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CN109256594A - A kind of reparation liquid using storage battery - Google Patents

A kind of reparation liquid using storage battery Download PDF

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Publication number
CN109256594A
CN109256594A CN201811202340.7A CN201811202340A CN109256594A CN 109256594 A CN109256594 A CN 109256594A CN 201811202340 A CN201811202340 A CN 201811202340A CN 109256594 A CN109256594 A CN 109256594A
Authority
CN
China
Prior art keywords
parts
acid
storage battery
reparation liquid
halogen acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811202340.7A
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Chinese (zh)
Inventor
贾高锋
吕金镯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Yong Ye Environmental Protection Engineering Co Ltd
Original Assignee
Henan Yong Ye Environmental Protection Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Yong Ye Environmental Protection Engineering Co Ltd filed Critical Henan Yong Ye Environmental Protection Engineering Co Ltd
Priority to CN201811202340.7A priority Critical patent/CN109256594A/en
Publication of CN109256594A publication Critical patent/CN109256594A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4242Regeneration of electrolyte or reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of reparation liquid using storage battery, each constituent is formed according to following parts by weight: 2-8 parts of 1-5 parts of 4-8 parts of 11-15 parts of inorganic acid fluid, polyvinyl alcohol, polyethylene glycol, halogen acids, 3-7 parts of polyvinylpyrrolidone part, 17-21 parts of salicylic acid, 3-7 parts of boric acid, 2-6 parts of silica, 3-7 parts of stannous sulfate, 6-10 parts of graphene, 1-5 parts of magnesium sulfate, 21-25 parts of deionized water with oxidisability.The present invention repairs storage battery effect stability, and it is high to repair success rate, qualification rate is repaired using its capacity of the storage battery of the reparation liquid reparation and cycle life repairs qualification rate and can obtain further promotion, long service life, it is at low cost, and Environmental Safety, can be used for repairing it is various scrap storage battery, be suitable for industrialization promotion etc..

