CN109260492A - Solid air freshening agent and preparation method thereof - Google Patents
Solid air freshening agent and preparation method thereof Download PDFInfo
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- CN109260492A CN109260492A CN201811137207.8A CN201811137207A CN109260492A CN 109260492 A CN109260492 A CN 109260492A CN 201811137207 A CN201811137207 A CN 201811137207A CN 109260492 A CN109260492 A CN 109260492A
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- Prior art keywords
- mixture
- air freshening
- solid air
- added
- freshening agent
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- 239000007787 solid Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 63
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 238000002845 discoloration Methods 0.000 claims abstract description 39
- 239000000049 pigment Substances 0.000 claims abstract description 39
- 239000002904 solvent Substances 0.000 claims abstract description 37
- 230000002906 microbiologic effect Effects 0.000 claims abstract description 20
- 150000001768 cations Chemical class 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 229920002148 Gellan gum Polymers 0.000 claims description 13
- 239000000216 gellan gum Substances 0.000 claims description 13
- 235000010492 gellan gum Nutrition 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 229920001285 xanthan gum Polymers 0.000 claims description 11
- 239000002386 air freshener Substances 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 10
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 9
- 239000001110 calcium chloride Substances 0.000 claims description 9
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 9
- 239000000230 xanthan gum Substances 0.000 claims description 9
- 235000010493 xanthan gum Nutrition 0.000 claims description 9
- 229940082509 xanthan gum Drugs 0.000 claims description 9
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 8
- 229960002401 calcium lactate Drugs 0.000 claims description 8
- 239000001527 calcium lactate Substances 0.000 claims description 8
- 235000011086 calcium lactate Nutrition 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000003125 aqueous solvent Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 241000206575 Chondrus crispus Species 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 3
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims description 3
- 229920002581 Glucomannan Polymers 0.000 claims description 3
- 229920002752 Konjac Polymers 0.000 claims description 3
- 229940046240 glucomannan Drugs 0.000 claims description 3
- 239000000252 konjac Substances 0.000 claims description 3
- 235000010485 konjac Nutrition 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 239000011540 sensing material Substances 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 241001312219 Amorphophallus konjac Species 0.000 claims 1
- 235000011148 calcium chloride Nutrition 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract description 8
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 239000000843 powder Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000006210 lotion Substances 0.000 description 10
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 9
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 9
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
- 244000251953 Agaricus brunnescens Species 0.000 description 8
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000011049 filling Methods 0.000 description 6
- 229920002690 Polyoxyl 40 HydrogenatedCastorOil Polymers 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229960005069 calcium Drugs 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- -1 polyoxyethylene Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 235000011613 Pinus brutia Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 230000027756 respiratory electron transport chain Effects 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- 244000247812 Amorphophallus rivieri Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- 102000004310 Ion Channels Human genes 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229960002816 potassium chloride Drugs 0.000 description 1
- 239000001521 potassium lactate Substances 0.000 description 1
- 235000011085 potassium lactate Nutrition 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Botany (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses solid air freshening agents and preparation method thereof.Above-mentioned solid air freshening agent, the component including following parts by weight: microbiological gum 0.2%-2%, essence 2%-12%, cation 0.03%-0.5%, heat discoloration pigment 0.5%-3% and balance of solvent；Above-mentioned solid air freshening agent the preparation method comprises the following steps: microbiological gum is added in solvent, be heated to 85 DEG C -100 DEG C, keep the temperature 0.5-1.5 hours, obtain the first mixture；First mixture is cooled to 65 DEG C -75 DEG C, cation is added, stirs evenly, obtains the second mixture；Essence and solubilizer are mixed, are heated to 45 DEG C -55 DEG C, is added in second mixture, obtains third mixture；The third mixture is cooled to 50 DEG C -68 DEG C, heat discoloration pigment is added.Solid air freshening agent of the present invention, color lasting stability, and the various colors presented are colorful.
Description
Technical field
The present invention relates to air freshener technical fields, and in particular to solid air freshening agent and preparation method thereof.
Background technique
Air freshener is also known as " environment perfume ", is current purification air environment, improves the most common method of air quality,
With the continuous improvement of people's quality of life, air freshener has easy to carry, and application method is simple and price is economical etc.
