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CN109337483A - A kind of white marble lacquer coating and preparation method thereof - Google Patents

A kind of white marble lacquer coating and preparation method thereof Download PDF

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Publication number
CN109337483A
CN109337483A CN201811243330.8A CN201811243330A CN109337483A CN 109337483 A CN109337483 A CN 109337483A CN 201811243330 A CN201811243330 A CN 201811243330A CN 109337483 A CN109337483 A CN 109337483A
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CN
China
Prior art keywords
parts
white marble
lacquer coating
agent
sand
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Pending
Application number
CN201811243330.8A
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Chinese (zh)
Inventor
何其
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Susong Hanbang New Building Materials Co Ltd
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Susong Hanbang New Building Materials Co Ltd
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Priority to CN201811243330.8A priority Critical patent/CN109337483A/en
Publication of CN109337483A publication Critical patent/CN109337483A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to building coating technical field, specially a kind of white marble lacquer coating and preparation method thereof.The invention proposes a kind of white marble lacquer coating, raw material includes: 30-50 parts of acrylate copolymer emulsion, 20-30 parts of white marble sand, 10-25 parts of color sand, 7-15 parts of kaolin, 2-6 parts of talcum powder, 0.4-1.2 parts of cellulose, 1-3 parts of ethylene glycol, 1-2 parts of nano-titanium dioxide, 0.1-0.5 parts of 2-amino-2-methyl-1-propanol, 0.8-1.5 parts of gelling agent, 0.5~1 part of dispersing agent, 0.5-2 parts of wetting agent, 1-4 parts of coalescing agent, 2-5 parts of thickener, appropriate amount of water by weight.The present invention also proposes a kind of preparation method of above-mentioned white marble lacquer coating.White marble lacquer coating prepared by the present invention, water resistance, good weatherability be not easy to crack, and adhesion strength is high, and stability is strong.

