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CN109467878A - A kind of lightweight multiple-effect expansion fire-proof sealing material - Google Patents

A kind of lightweight multiple-effect expansion fire-proof sealing material Download PDF

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Publication number
CN109467878A
CN109467878A CN201811057483.3A CN201811057483A CN109467878A CN 109467878 A CN109467878 A CN 109467878A CN 201811057483 A CN201811057483 A CN 201811057483A CN 109467878 A CN109467878 A CN 109467878A
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parts
fire
sealing material
proof sealing
effect expansion
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CN201811057483.3A
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CN109467878B (en
Inventor
施兆武
赵连元
王勤丰
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Taicang Jin Mao Novel Material Science And Technology Ltd
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Taicang Jin Mao Novel Material Science And Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06Waxes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Sealing Material Composition (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention discloses a kind of lightweight multiple-effect expansion fire-proof sealing materials, including following parts by weight of component: 100 parts of epoxy resin, 20~30 parts of expanded graphite, 15~20 parts of IFR fire retardant, 8~10 parts of graphite oxide, 20~30 parts of adhesive of fire prevention, 30~50 parts of reinforcing fiber, 10~20 parts of hollow glass micropearl, 8~15 parts of function additive, 2~3 parts of zinc stearate, 10~15 parts of paraffin oil, 10~20 parts of promotion system of foaming and 5~10 parts of curing agent.For the present invention by the formula design of physical expansion flame-retardant system, IFR flame-retardant system, fire prevention adhesive, glass fibre and hollow glass microbead, the effect of on the one hand assigning material triple fire prevention and excellent expansion character can effectively improve fire protecting performance;Another aspect carbonation rate is high, and mechanical strength is good, and entire sealing material can be effectively prevent to occur situations such as broken, dusting in fire process, improves to the anti-performance of the resistance of flue gas and water.