Advantage, thus air freshener is increasingly becoming the necessity of consumer's fashionable life.Air freshener on the market at present, by object
Reason state is broadly divided into liquid type, solid kind and solid absorption class.The flavoring amount of air freshener and specific carrier mass
Can be related, the air freshener of different purposes is produced according to different volatile performances.
The air freshener of solid paste class, can be according to the perfume (or spice) of application demand and different carriers type addition 1%-90%
Essence, it is good that solid paste air freshener holds fragrant effect, and odor type selection is abundant, but comes with some shortcomings in terms of color addition.
First is that color is single, second is that decaying phenomenon, the higher color decay of essence content occur in use for the color of certain products
It is faster, leverage using effect.The phenomenon that in view of color decay, also there are addition antioxidant and sun-screening agent to protect product
Color, but the raw material of certain products plays main influence to the decay of color, and addition protective agent effect is frequently not highly desirable.
Summary of the invention
Based on this, it is necessary to provide a kind of color lasting stabilities by the present invention, and the solid sky that the various colors presented are colorful
Gas freshener.
The present invention there is a need to provide a kind of preparation method of solid air freshening agent.
In order to achieve the object of the present invention, the invention adopts the following technical scheme:
A kind of solid air freshening agent, the component including following parts by weight: microbiological gum 0.2%-2%, essence 2%-
12%, cation 0.03%-0.5%, solubilizer 5%-10%, heat discoloration pigment 0.5%-3% and balance of solvent.
Heat discoloration pigment is added in champignon lotion by above-mentioned solid air freshening agent, makes lotion in specific temperature
Specific color is shown under degree, multiple color can also be combined together, and shows different colors at different temperatures,
So that colourful colour-change phenomena, and color lasting stability, sensory effects are also presented in champignon product while assigning fragrance
It is good, improve the deficiency that existing champignon product can only be presented solid color and color decay may occur.
In some of embodiments, the solid air freshening agent, the component including following parts by weight: microbiological gum
0.5%-1.5%, essence 4%-10%, cation 0.06%-0.1%, solubilizer 5%-10%, heat discoloration pigment 1%-
2% and balance of solvent.
In some of embodiments, the solvent is aqueous solvent.
In some of embodiments, the solid air freshening agent further includes the component of following parts by weight: dispersing agent
And/or defoaming agent.
In some of embodiments, the heat discoloration pigment is made of electron transfer type organic compound system.
In some of embodiments, the heat discoloration pigment is the temperature sensing material of single discoloring temperature；Or, the temperature-sensitive
Camouflage paint is that the material interworking of a variety of discoloring temperatures is formed；Or, the heat discoloration pigment is mutual for the off-color material of Essential colour
With formation.
In some of embodiments, the pH value of the microbiological gum is 5.5-7.5, and the microbiological gum is gellan gum, card
Draw one or more of glue, xanthan gum and konjac glucomannan.
In some of embodiments, the essence is the essence of polar solvent dissolution；The cation is calcium chloride, chlorination
One or more of potassium and calcium lactate.
The present invention also provides a kind of preparation methods of solid air freshening agent should using the solid air freshening agent
Method includes the following steps:
Microbiological gum is added in solvent, is heated to 85 DEG C -100 DEG C, 0.5-1.5 hours is kept the temperature, obtains the first mixture；
First mixture is cooled to 65 DEG C -75 DEG C, cation is added, stirs evenly, obtains the second mixture；
Essence and solubilizer are mixed, are heated to 45 DEG C -55 DEG C, is added in second mixture, third mixing is obtained
Object；
The third mixture is cooled to 50 DEG C -68 DEG C, heat discoloration pigment is added.
When containing dispersing agent in some of embodiments, in the solid air freshening agent, by the dispersing agent and micro- life
Object glue is added in solvent together；When containing defoaming agent in the solid air freshening agent, together with cation by the defoaming agent
It is added in first mixture.
Specific embodiment
It to facilitate the understanding of the present invention, below will be to invention is more fully described.But the present invention can be to be permitted
Mostly different form is realized, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is makes
It is more thorough and comprehensive to the understanding of the disclosure.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The present invention provides a kind of solid air freshening agent, the component including following parts by weight: microbiological gum 0.2%-2%,
More than essence 2%-12%, cation 0.03%-0.5%, solubilizer 5%-10%, heat discoloration pigment 0.5%-3% and solvent
Amount.
