CN109542150B - A method for adjusting the influent load of rural domestic sewage treatment facilities - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及废水处理技术领域,尤其涉及农村生活污水处理设施进水负荷的调节方法。The invention relates to the technical field of wastewater treatment, in particular to a method for adjusting the influent load of rural domestic sewage treatment facilities.
背景技术Background technique
近年来,我国农村生活污水处理设施的数量急剧增加。以浙江为例,农村生活污水处理设施基本上实现了村、户的全覆盖,一个县区的设施就能达到成百上千座,且地理位置高度分散。这些设施的数量大、面积广,目前主要依靠人工运维管理;而利用国标法监测水质指标,在监管过程中取样与水质测试的成本较高、周期较长且工作量较大,不仅难以实时地指示进水的水质变化,而且也难以在设施运行过程中及时应对农村生活污水水质变化大、处理设施污染负荷波动大的难题,影响了设施作用的发挥。In recent years, the number of rural domestic sewage treatment facilities in my country has increased dramatically. Taking Zhejiang as an example, the rural domestic sewage treatment facilities have basically achieved full coverage of villages and households, and the number of facilities in a county can reach hundreds of thousands, and the geographical location is highly dispersed. These facilities are large in number and wide in area, and currently mainly rely on manual operation and maintenance management. However, using the national standard method to monitor water quality indicators, sampling and water quality testing in the supervision process is costly, the cycle is long, and the workload is large, which is not only difficult to real-time In addition, it is difficult to timely respond to the problems of large changes in the quality of rural domestic sewage and large fluctuations in the pollution load of treatment facilities during the operation of the facility, which affects the performance of the facility.
目前,农村生活污水处理设施主要分为生物处理工艺(例如厌氧-缺氧-好氧(A2O)组合工艺、厌氧-好氧(AO)组合工艺、序批式反应器以及厌氧、好氧单独处理)和生态处理(最常见的是人工湿地)。各种农村污水处理设施的构成一般都比较简单,生物处理设施涉及到的设备主要是进水提升泵、回流泵、风机,而生态处理设施涉及到的设备一般只有进水提升泵。设施运行的自控目前主要体现在通过电控柜控制提升泵的启停来调控进水量,通过控制风机的启停和频率来调控曝气量。另外,由于农村污水的水质水量变化大,一般在处理设施前端会设有调节池,调节池一端设有进水口,另一端安装有提升泵,污水由提升泵提升进入厌氧池或者人工湿地中,提升泵出水管设有回流管,用以将污水回流至调节池内,以便控制进入厌氧池或者人工湿地中污水的流量。At present, rural domestic sewage treatment facilities are mainly divided into biological treatment processes (such as anaerobic-anoxic-aerobic (A 2 O) combined process, anaerobic-aerobic (AO) combined process, sequencing batch reactor and anaerobic , aerobic treatment alone) and ecological treatment (most commonly constructed wetlands). The composition of various rural sewage treatment facilities is generally relatively simple. The equipment involved in biological treatment facilities are mainly influent lifting pumps, return pumps, and fans, while the equipment involved in ecological treatment facilities is generally only influent lifting pumps. The automatic control of the operation of the facility is currently mainly reflected in the control of the water inflow by controlling the start and stop of the lift pump through the electric control cabinet, and the aeration volume by controlling the start and stop and frequency of the fan. In addition, due to the large changes in the quality and quantity of rural sewage, there is generally a conditioning tank at the front end of the treatment facility, with a water inlet at one end and a lift pump at the other end. , The water outlet pipe of the lift pump is provided with a return pipe, which is used to return the sewage to the adjustment tank, so as to control the flow of sewage into the anaerobic tank or constructed wetland.
一些地区为了提高设施的运维效果,开发建立了设施运维的远程监管平台,通过远程监管平台实时监控水泵和风机的运行状态,有些平台还可以看到瞬时与累计流量、以及运维人员的运维轨迹和运维记录。In order to improve the operation and maintenance effect of facilities, some regions have developed and established a remote monitoring platform for facility operation and maintenance. Through the remote monitoring platform, the operation status of pumps and fans can be monitored in real time. O&M track and O&M record.
例如:公开号为CN105717859A的发明专利申请公开了一种全流程管理分散式农村污水处理设施的远程监管方法,该方法包括:污水处理设施采集的数据通过无线通讯网络实时传送至监控管理服务器,监控管理服务器将采集的数据信息进行存储和处理,并将分析结果传输至远程操作设备,用户通过远程操作设备的平台实时调整污水处理设施的运行参数,调整数据通过无线通讯网络传回至污水处理设施,对现场设备运行状态监察仪和数据采集仪进行调整,实现对污水处理设施的分布式管理。其中,所采集的数据包括实时监控画面,水泵或者风机的运行状态,污水进水和出水流量,COD浓度,BOD浓度,pH值以及氨氮浓度。For example, the invention patent application with publication number CN105717859A discloses a remote monitoring method for the whole-process management of decentralized rural sewage treatment facilities. The management server stores and processes the collected data information, and transmits the analysis results to the remote operation equipment. The user adjusts the operating parameters of the sewage treatment facility in real time through the platform of the remote operation equipment, and the adjusted data is transmitted back to the sewage treatment facility through the wireless communication network. , to adjust the field equipment operation status monitor and data acquisition instrument to realize the distributed management of sewage treatment facilities. Among them, the collected data includes real-time monitoring images, operating status of pumps or fans, sewage inflow and outflow flow, COD concentration, BOD concentration, pH value and ammonia nitrogen concentration.
但是,由于资金限制,农村污水处理设施不可能像城市污水厂一样,采用大量的在线监测技术对进出水的水质和生化反应参数进行系统的监测与管理;因此对进出水的水质和污染负荷的监管是农村污水处理设施运维的难题。However, due to financial constraints, it is impossible for rural sewage treatment facilities to use a large number of online monitoring technologies to systematically monitor and manage the water quality and biochemical reaction parameters of incoming and outgoing water like urban sewage plants. Supervision is a difficult problem in the operation and maintenance of rural sewage treatment facilities.
