CN109281179A - A kind of preparation method of uvioresistant Antistatic Fabric - Google Patents
A kind of preparation method of uvioresistant Antistatic Fabric Download PDFInfo
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- CN109281179A CN109281179A CN201811104099.4A CN201811104099A CN109281179A CN 109281179 A CN109281179 A CN 109281179A CN 201811104099 A CN201811104099 A CN 201811104099A CN 109281179 A CN109281179 A CN 109281179A
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- 239000004744 fabric Substances 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000009987 spinning Methods 0.000 claims abstract description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 14
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 9
- 238000003851 corona treatment Methods 0.000 claims description 8
- 238000010041 electrostatic spinning Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 238000001523 electrospinning Methods 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 238000002386 leaching Methods 0.000 claims 1
- 229940068984 polyvinyl alcohol Drugs 0.000 abstract description 12
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 8
- 238000007598 dipping method Methods 0.000 abstract description 7
- 238000005096 rolling process Methods 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 4
- 230000003993 interaction Effects 0.000 abstract description 2
- 238000013021 overheating Methods 0.000 abstract 1
- 230000005855 radiation Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010058130 Asteatosis Diseases 0.000 description 1
- 201000009030 Carcinoma Diseases 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/24—Polymers or copolymers of alkenylalcohols or esters thereof; Polymers or copolymers of alkenylethers, acetals or ketones
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of preparation methods of uvioresistant Antistatic Fabric, belong to fabric technical field.ATO powder and zinc oxide is added as spinning solution in the present invention in poly-vinyl alcohol solution, tunica fibrosa is made, tunica fibrosa through Overheating Treatment is clipped between two layers of non-woven cloth, tunica fibrosa and non-woven cloth are bonded by heat treatment, constitute non-woven cloth-nano fibrous membrane-non-woven cloth form sandwich material, Bis-quaternary Ammonium Salt Surfactant is arranged onto sandwich material using the method for sorting of second dipping and rolling, prepare uvioresistant Antistatic Fabric, ATO powder is dispersed in interaction in fabric and forms conductive film, the mobile achievable high-transmission rate of charge and antistatic in conductive film；A kind of uvioresistant Antistatic Fabric of the present invention, has good anti-ultraviolet property and antistatic property, and washing fastness is excellent, has broad application prospects and market prospects.
Description
Technical field
The present invention relates to a kind of preparation methods of uvioresistant Antistatic Fabric, belong to fabric technical field.
Background technique
With the continuous development of China's textile technology, the functionality of fabric is gradually completed.In some special dimensions, tradition
The use of fabric is greatly limited.The general new function of fabric that assigns is improved using following methods: use spray,
The methods of immersion coating is surface-treated fabric, is perhaps modified using chemic modified method or in spinning solution
Middle addition auxiliary agent is to assign fabric new performance.
For human body, suitable ultraviolet radiation has bactericidal effect and can promote the synthesis of vitamin D, is conducive to people
Body health.But under burning sun prolonged exposure, human skin can lose resilience, easily burn, and erythema or bubble occur.It crosses
The ultraviolet light irradiation of amount can also induce skin disease (such as dermatitis, pigment asteatosis cutis) or even cutaneum carcinoma, promote the generation of cataract simultaneously
Reduce the immune function of human body.
From optical principle, ultraviolet radiation to fabric, is partially reflected on surface, is partially absorbed by fabric,
Remaining then penetrates fabric.Under normal circumstances, transmitance+reflectivity+absorptivity=100% of ultraviolet light.Therefore, fabric pair is improved
The absorptivity and reflectivity of ultraviolet light can reduce the transmitance of ultraviolet light.Although current existing anti-ultraviolet radiation treatment liquid meeting
Assign fabric certain ultraviolet reflection rate and absorptivity, but after long-time is cleaned, anti-ultraviolet property can gradually subtract
It is weak until disappear.