Such as microbiological gum 0.2%, 0.4%, 0.5%, 0.8%, 1%, 1.2%, 1.4%, 1.5%, 1.8% and 2%；
Essence 2%, 3%, 4%, 5%, 7%, 8%, 9%, 10%, 11% and 12%；Cation 0.03%, 0.05%, 0.06%,
0.07%, 0.08%, 0.09%, 0.1%, 0.3% and 0.5%；Solubilizer 5%, 6%, 7%, 7.5%, 8%, 9% and
10%；Heat discoloration pigment 0.5%, 0.8%, 1%, 1.2%, 1.5%, 1.8%, 2%, 2.5% and 3%；Solvent 70%,
72%, 73%, 75%, 78% and 80%.
Further, above-mentioned solid air freshening agent, the component including following parts by weight: 0.5%-1.5%, essence
4%-10%, cation 0.06%-0.1%, solubilizer 5%-10%, heat discoloration pigment 1%-2% and balance of solvent.
Such as microbiological gum 0.5%, 0.8%, 1%, 1.2%, 1.4% and 1.5%；Essence 4%, 5%, 7%, 8%,
9% and 10%；Cation 0.06%, 0.07%, 0.08%, 0.09% and 0.1%；Solubilizer 5%, 6%, 7%, 7.5%,
8%, 9% and 10%；Heat discoloration pigment 1%, 1.1%, 1.2%, 1.5%, 1.8%, 1.9% and 2%；Solvent 72%,
73%, 74%, 75%, 76%, 77% and 78%.
In solid air freshening agent, it is typically prepared into aqueous lotion, that is, uses aqueous solvent and aqueous essence.I.e. solvent is adopted
Use aqueous solvent.
Microbiological gum is preferably low acyl group type colloid, and the content of colloid is 80%-100%, and preferably colloidal content is
97.2%-100%；The pH value range of microbiological gum is 5.5-7.5, preferably 6.7-6.9；It is chosen as gellan gum, carragheen, xanthan
One or more of glue and konjac glucomannan.
The effect of essence is mainly assigned fragrant.The preferred hydrophilic essence of polarity essence, flavor of raw material chemical substance polarity are got over
Greatly, hydrophily is better, better with the dissolubility of aqueous solvent, preferably the essence of polar solvent dissolution, such as solvent is DPM
The essence of (dipropylene glycol methyl ether) dissolution.
Cationic main function is to provide ion channel, and microbiological gum body is made to form space network.It is chosen as chlorination
One or more of calcium, potassium chloride and calcium lactate.
Solubilizer is mainly nonionic surface active agent, by essence oily matter solubilising into water-based system.Optional HLB
The surfactant that value is 8~18, preferably HLB value 13~18.Solubilizer is Cremophor RH40, oleic alcohol polyoxyethylene
One or more of ether -20, PEG-40 stearate.
Since aqueous champignon lotion must add the solubilizer of corresponding amount, solubilizer often has biggish shadow to pigment raw material
It rings, this, which imports color to lotion, certain test.However do not influenced by each raw material of champignon lotion using temperature-sensitive camouflage paint,
And all kinds of sensitive pigments may be selected and be presented different colours, color persistently, heat discoloration.
Heat discoloration pigment is prepared by electron transfer type organic compound system, electron transfer type organic compound
Object is a kind of organic chromophoric system with special chemical structure, at a certain temperature because electronics transfer makes the molecule of the organic matter
Structure changes, to realize color transition.This electrochromic substance is not only bright-colored, but also may be implemented to become from coloured
It is colourless and become coloured color change from colourless.
The color change of heat discoloration pigment is reversible, and when temperature reaches specific temperature, shows color；Work as temperature
When degree is reduced or increased, color reverses back is colourless.
Heat discoloration pigment is the reversible temperature-sensitive electrochromic substance of microencapsulation, is commonly called as: warm variable pigments, temperature-sensitive powder or temperature become
Powder.The particle of this pigment is spherical, and average diameter is 2 μm -7 μm.Electrochromic substance inside it, outside be a thickness about
0.2 μm -0.5 μm can neither dissolve the transparent outer cover that will not melt, it protects electrochromic substance from other chemical substances
Erosion.
Heat discoloration pigment is mainly by thermal discoloration type and hot color development type.