另一方面,由于全国各地对农村污水排放要求的不断提高,农村分散污水处理设施越来越多地采用生物或/和生态处理工艺,上述生物生态处理工艺能否正常运行,不仅取决于水泵和风机是否运转,更取决于反应器内是否保持有合理的水力负荷与污染物容积/表面负荷。研究表明,我国农村生活污水普遍碳氮比低。以浙江为例,COD/TN基本低于3,绝大多数低于2.0。各类农村污水生物处理工艺中,COD达标率最高,为90%以上;氨氮、总氮、总磷是达标排放的限制因素,且受进水影响很大。On the other hand, due to the continuous improvement of rural sewage discharge requirements throughout the country, more and more biological or/and ecological treatment processes are used in rural decentralized sewage treatment facilities. The normal operation of the above-mentioned biological and ecological treatment processes depends not only on pumps and The operation of the fan is more dependent on whether a reasonable hydraulic load and contaminant volume/surface load are maintained in the reactor. Studies have shown that the carbon-nitrogen ratio of rural domestic sewage in my country is generally low. Taking Zhejiang as an example, COD/TN is basically lower than 3, and most of them are lower than 2.0. Among all kinds of rural sewage biological treatment processes, the COD compliance rate is the highest, which is more than 90%; ammonia nitrogen, total nitrogen and total phosphorus are the limiting factors of compliance discharge, and are greatly affected by water inflow.
目前,导致农村污水处理设施处理出水不达标的主要原因,就是进水浓度太高,或者进水负荷太大;如果能够在线监控,并调整进水负荷,将大幅度提升以AAO、人工湿地为代表的生物或/和生态处理效率。因此,远程监管对适合农村污水使用的低价耐用的水质在线监测设备产生了迫切需求。At present, the main reason that the effluent of rural sewage treatment facilities does not meet the standard is that the concentration of the influent is too high, or the influent load is too large; if online monitoring and adjustment of the influent load can be carried out, it will greatly improve the use of AAO and constructed wetlands. Represents the biological or/and ecological treatment efficiency. Therefore, remote supervision has created an urgent need for low-cost and durable online water quality monitoring equipment suitable for rural sewage.
然而,氨氮、总氮、总磷等在线监测仪器的价格较高,从几万至十几万元不等,显然无法适应农村生活污水处理设施监测的特殊性。因此,有必要去探究新的监测方法以替代常规的氨氮、总氮、总磷等在线监测仪器,从而有效实现农村生活污水的高效监测。However, the price of online monitoring instruments such as ammonia nitrogen, total nitrogen, and total phosphorus is relatively high, ranging from tens of thousands to hundreds of thousands of yuan, which obviously cannot adapt to the particularity of monitoring of rural domestic sewage treatment facilities. Therefore, it is necessary to explore new monitoring methods to replace conventional online monitoring instruments such as ammonia nitrogen, total nitrogen, and total phosphorus, so as to effectively realize the efficient monitoring of rural domestic sewage.
发明内容SUMMARY OF THE INVENTION
本发明提供了一种农村生活污水处理设施进水负荷的调节方法,该方法通过测定处理设施进水的电导率,来监测和管理控制农村生活污水处理设施的进水水质,在降低监测成本的情况下,实现了农村生活污水处理设施进水负荷的高效调节。The invention provides a method for adjusting the influent load of rural domestic sewage treatment facilities. The method monitors and manages and controls the influent water quality of the rural domestic sewage treatment facilities by measuring the conductivity of the influent water of the treatment facilities, thereby reducing monitoring costs. Under the circumstance, the efficient adjustment of the influent load of the rural domestic sewage treatment facilities is realized.
具体技术方案如下:The specific technical solutions are as follows:
一种农村生活污水处理设施的监管方法,包括以下步骤:A monitoring method for rural domestic sewage treatment facilities, comprising the following steps:
(1)选定若干由进水调节池和污水处理装置两部分组成的农村生活污水处理设施,进水调节池内设有将池内污水输入污水处理装置的提升泵;对各农村生活污水处理设施进水调节池内的污水进行取样,检测样品中污染物的浓度和电导率;所述农村生活污水由厨房污水、洗衣污水和经化粪池处理后的粪尿污水组成;所述污染物为总氮、氨氮或总磷;(1) Select a number of rural domestic sewage treatment facilities composed of two parts: an influent adjustment tank and a sewage treatment device. The influent adjustment tank is equipped with a lift pump for inputting the sewage in the tank into the sewage treatment device; The sewage in the water conditioning tank is sampled, and the concentration and conductivity of the pollutants in the samples are detected; the rural domestic sewage is composed of kitchen sewage, laundry sewage and fecal sewage treated by the septic tank; the pollutants are total nitrogen , ammonia nitrogen or total phosphorus;
(2)根据步骤(1)中样品的检测数据,进行线性回归分析和方程拟合,得到电导率与污染物浓度之间的线性关系;(2) according to the detection data of the sample in step (1), carry out linear regression analysis and equation fitting, obtain the linear relationship between conductivity and pollutant concentration;
其中,线性回归方程为:y=ax+b;x为电导率,y为污染物的浓度,a为斜率,b为截距;Among them, the linear regression equation is: y=ax+b; x is the conductivity, y is the concentration of pollutants, a is the slope, and b is the intercept;
(3)在各农村生活污水处理设施的进水调节池内安装电导率仪和液位计,分别监测进水调节池内污水的电导率值和水位高度,计算得到进水调节池内污染物的浓度和总量,再根据污水处理装置的污染物容积负荷或污染物表面负荷,确定提升泵开启的时长,从而调节农村生活污水处理设施的进水负荷。(3) Install a conductivity meter and a liquid level gauge in the influent adjustment tank of each rural domestic sewage treatment facility to monitor the conductivity value and water level of the sewage in the influent adjustment tank respectively, and calculate the concentration of pollutants in the influent adjustment tank and the water level. The total amount, and then according to the volume load of pollutants or the surface load of pollutants in the sewage treatment plant, determine the length of time that the lift pump is turned on, so as to adjust the influent load of rural domestic sewage treatment facilities.
