CN109276482A - Without silicone oil suncream and preparation method thereof - Google Patents
Without silicone oil suncream and preparation method thereof Download PDFInfo
- Publication number
- CN109276482A CN109276482A CN201811506385.3A CN201811506385A CN109276482A CN 109276482 A CN109276482 A CN 109276482A CN 201811506385 A CN201811506385 A CN 201811506385A CN 109276482 A CN109276482 A CN 109276482A
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- Prior art keywords
- parts
- silicone oil
- acid
- suncream
- glycerol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000516 sunscreening agent Substances 0.000 title claims abstract description 97
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 145
- 239000003974 emollient agent Substances 0.000 claims abstract description 36
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 32
- 239000002904 solvent Substances 0.000 claims abstract description 31
- 238000002156 mixing Methods 0.000 claims abstract description 28
- -1 polytetramethylene Polymers 0.000 claims abstract description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000654 additive Substances 0.000 claims abstract description 23
- 230000000996 additive effect Effects 0.000 claims abstract description 23
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 13
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims abstract description 11
- MBWXDZRHBUALQL-XHBICQFHSA-N (2s)-2-formamido-4-methylsulfinylbutanoic acid Chemical compound CS(=O)CC[C@@H](C(O)=O)NC=O MBWXDZRHBUALQL-XHBICQFHSA-N 0.000 claims abstract description 9
- YLNICVZSJDUCOC-LFUZPPSTSA-N CS(=O)CC[C@@H](C(=O)O)NC(CCCCCCCCCCCCC)=O Chemical compound CS(=O)CC[C@@H](C(=O)O)NC(CCCCCCCCCCCCC)=O YLNICVZSJDUCOC-LFUZPPSTSA-N 0.000 claims abstract description 7
- YGXZUSJWSRATRC-NGMICRHFSA-N (2S)-2-(dodecanoylamino)-4-methylsulfinylbutanoic acid Chemical compound C(CCCCCCCCCCC)(=O)N[C@H](C(=O)O)CCS(=O)C YGXZUSJWSRATRC-NGMICRHFSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 27
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 26
- 150000002148 esters Chemical class 0.000 claims description 25
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical group COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 14
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 13
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 13
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 13
- 229960001679 octinoxate Drugs 0.000 claims description 13
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 12
- 241000723346 Cinnamomum camphora Species 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 229920002385 Sodium hyaluronate Polymers 0.000 claims description 12
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- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 12
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- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 12
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- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims description 11
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- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 claims description 11
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 11
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 11
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 9
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 150000001413 amino acids Chemical class 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 7
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical group NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 claims description 6
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- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 4
- 235000020778 linoleic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
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- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of no silicone oil suncream, is made of following components by following mass parts: 5-15 parts of sun-screening agent, 20-50 parts of emollient, 30-55 parts of solvent, 2-5 parts of emulsifier, 0.2-6 parts of additive.Wherein the emollient is free of silicone oil component；The emulsifier is N- certain herbaceous plants with big flowers formyl methionine sulfoxide, N- lauroyl methionine sulfoxide, N- myristoyl methionine sulfoxide, N- palmityl methionine sulfoxide, PEG-40 stearate, any one or any several mixing with arbitrary proportion in -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol.The no silicone oil suncream emulsification system is stablized, and sun-proof result is good.The present invention also provides a kind of preparation methods of no silicone oil suncream.
Description
Technical field
The present invention relates to cosmetic technical fields more particularly to a kind of no silicone oil suncream and preparation method thereof.
Background technique
There are also ultraviolet lights other than visible light in daylight, and when people are when carrying out illumination, ultraviolet light also can be to human body
Skin damages, and not only appearance is impaired, is more likely to influence skin health.Moreover, as environmental pollution is increasingly severe, greatly
The destruction of gas ozone layer is also increasingly severe, and the intensity of daylight middle-ultraviolet lamp is caused to become strong, people under light illumination ultraviolet light to skin
The damage of skin is also more and more obvious, and consumer is increasing to sunscreen product demand.On the other hand, with people's level of consumption
It improves, green, healthy sunscreen product are gradually by the favor of consumer.Currently, most of sunscreen product types are numerous in the market
It is more, such as: suncream, sunscreen, sunscreen stick, sunscreen spray etc..But mostly all contains silicone oil component, can not really meet use
Family demand.And a small number of sunscreen products without silicone oil only simply remove silicone oil in formula, cause formula to be not sufficiently stable, are using
The case where water-oil separating is easy to appear after a period of time needs to rock, make troubles to user before use.