Thermal discoloration is in low temperature in colored state, and when temperature rises to setting value, pigment becomes colorless from coloured.It
Discoloring temperature can need to set within the scope of -20 DEG C -80 DEG C according to user.The kind of thermal discoloration type camouflage paint is most, chromatography
It is complete, it is most common camouflage paint series.
The color temperature characteristic and thermal discoloration type of hot color development type are on the contrary, be in colorless state in low temperature, when temperature rises to setting value
When pigment from colourless become coloured, color development temperature range is 60 DEG C -65 DEG C.
Heat discoloration pigment has 15 or so Essential colour because heat discoloration pigment be in procrypsis state it is colourless,
This make different colours, different discoloring temperature, different series camouflage paint between can be with interworking and colorant match, to obtain more
Colourful discoloration effect.And by interworking by a certain percentage between Essential colour, many intermediate colors can be obtained.
The additional amount of heat discoloration pigment has a certain impact to color developing effect, and when being added very little, colour developing degree is not high, is added
When excessive, color can be variant with preparatory color, therefore the additional amount of heat discoloration pigment is between 0.5-3 parts, with other
Ingredient forms certain proportion, adjusts with the adjustment of other compositions.
For example, heat discoloration pigment is the temperature sensing material of single discoloring temperature, color is presented at a temperature of certain, other temperature
It presents colourless.
Alternatively, the material interworking that heat discoloration pigment is a variety of discoloring temperatures is formed, at a certain temperature, show specific
Color, multiple color can be presented in various temperature, so that lotion shows colorful color.
Alternatively, the off-color material interworking that heat discoloration pigment is Essential colour is formed, at a certain temperature, shows user and think
The color wanted.
Above-mentioned solid air freshening agent, further includes other acceptable auxiliary agents, such as dispersing agent 5%-10% and is disappeared
Infusion.Such as dispersing agent 5%, 6%, 7%, 7.5%, 8% and 10%.Dispersing agent can help each substance dispersion in a solvent,
Defoaming agent removes the foam formed in preparation process.
Defoaming agent is preferably methyl silicone oil or polyoxyethyl propyl polyoxyethanyl glycerin ether.
Above-mentioned auxiliary agent further includes opalizer and rotten agent.Opalizer can improve the appearance of lotion, and preservative can extend cream
The service life of body.
Above-mentioned solid air freshening agent the preparation method comprises the following steps:
Microbiological gum is added in solvent, is heated to 85 DEG C -100 DEG C, 0.5-1.5 hours is kept the temperature, obtains the first mixture；
First mixture is cooled to 65 DEG C -75 DEG C, cation is added, stirs evenly, obtains the second mixture；
Essence and solubilizer are mixed, are heated to 45 DEG C -55 DEG C, is added in the second mixture, obtains third mixture；
Third mixture is cooled to 50 DEG C -68 DEG C, heat discoloration pigment is added.
When containing dispersing agent in solid air freshening agent therein, dispersing agent and microbiological gum are added in solvent together；
When containing defoaming agent in solid air freshening agent, defoaming agent and cation are added together in the first mixture.
When containing opalizer and preservative in solid air freshening agent, opalizer, preservative and cation are added together
Enter in the first mixture.
Heat discoloration pigment is added in champignon lotion by above-mentioned solid air freshening agent, makes lotion in specific temperature
Specific color is shown under degree, multiple color can also be combined together, and shows different colors at different temperatures,
So that colourful colour-change phenomena, and color lasting stability, sensory effects are also presented in champignon product while assigning fragrance
It is good, improve the deficiency that existing champignon product can only be presented solid color and color decay may occur.
Hereinafter embodiments of the present invention will be further illustrated by several embodiments.
Embodiment one
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: gellan gum 0.8%, xanthan
Glue 0.2%, polarity essence 5%, Cremophor RH40 6%, dipropylene glycol 10%, calcium chloride 0.06%, Kathon CG 0.1%,
Methyl silicone oil 0.6%, opalizer 0.6%, warm color-change powder 1% and deionized water 75.64%.