Description

A kind of reparation liquid using storage battery
Technical field
The present invention relates to a kind of reparation liquid more particularly to a kind of reparation liquid using storage battery.
Background technique
Storage battery is one kind of battery, is also battery, its working principle is that chemical energy is converted into electric energy.Usual people Described storage battery refers to lead-acid accumulator, i.e., a kind of mainly to do electrode by lead and its oxide, sulfuric acid solution does the storage of electrolyte Battery.The length of service lifetime of accumulator, depends not only on the structure and quality of battery, and with use and safeguard close phase It closes.To in the maintenance of battery, there is also many mistaken ideas, lead to the earlier period damage of battery, should cause our attention.
Battery " irreversible vulcanization " is to result in being greatly lowered for service lifetime of accumulator, and then cause battery It scraps in advance.Lead-acid accumulator scraps reason and is presented with the factor of battery inherent quality, also there is battery application method and occasion Factor, but 80% or more or because lead-acid accumulators itself principle of electrochemical reaction institute extremely.Lead-acid accumulator is can be into The power supply of row charge and discharge reversible reaction, the substance reaction in storage battery is converted to a kind of crystalline solid for being lead sulfate after discharge, Lead sulfate is converted into lead and sulfuric acid again after charging, so reacts reversible.But when reaction condition is not complete and abundant enough, sulfuric acid Lead is impossible to be converted completely, so that the accumulation of lead sulfate is caused, to reduce the amount of material for participating in reaction, instead Reflecting in the output of battery is exactly that battery capacity is fewer and fewer, finally loses its basic charging/discharging function as waste.
Existing storage battery repairing effect is unstable, and it is relatively low to repair success rate.Therefore it provides a kind of repairing using storage battery Multiple liquid, it is unstable can efficiently solve repairing effect, and repair the problems such as success rate is relatively low.
Summary of the invention
To overcome above-mentioned deficiency, the present invention provides a kind of reparation liquid using storage battery.
The present invention takes following technical scheme to realize: a kind of reparation liquid using storage battery, each constituent It is formed according to following parts by weight: 1-5 parts of 4-8 parts of 11-15 parts of inorganic acid fluid, polyvinyl alcohol, polyethylene glycol, hydrogen with oxidisability 2-8 parts of hydracid, 3-7 parts of polyvinylpyrrolidone part, 17-21 parts of salicylic acid, 3-7 parts of boric acid, 2-6 parts of silica, sulfuric acid are sub- 3-7 parts of tin, 6-10 parts of graphene, 1-5 parts of magnesium sulfate, 21-25 parts of deionized water;The relative molecular mass of the polyvinyl alcohol It is 500~2000;The inorganic acid fluid with oxidisability is the mixed solution of hydrogen peroxide and oxalic acid, the pH of the mixed solution For 1.5-2.5;The composition weight of the halogen acids matches: 3-7 parts of hydrofluoric acid, 1 part of hydrobromic acid, 2-4 parts of citric acid;The reparation Liquid the preparation method comprises the following steps: each component is stocked up according to parts by weight respectively, first stirring at normal temperature 30min, heating water bath to 35 DEG C of constant temperature 60min is stirred, is cooled to room temperature and gets product.
Further, its each constituent of the invention is formed according to following parts by weight: the inorganic acid fluid 11 with oxidisability Part, 8 parts of polyvinyl alcohol, 1 part of polyethylene glycol, 8 parts of halogen acids, 3 parts of polyvinylpyrrolidone part, 21 parts of salicylic acid, 3 parts of boric acid, 6 parts of silica, 3 parts of stannous sulfate, 10 parts of graphene, 1 part of magnesium sulfate, 25 parts of deionized water.
Further, its each constituent of the invention is formed according to following parts by weight: the inorganic acid fluid 13 with oxidisability Part, 6 parts of polyvinyl alcohol, 3 parts of polyethylene glycol, 5 parts of halogen acids, 5 parts of polyvinylpyrrolidone part, 19 parts of salicylic acid, 5 parts of boric acid, 4 parts of silica, 5 parts of stannous sulfate, 8 parts of graphene, 3 parts of magnesium sulfate, 23 parts of deionized water.
Further, its each constituent of the invention is formed according to following parts by weight: the inorganic acid fluid 15 with oxidisability Part, 4 parts of polyvinyl alcohol, 5 parts of polyethylene glycol, 2 parts of halogen acids, 7 parts of polyvinylpyrrolidone part, 17 parts of salicylic acid, 7 parts of boric acid, 2 parts of silica, 7 parts of stannous sulfate, 6 parts of graphene, 5 parts of magnesium sulfate, 21 parts of deionized water.
Further, it according to volume ratio is 1 that the inorganic acid fluid of the present invention with oxidisability, which is hydrogen peroxide and oxalic acid: 1.2 mixed solutions prepared.
Further, the composition weight proportion of halogen acids of the present invention: hydrofluoric acid: 5 parts, 1 part of hydrobromic acid, citric acid 3 parts.
In summary the invention has the following advantages: the present invention repairs storage battery effect stability, and success rate height is repaired, Qualification rate is repaired using its capacity of the storage battery of the reparation liquid reparation and cycle life is repaired qualification rate and can be obtained further Promoted, long service life is at low cost, and Environmental Safety, can be used for repairing it is various scrap storage battery, be suitable for industrialization promotion etc..
Specific embodiment
To be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, below with reference to Specific embodiment, the present invention is further explained.
Embodiment 1
A kind of reparation liquid using storage battery, each constituent are formed according to following parts by weight: the nothing with oxidisability 11 parts of machine acid solution, 8 parts of polyvinyl alcohol, 1 part of polyethylene glycol, 8 parts of halogen acids, 3 parts of polyvinylpyrrolidone part, 21 parts of salicylic acid, 3 parts of boric acid, 6 parts of silica, 3 parts of stannous sulfate, 10 parts of graphene, 1 part of magnesium sulfate, 25 parts of deionized water;The poly- second The relative molecular mass of enol is 500~2000;The inorganic acid fluid with oxidisability is molten for the mixing of hydrogen peroxide and oxalic acid Liquid, the pH of the mixed solution are 1.5-2.5;The composition weight of the halogen acids matches: 3-7 parts of hydrofluoric acid, hydrobromic acid 1 Part, 2-4 parts of citric acid;The reparation liquid the preparation method comprises the following steps: each component is stocked up according to parts by weight respectively, first stirring at normal temperature 30min, heating water bath to 35 DEG C of constant temperature stir 60min, are cooled to room temperature and get product.
As priority scheme of the invention, the inorganic acid fluid of the present invention with oxidisability be hydrogen peroxide and oxalic acid according to Volume ratio is 1: 1.2 mixed solution prepared.
As priority scheme of the invention, the composition weight of halogen acids of the present invention is matched: hydrofluoric acid: 5 parts, hydrogen bromine 1 part, 3 parts of citric acid of acid.
Embodiment 2
A kind of reparation liquid using storage battery, each constituent are formed according to following parts by weight: the nothing with oxidisability 13 parts of machine acid solution, 6 parts of polyvinyl alcohol, 3 parts of polyethylene glycol, 5 parts of halogen acids, 5 parts of polyvinylpyrrolidone part, 19 parts of salicylic acid, 5 parts of boric acid, 4 parts of silica, 5 parts of stannous sulfate, 8 parts of graphene, 3 parts of magnesium sulfate, 23 parts of deionized water.
As priority scheme of the invention, the inorganic acid fluid of the present invention with oxidisability be hydrogen peroxide and oxalic acid according to Volume ratio is 1: 1.2 mixed solution prepared.
As priority scheme of the invention, the composition weight of halogen acids of the present invention is matched: hydrofluoric acid: 5 parts, hydrogen bromine 1 part, 3 parts of citric acid of acid.
Embodiment 3
A kind of reparation liquid using storage battery, each constituent are formed according to following parts by weight: the nothing with oxidisability 15 parts of machine acid solution, 4 parts of polyvinyl alcohol, 5 parts of polyethylene glycol, 2 parts of halogen acids, 7 parts of polyvinylpyrrolidone part, 17 parts of salicylic acid, 7 parts of boric acid, 2 parts of silica, 7 parts of stannous sulfate, 6 parts of graphene, 5 parts of magnesium sulfate, 21 parts of deionized water.
As priority scheme of the invention, the inorganic acid fluid of the present invention with oxidisability be hydrogen peroxide and oxalic acid according to Volume ratio is 1: 1.2 mixed solution prepared.
As priority scheme of the invention, the composition weight of halogen acids of the present invention is matched: hydrofluoric acid: 5 parts, hydrogen bromine 1 part, 3 parts of citric acid of acid.
The above is the embodiment of the present invention, therefore all according to the institute of structure, feature and principle described in the present patent application range The equivalent change or modification done, is included in the scope of the patent application of the present invention.

