CN109456718A - A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof - Google Patents
A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof Download PDFInfo
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- CN109456718A CN109456718A CN201811310113.6A CN201811310113A CN109456718A CN 109456718 A CN109456718 A CN 109456718A CN 201811310113 A CN201811310113 A CN 201811310113A CN 109456718 A CN109456718 A CN 109456718A
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- Prior art keywords
- feel
- washing
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- adhesive
- ales
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
- C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of high fastness, washing and the superior adhesives of feel and preparation method thereof, the component material of the chemical rubber metal fever vulcanizing adhesive includes: the composition such as butyl acrylate, styrene, acrylonitrile, acrylic acid, preparation method includes pre-emulsification, reaction, post-treating and other steps, the present invention uses acrylic amide modified crosslinking agent as function monomer, it is crosslinked mutually in polymerization process, final adhesive feel is excellent, cheap, and meet International Environmental Protection standard, it is more conducive to subsequent popularization and use.
Description
Technical field
The present invention relates to adhesive and preparation method thereof technical field, specially a kind of high fastness, washing and feel are superior
Adhesive and preparation method thereof.
Background technique
Low-temperature adhesive is usually used in pigment printing industry, and it is to embody its performance that adhesive understands its feel after drying of drawing a design
An important indicator, and the feel, fastness of many adhesives and washing at present is all less desirable, limits it and is widely used.
Summary of the invention
The purpose of the present invention is to provide a kind of high fastness, washing and the superior adhesive of feel and preparation method thereof, with
The feel, fastness and washing for solving most adhesive mentioned above in the background art are all less desirable, and limit it makes extensively
The problem of using.
To achieve the above object, the invention provides the following technical scheme: a kind of high fastness, washing and the superior bonding of feel
Agent, the component material of the high fastness, washing and the superior adhesive of feel include: butyl acrylate, styrene, acrylonitrile,
Acrylic amide modified cross-linking monomer, acrylic acid, acrylamide, fatty alcohol polyoxyethylene ether (TO40), lauroyl ether sulphur ammonium
(ALES), silicone oil, tert-butyl hydroperoxide, ammonium persulfate (APS) and deionized water.
Preferably, the mixing ratio by weight between each component is,
Preferably, the high fastness, washing and the superior adhesive of feel, preparation method are prepared by following process
:
(1) each raw material is weighed respectively by above-mentioned mass percent；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, propylene
Sour, acrylic amide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre- cream is made
Liquid；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, controlled during being added dropwise
Temperature is maintained within 80 DEG C, and time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
Compared with prior art, the beneficial effects of the present invention are:
1, by the present invention in that with higher soft or hard monomer ratio, and acrylic amide modified crosslinking agent is added, so that system
Crosslinking sufficiently, is had excellent performance while the low-temperature adhesive obtained is very soft, and preparation method is simple, at low cost, high-efficient；
2, the low-temperature adhesive of the method for the present invention preparation is had excellent performance, especially in terms of feel, washing and fastness；
3, the present invention mutually intersects as function monomer in polymerization process using acrylic amide modified crosslinking agent
Connection, final adhesive feel is excellent, cheap, and meets International Environmental Protection standard, is more conducive to subsequent popularization and use,
Low-temperature adhesive has a wide range of applications textile industry is more multi-field.
Specific embodiment
The embodiment of the present application is by providing a kind of high fastness, washing and the superior adhesive of feel and preparation method thereof, solution
The feel, fastness of most adhesive in the prior art of having determined and washing are all less desirable, limit the problem of it is widely used,
Use acrylic amide modified crosslinking agent as function monomer, is crosslinked mutually in polymerization process, final adhesive feel
It is excellent, cheap, and meet International Environmental Protection standard, it is more conducive to subsequent popularization and use.
The present invention provides a kind of technical solution: the invention discloses a kind of high fastness, washing and the superior adhesive of feel,
The component material of high fastness, washing and the superior adhesive of feel includes: butyl acrylate, styrene, acrylonitrile, acrylamide
Modified crosslinking monomer, acrylic acid, acrylamide, TO40, ALES, silicone oil, tert-butyl hydroperoxide, APS and deionized water.
