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CN109679189A - A kind of preparation method of preserving jar - Google Patents

A kind of preparation method of preserving jar Download PDF

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Publication number
CN109679189A
CN109679189A CN201811617079.7A CN201811617079A CN109679189A CN 109679189 A CN109679189 A CN 109679189A CN 201811617079 A CN201811617079 A CN 201811617079A CN 109679189 A CN109679189 A CN 109679189A
Authority
CN
China
Prior art keywords
stalk
preserving jar
preparation
powder
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811617079.7A
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Chinese (zh)
Inventor
田耀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Harriet New Mstar Technology Ltd
Original Assignee
Suzhou Harriet New Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Harriet New Mstar Technology Ltd filed Critical Suzhou Harriet New Mstar Technology Ltd
Priority to CN201811617079.7A priority Critical patent/CN109679189A/en
Publication of CN109679189A publication Critical patent/CN109679189A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to packing material technical field more particularly to a kind of preparation methods of preserving jar, and stalk is crushed, and stalk powder is mixed with silane coupling agent, obtains modified straw powder;High density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, granulation obtains straw composite granular;Straw composite granular injection molding, obtains preserving jar.A kind of preparation method of preserving jar provided by the invention, stalk resource is made full use of, stalk preserving jar is produced, which is prepared by plastics and stalk powder for primary raw material, product water-tolerant, manufacture craft is simple, and production cost is low, safe and non-toxic, not only make stalk preserving jar that can keep stalk plant fiber naturally honest color, and dimensionally stable, material is durable, has good mechanical strength.