Description

A kind of white marble lacquer coating and preparation method thereof
Technical field
The present invention relates to building coating technical field, specially a kind of white marble lacquer coating and preparation method thereof.
Background technique
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using various colors Powder is formulated, applied to the imitation stone effect of external wall, therefore also known as liquid stone.Building after lacquer finishing, tool There is natural true natural colour, gives graceful, harmonious, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings. Especially decorated on curved-surface building object, it is vivid, there is a kind of effect of back to nature.Lacquer has fire prevention, waterproof, resistance to Soda acid, anti-pollution.It is nontoxic, tasteless, bonding force is strong, it is will never fade the features such as, can effectively stop extraneous adverse circumstances to building Object corrodes, and extends the service life of building, since lacquer has good adhesive force and freeze-thaw resistance property, is suitble in cold Area uses.
The color of lacquer finished product derives from natural colour sand color, adjusts product by the collocation of the different meshes of color sand Color, the anti-stone effect of product is true to nature, and quality is far smaller than stone material, can significantly mitigate to wall and bear a heavy burden, and cost is much low In the price of stone material.But presently commercially available common lacquer, the phenomenon that easily falling in the prevalence of natural colour sand, color sand is fallen Afterwards, lacquer not only loses decorative effect, but also protection effect is also had a greatly reduced quality;Meanwhile lacquer currently on the market Have the shortcomings that easy to crack, viscosity and gel consistency are small, stability is poor, water resistance and weatherability be not high more.
Summary of the invention
The purpose of the present invention is to provide a kind of white marble lacquer coating and preparation method thereof, to solve above-mentioned background skill The problem of being proposed in art.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of white marble lacquer coating, raw material include: by weight
30-50 parts of acrylate copolymer emulsion, 20-30 parts of white marble sand, 10-25 parts of color sand, 7-15 parts of kaolin, talcum 2-6 parts of powder, 0.4-1.2 parts of cellulose, 1-3 parts of ethylene glycol, 1-2 parts of nano-titanium dioxide, 2-amino-2-methyl-1-propanol 0.1-0.5 parts, 0.8-1.5 parts of gelling agent, 0.5~1 part of dispersing agent, 0.5-2 parts of wetting agent, 1-4 parts of coalescing agent, thickener 2- 5 parts, appropriate amount of water.
Preferably, a kind of preparation method of white marble lacquer coating, includes the following steps:
S1, white marble sand is placed in wet ball mill, and suitable quantity of water is added and is ground as grinding aid, be sieved, dry It is dry to obtain white marble powder;
S2, suitable quantity of water, kaolin, cellulose are sequentially added in dispersion cylinder, stir under conditions of 600-800 revs/min It mixes uniformly, obtains mixed liquor;
S3, in lacquer stirred tank, sequentially add mixed liquor, acrylate copolymer emulsion, white marble powder, coloured silk Sand, talcum powder, cellulose, ethylene glycol, nano-titanium dioxide, gelling agent, dispersing agent, wetting agent, coalescing agent, thickener, Revolving speed stirs 5-10 minutes under conditions of being 500-700 revs/min, and 2-amino-2-methyl-1-propanol is added while stirring, then Continue stirring 10-20 minutes to get white marble lacquer coating finished product is arrived.
Preferably, the white marble sand powder diameter is 1200-1500 mesh.
Preferably, raw material include: by weight 40 parts of acrylate copolymer emulsion, 25 parts of white marble sand, 18 parts of color sand, 11 parts of kaolin, 4 parts of talcum powder, 0.8 part of cellulose, 2 parts of ethylene glycol, 1.5 parts of nano-titanium dioxide, 2- amino-2-methyl -1- 0.3 part of propyl alcohol, 1.2 parts of gelling agent, 0.7 part of dispersing agent, 1.3 parts of wetting agent, 2.5 parts of coalescing agent, 3.5 parts of thickener, water are suitable Amount.
Preferably, the water is deionized water.
Preferably, the cellulose is hydroxyethyl cellulose.
Preferably, the coalescing agent is decylene glycol ester.
Preferably, the thickener is hydrophobically modified alkali-swelling type thickener.
Beneficial effects of the present invention:
A kind of white marble lacquer coating of the invention, raw material with acrylate copolymer emulsion, white marble sand, color sand, Based on kaolin, the white marble powder for using wet ball mill that white marble emery dust is broken into powder diameter as 1200-1500 mesh, with Other raw materials are reasonably combined, and the lacquer coating of preparation, water resistance, good weatherability be not easy to crack, and adhesion strength is high, stability By force.
Specific embodiment
In order to facilitate the understanding of those skilled in the art, the present invention is further illustrated combined with specific embodiments below.
Embodiment 1:
A kind of white marble lacquer coating, raw material include: by weight
50 parts of acrylate copolymer emulsion, 20 parts of white marble sand, 10 parts of color sand, 15 parts of kaolin, 6 parts of talcum powder, hydroxyl second 0.4 part of base cellulose, 3 parts of ethylene glycol, 1 part of nano-titanium dioxide, 0.5 part of 2-amino-2-methyl-1-propanol, gelling agent 0.8 Part, 1 part of dispersing agent, 0.5 part of wetting agent, 4 parts of decylene glycol ester coalescing agent, 2 parts of hydrophobically modified alkali-swelling type thickener, deionization Appropriate amount of water.
A kind of preparation method of white marble lacquer coating, includes the following steps:
S1, white marble sand is placed in wet ball mill, and suitable quantity of water is added and is ground as grinding aid, be sieved, dry It is dry to obtain the white marble powder that partial size is 1200-1500 mesh;
S2, suitable quantity of water, kaolin, cellulose are sequentially added in dispersion cylinder, stir under conditions of 600 revs/min equal It is even, obtain mixed liquor;
S3, in lacquer stirred tank, sequentially add mixed liquor, acrylate copolymer emulsion, white marble powder, coloured silk Sand, talcum powder, cellulose, ethylene glycol, nano-titanium dioxide, gelling agent, dispersing agent, wetting agent, coalescing agent, thickener, Revolving speed stirs 5 minutes under conditions of being 500 revs/min, and 2-amino-2-methyl-1-propanol is added while stirring, is further continued for stirring 10 minutes to get arrive white marble lacquer coating finished product.
Embodiment 2:
A kind of white marble lacquer coating, raw material include: by weight
30 parts of acrylate copolymer emulsion, 30 parts of white marble sand, 25 parts of color sand, 7 parts of kaolin, 2 parts of talcum powder, ethoxy 1.2 parts of cellulose, 1 part of ethylene glycol, 2 parts of nano-titanium dioxide, 0.1 part of 2-amino-2-methyl-1-propanol, 1.5 parts of gelling agent, 0.5 part of dispersing agent, 2 parts of wetting agent, 1 part of decylene glycol ester coalescing agent, 5 parts of hydrophobically modified alkali-swelling type thickener, deionized water In right amount.
A kind of preparation method of white marble lacquer coating, includes the following steps:
S1, white marble sand is placed in wet ball mill, and suitable quantity of water is added and is ground as grinding aid, be sieved, dry It is dry to obtain the white marble powder that partial size is 1200-1500 mesh;
S2, suitable quantity of water, kaolin, cellulose are sequentially added in dispersion cylinder, stir under conditions of 800 revs/min equal It is even, obtain mixed liquor;
S3, in lacquer stirred tank, sequentially add mixed liquor, acrylate copolymer emulsion, white marble powder, coloured silk Sand, talcum powder, cellulose, ethylene glycol, nano-titanium dioxide, gelling agent, dispersing agent, wetting agent, coalescing agent, thickener, Revolving speed stirs 10 minutes under conditions of being 700 revs/min, and 2-amino-2-methyl-1-propanol is added while stirring, is further continued for stirring 20 minutes are mixed to get white marble lacquer coating finished product is arrived.
Embodiment 3:
A kind of white marble lacquer coating, raw material include: by weight
40 parts of acrylate copolymer emulsion, 25 parts of white marble sand, 18 parts of color sand, 11 parts of kaolin, 4 parts of talcum powder, hydroxyl second 0.8 part of base cellulose, 2 parts of ethylene glycol, 1.5 parts of nano-titanium dioxide, 0.3 part of 2-amino-2-methyl-1-propanol, gelling agent 1.2 Part, 0.7 part of dispersing agent, 1.3 parts of wetting agent, 2.5 parts of decylene glycol ester coalescing agent, 3.5 parts of hydrophobically modified alkali-swelling type thickener, Appropriate deionized water.
A kind of preparation method of white marble lacquer coating, includes the following steps:
S1, white marble sand is placed in wet ball mill, and suitable quantity of water is added and is ground as grinding aid, be sieved, dry It is dry to obtain the white marble powder that partial size is 1200-1500 mesh;
S2, suitable quantity of water, kaolin, cellulose are sequentially added in dispersion cylinder, stir under conditions of 700 revs/min equal It is even, obtain mixed liquor;
S3, in lacquer stirred tank, sequentially add mixed liquor, acrylate copolymer emulsion, white marble powder, coloured silk Sand, talcum powder, cellulose, ethylene glycol, nano-titanium dioxide, gelling agent, dispersing agent, wetting agent, coalescing agent, thickener, Revolving speed stirs 8 minutes under conditions of being 600 revs/min, and 2-amino-2-methyl-1-propanol is added while stirring, is further continued for stirring 15 minutes to get arrive white marble lacquer coating finished product.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple Described specific embodiment does various modifications or additions or is substituted in a similar manner, without departing from invention Structure or beyond the scope defined by this claim, is within the scope of protection of the invention.