Preferably, the mixing ratio by weight between each component is,
Preferably, high fastness, washing and the superior adhesive of feel, preparation method are prepared by following process:
(1) each raw material is weighed respectively by above-mentioned mass percent；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, propylene
Sour, acrylic amide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre- cream is made
Liquid；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, controlled during being added dropwise
Temperature is maintained within 80 DEG C, and time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
Embodiment one:
A kind of high fastness, washing and the superior adhesive of feel, high fastness, the component of washing and the superior adhesive of feel
Material include: butyl acrylate, styrene, acrylonitrile, acrylic amide modified cross-linking monomer, acrylic acid, acrylamide, TO40,
ALES, silicone oil, tert-butyl hydroperoxide, APS and deionized water.
In the present embodiment, a kind of high fastness, washing and the superior adhesive of feel, preparation method include the following steps:
(1) each raw material is weighed respectively by following mass percents；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, propylene
Sour, acrylic amide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre- cream is made
Liquid；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, controlled during being added dropwise
Temperature is maintained within 80 DEG C, and time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
In the present embodiment, the large scale of butyl acrylate is added, and butyl acrylate colourless transparent liquid is not soluble in water, can
It is miscible in ethyl alcohol, ether, acrylicacidandesters class is industrially used widely, for manufacturing acrylate solvent type and cream
The soft monomer of liquid type adhesive can be used as among organic synthesis with homopolymerization, copolymerization and graft copolymerization, high molecular polymer monomer
Body, can be with various hard monomers such as methyl methacrylate, styrene, acrylonitrile, vinyl acetate etc. and functional monomer such as
(methyl) hydroxy-ethyl acrylate, hydroxypropyl acrylate, ethylene oxidic ester, (methyl) acrylamide and radical derivative etc. be copolymerized, be crosslinked,
Grafting etc., is made into more kinds of acrylic resin products of 200-700, has excellent performance, preparation method is simple.
Embodiment two
A kind of high fastness, washing and the superior adhesive of feel, high fastness, the component of washing and the superior adhesive of feel
Material include: butyl acrylate, styrene, acrylonitrile, acrylic amide modified cross-linking monomer, acrylic acid, acrylamide, TO40,
ALES, silicone oil, tert-butyl hydroperoxide, APS and deionized water.
In the present embodiment, a kind of high fastness, washing and the superior adhesive of feel, preparation method include the following steps:
(1) each raw material is weighed respectively by following mass percents；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, propylene
Sour, acrylic amide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre- cream is made
Liquid；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, controlled during being added dropwise
Temperature is maintained within 80 DEG C, and time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
In the present embodiment, the large scale of styrene is added, and most important purposes is the monomer as synthetic rubber and plastics,
For producing butadiene-styrene rubber, polystyrene, foamed polystyrene, it is also used for being copolymerized a variety of different purposes of manufacture from other monomers
Engineering plastics are mainly used for improving the superiority of low-temperature adhesive performance, especially in terms of feel, washing and fastness.
Embodiment three
A kind of high fastness, washing and the superior adhesive of feel, high fastness, the component of washing and the superior adhesive of feel
Material include: butyl acrylate, styrene, acrylonitrile, acrylic amide modified cross-linking monomer, acrylic acid, acrylamide, TO40,
ALES, silicone oil, tert-butyl hydroperoxide, APS and deionized water.
In the present embodiment, a kind of high fastness, washing and the superior adhesive of feel, preparation method include the following steps:
(1) each raw material is weighed respectively by following mass percents；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, propylene
Sour, acrylic amide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre- cream is made
Liquid；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, controlled during being added dropwise
Temperature is maintained within 80 DEG C, and time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
In the present embodiment, acrylic amide modified crosslinking agent is being used as function monomer, in polymerization process mutually
Crosslinking, final adhesive feel is excellent, cheap, and meets International Environmental Protection standard, and being more conducive to subsequent popularization makes
It is had a wide range of applications with, low-temperature adhesive textile industry is more multi-field.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
1. a kind of high fastness, washing and the superior adhesive of feel, it is characterised in that: the high fastness, washing and feel are superior
Adhesive component material include: butyl acrylate, styrene, acrylonitrile, acrylic amide modified cross-linking monomer, acrylic acid,
Acrylamide, TO40, ALES, silicone oil, tert-butyl hydroperoxide, APS and deionized water.