And the antistatic property of fabric is also particularly important, especially in special occasions, the electrostatic that fabric generates often generates cause
Therefore the harm of life is also particularly important the research of the antistatic property of fabric.
Therefore, it studies a kind of uvioresistant Antistatic Fabric and preparation method thereof haveing excellent performance and has become art technology
Personnel's technical problem urgently to be resolved.
Summary of the invention
The technical problems to be solved by the invention: for anti-ultraviolet radiation treatment liquid fabric after long-time is cleaned, anti-purple
Outside line and antistatic property can gradually weaken until the problem of disappearing, provides a kind of preparation side of uvioresistant Antistatic Fabric
Method.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
(1) according to parts by weight, 20~30 parts of polyvinyl alcohol, 50~60 parts of deionized waters, 10~15 parts of ATO powder are weighed respectively
End, 8~12 parts of zinc oxide, 1~5 part of lauryl sodium sulfate, polyvinyl alcohol and deionized water are mixed, and insulated and stirred obtains mixed
Liquid is closed, is cooled to room temperature, ATO powder, zinc oxide and lauryl sodium sulfate is added, continues 30~50min of stirring, and ultrasound point
10~15min is dissipated, spinning solution is obtained；Spinning solution is subjected to electrostatic spinning, obtains tunica fibrosa, at tunica fibrosa heat treatment and plasma
Reason, obtains modified fibre film, modified fibre film is placed between two layers of non-woven cloth and carries out 10~20min of heat treatment, is cooled to room
Temperature is up to compound base fabric；
(2) compound base fabric is padded into processing, base fabric must be padded, baked 5~10min at being 70~80 DEG C in temperature, take out and wash
It washs, obtains washing base fabric, dry to constant weight in the baking oven that temperature is 80~90 DEG C to get uvioresistant Antistatic Fabric.
It is 85~95 DEG C that insulated and stirred described in step (1), which is in temperature, and mixing speed is to stir under 100~200r/min
2~3h.
Electrospinning conditions described in step (1) are 60~70kV of spinning voltage, 10~20r/min of generator revolving speed, spinning
Flight lead is from 180~200mm, receiver 1~5m/min of revolving speed, using non-woven cloth as reception source.
Heat treatment described in step (1) and corona treatment be 200~220 DEG C in temperature at heat treatment 10~
20min and 1~3min of corona treatment at 200~220W.
Heat treatment described in step (1) be in temperature be 135~145 DEG C, pressure be heat treatment 10 under 100~200Pa~
20min。
It is that compound base fabric is immersed in 5~10min in Bis-quaternary Ammonium Salt Surfactant that processing is padded described in step (2),
And the second dipping and rolling in padding machine, pick-up are 60%~70%.
Washing described in step (2) is the deionized water for being 70~80 DEG C with temperature and soap water washing 3~5 times.
The present invention is compared with other methods, and advantageous effects are:
(1) ATO powder and zinc oxide is added as spinning solution in the present invention in poly-vinyl alcohol solution, and tunica fibrosa is made, passes through
The tunica fibrosa of heat treatment is clipped between two layers of non-woven cloth, is bonded tunica fibrosa and non-woven cloth by heat treatment, is constituted
Non-woven cloth-nano fibrous membrane-non-woven cloth form sandwich material, using the method for sorting of second dipping and rolling by double seasons
Ammonium surfactant is arranged onto sandwich material, prepares uvioresistant Antistatic Fabric, ATO powder is evenly dispersed
Interaction forms conductive film in fabric, the mobile achievable high-transmission rate of charge and antistatic in conductive film；
(2) antistatic property of Bis-quaternary Ammonium Salt Surfactant is based on the alignment capability and molecule in web surface in the present invention
The associative ability of water, bi-quaternary ammonium salt all have two or more hydrophobic group long-chains and stronger hydrophilic group in middle polar group and air
Group, processing fabric are that long chain hydrophobic group is combined to hydrophobic fibre surface, and hydrophilic group stretches to air, in air with fibre
It is aligned on the interface of dimension, the surface of fiber is made to form the adsorption layer of a water, wherein can also be moved in water layer
Br-Or Cl-, play the role of ionic conduction, to reduce the specific resistance of fiber, accelerates the loss of electrostatic, thus it is anti-
Electrostatic efficiency is significant.