本发明中,所述的农村生活污水是指农村居民生活所产生的污水,具体包括三类污水,即:粪尿污水(经化粪池处理后的)、厨房污水和洗衣污水。In the present invention, the rural domestic sewage refers to the sewage generated by rural residents, and specifically includes three types of sewage, namely: fecal and urine sewage (treated by septic tanks), kitchen sewage and laundry sewage.
经试验发现,对于上述农村生活污水而言,电导率与总氮、氨氮和总磷的浓度之间存在线性关系,能够通过电导率数据来反映农村生活污水中总氮、氨氮和总磷的浓度,进而反映农村生活污水处理设施进水的水质。The test found that for the above rural domestic sewage, there is a linear relationship between the conductivity and the concentrations of total nitrogen, ammonia nitrogen and total phosphorus, and the conductivity data can reflect the concentration of total nitrogen, ammonia nitrogen and total phosphorus in rural domestic sewage. , and then reflect the quality of the influent water of rural domestic sewage treatment facilities.
然而,其他类型的污水却不存在上述规律,例如:城市污水(城市生活污水和城市生产污水)中的电导率与总氮、氨氮和总磷的浓度之间并没有较好地线性关系;并且农村生活污水中的其它指标,如:COD、SS浓度等,与总氮、氨氮和总磷的浓度之间也无线性关系存在;农村生产污水的电导率,例如:散户的畜牧养殖污水、家庭酿造污水或农家乐排放污水等的电导率,与总氮、氨氮和总磷的浓度之间也无线性关系存在。甚至于,农村生活污水中的粪尿污水是否经过化粪池处理,也对其电导率与总氮、氨氮和总磷的浓度之间的线性关系造成影响,试验发现,没有经过化粪池处理的污水中的电导率只与氨氮有较弱的线性相关性,与总氮和总磷线性关系不成立。However, other types of sewage do not have the above rules, for example: the electrical conductivity in urban sewage (urban domestic sewage and urban production sewage) does not have a good linear relationship with the concentrations of total nitrogen, ammonia nitrogen and total phosphorus; and Other indicators in rural domestic sewage, such as: COD, SS concentration, etc., also have no linear relationship with the concentration of total nitrogen, ammonia nitrogen and total phosphorus; There is also no linear relationship between the electrical conductivity of brewing sewage or farmhouse discharge sewage and the concentrations of total nitrogen, ammonia nitrogen and total phosphorus. Even whether the fecal and urine sewage in rural domestic sewage has been treated by septic tanks also affects the linear relationship between its electrical conductivity and the concentrations of total nitrogen, ammonia nitrogen and total phosphorus. The conductivity in the wastewater has only a weak linear correlation with ammonia nitrogen, and the linear relationship with total nitrogen and total phosphorus does not hold.
本发明所述的农村生活污水处理设施由进水调节池和污水处理装置两部分组成;提升泵位于进水调节池内,农村生活污水处理设施的进水是指进水调节池(或调节池)内的污水,农村生活污水处理设施的出水是指污水处理装置处理后的出水。本发明所述的污水处理装置所能承受的污染物容积负荷或污染物表面负荷是指各类污水处理装置在安装时就已确定的单位时间内所能承受的总氮、氨氮和总磷的量。The rural domestic sewage treatment facility of the present invention is composed of two parts: an inflow regulating tank and a sewage treatment device; the lift pump is located in the influent regulating tank, and the influent of the rural domestic sewage treatment facility refers to the influent regulating tank (or the regulating tank) The effluent of rural domestic sewage treatment facilities refers to the effluent treated by the sewage treatment device. The pollutant volume load or pollutant surface load that the sewage treatment device of the present invention can bear refers to the total nitrogen, ammonia nitrogen and total phosphorus that various sewage treatment devices can bear in a unit time that has been determined at the time of installation. quantity.
由于电导率值与水温有关,本领域普遍以水温20℃时的电导率值作为参比进行校正,且常规电导率仪一般会自动校正,所以本发明所述的电导率值实际上是经过校正后的水温20℃时的电导率值。Since the conductivity value is related to the water temperature, the conductivity value at a water temperature of 20°C is generally used as a reference for calibration in this field, and conventional conductivity meters are generally automatically calibrated, so the conductivity value described in the present invention is actually corrected. The conductivity value when the water temperature is 20°C.
取样时间、次数和方式都会影响电导率与污染物浓度之间线性关系的准确性。作为优选,步骤(1)中,分别在取样当天的早上、中午和晚上取三次水样,以三次水样中污染物浓度和电导率的平均值作为最终取样结果。The time, frequency, and method of sampling can affect the accuracy of the linear relationship between conductivity and contaminant concentration. Preferably, in step (1), three water samples are taken in the morning, noon and evening of the sampling day, and the average value of the pollutant concentration and conductivity in the three water samples is used as the final sampling result.
作为优选,步骤(3)中,所述电导率仪为在线监测电导率仪,电导率仪的探头通过支架固定在调节池的内壁上,距离调节池内壁20-50cm,处于低液位下方0~30cm处,且位于回流管的出口处。As preferably, in the step (3), the conductivity meter is an online monitoring conductivity meter, and the probe of the conductivity meter is fixed on the inner wall of the regulating pond by a bracket, 20-50cm from the inner wall of the regulating pond, below the low liquid level. ~30cm and at the outlet of the return line.
通过支架固定探头可以防止探头随调节池内水流流动而碰撞井壁,造成探头损坏;将探头置于低液位下方0~30cm处,是为了保证电导率仪始终浸没在水体中;而将探头置于回流管的出口处,可实现回流液对探头的不定期自动清洗。Fixing the probe by the bracket can prevent the probe from colliding with the well wall with the flow of water in the adjustment tank, causing the probe to be damaged; the probe is placed 0-30cm below the low liquid level to ensure that the conductivity meter is always immersed in the water body; At the outlet of the return pipe, the irregular automatic cleaning of the probe by the return liquid can be realized.