Claims (6)

1. a kind of reparation liquid using storage battery, it is characterised in that: its each constituent is formed according to following parts by weight: having oxygen 11-15 parts of inorganic acid fluid, 4-8 parts of the polyvinyl alcohol, 1-5 parts of polyethylene glycol, 2-8 parts of halogen acids, polyvinylpyrrolidone for the property changed Part 3-7 parts, 17-21 parts of salicylic acid, 3-7 parts of boric acid, 2-6 parts of silica, 3-7 parts of stannous sulfate, 6-10 parts of graphene, sulfuric acid 1-5 parts of magnesium, 21-25 parts of deionized water;The relative molecular mass of the polyvinyl alcohol is 500~2000;It is described that there is oxidation Property inorganic acid fluid be hydrogen peroxide and oxalic acid mixed solution, the pH of the mixed solution is 1.5-2.5;The halogen acids Composition weight proportion: 3-7 parts of hydrofluoric acid, 1 part of hydrobromic acid, 2-4 parts of citric acid;The reparation liquid the preparation method comprises the following steps: by each component It stocks up respectively according to parts by weight, first stirring at normal temperature 30min, heating water bath to 35 DEG C of constant temperature stirs 60min, is cooled to room temperature to obtain the final product Finished product.
2. a kind of reparation liquid using storage battery according to claim 1, it is characterised in that: its each constituent according to Lower parts by weight composition: 8 parts of 1 part of 8 parts of 11 parts of inorganic acid fluid, polyvinyl alcohol, polyethylene glycol, halogen acids, poly- second with oxidisability 3 parts of alkene pyrrolidone part, 21 parts of salicylic acid, 3 parts of boric acid, 6 parts of silica, 3 parts of stannous sulfate, 10 parts of graphene, magnesium sulfate 1 Part, 25 parts of deionized water.
3. a kind of reparation liquid using storage battery according to claim 1, it is characterised in that: its each constituent according to Lower parts by weight composition: 5 parts of 3 parts of 6 parts of 13 parts of inorganic acid fluid, polyvinyl alcohol, polyethylene glycol, halogen acids, poly- second with oxidisability 5 parts of alkene pyrrolidone part, 19 parts of salicylic acid, 5 parts of boric acid, 4 parts of silica, 5 parts of stannous sulfate, 8 parts of graphene, magnesium sulfate 3 Part, 23 parts of deionized water.
4. a kind of reparation liquid using storage battery according to claim 1, it is characterised in that: its each constituent according to Lower parts by weight composition: 2 parts of 5 parts of 4 parts of 15 parts of inorganic acid fluid, polyvinyl alcohol, polyethylene glycol, halogen acids, poly- second with oxidisability 7 parts of alkene pyrrolidone part, 17 parts of salicylic acid, 7 parts of boric acid, 2 parts of silica, 7 parts of stannous sulfate, 6 parts of graphene, magnesium sulfate 5 Part, 21 parts of deionized water.
5. a kind of reparation liquid using storage battery according to claim 1, it is characterised in that: the nothing with oxidisability It is 1: 1.2 mixed solution prepared that machine acid solution, which is hydrogen peroxide and oxalic acid according to volume ratio,.
6. a kind of reparation liquid using storage battery according to claim 1, it is characterised in that: the component of the halogen acids Weight proportion: hydrofluoric acid: 5 parts, 1 part of hydrobromic acid, 3 parts of citric acid.
CN201811202340.7A 2018-10-15 2018-10-15 A kind of reparation liquid using storage battery Pending CN109256594A (en)