Specific embodiment
According to parts by weight, 20~30 parts of polyvinyl alcohol, 50~60 parts of deionized waters, 10~15 parts of ATO powder are weighed respectively
End, 8~12 parts of zinc oxide, 1~5 part of lauryl sodium sulfate mix polyvinyl alcohol and deionized water, are 85~95 in temperature
DEG C, mixing speed is that 2~3h is stirred under 100~200r/min, obtains mixed liquor, is cooled to room temperature, and ATO powder, zinc oxide is added
And lauryl sodium sulfate, continue 30~50min of stirring, and 10~15min of ultrasonic disperse, obtains spinning solution；Spinning solution is carried out
Electrostatic spinning, 60~70kV of spinning voltage, 10~20r/min of generator revolving speed, 180~200mm of spinning distance, receiver revolving speed
1~5m/min obtains tunica fibrosa using non-woven cloth as reception source, is heat-treated 10 at being 200~220 DEG C in temperature by tunica fibrosa
~20min, and 1~3min of corona treatment at 200~220W, obtain modified fibre film, and modified fibre film is placed in two layers
It is 135~145 DEG C in temperature between non-woven cloth, pressure is that 10~20min is heat-treated under 100~200Pa, is cooled to room temperature
Up to compound base fabric；Compound base fabric is immersed in 5~10min in Bis-quaternary Ammonium Salt Surfactant, and the second dipping and rolling in padding machine,
Pick-up is 60%~70%, must pad base fabric, bakes 5~10min at being 70~80 DEG C in temperature, takes out, with temperature for 70~
80 DEG C of deionized water and soap water washing 3~5 times, obtain washing base fabric, dry in the baking oven that temperature is 80~90 DEG C to perseverance
Weight is to get uvioresistant Antistatic Fabric.
According to parts by weight, weigh respectively 20 parts of polyvinyl alcohol, 50 parts of deionized waters, 10 parts of ATO powder, 8 parts of zinc oxide,
1 part of lauryl sodium sulfate mixes polyvinyl alcohol and deionized water, is 85 DEG C in temperature, mixing speed is under 100r/min
2h is stirred, mixed liquor is obtained, is cooled to room temperature, ATO powder, zinc oxide and lauryl sodium sulfate is added, continues to stir 30min,
And ultrasonic disperse 10min, obtain spinning solution；Spinning solution is subjected to electrostatic spinning, spinning voltage 60kV, generator revolving speed 10r/min,
Spinning distance 180mm, receiver revolving speed 1m/min obtain tunica fibrosa using non-woven cloth as reception source, are in temperature by tunica fibrosa
It is heat-treated 10min, and the corona treatment 1min at 200W at 200 DEG C, obtains modified fibre film, modified fibre film is placed in two
It is 135 DEG C in temperature between layer non-woven cloth, pressure is to be heat-treated 10min under 100Pa, is cooled to room temperature up to compound base fabric；
Compound base fabric is immersed in 5min in Bis-quaternary Ammonium Salt Surfactant, and the second dipping and rolling in padding machine, pick-up 60% must soak
Base fabric is rolled, 5min is baked at being 70 DEG C in temperature, takes out, be 70 DEG C of deionized water and soap water washing 3 times with temperature, must wash
Base fabric is washed, is dried to constant weight in the baking oven that temperature is 80 DEG C to get uvioresistant Antistatic Fabric.