Summary of the invention
The present invention provides a kind of formulation stable, no silicone oil suncream easy to use.
To solve the above-mentioned problems, the present invention provides a kind of no silicone oil suncreams, press following mass parts by following components
Composition: 5-15 parts of sun-screening agent, 20-50 parts of emollient, 30-55 parts of solvent, 2-5 parts of emulsifier, 0.2-6 parts of additive；Wherein, institute
State emollient be rilanit special dimerized linoleic acid ester, Butyrospermum parkii fruit rouge, ethylhexyl palmitate, isopropyl myristate,
Octanoic acid/certain herbaceous plants with big flowers acid glycerol three ester, three isostearate of polyglycereol -2-, pentaerythritol tetraoctyl stearate, isopropyl isostearate,
Triethyl group capronate, glycerol three (thylhexoic acid) ester, tridecanol trimellitate, any several group in seed oil of Moringa oleigera
It closes；The emulsifier includes amino acid type surfactant and nonionic surface active agent, wherein the amino acid pattern surface
Activating agent is N- certain herbaceous plants with big flowers formyl methionine sulfoxide, N- lauroyl methionine sulfoxide, N- myristoyl methionine sulfoxide, N- palm
Formyl methionine sulfoxide, in any one or any several mixing；The nonionic surface active agent is that PEG-40 is hard
The mixing of any one or two kinds in resin acid ester, -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol.
Being compounded by using the emollient and the emulsifier for the no silicone oil suncream, forms stable
Emulsification system: the emulsifier includes lipophilic group and hydrophilic group, is a kind of surface reactive material of function admirable.The emollient
It is made of health, mild grease, does not contain silicone oil component.The lipophilic group of the emulsifier is dissolved in the emollient, described
The hydrophilic group of emulsifier is dissolved in the solvent, to reduce the tension at interface, it is poor to reduce oil, the polarity of water two-phase, will
The emollient and the solvent mix.
Further, the sun-screening agent includes physical sunscreen agent and chemical sun, wherein the physical sunscreen agent is to receive
Rice titanium dioxide, nano zine oxide, titanium dioxide, any one or any several mixing in zinc oxide；The chemistry is anti-
Solarization agent is benzophenone-3, Octocrilene, octyl methoxycinnamate, butylmethoxydibenzoylmethane, 4- Methylbenzylidene
Any one in subunit camphor or any several mixing.By between the physical sunscreen agent and the chemical sun
Cooperation, the no silicone oil suncream can effectively absorb ultraviolet B radiation (UVB, 290-320nm), long wave ultraviolet (UVA,
320-400nm), skin sparing barrier is formed.
Further, the additive includes preservative, acid-base modifier, essence and functional component.Wherein, described anti-
Rotten agent is methylparaben, propylben, any one or any several mixing in tocopherol acetate, micro- for preventing
The infection and breeding of biology, so that the no silicone oil suncream has certain preservation term；The acid-base modifier is three ethyl alcohol
Any one in amine, sodium hydrate aqueous solution, citric acid, sodium carbonate and sodium citrate or any several mixing, it is steady to be used as emulsification
Determine agent, the pH of system is adjusted, maintains the stabilization of emulsification system；The essence be bouquet type composition, Fruity type essence and
Any one in food type essence or any several mixing, as flavouring agent, the imparting no silicone oil suncream is pleasant
Fragrance；The functional component is that allantoin, hydrolytic collagen, saualane, oriental cherry flower extract, ginseng root extract, pot marigold mention
Object, apple seed extract, any one in oil-soluble Sodium Hyaluronate or any several mixing, the functional component is taken to add
Add so that the no silicone oil suncream has the function of whitening, moisturizing, anti-aging, crease-resistant etc..
Further, the solvent be water, glycerol, propylene glycol, butanediol, in octanoic acid any one or it is any several
Mixing.
Further, the no silicone oil suncream includes following components:
Emollient: Butyrospermum parkii fruit rouge, ethylhexyl palmitate, isopropyl myristate, octanoic acid/certain herbaceous plants with big flowers acid glycerol three ester,
Triethyl group capronate, glycerol three (thylhexoic acid) ester, tridecanol trimellitate；
Emulsifier: PEG-40 stearate, -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- myristoyl methionine are sub-
Sulfone；
Sun-screening agent: nano-titanium dioxide, nano zine oxide, octyl methoxycinnamate, 4- Methylbenzylidene subunit camphor；
Additive: methylparaben, sodium citrate, olive essence, apple seed extract, oil-soluble Sodium Hyaluronate；
Solvent: water, glycerol, butanediol.