Priority Applications (1)

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Publication Number Publication Date
CN109256594A true CN109256594A (en) 2019-01-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112086639A (en) * 2020-08-04 2020-12-15 中国核电工程有限公司 Nuclear power station fixed acid-proof lead-acid storage battery activator and preparation method thereof
CN113437372A (en) * 2021-06-21 2021-09-24 河南润祥能源科技有限公司 Restoration method of retired lead-acid battery, restoration electrolyte and preparation method of restoration electrolyte

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101312262A (en) * 2007-05-25 2008-11-26 北京清大华研科技发展有限公司 Environment-friendly type accumulator rehabilitation liquor manufacture method
US20090311607A1 (en) * 2007-12-25 2009-12-17 Byd Co., Ltd. Battery electrode sheet
CN102082305A (en) * 2010-12-21 2011-06-01 无锡市霄鹰环境科技有限公司 Ionic lead-acid cell repair protection solution
CN107591573A (en) * 2016-07-07 2018-01-16 安徽省宁国倍特瑞蓄能科技有限公司 Lead-acid accumulator repairs liquid and preparation method thereof
CN108110343A (en) * 2017-12-30 2018-06-01 天津华庆百胜能源有限公司 A kind of lead-acid accumulator of environmental protection repairs liquid and its preparation process
CN108183266A (en) * 2017-12-29 2018-06-19 北京峥程环保科技有限公司 The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery
CN108232341A (en) * 2017-12-30 2018-06-29 天津华庆百胜能源有限公司 A kind of lead-acid accumulator neutrality repairs liquid and its preparation process

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101312262A (en) * 2007-05-25 2008-11-26 北京清大华研科技发展有限公司 Environment-friendly type accumulator rehabilitation liquor manufacture method
US20090311607A1 (en) * 2007-12-25 2009-12-17 Byd Co., Ltd. Battery electrode sheet
CN102082305A (en) * 2010-12-21 2011-06-01 无锡市霄鹰环境科技有限公司 Ionic lead-acid cell repair protection solution
CN107591573A (en) * 2016-07-07 2018-01-16 安徽省宁国倍特瑞蓄能科技有限公司 Lead-acid accumulator repairs liquid and preparation method thereof
CN108183266A (en) * 2017-12-29 2018-06-19 北京峥程环保科技有限公司 The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery
CN108110343A (en) * 2017-12-30 2018-06-01 天津华庆百胜能源有限公司 A kind of lead-acid accumulator of environmental protection repairs liquid and its preparation process
CN108232341A (en) * 2017-12-30 2018-06-29 天津华庆百胜能源有限公司 A kind of lead-acid accumulator neutrality repairs liquid and its preparation process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112086639A (en) * 2020-08-04 2020-12-15 中国核电工程有限公司 Nuclear power station fixed acid-proof lead-acid storage battery activator and preparation method thereof
CN112086639B (en) * 2020-08-04 2022-05-20 中国核电工程有限公司 Nuclear power station fixed acid-proof lead acid storage battery activator and preparation method thereof
CN113437372A (en) * 2021-06-21 2021-09-24 河南润祥能源科技有限公司 Restoration method of retired lead-acid battery, restoration electrolyte and preparation method of restoration electrolyte

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Application publication date: 20190122