Description

A kind of lightweight multiple-effect expansion fire-proof sealing material
Technical field
The present invention relates to ship waterproof fireproofing technical fields, more particularly to a kind of lightweight multiple-effect expansion fire-proof sealing material Material.
Background technique
It needs that through hole is arranged on the deck of ship or bulkhead, and adds pipeline in through hole and be used in different regions Between transmit water, electricity, gas and signal etc..When fire occurs, fire and cigarette can be fast between different zones through device by pipeline Speed diffusion is a big threat for expensive commanding apparatus, cable data processing equipment and ship navigation, not only destroys ship The maneuvering performance of oceangoing ship, and a large amount of toxic smog and toxic gas are generated in cable burning process, easily cause great personnel Safety hazard.
In ship in device, sealant will have both waterproof and fireproof double effects, to keep ship to have watertight With the dual integrality of fireproof.This is for guaranteeing that ship insubmersibility and fire savety are of great importance.But spot ship is used anti- There are the following problems when fire occurs for fiery sealant: although sealant itself does not burn, and self-extinguishing without fire, but still ash can occur Change, so that colloid is broken, dusting, lose plugging action, leads to the safety accidents such as fire and smoke spread and the heavy water of ship.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of lightweight multiple-effect expansion fire-proof sealing materials, are able to solve Drawbacks described above existing for spot ship fireproof seal gum.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of lightweight multiple-effect intumescent is provided Fireproof sealing material, including following parts by weight of component: 100 parts of epoxy resin, 20~30 parts of expanded graphite, IFR fire retardant 15~ 20 parts, 8~10 parts of graphite oxide, fire prevention 20~30 parts of adhesive, 30~50 parts of reinforcing fiber, hollow glass micropearl 10~20 Part, 8~15 parts of function additive, 2~3 parts of zinc stearate, 10~15 parts of paraffin oil, 10~20 parts of promotion system of foaming and curing agent 5~10 parts.
In a preferred embodiment of the present invention, the IFR fire retardant includes phosphate, polyphosphoric acid amine and pentaerythrite.
In a preferred embodiment of the present invention, the weight ratio of the phosphate, polyphosphoric acid amine and pentaerythrite is 3~5: 2~3:1~2.
In a preferred embodiment of the present invention, the fire prevention adhesive be α, β-hydroxyl-terminated injecting two methyl siloxane, at Porcelain agent, ceramic powder and magnesium hydroxide mixture.
In a preferred embodiment of the present invention, the fire prevention adhesive be α, β-hydroxyl-terminated injecting two methyl siloxane, at The mixed weight of porcelain agent, ceramic powder and magnesium hydroxide is than for 5~10:0.5~1:2~3:1~2 mixture.
In a preferred embodiment of the present invention, the function additive includes smoking agent and hydrophober.
In a preferred embodiment of the present invention, the reinforcing fiber is glass fibre.
In a preferred embodiment of the present invention, the foaming promotion system includes that epoxy resin foaming agent and foaming promote Agent.
In order to solve the above technical problems, another technical solution used in the present invention is: providing a kind of lightweight multiple-effect expansion The preparation method of type fireproof sealing material, includes the following steps:
(1) it prepares physics Intumescent Retardant System: according to formula ratio, expanded graphite being mixed with the graphite oxide of half parts by weight It is even, it is spare;
(2) it prepares IFR flame-retardant system: according to formula ratio, IFR fire retardant being mixed with the graphite oxide of remaining half parts by weight It is even, it is spare;
(3) preparation fire prevention adhesive: first being uniformly mixed at porcelain agent, ceramic powder and magnesium hydroxide by formula ratio obtains ceramic powder, Then with the α of formula ratio, β-hydroxyl-terminated injecting two methyl siloxane is uniformly mixed, obtains fire prevention adhesive;
(4) material mix: press formula ratio, by epoxy resin, reinforcing fiber, hollow glass micropearl, function additive, zinc stearate, The IFR flame-retardant system mixing prepared in paraffin oil, foaming promotion system and step (2), and stirred evenly with blender;
(5) finished product: by the fire prevention adhesive prepared in the physical expansion flame-retardant system prepared in step (1), step (3), solidification Agent is added in the mixed material of step (4), is uniformly mixed, and solidify, is obtained the lightweight multiple-effect expansion fire-proof sealing material Material.
The beneficial effects of the present invention are: a kind of lightweight multiple-effect expansion fire-proof sealing material of the present invention, has the advantages that It is designed by the formula of physical expansion flame-retardant system, IFR flame-retardant system, fire prevention adhesive, glass fibre and hollow glass microbead, On the one hand the effect of assigning material triple fire prevention and excellent expansion character, can effectively improve fire protecting performance;On the other hand it is carbonized Rate is high, and mechanical strength is good, and entire sealing material can be effectively prevent to occur situations such as broken, dusting in fire process, improves To the anti-performance of the resistance of flue gas and water.
Specific embodiment
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
The embodiment of the present invention includes:
Embodiment 1
Present invention discloses a kind of lightweight multiple-effect expansion fire-proof sealing materials, including following parts by weight of component: epoxy resin 100 Part, 20 parts of expanded graphite, 15 parts of IFR fire retardant, 8 parts of graphite oxide, fire prevention 20 parts of adhesive, 30 parts of reinforcing fiber, hollow glass 10 parts of glass microballon, 8 parts of function additive, 2 parts of zinc stearate, 10 parts of paraffin oil, 100 parts of promotion system of foaming and 5 parts of curing agent.