Claims (8)

1. a kind of white marble lacquer coating, which is characterized in that its raw material includes: by weight
30-50 parts of acrylate copolymer emulsion, 20-30 parts of white marble sand, 10-25 parts of color sand, 7-15 parts of kaolin, talcum powder 2- 6 parts, 0.4-1.2 parts of cellulose, 1-3 parts of ethylene glycol, 1-2 parts of nano-titanium dioxide, 2-amino-2-methyl-1-propanol 0.1-0.5 Part, 0.8-1.5 parts of gelling agent, 0.5~1 part of dispersing agent, 0.5-2 parts of wetting agent, 1-4 parts of coalescing agent, 2-5 parts of thickener, water In right amount.
2. a kind of preparation method of white marble lacquer coating according to claim 1, which is characterized in that including walking as follows It is rapid:
S1, white marble sand is placed in wet ball mill, and suitable quantity of water is added and is ground as grinding aid, sieving, drying take Obtain white marble powder;
S2, suitable quantity of water, kaolin, cellulose are sequentially added in dispersion cylinder, stir under conditions of 600-800 revs/min equal It is even, obtain mixed liquor;
S3, in lacquer stirred tank, sequentially add mixed liquor, acrylate copolymer emulsion, white marble powder, color sand, cunning Mountain flour, cellulose, ethylene glycol, nano-titanium dioxide, gelling agent, dispersing agent, wetting agent, coalescing agent, thickener are in revolving speed It is stirred 5-10 minutes under conditions of 500-700 revs/min, 2-amino-2-methyl-1-propanol is added while stirring, is further continued for stirring 10-20 minutes are mixed to get white marble lacquer coating finished product is arrived.
3. a kind of white marble lacquer coating according to claim 2, which is characterized in that the partial size of the white marble powder For 1200-1500 mesh.
4. a kind of white marble lacquer coating according to claim 1, which is characterized in that its raw material includes: by weight
40 parts of acrylate copolymer emulsion, 25 parts of white marble sand, 18 parts of color sand, 11 parts of kaolin, 4 parts of talcum powder, cellulose 0.8 Part, 2 parts of ethylene glycol, 1.5 parts of nano-titanium dioxide, 0.3 part of 2-amino-2-methyl-1-propanol, 1.2 parts of gelling agent, dispersing agent 0.7 part, 1.3 parts of wetting agent, 2.5 parts of coalescing agent, 3.5 parts of thickener, appropriate amount of water.
5. a kind of white marble lacquer coating according to claim 1, which is characterized in that the water is deionized water.
6. a kind of white marble lacquer coating according to claim 1, which is characterized in that the cellulose is that ethoxy is fine Dimension element.
7. a kind of white marble lacquer coating according to claim 1, which is characterized in that the coalescing agent is lauryl alcohol Ester.
8. a kind of white marble lacquer coating according to claim 1, which is characterized in that the thickener is hydrophobically modified Alkali-swelling type thickener.
CN201811243330.8A 2018-10-24 2018-10-24 A kind of white marble lacquer coating and preparation method thereof Pending CN109337483A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811243330.8A CN109337483A (en) 2018-10-24 2018-10-24 A kind of white marble lacquer coating and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201811243330.8A CN109337483A (en) 2018-10-24 2018-10-24 A kind of white marble lacquer coating and preparation method thereof

