CN101307185A - Plant fiber polymerized wood and manufacturing method thereof - Google Patents
Plant fiber polymerized wood and manufacturing method thereof Download PDFInfo
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- CN101307185A CN101307185A CNA2007102006248A CN200710200624A CN101307185A CN 101307185 A CN101307185 A CN 101307185A CN A2007102006248 A CNA2007102006248 A CN A2007102006248A CN 200710200624 A CN200710200624 A CN 200710200624A CN 101307185 A CN101307185 A CN 101307185A
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- 239000000835 fiber Substances 0.000 title claims abstract description 44
- 239000002023 wood Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 36
- 241000196324 Embryophyta Species 0.000 claims abstract description 33
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- 239000000314 lubricant Substances 0.000 claims abstract description 13
- 239000000088 plastic resin Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 claims abstract description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 5
- 235000009566 rice Nutrition 0.000 claims abstract description 5
- 235000017060 Arachis glabrata Nutrition 0.000 claims abstract description 3
- 244000105624 Arachis hypogaea Species 0.000 claims abstract description 3
- 235000010777 Arachis hypogaea Nutrition 0.000 claims abstract description 3
- 235000018262 Arachis monticola Nutrition 0.000 claims abstract description 3
- 241000353135 Psenopsis anomala Species 0.000 claims abstract description 3
- 235000020232 peanut Nutrition 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 15
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- 238000007664 blowing Methods 0.000 claims description 13
- 235000013311 vegetables Nutrition 0.000 claims description 13
- 239000004902 Softening Agent Substances 0.000 claims description 12
- -1 polypropylene Polymers 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 10
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 6
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 5
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 5
- 229920001903 high density polyethylene Polymers 0.000 claims description 5
- 239000004700 high-density polyethylene Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000010903 husk Substances 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229920001179 medium density polyethylene Polymers 0.000 claims description 3
- 239000004701 medium-density polyethylene Substances 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 claims description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 2
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 239000010721 machine oil Substances 0.000 claims description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000010902 straw Substances 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 8
- 239000002131 composite material Substances 0.000 abstract description 3
- 244000025254 Cannabis sativa Species 0.000 abstract description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract description 2
- 244000020551 Helianthus annuus Species 0.000 abstract description 2
- 235000003222 Helianthus annuus Nutrition 0.000 abstract description 2
- 244000046052 Phaseolus vulgaris Species 0.000 abstract description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 abstract description 2
- 244000061458 Solanum melongena Species 0.000 abstract description 2
- 235000002597 Solanum melongena Nutrition 0.000 abstract description 2
- 240000006394 Sorghum bicolor Species 0.000 abstract description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 abstract description 2
- 235000021307 Triticum Nutrition 0.000 abstract description 2
- 244000098338 Triticum aestivum Species 0.000 abstract description 2
- 240000008042 Zea mays Species 0.000 abstract description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 2
- 235000009120 camo Nutrition 0.000 abstract description 2
- 235000005607 chanvre indien Nutrition 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000011487 hemp Substances 0.000 abstract description 2
- 239000004088 foaming agent Substances 0.000 abstract 2
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 abstract 1
- 235000003097 Artemisia absinthium Nutrition 0.000 abstract 1
- 240000001851 Artemisia dracunculus Species 0.000 abstract 1
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 abstract 1
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- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 239000001138 artemisia absinthium Substances 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- 239000002667 nucleating agent Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 240000006891 Artemisia vulgaris Species 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- 235000015505 Sorghum bicolor subsp. bicolor Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
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- 230000007812 deficiency Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an artificial composite wood, namely a plant fiber polymeric wood and a manufacturing method thereof. The material is prepared from the following raw materials in percentage by weight: 50-85% of plant fiber powder, 10-45% of plastic resin, 0.5-1.5% of coupling agent, 2-5% of foaming agent, 0.5-1.5% of co-foaming agent, 1-2% of plasticizer, 0.5-1% of nucleating agent and 0.5-3% of lubricant. The plant fiber powder is one or a combination of more of wood powder, rice hull powder, straw powder (corn straw, sorghum straw, wheat straw, rice straw, sunflower straw, eggplant straw, bean straw, wormwood straw, hemp straw and other crop straws), branch powder, weed powder, peanut and melon seed shell powder and the like. The wood-saving composite material has the characteristics of high strength, wood saving, low cost, long service life, recyclability and contribution to environmental protection. The process is simple, scientific and reasonable.
Description
Technical field
The present invention relates to a kind of artificial compounded timber, i.e. plant fiber polymerization wood and manufacture method thereof.
Background technology
In prior art, natural timber is day by day in short supply, and the price height causes wooden product cost height.In recent years, artificial composite plank was comparatively popular, was used in floor, finishing material but be only limited to.A pillar part or wooden prop that mine underworkings supporting is at present used, its shortcoming are waste timber, the cost height, and its nonmetallic substitute products do not appear in the newspapers.
Summary of the invention
The supporting that the objective of the invention is to provide at above-mentioned deficiency a kind of alternative mine wooden prop is with plant fiber polymerization wood material and manufacture method thereof.