Further, the no silicone oil suncream includes 35 parts of emollient and 4 parts of emulsifier,
The emollient includes 2 parts of Butyrospermum parkii fruit rouge, 3 parts of ethylhexyl palmitate, 7 parts of isopropyl myristate, pungent
Acid/4 parts of certain herbaceous plants with big flowers acid glycerol three ester, 7 parts of triethyl group capronate, 6 parts of glycerol three (thylhexoic acid) ester, tridecanol trimellitate 6
Part；
The emulsifier includes 1.5 parts of PEG-40 stearate, 1.5 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N-
1 part of myristoyl methionine sulfoxide.
Further, the no silicone oil it is sun-proof include 13 parts of sun-screening agent, the sun-screening agent include 6 parts of nano-titanium dioxide,
3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 2 parts of camphor of 4- Methylbenzylidene subunit.
Further, the no silicone oil suncream includes 4.5 parts of additive, and the additive includes methylparaben
0.3 part, 0.2 part of sodium citrate, 1 part of olive essence, 2 parts of apple seed extract, 1 part of oil-soluble Sodium Hyaluronate.
Further, the no silicone oil suncream includes 34 parts of solvent, the solvent include 19 parts of water, 11 parts of glycerol,
4 parts of butanediol.
In addition, the invention also includes a kind of preparation methods of no silicone oil suncream, which comprises the following steps:
Step S1: being divided into two parts for emollient, and sub-fraction therein is mixed with sun-screening agent, and grinds uniformly, obtains
To the first mixture；
Step S2: another part emollient and emulsifier being mixed, are heated to 80-85 DEG C, heat while stirring until
Homogeneously, the second mixture is obtained；Solvent is heated to 80-85 DEG C, is heated while stirring until homogeneous；
Step S3: carrying out first mixture and second mixture to be mixed to get third mixture, will be described
Third mixture is added in the solvent by step S2 processing, and temperature is kept for 80-85 DEG C, and starts homogenizer and carry out homogeneous
About 30-40 minutes, obtain the 4th uniform and stable mixture；
Step S4: the 4th mixture is cooled to 60-70 DEG C, and additive is added thereto, starts homogeneous again
Machine obtains the 5th mixture after carrying out homogeneous about 10-15 minutes, is stirred continuously until that the temperature of the 5th mixture is reduced to
Room temperature obtains no silicone oil suncream.
Detailed description of the invention
The present invention is further described with embodiment with reference to the accompanying drawing.
Fig. 1 is the skeleton symbol of amino acid type surfactant of the present invention.
Specific embodiment
It is clear in order to be more clear the purpose of the present invention, technical scheme and beneficial effects, below in conjunction with of the invention real
The attached drawing in mode is applied, the technical solution in embodiment of the present invention is clearly and completely described, it is clear that described
Embodiment is only some embodiments of the invention, rather than whole embodiments.Based on the embodiment party in the present invention
Formula, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all belongs to
In the scope of protection of the invention.
First embodiment
A kind of no silicone oil suncream is made of following components by following mass parts: 5-15 parts of sun-screening agent, emollient 20-50
Part, 30-55 parts of solvent, 2-5 parts of emulsifier, 0.2-6 parts of additive；
The emollient is rilanit special dimerized linoleic acid ester, Butyrospermum parkii fruit rouge, ethylhexyl palmitate, nutmeg
Isopropyl propionate, octanoic acid/certain herbaceous plants with big flowers acid glycerol three ester, three isostearate of polyglycereol -2-, pentaerythritol tetraoctyl stearate, different tristearin
It is isopropyl propionate, triethyl group capronate, glycerol three (thylhexoic acid) ester, tridecanol trimellitate, any in seed oil of Moringa oleigera
Several combinations；
The emulsifier includes amino acid type surfactant and nonionic surface active agent, wherein the amino acid
Type surfactant be N- certain herbaceous plants with big flowers formyl methionine sulfoxide, N- lauroyl methionine sulfoxide, N- myristoyl methionine sulfoxide,
N- palmityl methionine sulfoxide, in any one or any several mixing；The nonionic surface active agent is
The mixing of any one or two kinds in PEG-40 stearate, -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol.