在调节池内分别设有高液位和低液位,具体值根据实际情况进行设定;通过液位高低来控制提升泵的开关是农村生活污水处理设施的常规调节方法之一,现有调节方法为:当实际液位高于高液位时提升泵启动,开始从调节池抽水到厌氧池或人工湿地中,当实际液位低于低液位时,提升泵关闭,停止抽水。There are high liquid level and low liquid level in the adjustment tank, and the specific value is set according to the actual situation; controlling the switch of the lifting pump through the liquid level is one of the conventional adjustment methods of rural domestic sewage treatment facilities. The existing adjustment method It is: when the actual liquid level is higher than the high liquid level, the lift pump starts, and starts to pump water from the regulating tank to the anaerobic tank or constructed wetland. When the actual liquid level is lower than the low liquid level, the lift pump is turned off and stops pumping.
作为优选,所述探头的外部固定有保护套管。该保护套管为穿孔的PVC管,用于避免调节池中较大杂物与探头的接触碰撞,也避免探头与井壁直接碰撞接触的可能。Preferably, a protective sleeve is fixed on the outside of the probe. The protective sleeve is a perforated PVC pipe, which is used to avoid the contact and collision of large debris in the adjustment tank and the probe, and also to avoid the possibility of direct collision and contact between the probe and the well wall.
电导率与总氮、氨氮和总磷的浓度之间的线性关系与具体农村生活污水的处理工艺无关,所以,理论上,目前本领域可采用的农村生活污水处理设施,例如:A2O、AO、SBR、厌氧-曝气生物滤池和厌氧-人工湿地等,均适用本发明方法。The linear relationship between the electrical conductivity and the concentrations of total nitrogen, ammonia nitrogen and total phosphorus has nothing to do with the specific treatment process of rural domestic sewage. Therefore, theoretically, the rural domestic sewage treatment facilities currently available in this field, such as : AO, SBR, anaerobic-aerated biological filter and anaerobic-constructed wetland, etc., are all applicable to the method of the present invention.
作为优选,步骤(1)中,选择采用相同污水处理装置的农村生活污水处理设施进行统一调节;所述污水处理装置为A2O设施或厌氧-人工湿地设施。Preferably, in step (1), a rural domestic sewage treatment facility using the same sewage treatment device is selected for unified adjustment; the sewage treatment device is an A 2 O facility or an anaerobic-constructed wetland facility.
进一步地,步骤(3)中,将提升泵设置为循环模式,每3~8个小时开启一次提升泵,根据污水处理装置所能承受的污染物容积负荷,计算提升泵开启的时长。Further, in step (3), the lift pump is set to the circulation mode, the lift pump is turned on every 3 to 8 hours, and the duration of the lift pump on is calculated according to the pollutant volume load that the sewage treatment device can bear.
更进一步地,当污水处理装置为A2O设施时,提升泵开启时长的计算公式如下:Further, when the sewage treatment device is an A 2 O facility, the calculation formula for the opening time of the lift pump is as follows:
其中,t为每次提升泵开启的时长单位为h;LTN为A2O设施内TN的容积负荷,LNH3-N为A2O设施内NH3-N的容积负荷,LTP为A2O设施内TP的容积负荷,单位为g/m3d;V有效为A2O设施有效体积,单位为m3;n为每天进水次数,3-8次/d;x为电导率,单位为mS/cm;q为提升泵额定流量,单位为m3/h;a为电导率与污染物浓度之间线性回归方程的斜率;b为电导率与污染物浓度之间线性回归方程的截距。Among them, t is the time when the lift pump is turned on, the unit is h; L TN is the volume load of TN in the A 2 O facility, L NH3-N is the volume load of NH 3 -N in the A 2 O facility, and L TP is A The volumetric load of TP in the 2 O facility, the unit is g/m 3 d; V effective is the effective volume of the A 2 O facility, the unit is m 3 ; n is the number of water inflows per day, 3-8 times/d; x is the electrical conductivity , the unit is mS/cm; q is the rated flow of the lift pump, the unit is m 3 /h; a is the slope of the linear regression equation between conductivity and pollutant concentration; b is the linear regression equation between conductivity and pollutant concentration intercept.
A2O设施的污染物容积负荷一般为:LTN为150-600g/m3d;LNH3-N为80-500g/m3d;LTP为50-200g/m3d。The pollutant volume load of A 2 O facility is generally: L TN is 150-600g/m 3 d; L NH3-N is 80-500g/m 3 d; L TP is 50-200g/m 3 d.
更进一步地,当污水处理装置为厌氧-人工湿地设施时,提升泵开启时长的计算公式如下:Further, when the sewage treatment device is an anaerobic-constructed wetland facility, the calculation formula for the opening time of the lift pump is as follows:
其中,t为每次提升泵开启的时长单位为h;LTN为厌氧-人工湿地设施TN的表面负荷,LNH3-N为厌氧-人工湿地设施NH3-N的表面负荷,LTP为厌氧-人工湿地设施TP的表面负荷,单位为g/m2d;S有效为人工湿地设施的有效面积,单位为m2;n为每天进水次数,4-12次/d;x为电导率,单位为mS/cm;q为提升泵额定流量,单位为m3/h;a为电导率与污染物浓度之间线性回归方程的斜率;b为电导率与污染物浓度之间线性回归方程的截距。Among them, t is the time when the lift pump is turned on each time, the unit is h; L TN is the surface load of the anaerobic-constructed wetland facility TN, L NH3-N is the surface load of the anaerobic-constructed wetland facility NH 3 -N, and L TP is the surface load of the anaerobic-constructed wetland facility TP, in g/m 2 d; S is the effective area of the constructed wetland facility, in m 2 ; n is the number of water inflows per day, 4-12 times/d; x is the electrical conductivity, in mS/cm; q is the rated flow of the lift pump, in m 3 /h; a is the slope of the linear regression equation between electrical conductivity and pollutant concentration; b is the relationship between electrical conductivity and pollutant concentration The intercept of the linear regression equation.
厌氧-人工湿地设施的污染物表面负荷一般为:LTN为5-15g/m2d,LNH3-N为2-10g/m2d,LTP为0.5-5g/m2d。The pollutant surface load of anaerobic-constructed wetland facilities is generally: L TN is 5-15g/m 2 d, L NH3-N is 2-10g/m 2 d, and L TP is 0.5-5g/m 2 d.