Technical solution of the present invention is: a kind of plant fiber polymerization wood comprises that following raw materials by weight percent makes:
Vegetable fibre powder 50-85%, Plastic Resin 10-45%, coupling agent 0.5-1.5%, whipping agent 2-5%, blowing promotor 0.5-1.5%, softening agent 1-2%, nucleator 0.5-1%, lubricant 0.5-3%.
Also add in the above-mentioned prescription whipping agent 2-5%, blowing promotor 0.5-1.5% are arranged.
Screening formulation is: vegetable fibre powder 80%, Plastic Resin 10%, coupling agent 1%, whipping agent 5%, blowing promotor 1%, softening agent 2%, nucleator 0.5%, lubricant 0.5%.
Described vegetable fibre powder is the one or more combination in wood powder, rice husk powder, stalk powder (crops stalks such as maize straw, broomcorn straw, wheat straw, straw, sunflower stalk, eggplant stalk, beans stalk, wormwood artemisia stalk, hemp stalk), brush wood powder, weeds powder, the peanut melon seed cases powder etc.
Described Plastic Resin is meant PE, PVC or PP; PE is high density polyethylene(HDPE) (HDPE), new LDPE (film grade) (VLDPE), ultra-low density polyethylene (ULDPE) or medium-density polyethylene etc.; PVC is hard class polyvinyl chloride or soft class polyvinyl chloride, and model has 4,5,7 types etc.; PP is film-grade polypropylene, injection grade polypropylene or ethylene copolymer polypropylene etc.General PE, PVC or PP waste or used plastics can utilize.
Described coupling agent is meant titanate coupling agent (2246), silane coupling agent, (productions of U.S. CAVEDON chemical company) such as diethylene titanate coupling agent or Cavedon coupling agents.
Described whipping agent is meant bicarbonate of ammonia, Cellmic C 121 (or claiming the A whipping agent) or N-N '-dinitroso five methyne tetramines (or claiming the H whipping agent) etc.
Described blowing promotor is meant Hydrochlorofluorocarbons (HFC3), methylene dichloride, trichloroethane or acetone etc.
Described softening agent is meant O-phthalic acids, dibutyl phthalate (DBP), dioctyl phthalate (DOP) (DOP), stearic acid, clorafin (containing chlorine 50-54%) or phosphoric acid ester etc.
Described nucleator is meant silicon oxide, talcum powder, polycarboxylate or ethylene acrylate copolymer etc.
Described lubricant is meant external lubricant: as paraffin (white oil), silicone oil, machine oil etc.Internal lubricant: as polyethylene wax, tetrafluoroethylene wax, stearic acid or stearin etc.
The preparation method of plant fiber polymerization wood: get the vegetable fibre powder, drying is handled, add liquid type auxiliary agent-coupling agent, lubricant, mix, add Plastic Resin, remix, add powdery or solid kind auxiliary agent-softening agent, nucleator or whipping agent, blowing promotor, mix, extrude or mix, granulation is extruded.Plant fiber polymerization wood can be routine or special shapes such as sheet material, square column class material, tubing, section bar or profiled material.Plant fiber polymerization wood is used for fields such as mine support, building, decoration and substitutes the timber use.Use as pillar in post, to add the material of gaining in strength, skeleton etc., as reinforcing bar, concrete, Steel Concrete etc.
Advantage of the present invention is: is major ingredient 1,, is equipped with Plastic Resin and auxiliary agent, obtain plant fiber polymerization wood, have the intensity height, save timber with cheap vegetable fibre powder, and with low cost, long service life, can recycle, be beneficial to the characteristics of environmental protection.2, for the down-hole, mine provides novel supporting stay material, help the mine and increase production and improve productivity.3, technology is simple, and is scientific and reasonable.
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment
Embodiment 1
Plant fiber polymerization wood is by vegetable fibre powder 80%, Plastic Resin 10%, and coupling agent 1%, whipping agent 5%, blowing promotor 1%, softening agent 2%, nucleator 0.5%, lubricant 0.5% is made.
Embodiment 2
Plant fiber polymerization wood is by vegetable fibre powder 81%, Plastic Resin 10%, and coupling agent 1%, whipping agent 2%, blowing promotor 1%, softening agent 1.5%, nucleator 0.5%, lubricant 3% is made.
Embodiment 3
Plant fiber polymerization wood is by vegetable fibre powder 53%, Plastic Resin 41%, and coupling agent 0.5%, whipping agent 2%, blowing promotor 0.5%, softening agent 1%, nucleator 0.5%, lubricant 1.5% is made.
Embodiment 4
Plant fiber polymerization wood is by wood powder 50%, hard class polyvinyl chloride (PVC) 43.8%, and titanate coupling agent (2246) 0.5%, Cellmic C 121 3%, Hydrochlorofluorocarbons (HFC3) 0.5%, phthalic acid 1%, silicon oxide 0.2%, polyethylene wax 1% is made.