Being compounded by using the emollient and the emulsifier for the no silicone oil suncream, forms stable
Emulsification system: the emulsifier includes lipophilic group and hydrophilic group, is a kind of surface reactive material of function admirable.The emollient
It is made of health, mild grease, does not contain silicone oil component.The lipophilic group of the emulsifier is dissolved in the emollient, described
The hydrophilic group of emulsifier is dissolved in the solvent, to reduce the tension at interface, it is poor to reduce oil, the polarity of water two-phase, will
The emollient and the solvent mix.
The sun-screening agent includes physical sunscreen agent and chemical sun, and in the present embodiment, the physical sunscreen agent is
Nano-titanium dioxide, nano zine oxide, titanium dioxide, any one or any several mixing in zinc oxide；The chemistry
Sun-screening agent is benzophenone-3, Octocrilene, octyl methoxycinnamate, butylmethoxydibenzoylmethane, 4- methyl Asia
Any one in benzyl subunit camphor or any several mixing.By between the physical sunscreen agent and the chemical sun
Cooperation, the no silicone oil suncream can effectively absorb ultraviolet B radiation (UVB, 290-320nm), long wave ultraviolet
(UVA, 320-400nm) forms skin sparing barrier.
The additive includes preservative, acid-base modifier, essence and functional component.In the present embodiment, described
Preservative is methylparaben, propylben, any one or any several mixing in tocopherol acetate, for preventing
The infection and breeding of microorganism, so that the no silicone oil suncream has certain preservation term；The acid-base modifier is three second
Any one in hydramine, sodium hydrate aqueous solution, citric acid, sodium carbonate and sodium citrate or any several mixing, are used as emulsification
The pH of system is adjusted in stabilizer, maintains the stabilization of emulsification system；The essence is bouquet type composition, Fruity type essence
And it is pleasant to assign the no silicone oil suncream as flavouring agent for any one in food type essence or arbitrarily several mixing
Fragrance；The functional component is allantoin, hydrolytic collagen, saualane, oriental cherry flower extract, ginseng root extract, pot marigold
Extract, apple seed extract, any one in oil-soluble Sodium Hyaluronate or any several mixing, the functional component
Addition is so that the no silicone oil suncream has the function of whitening, moisturizing, anti-aging, crease-resistant etc..
In the present embodiment, the solvent be water, glycerol, propylene glycol, butanediol, in octanoic acid any one or it is any
Several mixing.
Preferably, the no silicone oil suncream is grouped as by the group of following mass parts:
35 parts of emollient: 2 parts of Butyrospermum parkii fruit rouge, 3 parts of ethylhexyl palmitate, 7 parts of isopropyl myristate, octanoic acid/
4 parts of certain herbaceous plants with big flowers acid glycerol three ester, 7 parts of triethyl group capronate, 6 parts, 6 parts of tridecanol trimellitate of glycerol three (thylhexoic acid) ester；
1.5 parts of 4 parts: PEG-40 stearate of emulsifier, 1.5 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- Pork and beans
1 part of cool formyl methionine sulfoxide；
13 parts of sun-screening agent: 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 4- methyl are sub-
2 parts of benzyl subunit camphor；
4.5 parts of additive: 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, apple seed extract 2
Part, 1 part of oil-soluble Sodium Hyaluronate；
34 parts of solvent: 19 parts of water, 11 parts of glycerol, 4 parts of butanediol.
The preparation method of the no silicone oil suncream, comprising the following steps:
Step S1: being divided into two parts for the emollient, and sub-fraction therein is mixed with the sun-screening agent, and grinds
Uniformly, the first mixture is obtained；
Step S2: emollient described in another part and the emulsifier being mixed, are heated to 80-85 DEG C, in heating
Stirring is until homogeneously, obtain the second mixture；The solvent is heated to 80-85 DEG C, is heated while stirring until homogeneous；
Step S3: carrying out first mixture and second mixture to be mixed to get third mixture, will be described
Third mixture is added in the solvent by step S2 processing, and temperature is kept for 80-85 DEG C, and starts homogenizer and carry out homogeneous
About 30-40 minutes, obtain the 4th uniform and stable mixture；
Step S4: the 4th mixture is cooled to 60-70 DEG C, and the additive is added thereto, is started again
Homogenizer obtains the 5th mixture after carrying out homogeneous about 10-15 minutes, is stirred continuously until the temperature drop of the 5th mixture
No silicone oil suncream is obtained down to room temperature.