According to parts by weight, 25 parts of polyvinyl alcohol, 55 parts of deionized waters, 13 parts of ATO powder, 10 parts of oxidations are weighed respectively
Zinc, 3 parts of lauryl sodium sulfate mix polyvinyl alcohol and deionized water, are 90 DEG C in temperature, mixing speed 150r/min
Lower stirring 2h, obtains mixed liquor, is cooled to room temperature, and ATO powder, zinc oxide and lauryl sodium sulfate is added, continues to stir
40min, and ultrasonic disperse 13min, obtain spinning solution；Spinning solution is subjected to electrostatic spinning, spinning voltage 65kV, generator revolving speed
15r/min, spinning distance 190mm, receiver revolving speed 3m/min obtain tunica fibrosa using non-woven cloth as reception source, by tunica fibrosa
It is heat-treated 15min, and the corona treatment 2min at 210W at being 210 DEG C in temperature, modified fibre film is obtained, by modified fibre
Film is placed between two layers of non-woven cloth, is 140 DEG C in temperature, and pressure is to be heat-treated 15min under 150Pa, is cooled to room temperature to obtain the final product
Compound base fabric；Compound base fabric is immersed in 7min in Bis-quaternary Ammonium Salt Surfactant, and the second dipping and rolling in padding machine, pick-up are
65%, base fabric must be padded, 7min is baked at being 75 DEG C in temperature, takes out, the deionized water and soap water washing for being 75 DEG C with temperature
4 times, washing base fabric is obtained, is dried to constant weight in the baking oven that temperature is 85 DEG C to get uvioresistant Antistatic Fabric.
According to parts by weight, 30 parts of polyvinyl alcohol, 60 parts of deionized waters, 15 parts of ATO powder, 12 parts of oxidations are weighed respectively
Zinc, 5 parts of lauryl sodium sulfate mix polyvinyl alcohol and deionized water, are 95 DEG C in temperature, mixing speed 200r/min
Lower stirring 3h, obtains mixed liquor, is cooled to room temperature, and ATO powder, zinc oxide and lauryl sodium sulfate is added, continues to stir
50min, and ultrasonic disperse 15min, obtain spinning solution；Spinning solution is subjected to electrostatic spinning, spinning voltage 70kV, generator revolving speed
20r/min, spinning distance 200mm, receiver revolving speed 5m/min obtain tunica fibrosa using non-woven cloth as reception source, by tunica fibrosa
It is heat-treated 20min, and the corona treatment 3min at 220W at being 220 DEG C in temperature, modified fibre film is obtained, by modified fibre
Film is placed between two layers of non-woven cloth, is 145 DEG C in temperature, and pressure is to be heat-treated 20min under 200Pa, is cooled to room temperature to obtain the final product
Compound base fabric；Compound base fabric is immersed in 10min in Bis-quaternary Ammonium Salt Surfactant, and the second dipping and rolling in padding machine, pick-up
It is 70%, base fabric must be padded, bakes 10min at being 80 DEG C in temperature, take out, deionized water and suds with temperature for 80 DEG C
Washing 5 times, obtains washing base fabric, dries to constant weight in baking oven at a temperature of 90 °C to get uvioresistant Antistatic Fabric.
Uvioresistant Antistatic Fabric prepared by the present invention is detected, specific testing result is as follows:
Detection method: carrying out uvioresistant to 1 to 3 gained uvioresistant Antistatic Fabric of embodiment and antistatic property detect,
Wherein, transmitance of the anti-ultraviolet property test fabric to ultraviolet light (the especially ultraviolet light of wavelength 290-400nm), antistatic property
Can with the resistance between the every square unit sample corresponding sides of the specific resistance Rs(of web surface) it indicates, meanwhile, it is washed in fabric
The antistatic property and anti-ultraviolet property of fabric are tested after 20 times again, reference examples are commercially available common uvioresistant fabrics, are surveyed
Test result such as the following table 1
1 uvioresistant Antistatic Fabric performance characterization of table
Uvioresistant Antistatic Fabric prepared by the present invention as shown in Table 1 has good anti-ultraviolet property and antistatic property
Can, and after washing 20 times, performance keeps inconvenient substantially, and durability is good, and uvioresistant is antistatic excellent, has a vast market
Prospect and application prospect.
