L.
试验过程中,具体实验用水取自北京某工业园区排放的高氨氮有机物废水,具体水质如下:COD浓度为650~1300mg/L,NH4 +-N浓度为200~250mg/L, NO2 --N浓度<1mg/L,NO3 --N浓度<1mg/L。During the test, the specific test water was taken from high-ammonia nitrogen organic wastewater discharged from an industrial park in Beijing. The specific water quality is as follows: COD concentration is 650-1300mg/L, NH 4 + -N concentration is 200-250mg/L, NO 2 - - N concentration < 1mg/L, NO 3 - -N concentration < 1mg/L.
具体运行操作如下:The specific operation is as follows:
(1)系统的启动:(1) System startup:
(1.1)半短程硝化SBR反应器的启动:接种污泥为短程硝化污泥,接种后污泥浓度保持在3000-3500mg/L,污泥停留时间为25天,水力停留时间为3-4h,室温下运行;在每个周期内,将进水水箱(1)中的NH4 +-N为200~250mg/L,COD 为650~1300mg/L的高氨氮有机物废水通过第一蠕动泵(2.1)泵入半短程硝化SBR反应器(2)中,溶解氧保持在2~2.5mg/L,曝气搅拌3h,沉淀1h后排水,排水比60%;当出水中氨氮与亚硝态氮的质量浓度比为1~1.32时且稳定运行15d 及以上认为半短程硝化反应器启动成功。(1.1) Start-up of the semi-short-path nitrification SBR reactor: the inoculation sludge is short-path nitrification sludge, the sludge concentration after inoculation is maintained at 3000-3500mg/L, the sludge residence time is 25 days, and the hydraulic retention time is 3-4h. It operates at room temperature; in each cycle, the high ammonia nitrogen organic waste water with NH 4 + -N of 200-250 mg/L and COD of 650-1300 mg/L in the water inlet tank (1) is passed through the first peristaltic pump (2.1 ) is pumped into the semi-short-path nitrification SBR reactor (2), the dissolved oxygen is maintained at 2-2.5 mg/L, aerated and stirred for 3 hours, and drained after 1 hour of precipitation, with a drainage ratio of 60%; when the amount of ammonia nitrogen and nitrite nitrogen in the effluent When the mass concentration ratio is 1-1.32 and the stable operation time is 15 days or more, it is considered that the semi-short-path nitrification reactor starts up successfully.
(1.2)厌氧氨氧化UASB反应器的启动:接种污泥为厌氧氨氧化颗粒污泥,接种后污泥浓度保持在4500-5000mg/L,水力停留时间为4h,不主动排泥,通过温度控制装置保持温度在30±2℃;第一中间水箱(3)中的半短程硝化SBR反应器(2)出水通过第二蠕动泵(4.1)连续泵入厌氧氨氧化UASB反应器(4) 中;当出水中氨氮与亚硝态氮浓度均<1mg/L时且稳定运行15d及以上认为厌氧氨氧化UASB反应器启动成功。(1.2) Start-up of the anammox UASB reactor: the inoculated sludge is anaerobic ammonium oxidation granular sludge, the sludge concentration after inoculation is maintained at 4500-5000mg/L, the hydraulic retention time is 4h, and the sludge is not actively discharged. The temperature control device keeps the temperature at 30±2°C; the semi-short-path nitrification SBR reactor (2) effluent in the first intermediate water tank (3) is continuously pumped into the anaerobic ammonium oxidation UASB reactor (4) through the second peristaltic pump (4.1) ); when the concentrations of ammonia nitrogen and nitrite nitrogen in the effluent are both less than 1 mg/L and have been in stable operation for 15 days or more, the anaerobic ammonium oxidation UASB reactor is considered to be successfully started.
(1.3)短程反硝化厌氧氨氧化UASB反应器的启动:接种污泥为实验室稳定运行的短程反硝化厌氧氨氧化一体化反应器内污泥,接种后污泥浓度保持在 5000-5500mg/L,水力停留时间为4h,常温下运行,反应器设有回流,回流比为 3.0;第二中间水箱(5)中的厌氧氨氧化UASB反应器(4)出水与进水水箱(1) 中的高氨氮有机物废水混合后通过第三蠕动泵(6.1)连续泵入短程反硝化厌氧氨氧化UASB反应器(6)中,通过调整进水比例控制混合液中的NOX --N与 NH4 +-N质量浓度比为1-1.32;当出水中氨氮与硝态氮浓度均<1mg/L时且稳定运行15d及以上认为短程反硝化厌氧氨氧化UASB反应器启动成功。(1.3) Start-up of short-range denitrification anaerobic ammonium oxidation UASB reactor: the inoculated sludge is the sludge in the short-range denitrification anaerobic ammonium oxidation integrated reactor operated stably in the laboratory, and the sludge concentration after inoculation is maintained at 5000-5500mg /L, the hydraulic retention time is 4h, and it operates at normal temperature. The reactor is provided with reflux, and the reflux ratio is 3.0; the anaerobic ammonium oxidation UASB reactor (4) in the second intermediate water tank (5) has water outlet and water inlet water tank (1 ) mixed with high-ammonia-nitrogen organic waste water through the third peristaltic pump (6.1) and continuously pumped into the short-path denitrification anaerobic ammonium oxidation UASB reactor (6), and the NO X in the mixed solution is controlled by adjusting the ratio of influent - -N The mass concentration ratio of NH 4 + -N is 1-1.32; when the concentrations of ammonia nitrogen and nitrate nitrogen in the effluent are both less than 1 mg/L and have been in stable operation for 15 days or more, the short-range denitrification anaerobic ammonium oxidation UASB reactor is considered to be successfully started.