Second embodiment
A kind of no silicone oil suncream is grouped as by the group of following mass parts:
35 parts of emollient: 3 parts of rilanit special dimerized linoleic acid ester, 5 parts of three isostearate of polyglycereol -2-, Ji Wusi
7 parts of alcohol pentaerythritol tetraisostearate, 5 parts of isopropyl isostearate, 4 parts of triethyl group capronate, 5 parts of glycerol three (thylhexoic acid) ester, ten
Three 6 parts of alkanol trimellitates.
1.5 parts of 4 parts: PEG-40 stearate of emulsifier, 1.5 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- Pork and beans
1 part of cool formyl methionine sulfoxide；
13 parts of sun-screening agent: 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 4- methyl are sub-
2 parts of benzyl subunit camphor；
4.5 parts of additive: 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, apple seed extract 2
Part, 1 part of oil-soluble Sodium Hyaluronate；
34 parts of solvent: 19 parts of water, 11 parts of glycerol, 4 parts of butanediol.
In the present embodiment, the preparation method of the no silicone oil suncream is identical with first embodiment.
Third embodiment
A kind of no silicone oil suncream is grouped as by the group of following mass parts:
45 parts of emollient: 2 parts of Butyrospermum parkii fruit rouge, 7 parts of ethylhexyl palmitate, 10 parts of isopropyl myristate, octanoic acid/
4 parts of certain herbaceous plants with big flowers acid glycerol three ester, 7 parts of triethyl group capronate, 9 parts, 6 parts of tridecanol trimellitate of glycerol three (thylhexoic acid) ester；
1.5 parts of 4 parts: PEG-40 stearate of emulsifier, 1.5 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- Pork and beans
1 part of cool formyl methionine sulfoxide；
13 parts of sun-screening agent: 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 4- methyl are sub-
2 parts of benzyl subunit camphor；
4.5 parts of additive: 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, apple seed extract 2
Part, 1 part of oil-soluble Sodium Hyaluronate；
24 parts of solvent: 14 parts of water, 6 parts of glycerol, 4 parts of butanediol.
In the present embodiment, the preparation method of the no silicone oil suncream is identical with first embodiment.
4th embodiment
A kind of no silicone oil suncream is grouped as by the group of following mass parts:
35 parts of emollient: 2 parts of Butyrospermum parkii fruit rouge, 3 parts of ethylhexyl palmitate, 7 parts of isopropyl myristate, octanoic acid/
4 parts of certain herbaceous plants with big flowers acid glycerol three ester, 7 parts of triethyl group capronate, 6 parts, 6 parts of tridecanol trimellitate of glycerol three (thylhexoic acid) ester；
2 parts of 4 parts: PEG-40 stearate of emulsifier, 2 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol；
13 parts of sun-screening agent: 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 4- methyl are sub-
2 parts of benzyl subunit camphor；
4.5 parts of additive: 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, apple seed extract 2
Part, 1 part of oil-soluble Sodium Hyaluronate；
34 parts of solvent: 19 parts of water, 11 parts of glycerol, 4 parts of butanediol.
In the present embodiment, the preparation method of the no silicone oil suncream is identical with first embodiment.
5th embodiment
A kind of no silicone oil suncream is grouped as by the group of following mass parts:
35 parts of emollient: 2 parts of Butyrospermum parkii fruit rouge, 3 parts of ethylhexyl palmitate, 7 parts of isopropyl myristate, octanoic acid/
4 parts of certain herbaceous plants with big flowers acid glycerol three ester, 7 parts of triethyl group capronate, 6 parts, 6 parts of tridecanol trimellitate of glycerol three (thylhexoic acid) ester；
3 parts of 3 parts: N- myristoyl methionine sulfoxide of emulsifier；
13 parts of sun-screening agent: 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 4- methyl are sub-
2 parts of benzyl subunit camphor；
4.5 parts of additive: 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, apple seed extract 2
Part, 1 part of oil-soluble Sodium Hyaluronate；
34 parts of solvent: 19 parts of water, 11 parts of glycerol, 4 parts of butanediol.
In the present embodiment, the preparation method of the no silicone oil suncream is identical with first embodiment.
Comparative example
Certain commercially available silicate-containing oil suncream, composed of the following components:
Emollient: laruyl alcohol methacrylate/Sodium methacrylate cross-linked polymer, dimethyl silicone polymer, xylose
Alcohol, agar, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer；
Emulsifier: polyvinyl alcohol, stearine；
Sun-screening agent: ethylhexyl methoxy cinnamate, Uvinul A Plus；
Additive: Phenoxyethanol, sodium hydroxide, potassium hydroxide, EDETATE SODIUM, (daily) essence, Fructus Citri grandis extract, transparent
Matter acid sodium, citron berry extract, sweet orange berry extract；
Solvent: water, ethyl alcohol, butanediol, propylene glycol.