Above-mentioned solid air freshening agent the preparation method comprises the following steps: by gellan gum, xanthan gum and dipropylene glycol be added to from
In sub- water, 90 DEG C are heated to, 1 hour is kept the temperature, obtains the first mixture；First mixture is cooled to 70 DEG C, calcium chloride, card is added
Pine, methyl silicone oil and opalizer, stir evenly, obtain the second mixture；By essence mixing Cremophor RH40, heating
To 50 DEG C, it is added in the second mixture, obtains third mixture；Third mixture is cooled to 58 DEG C, warm color-change powder is added, stirs
It mixes uniformly, it is filling.
Embodiment two
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: gellan gum 0.7%, OK a karaoke club
Glue 0.3%, polarity essence 5%, Brij -20 6%, propylene glycol 10%, calcium lactate 0.06%, Kathon CG 0.1%,
Polyoxyethyl propyl polyoxyethanyl glycerin ether 0.6%, opalizer 0.6%, warm color-change powder 1% and deionized water 75.64%.
Above-mentioned solid air freshening agent the preparation method comprises the following steps: gellan gum, carragheen and propylene glycol are added to deionization
In water, 90 DEG C are heated to, 1 hour is kept the temperature, obtains the first mixture；First mixture is cooled to 70 DEG C, calcium lactate, card is added
Pine, polyoxyethyl propyl polyoxyethanyl glycerin ether and opalizer, stir evenly, obtain the second mixture；By essence mixing oleyl alcohol polyoxy second
Alkene ether -20 are heated to 50 DEG C, are added in the second mixture, obtain third mixture；Third mixture is cooled to 58 DEG C, is added
Enter warm color-change powder, stirs evenly, it is filling.
Embodiment three
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: gellan gum 0.5%, OK a karaoke club
Glue 0.3%, xanthan gum 0.2%, polarity essence 5%, PEG-40 stearate 6%, dipropylene glycol 10%, calcium chloride 0.06%,
Kathon CG 0.1%, polyoxyethyl propyl polyoxyethanyl glycerin ether 0.3%, methyl silicone oil 0.3%, opalizer 0.6%, warm color-change powder
1% and deionized water 75.64%.
Above-mentioned solid air freshening agent the preparation method comprises the following steps: by gellan gum, carragheen, xanthan gum and dipropylene glycol be added
Into deionized water, 90 DEG C are heated to, 1 hour is kept the temperature, obtains the first mixture；First mixture is cooled to 70 DEG C, chlorine is added
Change calcium, Kathon CG, polyoxyethyl propyl polyoxyethanyl glycerin ether, methyl silicone oil and opalizer, stirs evenly, obtain the second mixture；
By essence mixing PEG-40 stearate, 50 DEG C are heated to, is added in the second mixture, obtains third mixture；Third is mixed
It closes object and is cooled to 58 DEG C, warm color-change powder is added, stirs evenly, it is filling.
Example IV
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: gellan gum 0.8%, polarity
Essence 8%, Cremophor RH40 5%, PEG-40 stearate 3%, propylene glycol 7%, calcium chloride 0.05%, calcium lactate
0.02%, Kathon CG 0.1%, polyoxyethyl propyl polyoxyethanyl glycerin ether 0.6%, opalizer 0.6%, warm color-change powder 1.2% and go from
Sub- water 73.63%.
Above-mentioned solid air freshening agent the preparation method comprises the following steps: gellan gum and propylene glycol are add to deionized water, add
Heat keeps the temperature 1.5 hours, obtains the first mixture to 85 DEG C；First mixture is cooled to 65 DEG C, calcium chloride, lactic acid, card is added
Pine, polyoxyethyl propyl polyoxyethanyl glycerin ether and opalizer, stir evenly, obtain the second mixture；Essence mixing PEG-40 is hydrogenated
Castor oil, PEG-40 stearate are heated to 45 DEG C, are added in the second mixture, obtain third mixture；By third mixture
50 DEG C are cooled to, warm color-change powder is added, stirs evenly, it is filling.
Embodiment five
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: gellan gum 1%, xanthan gum
0.5%, polarity essence 10%, Cremophor RH40 2%, Brij -20 3%, dipropylene glycol 5%, chlorination
It calcium 0.06%, calcium lactate 0.04%, Kathon CG 0.1%, methyl silicone oil 0.6%, opalizer 0.6%, warm color-change powder 2% and goes
Ionized water 74.2%.Above-mentioned solid air freshening agent the preparation method comprises the following steps: gellan gum, xanthan gum and dipropylene glycol are added to
In deionized water, 95 DEG C are heated to, 0.5 hour is kept the temperature, obtains the first mixture；First mixture is cooled to 75 DEG C, chlorine is added
Change calcium, calcium lactate, Kathon CG, methyl silicone oil and opalizer, stirs evenly, obtain the second mixture；By essence mixing PEG-40
Rilanit special, Brij -20 are heated to 55 DEG C, are added in the second mixture, obtain third mixture；By
Three mixtures are cooled to 68 DEG C, and warm color-change powder is added, stirs evenly, filling.