进一步地,电导率值为提升泵开启前0~15min的电导率平均值。Further, the electrical conductivity value is the average value of electrical conductivity from 0 to 15 minutes before the lift pump is turned on.
本发明方法中的电导率在线监测仪可通过模拟信号或其他方式信号传输至电控箱,再传输至平台,实现设施进出水电导率的实时在线监测。The conductivity online monitor in the method of the present invention can transmit the signal to the electric control box by analog signal or other means, and then transmit to the platform, so as to realize the real-time online monitoring of the conductivity of the water in and out of the facility.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
(1)本发明通过测定处理设施进水的电导率,来监测和管控农村生活污水处理设施的进水水质,在降低监测成本的情况下,实现了农村生活污水处理设施进水负荷的高效调节。(1) The present invention monitors and controls the influent water quality of the rural domestic sewage treatment facilities by measuring the conductivity of the influent water of the treatment facilities, and realizes the efficient regulation of the influent load of the rural domestic sewage treatment facilities under the condition of reducing the monitoring cost. .
(2)本发明根据电导率的实时数据和水位数据,分别计算进水调节池内总氮、氨氮和总磷的浓度和总量,再根据污水处理装置所能承受的总氮、氨氮和总磷的量,计算提升泵从进水调节池内泵入污水处理装置的污水总量的最小值,进而在已知提升泵单位时间流量的情况下,确定提升泵的开启时长,给现有的农村生活污水处理设施提供了一种新的定量化的进水负荷调节方法。(2) The present invention calculates the concentration and total amount of total nitrogen, ammonia nitrogen and total phosphorus in the water inlet regulating tank respectively according to the real-time data of electrical conductivity and water level data, and then according to the total nitrogen, ammonia nitrogen and total phosphorus that the sewage treatment device can bear Calculate the minimum value of the total amount of sewage pumped into the sewage treatment device by the lift pump from the water inlet adjustment tank, and then determine the ON time of the lift pump when the flow rate per unit time of the lift pump is known, so as to provide the existing rural life Sewage treatment facilities provide a new quantitative influent load regulation method.
附图说明Description of drawings
图1为实施例1和实施例2中87个农村生活污水处理设施进水调节池的电导率与TN浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示TN浓度,单位(mg/L)。Fig. 1 is a graph showing the relationship between the electrical conductivity and TN concentration of the 87 rural domestic sewage treatment facilities in the influent conditioning tanks in Example 1 and Example 2, wherein the abscissa represents the conductivity of sewage, the unit (mS/cm), the vertical axis The coordinates represent the TN concentration in units (mg/L).
图2为实施例1和实施例2中87个农村生活污水处理设施进水调节池的电导率与NH3-N浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示NH3-N浓度,单位(mg/L)。Fig. 2 is a graph showing the relationship between the conductivity and NH 3 -N concentration of the 87 rural domestic sewage treatment facilities in the influent conditioning pools in Example 1 and Example 2, wherein the abscissa represents the conductivity of sewage, the unit (mS/cm ), and the ordinate represents the NH 3 -N concentration, unit (mg/L).
图3为实施例1和实施例2中87个农村生活污水处理设施进水调节池的电导率与TP浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示TP浓度,单位(mg/L)。Figure 3 is a graph showing the relationship between the electrical conductivity and TP concentration of the influent conditioning tanks of 87 rural domestic sewage treatment facilities in Example 1 and Example 2, wherein the abscissa represents the conductivity of sewage, the unit (mS/cm), the The coordinates represent the TP concentration in units (mg/L).
图4为对比例1中采用实施例1方法和对比例1方法的氨氮去除率的结果。FIG. 4 shows the results of ammonia nitrogen removal rates using the method of Example 1 and the method of Comparative Example 1 in Comparative Example 1.
图5为对比例2中采用实施例2方法和对比例2方法的氨氮去除率的结果。FIG. 5 is the result of ammonia nitrogen removal rate using the method of Example 2 and the method of Comparative Example 2 in Comparative Example 2.
图6为对比例3中12个城市污水厂调节池的电导率与TN浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示TN浓度,单位(mg/L)。Figure 6 is a graph showing the relationship between the electrical conductivity and the TN concentration of the 12 urban sewage treatment plants in Comparative Example 3, where the abscissa represents the conductivity of the sewage, in mS/cm, and the ordinate represents the TN concentration, in mg /L).
图7为对比例3中12个城市污水厂调节池的电导率与NH3-N浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示NH3-N浓度,单位(mg/L)。Fig. 7 is a graph showing the relationship between the electrical conductivity and the NH 3 -N concentration of the 12 urban sewage plant conditioning tanks in Comparative Example 3, wherein the abscissa represents the conductivity of the sewage, in mS/cm, and the ordinate represents the NH 3 -N N concentration, unit (mg/L).
图8为对比例3中12个城市污水厂调节池的电导率与TP浓度间的关系图,其中,横坐标表示污水电导率,单位(mS/cm),纵坐标表示TP浓度,单位(mg/L)。Figure 8 is a graph showing the relationship between the electrical conductivity and the TP concentration of the 12 urban sewage plant conditioning tanks in Comparative Example 3, where the abscissa represents the sewage conductivity, in mS/cm, and the ordinate represents the TP concentration, in mg /L).
图9为对比例4中农村生活污水处理设施进水调节池的电导率与COD浓度间的关系图。FIG. 9 is a graph showing the relationship between the conductivity and the COD concentration of the influent conditioning tank of the rural domestic sewage treatment facility in Comparative Example 4. FIG.
图10为对比例5中农村生活污水处理设施进水调节池的电导率与SS浓度间的关系图。FIG. 10 is a graph showing the relationship between the conductivity and the SS concentration of the influent conditioning tank of the rural domestic sewage treatment facility in Comparative Example 5.
图11为对比例6中农村生活污水处理设施进水调节池的电导率与TN浓度间的关系图。FIG. 11 is a graph showing the relationship between the conductivity and the TN concentration of the influent conditioning tank of the rural domestic sewage treatment facility in Comparative Example 6. FIG.