Stability test
It takes sun-proof without silicone oil suncream and the commercially available silicate-containing oil prepared by first embodiment to the 5th embodiment
Each 240g of frost；Six equal parts are carried out respectively and are fitted into the transparent plastic bottle of 50mL, in 50 DEG C of high temperature, 45 DEG C of high temperature, low temperature -10
DEG C, room temperature, LED light shine, tested under the conditions of high/low temperature circulation (high temperature 45 DEG C with low temperature -10 DEG C) etc. six, every other week
Check steadiness.If homogeneous, then have good stability；If grease is layered, stability is poor.Due in daily life,
The storage temperature of suncream is generally at 0-35 DEG C or so, the low temperature of the rarely possible high temperature and -10 DEG C that can reach 50 DEG C.If by
It after test in one month, has good stability, then can guarantee the lower 1 year stability of routine use state；If by two
After the test of the moon, has good stability, then can guarantee the stability of 2-3 under routine use state.
1 first embodiment stability test result of table
| 50 DEG C of high temperature | 45 DEG C of high temperature | - 10 DEG C of low temperature | Room temperature | LED light is shone | High/low temperature circulation | |
| 1 week | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 2 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 3 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 4 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 6 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 8 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
2 second embodiment stability test result of table
| 50 DEG C of high temperature | 45 DEG C of high temperature | - 10 DEG C of low temperature | Room temperature | LED light is shone | High/low temperature circulation | |
| 1 week | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 2 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 3 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 4 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 6 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 8 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
3 third embodiment stability test result of table
| 50 DEG C of high temperature | 45 DEG C of high temperature | - 10 DEG C of low temperature | Room temperature | LED light is shone | High/low temperature circulation | |
| 1 week | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 2 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 3 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 4 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 6 weeks | Grease layering | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 8 weeks | Grease layering | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
The 4th embodiment stability test result of table 4
| 50 DEG C of high temperature | 45 DEG C of high temperature | - 10 DEG C of low temperature | Room temperature | LED light is shone | High/low temperature circulation | |
| 1 week | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 2 weeks | Grease layering | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 3 weeks | Grease layering | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 4 weeks | Grease layering | Grease layering | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 6 weeks | Grease layering | Grease layering | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 8 weeks | Grease layering | Grease layering | Grease layering | Homogeneously | Homogeneously | Grease layering |
The 5th embodiment stability test result of table 5
| 50 DEG C of high temperature | 45 DEG C of high temperature | - 10 DEG C of low temperature | Room temperature | LED light is shone | High/low temperature circulation | |
| 1 week | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 2 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 3 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 4 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously |
| 6 weeks | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
| 8 weeks | Grease layering | Homogeneously | Homogeneously | Homogeneously | Homogeneously | Grease layering |
6 comparative example stability test result of table
It is from table 1, table 2 and table 6 as can be seen that sun-proof without silicone oil provided by first embodiment of the invention and second embodiment
Frost is still homogeneous system after undergoing bimestrial test, with good stability.The no silicone oil suncream is passing through
It crosses bimestrial test and is able to maintain homogeneous state later, then the no silicone oil suncream can be guaranteed by the daily of 2-3
The case where being still stable, be not in water-oil separating after use.
From table 1, table 2 and table 3 as can be seen that the ratio of the emollient and the solvent is to the no silicone oil suncream cream
The stability of change system has a certain impact.It is the present invention when the no silicone oil suncream is grouped as by the group of following parts by weight
Preferred embodiment: 35 parts of emollient, 4 parts of emulsifier, 13 parts of sun-screening agent, 4.5 parts of additive, 34 parts of solvent.
From table 1, table 4 and table five as can be seen that amino acid type surfactant N- myristoyl methionine sulfoxide and non-
Ionic surfactant PEG-40 stearate, the compounding of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol are anti-to the no silicone oil
The stability for shining frost plays a crucial role.
Sun-proof result test
It takes sun-proof without silicone oil suncream and the commercially available silicate-containing oil prepared by first embodiment and second embodiment
Frost is uniformly applied on the side transparent surface of quartz colorimetric utensil respectively in right amount, makes the surface suncream concentration 8mg/ of cuvette
cm2, then the absorbance within the scope of wavelength 280-380nm is measured using ultraviolet specrophotometer.Absorbance is bigger, sun-proof effect
Fruit is better.Absorbance and the relationship of sun-proof result are shown in Table 7, and test result is shown in Table 8.