(2)系统的运行:(2) System operation:
(2.1)半短程硝化SBR反应器的运行:NH4 +-N为200~250mg/L,COD为 650~1300mg/L的高氨氮有机物废水由进水水箱(1)通过第一蠕动泵(2.1)泵入半短程硝化SBR反应器中,AO运行,好氧段通过气体流量计将溶解氧控制在 2~2.5mg/L,定期排泥控制泥龄为25d;每天运行3个周期,每周期8h,包括进水10min、厌氧搅拌30~60min、曝气3~3.5h、沉淀1h、排水10min、闲置130~190min;排水比为60%,NH4 +-N与NO2 --N的质量浓度比为1~1.32的出水排入第一中间水箱(3)。(2.1) Operation of the semi-short-path nitrification SBR reactor: NH 4 + -N is 200 ~ 250mg/L, COD is 650 ~ 1300mg/L of high ammonia nitrogen organic waste water from the water inlet tank (1) through the first peristaltic pump (2.1 ) is pumped into the semi-short-path nitrification SBR reactor, AO is running, the dissolved oxygen in the aerobic section is controlled at 2-2.5 mg/L through the gas flow meter, and the sludge age is controlled by regular sludge discharge to 25 days; 3 cycles per day, each cycle 8 hours, including 10 minutes of water inflow, 30 to 60 minutes of anaerobic stirring, 3 to 3.5 hours of aeration, 1 hour of sedimentation, 10 minutes of drainage, and 130 to 190 minutes of idle time; the drainage ratio is 60%, and the mixture of NH 4 + -N and NO 2 - -N The effluent with a mass concentration ratio of 1-1.32 is discharged into the first intermediate water tank (3).
(2.2)厌氧氨氧化UASB反应器的运行:第一中间水箱(3)的污水通过第二蠕动泵(4.1)进入厌氧氨氧化UASB反应器中,污水流量为0.75L/h,水力停留时间为4h,不主动排泥,温度控制在30±2℃;厌氧氨氧化菌将进水中的NH4 +-N 和NO2 --N去除转化为N2,含有硝态氮的出水排入第二中间水箱(5)。(2.2) Operation of the anaerobic ammonium oxidation UASB reactor: the sewage of the first intermediate water tank (3) enters the anaerobic ammonium oxidation UASB reactor through the second peristaltic pump (4.1), and the sewage flow rate is 0.75L/h, hydraulic retention The time is 4 hours, without active sludge discharge, and the temperature is controlled at 30±2°C; the anammox bacteria remove NH 4 + -N and NO 2 - -N in the influent and convert them into N 2 , and the effluent containing nitrate nitrogen Drains into the second intermediate tank (5).
(2.3)短程反硝化厌氧氨氧化UASB反应器的运行:第二中间水箱(5)的污水和进水水箱(1)中的高氨氮有机物废水分别通过第三蠕动泵(6.1)和第五蠕动泵(6.7)进入短程反硝化厌氧氨氧化UASB反应器中,通过第三蠕动泵(6.1) 和第五蠕动泵(6.7)的污水流量分别为0.75L/h和0.125L/h,反应器上部的回流口(6.5)通过第四蠕动泵(6.3)与第三进水口(6.2)相连进行回流,回流量为 2.625L/h,回流比为3.0,出水通过U型管排出。(2.3) Operation of short-range denitrification anaerobic ammonium oxidation UASB reactor: the sewage in the second intermediate water tank (5) and the high-ammonia nitrogen organic waste water in the water inlet tank (1) pass through the third peristaltic pump (6.1) and the fifth respectively The peristaltic pump (6.7) enters the short-path denitrification anaerobic ammonium oxidation UASB reactor, and the sewage flows through the third peristaltic pump (6.1) and the fifth peristaltic pump (6.7) are respectively 0.75L/h and 0.125L/h, and the reaction The return port (6.5) on the upper part of the device is connected to the third water inlet (6.2) through the fourth peristaltic pump (6.3) for return flow, the return flow rate is 2.625L/h, the return flow ratio is 3.0, and the outlet water is discharged through the U-shaped pipe.
试验结果表明:系统运行稳定后,半短程硝化阶段可以实现40~50%的亚硝酸盐积累率,出水氨氮与亚硝态氮比例约为1~1.32;厌氧氨氧化阶段氨氮以亚硝态氮为电子受体转化为氮气,出水中的硝氮以及废水中的氨氮在短程反硝化厌氧氨氧化阶段被同步去除,出水COD小于50mg/L,出水氨氮小于5mg/L,出水总氮小于15mg/L,实现了高氨氮有机物废水的深度脱氮。The test results show that after the system runs stably, the semi-short-cut nitrification stage can achieve a 40-50% nitrite accumulation rate, and the ratio of effluent ammonia nitrogen to nitrite nitrogen is about 1-1.32; Nitrogen is converted into nitrogen gas as an electron acceptor. The nitrate nitrogen in the effluent and the ammonia nitrogen in the wastewater are simultaneously removed in the short-range denitrification anammox stage. The effluent COD is less than 50mg/L, the effluent ammonia nitrogen is less than 5mg/L, and the effluent total nitrogen is less than 15mg/L, realizing the deep denitrification of high ammonia nitrogen organic matter wastewater.
以上是本发明的具体实施例,便于该技术领域的技术人员能更好的理解和应用本发明,但本发明的实施不限于此,因此该技术领域的技术人员对本发明所做的简单改进都在本发明保护范围之内。The above are specific embodiments of the present invention, which are convenient for those skilled in the art to better understand and apply the present invention, but the implementation of the present invention is not limited thereto, so those skilled in the art can make simple improvements to the present invention. Within the protection scope of the present invention.
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