Embodiment 5
Plant fiber polymerization wood is by rice husk powder 65%, injection grade polypropylene (PP) 25%, and silane coupling agent 1.5%, bicarbonate of ammonia 3.5%, methylene dichloride 1%, dibutyl phthalate (DBP) 1.5%, talcum powder 0.5%, paraffin (white oil) 2% is made.
Embodiment 6
Plant fiber polymerization wood is by stalk powder 82.5%, medium-density polyethylene (PE) 12%, and titanate coupling agent (2246) 1.5%, clorafin (containing chlorine 50-54%) 2%, talcum powder 0.5%, polyethylene wax 1.5% is made.
Embodiment 7
The manufacture method of plant fiber polymerization wood: get vegetable fibre powder 200-600 order, drying is handled 50-70 ℃, add liquid type auxiliary agent-coupling agent, lubricant, mix, add Plastic Resin, remix, add powdery or solid kind auxiliary agent-softening agent, nucleator or whipping agent, blowing promotor, mixed 15-20 minute, extrude or mix, granulation is extruded.
Claims (12)
1. plant fiber polymerization wood is characterized in that comprising that following raw materials by weight percent makes:
Vegetable fibre powder 50-85%, Plastic Resin 10-45%, coupling agent 0.5-1.5%, softening agent 1-2%, nucleator 0.5-1%, lubricant 0.5-3%.
2. according to the described plant fiber polymerization wood of claim 1, it is characterized in that adding has whipping agent 2-5%, blowing promotor 0.5-1.5%.
3. according to the described plant fiber polymerization wood of claim 2, it is characterized in that vegetable fibre powder 80%, Plastic Resin 10%, coupling agent 1%, whipping agent 5%, blowing promotor 1%, softening agent 2%, nucleator 0.5%, lubricant 0.5%.
4. according to claim 1,2,3 arbitrary described plant fiber polymerization woods, it is characterized in that described vegetable fibre powder is the one or more combination in wood powder, rice husk powder, stalk powder, brush wood powder, weeds powder, the peanut melon seed cases powder.
5. according to claim 1,2,3 arbitrary described plant fiber polymerization woods, it is characterized in that described resin is meant PE, PVC or PP; PE is high density polyethylene(HDPE), new LDPE (film grade), ultra-low density polyethylene or medium-density polyethylene; PVC is hard class polyvinyl chloride or soft class polyvinyl chloride; PP is film-grade polypropylene, injection grade polypropylene or ethylene copolymer polypropylene.
6. according to claim 1,2,3 arbitrary described plant fiber polymerization woods, it is characterized in that described coupling agent is meant titanate coupling agent, silane coupling agent, diethylene titanate coupling agent or Cavedon coupling agent.
7. according to claim 2 or 3 described plant fiber polymerization woods, it is characterized in that described whipping agent is meant bicarbonate of ammonia, Cellmic C 121 or N-N '-dinitroso five methyne tetramines.
8. according to claim 2 or 3 described plant fiber polymerization woods, it is characterized in that described blowing promotor is meant Hydrochlorofluorocarbons, methylene dichloride, trichloroethane or acetone.
9. according to claim 1,2,3 arbitrary described plant fiber polymerization woods, it is characterized in that described softening agent is meant dibutyl phthalate, dioctyl phthalate (DOP), clorafin or phosphoric acid ester.
10. according to claim 1,2,3 arbitrary described plant fiber polymerization woods, it is characterized in that described nucleator is meant silicon oxide, talcum powder, polycarboxylate or ethylene acrylate copolymer.
11., it is characterized in that described lubricant is meant paraffin, silicone oil, machine oil, polyethylene wax, tetrafluoroethylene wax, stearic acid or stearin according to claim 1,2,3 arbitrary described plant fiber polymerization woods.
12. as according to claim 1,2,3 arbitrary as described in the manufacture method of plant fiber polymerization wood, it is characterized in that getting the vegetable fibre powder, drying is handled, and adds liquid type auxiliary agent-coupling agent, lubricant, mix, add Plastic Resin, remix adds powdery or solid kind auxiliary agent-softening agent, nucleator or whipping agent, blowing promotor, mix, extrude or mix, granulation is extruded.
Priority Applications (1)
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CNA2007102006248A CN101307185A (en) | 2007-05-16 | 2007-05-16 | Plant fiber polymerized wood and manufacturing method thereof |
Applications Claiming Priority (1)
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CNA2007102006248A CN101307185A (en) | 2007-05-16 | 2007-05-16 | Plant fiber polymerized wood and manufacturing method thereof |
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CNA2007102006248A Pending CN101307185A (en) | 2007-05-16 | 2007-05-16 | Plant fiber polymerized wood and manufacturing method thereof |
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CN101967294A (en) * | 2010-10-26 | 2011-02-09 | 曾广胜 | Vegetable fiber polyvinyl chloride plastic composite material and preparation method thereof |
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2007
- 2007-05-16 CN CNA2007102006248A patent/CN101307185A/en active Pending
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