Relationship between 7 absorbance of table and sun-proof result
| Absorbance | SPF | Sun-proof result | Use condition |
| 0.5-1.0 | 10 | Minimum sun-proof result | Weak sunlight (sooner or later, indoor) |
| 1.1-1.5 | 10-15 | Medium sun-proof result | Moderate strength illumination (spring, autumn) |
| 1.6-2.0 | 10-30 | Efficient sun-proof result | Moderate strength illumination (spring, autumn) |
| >2.1 | >30 | Complete sun-proof result | Strong illumination (summer is outdoor) |
8 sun-proof result test result of table
From table 7 and table 8 as can be seen that without silicone oil suncream energy provided by first embodiment and second embodiment
UVA and UVB are effectively protected, efficient sun-proof result is reached.
The above content is just an example and description of the concept of the present invention, affiliated those skilled in the art
Various modifications or additions are done to described specific embodiment or are substituted in a similar manner, without departing from hair
Bright design or beyond the scope defined by this claim, is within the scope of protection of the invention.
Claims (10)
1. a kind of no silicone oil suncream is made of following components by following mass parts: 5-15 parts of sun-screening agent, 20-50 parts of emollient,
30-55 parts of solvent, 2-5 parts of emulsifier, 0.2-6 parts of additive；It is characterized in that,
The emollient is that rilanit special dimerized linoleic acid ester, Butyrospermum parkii fruit rouge, ethylhexyl palmitate, myristic acid are different
Propyl ester, octanoic acid/certain herbaceous plants with big flowers acid glycerol three ester, three isostearate of polyglycereol -2-, pentaerythritol tetraoctyl stearate, isostearic acid are different
It is propyl ester, triethyl group capronate, glycerol three (thylhexoic acid) ester, tridecanol trimellitate, any several in seed oil of Moringa oleigera
Combination；
The emulsifier includes amino acid type surfactant and nonionic surface active agent, wherein the amino acid pattern table
Face activating agent is N- certain herbaceous plants with big flowers formyl methionine sulfoxide, N- lauroyl methionine sulfoxide, N- myristoyl methionine sulfoxide, N- palm fibre
Palmitic acid formyl methionine sulfoxide, in any one or any several mixing；The nonionic surface active agent is PEG-40
The mixing of any one or two kinds in stearate, -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol.
2. no silicone oil suncream according to claim 1, which is characterized in that the sun-screening agent includes physical sunscreen agent and change
Learn sun-screening agent, wherein the physical sunscreen agent is nano-titanium dioxide, nano zine oxide, titanium dioxide, any in zinc oxide
The mixing of one or any of several；The chemical sun is benzophenone-3, Octocrilene, octyl methoxycinnamate, butyl
Any one in methoxy dibenzoylmethane, 4- Methylbenzylidene subunit camphor or any several mixing.
3. no silicone oil suncream according to claim 2, which is characterized in that the additive includes preservative, soda acid tune
Save agent, essence and functional component, wherein the preservative is methylparaben, in propylben, tocopherol acetate
Any one or any several mixing；The acid-base modifier is triethanolamine, sodium hydrate aqueous solution, citric acid, sodium carbonate
With any one in sodium citrate or any several mixing；The essence is that bouquet type composition, Fruity type essence and food type are fragrant
Any one in essence or any several mixing；The functional component is allantoin, hydrolytic collagen, saualane, oriental cherry flower mention
Take object, ginseng root extract, calendula extract, apple seed extract, any one in oil-soluble Sodium Hyaluronate or any
Several mixing.
4. according to claim 1 without silicone oil suncream described in any one of -3, which is characterized in that
The solvent is water, glycerol, propylene glycol, butanediol, any one or any several mixing in octanoic acid.
5. no silicone oil suncream according to claim 4, which is characterized in that composed of the following components:
Emollient: Butyrospermum parkii fruit rouge, ethylhexyl palmitate, isopropyl myristate, octanoic acid/certain herbaceous plants with big flowers acid glycerol three ester, three second
Base capronate, glycerol three (thylhexoic acid) ester, tridecanol trimellitate；
Emulsifier: PEG-40 stearate, -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- myristoyl methionine sulfoxide；
Sun-screening agent: nano-titanium dioxide, nano zine oxide, octyl methoxycinnamate, 4- Methylbenzylidene subunit camphor；
Additive: methylparaben, sodium citrate, olive essence, apple seed extract, oil-soluble Sodium Hyaluronate；
Solvent: water, glycerol, butanediol.