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Publication Number Publication Date
CN109337483A true CN109337483A (en) 2019-02-15

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073426A (en) * 2019-12-31 2020-04-28 南京红枫环保材料有限公司 Super-hydrophobic colorful real stone paint coating and preparation method and application thereof
CN113881255A (en) * 2021-10-28 2022-01-04 贵州中亚高科涂料有限公司 Production method of high-performance environment-friendly durable stone-like paint
CN114806296A (en) * 2022-03-31 2022-07-29 苏州皇冠涂料科技发展有限公司 Natural stone paint and preparation method thereof
CN116814129A (en) * 2023-06-26 2023-09-29 广东英凯建筑材料有限公司 Earthworm grain stone coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449050A (en) * 2013-09-24 2015-03-25 天津单渡科技开发有限公司 Pure natural environment-friendly stone-like paint
CN104910737A (en) * 2015-06-23 2015-09-16 陈良伢 A kind of water-based composite multi-color real stone paint exterior wall coating
CN104974623A (en) * 2014-04-14 2015-10-14 铂恩塞尔新材料(上海)股份有限公司 Environment-friendly coating having granite-imitation texture, preparation method and application thereof
CN105907213A (en) * 2016-04-21 2016-08-31 江西天晟新材料有限公司 Marble-imitating colorful piece coating and preparation method of imitated marble
CN105969017A (en) * 2016-05-19 2016-09-28 厦门富思特新材料科技有限公司 Optical self-cleaning granite-like paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449050A (en) * 2013-09-24 2015-03-25 天津单渡科技开发有限公司 Pure natural environment-friendly stone-like paint
CN104974623A (en) * 2014-04-14 2015-10-14 铂恩塞尔新材料(上海)股份有限公司 Environment-friendly coating having granite-imitation texture, preparation method and application thereof
CN104910737A (en) * 2015-06-23 2015-09-16 陈良伢 A kind of water-based composite multi-color real stone paint exterior wall coating
CN105907213A (en) * 2016-04-21 2016-08-31 江西天晟新材料有限公司 Marble-imitating colorful piece coating and preparation method of imitated marble
CN105969017A (en) * 2016-05-19 2016-09-28 厦门富思特新材料科技有限公司 Optical self-cleaning granite-like paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073426A (en) * 2019-12-31 2020-04-28 南京红枫环保材料有限公司 Super-hydrophobic colorful real stone paint coating and preparation method and application thereof
CN113881255A (en) * 2021-10-28 2022-01-04 贵州中亚高科涂料有限公司 Production method of high-performance environment-friendly durable stone-like paint
CN114806296A (en) * 2022-03-31 2022-07-29 苏州皇冠涂料科技发展有限公司 Natural stone paint and preparation method thereof
CN116814129A (en) * 2023-06-26 2023-09-29 广东英凯建筑材料有限公司 Earthworm grain stone coating and preparation method thereof

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Application publication date: 20190215

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