图12为对比例6中农村生活污水处理设施进水调节池的电导率与NH3-N浓度间的关系图。FIG. 12 is a graph showing the relationship between the electrical conductivity and the NH 3 -N concentration of the influent conditioning tank of the rural domestic sewage treatment facility in Comparative Example 6. FIG.
图13为对比例6中农村生活污水处理设施进水调节池的电导率与TP浓度间的关系图。FIG. 13 is a graph showing the relationship between the conductivity of the influent conditioning tank of the rural domestic sewage treatment facility and the TP concentration in Comparative Example 6. FIG.
具体实施方式Detailed ways
下面结合具体实施例对本发明作进一步描述,以下列举的仅是本发明的具体实施例,但本发明的保护范围不仅限于此。The present invention will be further described below in conjunction with specific embodiments, the following are only specific embodiments of the present invention, but the protection scope of the present invention is not limited thereto.
由于电导率与污染物浓度之间的线性关系不受农村生活污水处理设施所采用的工艺类型的影响,所以,实施例1和实施例2中电导率与污染物浓度之间的线性关系图相同。Since the linear relationship between conductivity and pollutant concentration is not affected by the type of process adopted by rural domestic sewage treatment facilities, the linear relationship diagrams between conductivity and pollutant concentration in Example 1 and Example 2 are the same .
实施例1A2O工艺的农村生活污水处理设施Example 1A 2 O Process Rural Domestic Sewage Treatment Facility
一种农村生活污水处理设施的监管方法,包括以下步骤:A monitoring method for rural domestic sewage treatment facilities, comprising the following steps:
(1)在浙江省嘉兴市随机选取87个农村生活污水处理设施,对该87个站点调节池内的农村生活污水进行取样,并检测样品中TN、NH3-N、TP的浓度和电导率;分别在取样当天的早上、中午和晚上取三次水样,以三次水样中污染物浓度和电导率的平均值作为最终取样结果。(1) 87 rural domestic sewage treatment facilities were randomly selected in Jiaxing City, Zhejiang Province, and the rural domestic sewage in the conditioning tanks of the 87 stations was sampled, and the concentrations and conductivity of TN, NH 3 -N and TP in the samples were detected; Three water samples were taken in the morning, noon and evening of the sampling day, and the average value of pollutant concentration and electrical conductivity in the three water samples was taken as the final sampling result.
(2)根据步骤(1)中样品的检测数据,进行线性回归分析和方程拟合,得到电导率与TN、NH3-N、TP的浓度之间的线性关系;(2) according to the detection data of the sample in step (1), carry out linear regression analysis and equation fitting, obtain the linear relationship between the electrical conductivity and the concentration of TN, NH 3 -N, TP;
其中,线性回归方程为:y=ax+b;x为电导率,y为TN、NH3-N或TP;Wherein, the linear regression equation is: y=ax+b; x is conductivity, y is TN, NH 3 -N or TP;
基于电导率x来预测农村生活污水中的污染物浓度y,建立预测模型:Based on the conductivity x to predict the pollutant concentration y in rural domestic sewage, a prediction model is established:
TN:y=0.0723x-31.228(R2=0.7745);TN: y=0.0723x-31.228 (R2= 0.7745 );
NH3-N:y=0.0712x-34.516(R2=0.785);NH3-N: y=0.0712x-34.516 (R 2 =0.785);
TP:y=0.0059x-2.6007(R2=0.7468);TP: y=0.0059x-2.6007 (R 2 =0.7468);
模型的相关系数(R2)较高,表明电导率与TN、NH3-N、TP浓度的相关性较好,模型的符合程度较高。The correlation coefficient (R 2 ) of the model is high, indicating that the electrical conductivity has a good correlation with the concentrations of TN, NH 3 -N and TP, and the model is in good agreement.
(3)以一个有效容积为15m3的A2O工艺处理设施为例,污水收集在调节池中,通过提升泵提升依次流经厌氧池、缺氧池、好氧池得到处理。上述设施的总氮、氨氮、总磷容积负荷分别为180、100、50g/m3d,提升泵标准流量为3t/h,提升泵每隔4h开启一次,每天开启6次。(3) Taking an A 2 O process treatment facility with an effective volume of 15m 3 as an example, the sewage is collected in a regulating tank, and is lifted by a lift pump and flows through an anaerobic tank, an anoxic tank, and an aerobic tank for treatment. The volume loads of total nitrogen, ammonia nitrogen and total phosphorus of the above facilities are 180, 100, and 50 g/m 3 d, respectively. The standard flow rate of the lift pump is 3 t/h. The lift pump is turned on every 4 hours and 6 times a day.
在各农村生活污水处理设施的调节池内安装在线监测电导率仪,电导率仪的探头通过支架固定在调节池的内壁上,距离调节池内壁35cm,处于低液位下方15cm处,且位于回流管的出口处。探头的外部设有保护套管,保护套管为穿孔的PVC管。An online monitoring conductivity meter is installed in the adjustment tank of each rural domestic sewage treatment facility. The probe of the conductivity meter is fixed on the inner wall of the adjustment tank through a bracket, 35cm away from the inner wall of the adjustment tank, 15cm below the low liquid level, and located in the return pipe the exit. The outside of the probe is provided with a protective sleeve, which is a perforated PVC pipe.
测定电导率值(提升泵开启前15min的平均值),根据获取的电导率值,控制调节池内提升泵每次开启时间;Measure the conductivity value (the average value of 15 minutes before the lift pump is turned on), and control and adjust the time when the lift pump is turned on in the pool according to the obtained conductivity value;
某天第1-6次,所测得的电导率平均值依次为891、1230、1005、985、1206、1065mS/cm。From the 1st to the 6th time on a certain day, the average value of the measured conductivity is 891, 1230, 1005, 985, 1206, 1065 mS/cm.