6. no silicone oil suncream according to claim 5, which is characterized in that including 35 parts of emollient and 4 parts of emulsifier,
The emollient includes 2 parts of Butyrospermum parkii fruit rouge, 3 parts of ethylhexyl palmitate, 7 parts of isopropyl myristate, octanoic acid/certain herbaceous plants with big flowers
4 parts of acid glycerol three ester, 7 parts of triethyl group capronate, 6 parts, 6 parts of tridecanol trimellitate of glycerol three (thylhexoic acid) ester；
The emulsifier includes 1.5 parts of PEG-40 stearate, 1.5 parts of -8/5/3 glycerol of PEG/PPG/ polytetramethylene glycol, N- Pork and beans
1 part of cool formyl methionine sulfoxide.
7. no silicone oil suncream according to claim 5, which is characterized in that including 13 parts of sun-screening agent, the sun-screening agent packet
Include 6 parts of nano-titanium dioxide, 3 parts of nano zine oxide, 3 parts of octyl methoxycinnamate, 2 parts of camphor of 4- Methylbenzylidene subunit.
8. no silicone oil suncream according to claim 5, which is characterized in that including 4.5 parts of additive, the additive packet
Include 0.3 part of methylparaben, 0.2 part of sodium citrate, 1 part of olive essence, 2 parts of apple seed extract, oil-soluble Sodium Hyaluronate 1
Part.
9. no silicone oil suncream according to claim 5, which is characterized in that including 34 parts of solvent, the solvent includes water
19 parts, 11 parts of glycerol, 4 parts of butanediol.
10. a kind of preparation method of no silicone oil suncream, which comprises the following steps:
Step S1: being divided into two parts for emollient, and sub-fraction therein is mixed with sun-screening agent, and grinds uniformly, obtains the
One mixture；
Step S2: another part emollient and emulsifier being mixed, are heated to 80-85 DEG C, heated while stirring up to homogeneous,
Obtain the second mixture；Solvent is heated to 80-85 DEG C, is heated while stirring until homogeneous；
Step S3: it carries out first mixture and second mixture to be mixed to get third mixture, by the third
Mixture is added in the solvent by step S2 processing, and temperature is kept for 80-85 DEG C, and starts homogenizer and carry out homogeneous about
30-40 minutes, obtain the 4th uniform and stable mixture；Step S4: being cooled to 60-70 DEG C for the 4th mixture, and to
Additive is wherein added, is started after homogenizer carries out homogeneous about 10-15 minutes again and obtains the 5th mixture, be stirred continuously until
The temperature of 5th mixture is reduced to room temperature to obtain no silicone oil suncream.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811506385.3A CN109276482A (en) | 2018-12-10 | 2018-12-10 | Without silicone oil suncream and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811506385.3A CN109276482A (en) | 2018-12-10 | 2018-12-10 | Without silicone oil suncream and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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Family
ID=65174097
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| Country | Link |
|---|---|
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009234933A (en) * | 2008-03-26 | 2009-10-15 | Picaso Cosmetic Laboratory Ltd | Skin external preparation |
| CN102058494A (en) * | 2009-11-18 | 2011-05-18 | 信越化学工业株式会社 | Cosmetic |
| CN107929097A (en) * | 2018-01-03 | 2018-04-20 | 中山市天图精细化工有限公司 | A kind of sun-proof foam aerosol |
| WO2018209382A1 (en) * | 2017-05-17 | 2018-11-22 | Advance NanoTek Ltd. | Sunscreen composition |
-
2018
- 2018-12-10 CN CN201811506385.3A patent/CN109276482A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009234933A (en) * | 2008-03-26 | 2009-10-15 | Picaso Cosmetic Laboratory Ltd | Skin external preparation |
| CN102058494A (en) * | 2009-11-18 | 2011-05-18 | 信越化学工业株式会社 | Cosmetic |
| WO2018209382A1 (en) * | 2017-05-17 | 2018-11-22 | Advance NanoTek Ltd. | Sunscreen composition |
| CN107929097A (en) * | 2018-01-03 | 2018-04-20 | 中山市天图精细化工有限公司 | A kind of sun-proof foam aerosol |
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| Title |
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| 徐良: "防晒化妆品配方技术与市场发展", 《日用化学品科学》 * |
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