Description

A kind of preparation method of preserving jar
Technical field
The present invention relates to packing material technical field more particularly to a kind of preparation methods of preserving jar.
Background technique
Agricultural crop straw, including wheat straw, straw, sorghum stalk, cornstalk, hemp stalk, Cotton Stalk, cigarette stalk etc., yield is big, resource It is abundant, stalk comprehensive utilization is explored, is currently Material Field one very promising environment protection field, now with conducive to stalk system At construction materials such as wood-based plates.
And on packing material, the carton or plastic products mainly still used at present, especially plastics use, and cause big The white pollution of amount, therefore environmentally friendly storing preserving jar is made using stalk, straw utilization rate not only can be improved, make full use of money Source can also reduce white garbage.
Summary of the invention
It is an object of the present invention to provide a kind of preparation methods of preserving jar to produce straw for straw resource utilization Stalk preserving jar.
To achieve the above object, the preparation method of a kind of preserving jar provided by the invention, comprising the following steps:
(1) stalk is removed impurity removing by stalk pretreatment, then drying control moisture is crushed, grinding and sieving with pulverizer Obtain stalk powder;
(2) stalk powder is modified, and stalk powder is proportionally mixed with silane coupling agent, and is stirred, and obtains modified straw Stalk powder;
(3) high density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, and stirs evenly;
(4) mixture obtained by step (3) is granulated using pelletizer, obtains straw composite granular;
(5) straw composite granular injection moulding machine injection molding, obtains preserving jar.
Wherein, moisture is controlled 5% hereinafter, sieving is 200~500 mesh stalk described in step (1) after drying.
Each material is according to mass fraction in step (2), 30~65 parts of stalk powder, 3~5 parts of silane coupling agent.
Further, the modified method of step (2) is that stalk powder is put into high-speed solid blender, by silane idol The aqueous solution of connection agent is sprayed on stalk powder and stirs, and stirs 10~30 minutes, 1.5~2 are then dried under the conditions of 120 DEG C Hour.
Preferably, each material according to mass fraction is 35~50 parts of modified straw powder, high-density polyethylene in step (3) 35~50 parts of alkene, 2~5 parts of plasticizer, 3~6 parts of lubricant, 0.5~1.5 part of release agent.
The lubricant is any one or more mixing in stearic acid, calcium stearate and zinc stearate.
The release agent is higher fatty acids, one or two mix in fatty acid amide.
The plasticizer is dibutyl phthalate, dihexyl phthalate, dioctyl phthalate, adjacent benzene two Any one or more in formic acid diisodecyl ester, diisononyl phthalate and phthalic acid butyloxy phenyl mixes.
The temperature of the screw rod feeding section of injection moulding machine described in step (5), compression section and homogenizing zone is respectively 155~ 160 DEG C, 165~170 DEG C and 175~180 DEG C.
Compared with prior art, the preparation method of a kind of preserving jar provided by the invention, stalk resource is made full use of, system Stalk preserving jar is produced, which is prepared by plastics and stalk powder for primary raw material, product water-tolerant, makes work Skill is simple, and production cost is low, safe and non-toxic, not only makes stalk preserving jar that can keep stalk plant fiber naturally honest color, and And dimensionally stable, material is durable, has good mechanical strength.
Specific embodiment
The present invention is further illustrated below with reference to embodiment, can make those skilled in the art that this hair be more completely understood It is bright, but do not limit the invention in any way.
Embodiment 1
A kind of preparation method of preserving jar, comprising the following steps:
(1) stalk is removed impurity removing by stalk pretreatment, then drying control moisture is crushed, grinding and sieving with pulverizer Obtain stalk powder;Moisture is controlled 5% hereinafter, sieving is 500 mesh the stalk after drying.
(2) stalk powder is modified, and stalk powder is proportionally mixed with silane coupling agent, and is stirred, and obtains modified straw Stalk powder;Each material is 55 parts of stalk powder according to mass fraction, 5 parts of silane coupling agent.
Stalk powder is put into high-speed solid blender, the aqueous solution of silane coupling agent is sprayed on stalk powder simultaneously Stirring is stirred 25 minutes, is then dried 1.5 hours under the conditions of 120 DEG C.
(3) high density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, and stirs evenly;
Each material is 45 parts of modified straw powder, 45 parts of high density polyethylene (HDPE), 4 parts of plasticizer, lubrication according to mass fraction 5 parts of agent, 0.5 part of release agent.
The lubricant is the mixture of stearic acid, calcium stearate and zinc stearate 1:1.The release agent is higher aliphatic Acid.
The plasticizer is dibutyl phthalate.
(4) mixture obtained by step (3) is granulated using pelletizer, obtains straw composite granular;
(5) straw composite granular injection moulding machine injection molding, obtains preserving jar.The screw rod of injection moulding machine feeds Section, the temperature in 3rd area of compression section and homogenizing zone are respectively 160 DEG C, 160 DEG C and 175 DEG C.
Embodiment 2
A kind of preparation method of preserving jar, comprising the following steps:
(1) stalk is removed impurity removing by stalk pretreatment, then drying control moisture is crushed, grinding and sieving with pulverizer Obtain stalk powder;Moisture is controlled 5% hereinafter, sieving is 300 mesh the stalk after drying.
(2) stalk powder is modified, and stalk powder is proportionally mixed with silane coupling agent, and is stirred, and obtains modified straw Stalk powder;Each material is 50 parts of stalk powder according to mass fraction, 3 parts of silane coupling agent.Stalk powder is put into high-speed solid In blender, the aqueous solution of silane coupling agent is sprayed on stalk powder and is stirred, stirred 30 minutes, then in 120 DEG C of items It is dried 2 hours under part.
(3) high density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, and stirs evenly;
Each material is 35 parts of modified straw powder, 45 parts of high density polyethylene (HDPE), 5 parts of plasticizer, lubrication according to mass fraction 3 parts of agent, 1.5 parts of release agent.
The lubricant is stearic acid, and the release agent is higher fatty acids.
The plasticizer is dioctyl phthalate.
(4) mixture obtained by step (3) is granulated using pelletizer, obtains straw composite granular;
(5) straw composite granular injection moulding machine injection molding, obtains preserving jar.The screw rod of injection moulding machine feeds Section, the temperature in 3rd area of compression section and homogenizing zone are respectively 155 DEG C, 170 DEG C and 175 DEG C.
Embodiment 3
A kind of preparation method of preserving jar, comprising the following steps:
(1) stalk is removed impurity removing by stalk pretreatment, then drying control moisture is crushed, grinding and sieving with pulverizer Obtain stalk powder;Moisture is controlled 5% hereinafter, sieving is 200 mesh the stalk after drying.
(2) stalk powder is modified, and stalk powder is proportionally mixed with silane coupling agent, and is stirred, and obtains modified straw Stalk powder;Each material is 30 parts of stalk powder according to mass fraction, 5 parts of silane coupling agent.Stalk powder is put into high-speed solid In blender, the aqueous solution of silane coupling agent is sprayed on stalk powder and is stirred, stirred 10 minutes, then in 120 DEG C of items It is dried 1.5 hours under part.
(3) high density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, and stirs evenly;
Each material is 50 parts of modified straw powder, 35 parts of high density polyethylene (HDPE), 2 parts of plasticizer, lubrication according to mass fraction 6 parts of agent, 1 part of release agent.
The lubricant is calcium stearate, and the release agent is fatty acid amide.
The plasticizer is diisononyl phthalate.
(4) mixture obtained by step (3) is granulated using pelletizer, obtains straw composite granular;
(5) straw composite granular injection moulding machine injection molding, obtains preserving jar.The screw rod of injection moulding machine feeds Section, the temperature in 3rd area of compression section and homogenizing zone are respectively 160 DEG C, 170 DEG C and 180 DEG C.
To above-described embodiment 1~3 obtain stalk preserving jar be tested for the property, the project of test include impact strength, The method of tensile strength, bending strength, test is tested referring to the national standard method of plastic products, and test result is as shown in table 1.
1 test result of table
Test item Impact strength KJ/m2 Tensile strength MPa Bending strength MPa
Embodiment 1 3.8 31.5 33
Embodiment 2 4.1 30.7 32.4
Embodiment 3 3.7 30.3 33.1
It is found that the stalk preserving jar of the embodiment of the present application 1~3 has excellent impact strength, draws from 1 test result of table Intensity and bending strength are stretched, meets every demand of preserving jar well.