Claims (7)
1. a kind of preparation method of uvioresistant Antistatic Fabric, it is characterised in that specific preparation step are as follows:
(1) according to parts by weight, 20~30 parts of polyvinyl alcohol, 50~60 parts of deionized waters, 10~15 parts of ATO powder are weighed respectively
End, 8~12 parts of zinc oxide, 1~5 part of lauryl sodium sulfate, polyvinyl alcohol and deionized water are mixed, and insulated and stirred obtains mixed
Liquid is closed, is cooled to room temperature, ATO powder, zinc oxide and lauryl sodium sulfate is added, continues 30~50min of stirring, and ultrasound point
10~15min is dissipated, spinning solution is obtained；Spinning solution is subjected to electrostatic spinning, obtains tunica fibrosa, at tunica fibrosa heat treatment and plasma
Reason, obtains modified fibre film, modified fibre film is placed between two layers of non-woven cloth and carries out 10~20min of heat treatment, is cooled to room
Temperature is up to compound base fabric；
(2) compound base fabric is padded into processing, base fabric must be padded, baked 5~10min at being 70~80 DEG C in temperature, take out and wash
It washs, obtains washing base fabric, dry to constant weight in the baking oven that temperature is 80~90 DEG C to get uvioresistant Antistatic Fabric.
2. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (1)
It is 85~95 DEG C that the insulated and stirred, which is in temperature, and mixing speed is that 2~3h is stirred under 100~200r/min.
3. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (1)
The electrospinning conditions be 60~70kV of spinning voltage, 10~20r/min of generator revolving speed, spinning distance 180~
200mm, receiver 1~5m/min of revolving speed, using non-woven cloth as reception source.
4. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (1)
The heat treatment and corona treatment be 200~220 DEG C in temperature at be heat-treated 10~20min and in 200~220W
1~3min of lower corona treatment.
5. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (1)
It is 135~145 DEG C that the heat treatment, which is in temperature, and pressure is that 10~20min is heat-treated under 100~200Pa.
6. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (2)
Described pads processing for compound base fabric is immersed in 5~10min in Bis-quaternary Ammonium Salt Surfactant, and two leaching two in padding machine
It rolls, pick-up is 60%~70%.
7. a kind of preparation method of uvioresistant Antistatic Fabric according to claim 1, it is characterised in that: step (2)
The washing is the deionized water for being 70~80 DEG C with temperature and soap water washing 3~5 times.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811104099.4A CN109281179A (en) | 2018-09-21 | 2018-09-21 | A kind of preparation method of uvioresistant Antistatic Fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811104099.4A CN109281179A (en) | 2018-09-21 | 2018-09-21 | A kind of preparation method of uvioresistant Antistatic Fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109281179A true CN109281179A (en) | 2019-01-29 |
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| CN110130092A (en) * | 2019-05-25 | 2019-08-16 | 北京化工大学 | A method for finishing modified polypropylene non-woven fabric after flame retardant with intumescent flame retardant |
| CN111136968A (en) * | 2019-08-27 | 2020-05-12 | 深圳市大毛牛新材料科技有限公司 | Waterproof anti ultraviolet textile fabric |
| CN112323212A (en) * | 2020-10-20 | 2021-02-05 | 江苏晨越高新材料有限公司 | Production method of anti-ultraviolet fabric |
| CN113815278A (en) * | 2021-10-18 | 2021-12-21 | 北京熵图医疗科技合伙企业(有限合伙) | Medical wrapping cloth with high antibacterial performance and preparation method thereof |
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| CN113815278A (en) * | 2021-10-18 | 2021-12-21 | 北京熵图医疗科技合伙企业(有限合伙) | Medical wrapping cloth with high antibacterial performance and preparation method thereof |
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