提升泵开启时长的计算公式如下:The formula for calculating the opening time of the lift pump is as follows:
其中,t为每次提升泵开启的时长单位为h;LTN为A2O设施内TN的容积负荷,LNH3-N为A2O设施内NH3-N的容积负荷,LTP为A2O设施内TP的容积负荷,单位为g/m3d;V有效为A2O设施有效体积,单位为m3;n为每天进水次数,单位为次/d;x为电导率,单位为mS/cm;q为提升泵额定流量,单位为m3/h。Among them, t is the time when the lift pump is turned on, the unit is h; L TN is the volume load of TN in the A 2 O facility, L NH3-N is the volume load of NH 3 -N in the A 2 O facility, and L TP is A The volumetric load of TP in the 2 O facility, in g/m 3 d; V effective is the effective volume of the A 2 O facility, in m 3 ; n is the number of water inflows per day, in times/d; x is the electrical conductivity, The unit is mS/cm; q is the rated flow of the lift pump, and the unit is m 3 /h.
按照A2O设施公式计算得到Calculated according to the A 2 O facility formula
对比例1Comparative Example 1
以2组有效容积为15m3且运转状况类似的A2O设施为例,1组采用实施例1监管方法进行运转,另一组采用常规方法进行运转(即:当液位高于高水位时,一次性将调节池中的污水提升进入设施厌氧池,直至液位低于低水位)。Take two groups of A 2 O facilities with an effective volume of 15m 3 and similar operating conditions as examples, one group operates with the supervision method of Example 1, and the other group operates with the conventional method (ie: when the liquid level is higher than the high water level) , lift the sewage in the adjustment tank into the anaerobic tank of the facility at one time, until the liquid level is lower than the low water level).
每日8时,14时,20时对设施调节池中污水和出水井中的出水取样3次,测试氨氮浓度,持续10天,计算氨氮的每日平均值去除率。At 8:00, 14:00, and 20:00 every day, the sewage in the adjustment tank of the facility and the effluent from the outlet well were sampled 3 times to test the ammonia nitrogen concentration for 10 days, and the daily average removal rate of ammonia nitrogen was calculated.
结果如图4所示:采用实施例1监管方法运转的设施的氨氮去除率明显高于常规设施,且去除效果更为稳定。The results are shown in Figure 4: the ammonia nitrogen removal rate of the facility operated by the supervision method of Example 1 was significantly higher than that of the conventional facility, and the removal effect was more stable.
实施例2厌氧-人工湿地工艺的农村生活污水处理设施Example 2 Rural Domestic Sewage Treatment Facility of Anaerobic-Constructed Wetland Process
(1)在浙江省嘉兴市随机选取87个农村生活污水处理设施,对该87个站点调节池内的农村生活污水进行取样,并检测样品中TN、NH3-N、TP的浓度和电导率;分别在取样当天的早上、中午和晚上取三次水样,以三次水样中污染物浓度和电导率的平均值作为最终取样结果。(1) 87 rural domestic sewage treatment facilities were randomly selected in Jiaxing City, Zhejiang Province, and the rural domestic sewage in the conditioning tanks of the 87 stations was sampled, and the concentrations and conductivity of TN, NH 3 -N and TP in the samples were detected; Three water samples were taken in the morning, noon and evening of the sampling day, and the average value of pollutant concentration and electrical conductivity in the three water samples was taken as the final sampling result.
(2)根据步骤(1)中样品的检测数据,进行线性回归分析和方程拟合,得到电导率与TN、NH3-N、TP的浓度之间的线性关系;(2) according to the detection data of the sample in step (1), carry out linear regression analysis and equation fitting, obtain the linear relationship between the electrical conductivity and the concentration of TN, NH 3 -N, TP;
其中,线性回归方程为:y=ax+b;x为电导率,y为TN、NH3-N或TP;Wherein, the linear regression equation is: y=ax+b; x is conductivity, y is TN, NH 3 -N or TP;
基于电导率x来预测农村生活污水中的污染物浓度y,建立预测模型:Based on the conductivity x to predict the pollutant concentration y in rural domestic sewage, a prediction model is established:
TN:y=0.0723x-31.228(R2=0.7745);TN: y=0.0723x-31.228 (R2= 0.7745 );
NH3-N:y=0.0712x-34.516(R2=0.7985);NH3-N: y=0.0712x-34.516 (R2= 0.7985 );
TP:y=0.0059x-2.6007(R2=0.7468);TP: y=0.0059x-2.6007 (R 2 =0.7468);
模型的相关系数(R2)较高,表明电导率与TN、NH3-N、TP浓度的相关性较好,模型的符合程度较高。The correlation coefficient (R 2 ) of the model is high, indicating that the electrical conductivity has a good correlation with the concentrations of TN, NH 3 -N and TP, and the model is in good agreement.
(3)以一个有效面积为40m2的厌氧+垂直流人工湿地处理设施为例,该设施主要有调节池和人工湿地构成,主要设备为提升泵,调节池中收集的污水通过提升泵流入人工湿地得到处理。上述设施的提升泵标准流量为3t/h。上述设施的总氮、氨氮、总磷表面负荷分别为10、8、2g/m2d,提升泵标准流量为3t/h,提升泵每隔4h开启一次,每天开启6次。( 3 ) Take an anaerobic + vertical flow constructed wetland treatment facility with an effective area of 40m2 as an example. The facility is mainly composed of a regulating pool and a constructed wetland. The main equipment is a lift pump. The sewage collected in the regulating pool flows into the lift pump through the lift pump. Constructed wetlands are treated. The standard flow rate of the lift pump of the above facilities is 3t/h. The surface loads of total nitrogen, ammonia nitrogen and total phosphorus in the above facilities are 10, 8 and 2 g/m 2 d, respectively. The standard flow rate of the lift pump is 3 t/h. The lift pump is turned on every 4 hours and 6 times a day.
在该农村生活污水处理设施的调节池内安装在线监测电导率仪,电导率仪的探头通过支架固定在调节池的内壁上,距离调节池内壁35cm,处于低液位下方15cm处,且位于回流管的出口处。探头的外部设有保护套管,保护套管为穿孔的PVC管。An online monitoring conductivity meter is installed in the adjustment tank of the rural domestic sewage treatment facility. The probe of the conductivity meter is fixed on the inner wall of the adjustment tank through a bracket, 35cm away from the inner wall of the adjustment tank, 15cm below the low liquid level, and located in the return pipe the exit. The outside of the probe is provided with a protective sleeve, which is a perforated PVC pipe.