2. high fastness according to claim 1, washing and the superior adhesive of feel, it is characterised in that: between each component
Mixing ratio by weight be,
3. high fastness according to claim 2, washing and the superior adhesive of feel, preparation method:
(1) each raw material is weighed respectively by above-mentioned mass percent；
(2) it dissolves: emulsifier ALES and TO40 being dissolved with hot water, then cooled down；
(3) pre-emulsification: by emulsifier ALES and TO40 after cooling and butyl acrylate, acrylonitrile, styrene, acrylic acid, third
Acrylamide modified crosslinking agent, ammonium hydroxide, deionized water are added sequentially to disperse in dispersion machine, and after dispersion completely, pre-emulsion is made；
(4) it heats up: taking part ALES and suitable water as bottom, water-bath is heated to 80 DEG C；
(5) just add: 10% pre-emulsion and suitable APS being taken to put into bottom；
(6) it is added dropwise: after previous step reaction temperature is stablized, starting to be added dropwise, remaining pre-emulsion, control temperature during being added dropwise
It is maintained within 80 DEG C, time for adding is controlled in 2.5h；
(7) keep the temperature: after completion of dropwise addition, water bath temperature is kept for 85 DEG C, keeps the temperature 1.5h；
(8) it post-processes: after heat preservation, being cooled to 70 DEG C, instill tert-butyl hydroperoxide, FF6, and protect 30min；
(9) cool down: leading to cooling water temperature to 40 DEG C or less；
(10) it adjusts PH: the pH value of adhesive is adjusted to 7.0 ± 0.5；
(11) it discharges.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811310113.6A CN109456718A (en) | 2018-11-05 | 2018-11-05 | A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811310113.6A CN109456718A (en) | 2018-11-05 | 2018-11-05 | A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof |
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| CN109456718A true CN109456718A (en) | 2019-03-12 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110358480A (en) * | 2019-07-22 | 2019-10-22 | 安徽聚合辐化化工有限公司 | A kind of high-temperature adhesives |
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| CN105733477A (en) * | 2016-05-04 | 2016-07-06 | 合肥聚合辐化技术有限公司 | High-fastness acrylic binder and preparation method thereof |
| CN107586357A (en) * | 2017-06-10 | 2018-01-16 | 合肥聚合辐化技术有限公司 | A kind of low-temperature adhesive of the high washing of high fastness |
| CN107602776A (en) * | 2017-06-10 | 2018-01-19 | 合肥聚合辐化技术有限公司 | A kind of method that color fastness is improved using modified propylene acid amides |
| CN108276517A (en) * | 2017-12-21 | 2018-07-13 | 合肥聚合辐化技术有限公司 | A kind of rubber cement resin and preparation method thereof that the adhesive force on cloth cover is preferable and anti-sticking |
-
2018
- 2018-11-05 CN CN201811310113.6A patent/CN109456718A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105733477A (en) * | 2016-05-04 | 2016-07-06 | 合肥聚合辐化技术有限公司 | High-fastness acrylic binder and preparation method thereof |
| CN107586357A (en) * | 2017-06-10 | 2018-01-16 | 合肥聚合辐化技术有限公司 | A kind of low-temperature adhesive of the high washing of high fastness |
| CN107602776A (en) * | 2017-06-10 | 2018-01-19 | 合肥聚合辐化技术有限公司 | A kind of method that color fastness is improved using modified propylene acid amides |
| CN108276517A (en) * | 2017-12-21 | 2018-07-13 | 合肥聚合辐化技术有限公司 | A kind of rubber cement resin and preparation method thereof that the adhesive force on cloth cover is preferable and anti-sticking |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110358480A (en) * | 2019-07-22 | 2019-10-22 | 安徽聚合辐化化工有限公司 | A kind of high-temperature adhesives |
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Application publication date: 20190312 |