Embodiment six
The present embodiment provides a kind of solid air freshening agent, the component including following parts by weight: xanthan gum 0.5%, polarity
Essence 4%, PEG-40 stearate 5%, dipropylene glycol 5%, calcium chloride 0.08%, Kathon CG 0.1%, polyoxyethyl propyl polyoxyethanyl
Glycerin ether 0.3%, methyl silicone oil 0.3%, opalizer 0.6%, warm color-change powder 1.5% and deionized water 75.64%.
Above-mentioned solid air freshening agent the preparation method comprises the following steps: xanthan gum and dipropylene glycol are add to deionized water,
92 DEG C are heated to, 1 hour is kept the temperature, obtains the first mixture；First mixture is cooled to 70 DEG C, calcium chloride, Kathon CG, polyoxy is added
Propyl polyoxyethanyl glycerin ether, methyl silicone oil and opalizer, stir evenly, and obtain the second mixture；By essence mixing PEG-
40 stearates are heated to 50 DEG C, are added in the second mixture, obtain third mixture；Third mixture is cooled to 58 DEG C,
Warm color-change powder is added, stirs evenly, it is filling.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of solid air freshening agent, which is characterized in that the component including following parts by weight: microbiological gum 0.2%-2%, perfume (or spice)
Smart 2%-12%, cation 0.03%-0.5%, solubilizer 5%-10%, heat discoloration pigment 0.5%-3% and balance of solvent.
2. solid air freshening agent according to claim 1, which is characterized in that the component including following parts by weight: micro- life
Object glue 0.5%-1.5%, essence 4%-10%, cation 0.06%-0.1%, solubilizer 5%-10%, heat discoloration pigment
1%-2% and balance of solvent.
3. solid air freshening agent according to claim 1 or 2, which is characterized in that the solvent is aqueous solvent.
4. solid air freshening agent according to claim 1 or 2, which is characterized in that further include the component of following parts by weight:
Dispersing agent and/or defoaming agent.
5. solid air freshening agent according to claim 1 or 2, which is characterized in that the heat discoloration pigment is by electronics
Transfevent organic compound objects system is made.
6. solid air freshening agent according to claim 1, which is characterized in that the heat discoloration pigment is single discoloration
The temperature sensing material of temperature；Or, the material interworking that the heat discoloration pigment is a variety of discoloring temperatures is formed；Or, the temperature-sensitive becomes
Color pigment is that the off-color material interworking of Essential colour is formed.
7. solid air freshening agent according to claim 1 or 2, which is characterized in that the pH value of the microbiological gum is
5.5-7.5；The microbiological gum is one or more of gellan gum, carragheen, xanthan gum and konjac glucomannan.
8. solid air freshening agent according to claim 1 or 2, which is characterized in that the essence is polar solvent dissolution
Essence；The cation is one or more of calcium chloride, potassium chloride and calcium lactate.
9. a kind of preparation method of solid air freshening agent, which is characterized in that use the described in any item solids of claim 1-8
Air freshener, this method comprises the following steps:
Microbiological gum is added in solvent, is heated to 85 DEG C -100 DEG C, 0.5-1.5 hours is kept the temperature, obtains the first mixture；
First mixture is cooled to 65 DEG C -75 DEG C, cation is added, stirs evenly, obtains the second mixture；
Essence and solubilizer are mixed, are heated to 45 DEG C -55 DEG C, is added in second mixture, obtains third mixture；
The third mixture is cooled to 50 DEG C -68 DEG C, heat discoloration pigment is added.
10. the preparation method of solid air freshening agent according to claim 9, which is characterized in that the solid air is clear
When containing dispersing agent in new agent, the dispersing agent and microbiological gum are added in solvent together；In the solid air freshening agent
When containing defoaming agent, the defoaming agent and cation are added together in first mixture.
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