测定电导率值(提升泵开启前15min的平均值),根据获取的电导率值,控制调节池内提升泵每次开启时间;Measure the conductivity value (the average value of 15 minutes before the lift pump is turned on), and control and adjust the time when the lift pump is turned on in the pool according to the obtained conductivity value;
某天第1-6次,所测得的电导率值依次为1056、1125、975、859、1352、1248mS/cm。From the 1st to the 6th time on a certain day, the measured conductivity values were 1056, 1125, 975, 859, 1352, and 1248 mS/cm.
当污水处理装置为厌氧-人工湿地设施时,提升泵开启时长的计算公式如下:When the sewage treatment device is an anaerobic-constructed wetland facility, the calculation formula for the opening time of the lift pump is as follows:
其中,t为每次提升泵开启的时长单位为h;LTN为人工湿地设施TN的表面负荷,LNH3-N为污水处理装置内NH3-N的表面负荷,LTP为人工湿地设施内TP的表面负荷,单位为g/m2d;S有效为人工湿地设施的有效面积,单位为m2;n为每天进水次数,单位为次/d;x为电导率,单位为mS/cm;q为提升泵额定流量,单位为m3/h。Among them, t is the time when the lift pump is turned on each time, and the unit is h; LTN is the surface load of the constructed wetland facility TN , LNH3 -N is the surface load of NH3-N in the sewage treatment device, and LTP is the constructed wetland facility. Surface load of TP, the unit is g/m 2 d; S effective is the effective area of the constructed wetland facility, the unit is m 2 ; n is the number of water inflows per day, the unit is times/d; x is the electrical conductivity, the unit is mS/ cm; q is the rated flow of the lift pump, in m 3 /h.
按照厌氧+垂直流人工湿地公式计算得到Calculated according to the formula of anaerobic + vertical flow constructed wetland
对比例2Comparative Example 2
以2组有效面积为40m2的且运转状况类似的人工湿地设施为例,1组采用实施例2监管方法进行运转,另一组采用常规方法进行运转(当液位高于高水位时,一次性将调节池中的污水提升进入设施厌氧池,直到液位低于低水位)。Taking 2 groups of constructed wetland facilities with an effective area of 40m2 and similar operating conditions as examples, 1 group is operated by the supervision method of Example 2, and the other group is operated by the conventional method (when the liquid level is higher than the high water level, once The sewage in the conditioning tank is lifted into the anaerobic tank of the facility until the liquid level is lower than the low water level).
每日8时,14时,20时对设施调节池中污水和出水井中的出水取样3次,测试氨氮浓度,持续10天,计算氨氮的每日平均值去除率。At 8:00, 14:00, and 20:00 every day, the sewage in the adjustment tank of the facility and the effluent from the outlet well were sampled 3 times to test the ammonia nitrogen concentration for 10 days, and the daily average removal rate of ammonia nitrogen was calculated.
结果如图5所示:采用实施例2监管方法运转的设施的氨氮去除率明显高于常规设施,且去除效果更为稳定。The results are shown in Figure 5: the ammonia nitrogen removal rate of the facility operated by the supervision method in Example 2 was significantly higher than that of the conventional facility, and the removal effect was more stable.
对比例3Comparative Example 3
对12个城市污水处理厂进水数据调研,同样在调节池中取样,取样方式与实施例1相同,然后测试其总氮、氨氮、总磷以及电导率的数值。Investigate the influent data of 12 urban sewage treatment plants, and also sample in the adjustment tank, the sampling method is the same as that of Example 1, and then test the values of total nitrogen, ammonia nitrogen, total phosphorus and electrical conductivity.
结果显示(图6~8):电导率与总氮、氨氮、总磷浓度的关系均没有呈现出与农村生活污水类似的线性相关性。The results showed (Figures 6-8): the relationship between electrical conductivity and the concentrations of total nitrogen, ammonia nitrogen, and total phosphorus did not show a linear correlation similar to that of rural domestic sewage.
对比例4Comparative Example 4
本对比例测定了农村生活污水中COD的浓度,取样方法与实施例1相同,分析数据发现(图9):农村生活污水中COD浓度与电导率线性关系不好:线性相关系数R2只有0.259。In this comparative example, the concentration of COD in rural domestic sewage was measured, and the sampling method was the same as that of Example 1. The analysis data found that (Figure 9): the linear relationship between COD concentration and electrical conductivity in rural domestic sewage is not good: the linear correlation coefficient R 2 is only 0.259 .
对比例5Comparative Example 5
本对比例测定了农村生活污水中SS的浓度,取样方法与实施例1相同,分析数据发现(图10):农村生活污水中SS浓度与电导率线性关系不好:线性相关系数R2只有0.0007。In this comparative example, the concentration of SS in rural domestic sewage was measured, and the sampling method was the same as that of Example 1. The analysis data found that (Fig. 10): the linear relationship between SS concentration and electrical conductivity in rural domestic sewage is not good: the linear correlation coefficient R 2 is only 0.0007 .
对比例6Comparative Example 6
在浙江省嘉兴市随机选取30个农村生活污水处理设施,该农村生活污水处理设施的进水来自于三股污水,分别是:粪尿污水(未经化粪池处理的)、厨房污水和洗衣污水。同样在调节池中取样,取样方式与实施例1相同,然后测试其总氮、氨氮、总磷以及电导率的数值。结果显示(图11~13):电导率与总氮、氨氮、总磷浓度的关系均没有呈现出实施例1与实施例2中农村生活污水那么好的线性相关性。30 rural domestic sewage treatment facilities were randomly selected in Jiaxing City, Zhejiang Province. The influent of this rural domestic sewage treatment facility comes from three streams of sewage, namely: fecal and urine sewage (without septic tank treatment), kitchen sewage and laundry sewage . Sampling was also taken in the conditioning tank, and the sampling method was the same as that of Example 1, and then the values of total nitrogen, ammonia nitrogen, total phosphorus and electrical conductivity were tested. The results show (Figures 11 to 13): the relationship between the electrical conductivity and the concentrations of total nitrogen, ammonia nitrogen and total phosphorus does not show a linear correlation as good as the rural domestic sewage in Example 1 and Example 2.
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