Claims (9)

1. a kind of preparation method of preserving jar, which comprises the following steps:
(1) stalk is removed impurity removing by stalk pretreatment, then drying control moisture is crushed, grinding and sieving is obtained with pulverizer Stalk powder;
(2) stalk powder is modified, and stalk powder is proportionally mixed with silane coupling agent, and is stirred, and modified straw powder is obtained End;
(3) high density polyethylene (HDPE), plasticizer, lubricant, release agent are added in modified straw powder, and stirs evenly;
(4) mixture obtained by step (3) is granulated using pelletizer, obtains straw composite granular;
(5) straw composite granular injection moulding machine injection molding, obtains preserving jar.
2. a kind of preparation method of preserving jar according to claim 1, which is characterized in that the warp of stalk described in step (1) Moisture control is 5% hereinafter, sieving is 200~500 mesh after drying.
3. a kind of preparation method of preserving jar according to claim 1, which is characterized in that in step (2) each material according to Mass fraction is 30~65 parts of stalk powder, 3~5 parts of silane coupling agent.
4. a kind of preparation method of preserving jar according to claim 1 or 3, which is characterized in that the modified method of step (2) For, stalk powder is put into high-speed solid blender, the aqueous solution of silane coupling agent is sprayed on stalk powder and is stirred, Stirring 10~30 minutes, is then dried 1.5~2 hours under the conditions of 120 DEG C.
5. a kind of preparation method of preserving jar according to claim 1, which is characterized in that in step (3) each material according to Mass fraction is 35~50 parts of modified straw powder, 35~50 parts of high density polyethylene (HDPE), 2~5 parts of plasticizer, lubricant 3~6 Part, 0.5~1.5 part of release agent.
6. a kind of preparation method of preserving jar according to claim 1 or 5, which is characterized in that the lubricant is tristearin Any one or more mixing in acid, calcium stearate and zinc stearate.
7. a kind of preparation method of preserving jar according to claim 1 or 5, which is characterized in that the release agent is advanced One or two kinds of mixing in fatty acid, fatty acid amide.
8. a kind of preparation method of preserving jar according to claim 1 or 5, which is characterized in that the plasticizer is adjacent benzene Dibutyl carboxylic acid, dihexyl phthalate, dioctyl phthalate, diisooctyl phthalate, phthalic acid Any one or more in dinonyl and phthalic acid butyloxy phenyl mixes.
9. a kind of preparation method of preserving jar according to claim 1, which is characterized in that step is molded into described in (5) The temperature of the screw rod feeding section of type machine, compression section and homogenizing zone is respectively 155~160 DEG C, 165~170 DEG C and 175~180 DEG C.
CN201811617079.7A 2018-12-28 2018-12-28 A kind of preparation method of preserving jar Pending CN109679189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811617079.7A CN109679189A (en) 2018-12-28 2018-12-28 A kind of preparation method of preserving jar

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811617079.7A CN109679189A (en) 2018-12-28 2018-12-28 A kind of preparation method of preserving jar

Publications (1)

Publication Number Publication Date
CN109679189A true CN109679189A (en) 2019-04-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112029168A (en) * 2020-08-11 2020-12-04 西安理工大学 A kind of preparation method of waste tobacco stalk fiber reinforced resin matrix composite material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307185A (en) * 2007-05-16 2008-11-19 吉林紫森装饰材料有限公司 Plant fiber polymerized wood and manufacturing method thereof
CN103937077A (en) * 2014-05-13 2014-07-23 江苏锦禾高新科技股份有限公司 Straw/plastic film blowing material and processing technique thereof
CN105295175A (en) * 2015-11-25 2016-02-03 河南工程学院 Polyethylene/wood powder composite wire for fused deposition modeling, and preparation method thereof
CN106700590A (en) * 2016-12-15 2017-05-24 南宁梦幻三体环保科技有限公司 Crop straw 3D printing material
CN107254186A (en) * 2017-06-29 2017-10-17 安徽国风木塑科技有限公司 A kind of DCP crosslinkings HDPE high density polyethylene (HDPE) Wood-plastic materials and preparation method thereof
CN108792180A (en) * 2018-06-05 2018-11-13 湖南工业大学 A kind of betel nut packing box and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307185A (en) * 2007-05-16 2008-11-19 吉林紫森装饰材料有限公司 Plant fiber polymerized wood and manufacturing method thereof
CN103937077A (en) * 2014-05-13 2014-07-23 江苏锦禾高新科技股份有限公司 Straw/plastic film blowing material and processing technique thereof
CN105295175A (en) * 2015-11-25 2016-02-03 河南工程学院 Polyethylene/wood powder composite wire for fused deposition modeling, and preparation method thereof
CN106700590A (en) * 2016-12-15 2017-05-24 南宁梦幻三体环保科技有限公司 Crop straw 3D printing material
CN107254186A (en) * 2017-06-29 2017-10-17 安徽国风木塑科技有限公司 A kind of DCP crosslinkings HDPE high density polyethylene (HDPE) Wood-plastic materials and preparation method thereof
CN108792180A (en) * 2018-06-05 2018-11-13 湖南工业大学 A kind of betel nut packing box and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112029168A (en) * 2020-08-11 2020-12-04 西安理工大学 A kind of preparation method of waste tobacco stalk fiber reinforced resin matrix composite material

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Application publication date: 20190426

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