Wherein, the IFR fire retardant includes phosphate, polyphosphoric acid amine and the pentaerythrite that weight ratio is 3:2:1.
The fire prevention adhesive is α that weight ratio is 5:0.5:2:1, β-hydroxyl-terminated injecting two methyl siloxane, at porcelain agent, pottery The mixture of porcelain powder and magnesium hydroxide.
The function additive includes the smoking agent and hydrophober that weight ratio is 1:2.
The reinforcing fiber is glass fibre.
The foaming promotion system includes epoxy resin foaming agent and foamed promoter.Epoxy resin foaming agent herein and Foamed promoter be it is commonly used in the art, details are not described herein again.
The preparation method of above-mentioned lightweight multiple-effect expansion fire-proof sealing material, includes the following steps:
(1) it prepares physics Intumescent Retardant System: according to formula ratio, expanded graphite being mixed with the graphite oxide of half parts by weight It is even, it is spare;Wherein graphite oxide is carbon forming agent, can effectively prevent being ashed;
(2) it prepares IFR flame-retardant system: according to formula ratio, IFR fire retardant being mixed with the graphite oxide of remaining half parts by weight It is even, it is spare;Wherein graphite oxide is carbon forming agent, can effectively prevent being ashed;
(3) preparation fire prevention adhesive: first being uniformly mixed at porcelain agent, ceramic powder and magnesium hydroxide by formula ratio obtains ceramic powder, Then with the α of formula ratio, β-hydroxyl-terminated injecting two methyl siloxane is uniformly mixed, obtains fire prevention adhesive;
(4) material mix: press formula ratio, by epoxy resin, reinforcing fiber, hollow glass micropearl, function additive, zinc stearate, The IFR flame-retardant system mixing prepared in paraffin oil, foaming promotion system and step (2), and stirred evenly with blender;
(5) finished product: by the fire prevention adhesive prepared in the physical expansion flame-retardant system prepared in step (1), step (3), solidification Agent is added in the mixed material of step (4), is uniformly mixed, and solidify, is obtained the lightweight multiple-effect expansion fire-proof sealing material Material.
Embodiment 2
The difference from embodiment 1 is that lightweight multiple-effect expansion fire-proof sealing material, including following parts by weight of component: asphalt mixtures modified by epoxy resin 100 parts of rouge, 30 parts of expanded graphite, 20 parts of IFR fire retardant, 10 parts of graphite oxide, fire prevention 30 parts of adhesive, 50 parts of reinforcing fiber, 20 parts of hollow glass micropearl, 15 parts of function additive, 3 parts of zinc stearate, 15 parts of paraffin oil, 20 parts of promotion system of foaming and curing agent 10 parts.
Wherein, the IFR fire retardant includes phosphate, polyphosphoric acid amine and the pentaerythrite that weight ratio is 5:3:2.
The fire prevention adhesive is α that weight ratio is 10:1:3:2, β-hydroxyl-terminated injecting two methyl siloxane, at porcelain agent, pottery The mixture of porcelain powder and magnesium hydroxide.
The function additive includes the smoking agent and hydrophober that weight ratio is 1:3.
The fire retardant mechanism of lightweight multiple-effect expansion fire-proof sealing material of the invention are as follows: in the case of fire, physics is fire-retardant System elder generation expanded by heating forms the first expandable flame retardant carbon-coating;As the temperature rises, the acid source in IFR flame-retardant system releases Esterification then occurs for inorganic acid, and expansion forms the second expandable flame retardant carbon-coating rapidly in the presence of carbon source and nitrogen source;? It is above-mentioned it is fire-retardant during, with the raising of environment temperature, the promotion system that foams is made epoxy-resin systems foaming and intumescing by heat foamable, On the one hand the environment temperature where fireproof sealing material can be effectively reduced, help to inhibit burning, it is on the other hand, swollen first Under the triple role of swollen fire-retardant carbon-coating, the second expandable flame retardant carbon-coating and epoxy-resin systems foaming and intumescing, so that fire proof seal material Expect that rapid Expansion sealing pipeline through the pore of pipeline in device, realizes the effect of preventing fire and smoke spread and blocking water.
Lightweight multiple-effect expansion fire-proof sealing material of the invention, has the advantages that
1, by the design of physical expansion flame-retardant system, IFR flame-retardant system and adhesive of preventing fires, the triple fireproof function of material are assigned Effect, effectively improves fire protecting performance;
2, pass through the triple role of the first expandable flame retardant carbon-coating, the second expandable flame retardant carbon-coating and epoxy-resin systems foaming and intumescing Under, so that pore of the rapid Expansion sealing pipeline of fireproof sealing material through pipeline in device, realizes and prevents fire and smoke spread and resistance The effect of water, and can reduce environment temperature;
3, by the use of graphite oxide, glass fibre and hollow glass microbead, on the one hand promote to prevent from being ashed at carbon, it is another Aspect improves the mechanical strength of fireproof sealing material entirety, and entire sealing material can be effectively prevent to occur in fire process It situations such as broken, dusting, improves to the anti-performance of the resistance of flue gas and water.
Lightweight multiple-effect expansion fire-proof sealing material of the invention, has the function of excellent fire resisting, back-fire relief and blocks water, After bonfire test in 1 hour, it is still resistant to the hydraulic pressure (relative to 10 meters of deep water pressures) of 0.1MPa, can effectively ensure that the cabin that catches fire Pipeline does not interfere with the cabin in next door through department.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of lightweight multiple-effect expansion fire-proof sealing material, which is characterized in that including following parts by weight of component: epoxy resin 100 parts, 20~30 parts of expanded graphite, 15~20 parts of IFR fire retardant, 8~10 parts of graphite oxide, fire prevention 20~30 parts of adhesive, 30~50 parts of reinforcing fiber, 10~20 parts of hollow glass micropearl, 8~15 parts of function additive, 2~3 parts of zinc stearate, paraffin oil 10 ~15 parts, 10~20 parts of promotion system of foaming and 5~10 parts of curing agent.
2. lightweight multiple-effect expansion fire-proof sealing material according to claim 1, which is characterized in that the IFR fire retardant Including phosphate, polyphosphoric acid amine and pentaerythrite.
3. lightweight multiple-effect expansion fire-proof sealing material according to claim 2, which is characterized in that the phosphate gathers The weight ratio of phosphamide and pentaerythrite is 3~5:2~3:1~2.
4. lightweight multiple-effect expansion fire-proof sealing material according to claim 2, which is characterized in that the fire prevention adhesive For α, β-hydroxyl-terminated injecting two methyl siloxane, at the mixture of porcelain agent, ceramic powder and magnesium hydroxide.
5. lightweight multiple-effect expansion fire-proof sealing material according to claim 4, which is characterized in that the fire prevention adhesive At the mixed weight ratio of porcelain agent, ceramic powder and magnesium hydroxide it is β-hydroxyl-terminated injecting two methyl siloxane, 5~10:0.5~1 for α: The mixture of 2~3:1~2.
6. lightweight multiple-effect expansion fire-proof sealing material according to claim 1, which is characterized in that the function additive packet Include smoking agent and hydrophober.
7. lightweight multiple-effect expansion fire-proof sealing material according to claim 6, which is characterized in that the smoking agent and hate The weight ratio of aqua is 1:2~3.
8. lightweight multiple-effect expansion fire-proof sealing material according to claim 1, which is characterized in that the reinforcing fiber is Glass fibre.
9. lightweight multiple-effect expansion fire-proof sealing material according to claim 1, which is characterized in that the foaming promotes body System includes epoxy resin foaming agent and foamed promoter.
10. a kind of preparation method of lightweight multiple-effect expansion fire-proof sealing material, which comprises the steps of:
(1) it prepares physics Intumescent Retardant System: according to formula ratio, expanded graphite being mixed with the graphite oxide of half parts by weight It is even, it is spare;
(2) it prepares IFR flame-retardant system: according to formula ratio, IFR fire retardant being mixed with the graphite oxide of remaining half parts by weight It is even, it is spare;
(3) preparation fire prevention adhesive: first being uniformly mixed at porcelain agent, ceramic powder and magnesium hydroxide by formula ratio obtains ceramic powder, Then with the α of formula ratio, β-hydroxyl-terminated injecting two methyl siloxane is uniformly mixed, obtains fire prevention adhesive;
(4) material mix: press formula ratio, by epoxy resin, reinforcing fiber, hollow glass micropearl, function additive, zinc stearate, The IFR flame-retardant system mixing prepared in paraffin oil, foaming promotion system and step (2), and stirred evenly with blender;
(5) finished product: by the fire prevention adhesive prepared in the physical expansion flame-retardant system prepared in step (1), step (3), solidification Agent is added in the mixed material of step (4), is uniformly mixed, and solidify, is obtained the lightweight multiple-effect expansion fire-proof sealing material Material.
CN201811057483.3A 2018-09-11 2018-09-11 Light multi-effect expansion type fireproof sealing material Active CN109467878B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113024219A (en) * 2019-12-25 2021-06-25 中国石油化工股份有限公司 Fireproof plugging material for rapid plugging, preparation method and use method
CN115893957A (en) * 2023-01-06 2023-04-04 太仓市金锚新材料科技有限公司 High-stability expansion plugging material and preparation process thereof
GB2616954A (en) * 2022-01-28 2023-09-27 Meggitt Aerospace Ltd Improved fire seals and methods of making same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0819411A (en) * 1994-07-06 1996-01-23 Tomosaburou Tsunoda Handle of umbrella having finger-pressure treatment function
CN1876740A (en) * 2006-07-12 2006-12-13 海洋化工研究院 Solvent-free expansion type fire-proof epoxy coating and its preparation method
CN102731931A (en) * 2012-06-18 2012-10-17 成都新兴富皇高分子材料科技有限公司 Fire-preventing intumescent sealing material and preparation method thereof
CN106967264A (en) * 2017-05-20 2017-07-21 尹书祥 A kind of fire-proof expansion seal strip and preparation method thereof
CN108203525A (en) * 2018-01-02 2018-06-26 佛山市南海崇泰防火材料有限公司 A kind of inflatable fire resistant flexible material and its application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0819411A (en) * 1994-07-06 1996-01-23 Tomosaburou Tsunoda Handle of umbrella having finger-pressure treatment function
CN1876740A (en) * 2006-07-12 2006-12-13 海洋化工研究院 Solvent-free expansion type fire-proof epoxy coating and its preparation method
CN102731931A (en) * 2012-06-18 2012-10-17 成都新兴富皇高分子材料科技有限公司 Fire-preventing intumescent sealing material and preparation method thereof
CN106967264A (en) * 2017-05-20 2017-07-21 尹书祥 A kind of fire-proof expansion seal strip and preparation method thereof
CN108203525A (en) * 2018-01-02 2018-06-26 佛山市南海崇泰防火材料有限公司 A kind of inflatable fire resistant flexible material and its application

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113024219A (en) * 2019-12-25 2021-06-25 中国石油化工股份有限公司 Fireproof plugging material for rapid plugging, preparation method and use method
GB2616954A (en) * 2022-01-28 2023-09-27 Meggitt Aerospace Ltd Improved fire seals and methods of making same
CN115893957A (en) * 2023-01-06 2023-04-04 太仓市金锚新材料科技有限公司 High-stability expansion plugging material and preparation process thereof

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Denomination of invention: A kind of light and multi effect intumescent fireproof sealing material

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