CN103413977B - A kind of production technology of accumulator - Google Patents
A kind of production technology of accumulator Download PDFInfo
- Publication number
- CN103413977B CN103413977B CN201310388565.7A CN201310388565A CN103413977B CN 103413977 B CN103413977 B CN 103413977B CN 201310388565 A CN201310388565 A CN 201310388565A CN 103413977 B CN103413977 B CN 103413977B
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- Prior art keywords
- hydrocerussitum
- ceruse
- prepared
- plate
- grid
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- Expired - Fee Related
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 38
- 238000005516 engineering process Methods 0.000 title claims abstract description 8
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 claims abstract description 25
- 239000003365 glass fiber Substances 0.000 claims abstract description 12
- 238000005266 casting Methods 0.000 claims abstract description 10
- 239000003094 microcapsule Substances 0.000 claims abstract description 9
- 229920006350 polyacrylonitrile resin Polymers 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 22
- 229910052782 aluminium Inorganic materials 0.000 claims description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
- 239000011505 plaster Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000084 colloidal system Substances 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000006479 redox reaction Methods 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000003723 Smelting Methods 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 238000003801 milling Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 7
- 238000002309 gasification Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses the production technology of a kind of accumulator, specifically include Hydrocerussitum (Ceruse) manufacture, grid casting, diaphragm manufacture, pole plate manufacture, pole plate chemical conversion and assemble operation;In the present invention diaphragm manufacture operation utilize the dividing plate being mixed by glass fibre, the polyacrylonitrile resin of inflatable microcapsule state and PAMC its to produce the accumulator liquid gasification speed obtained low, can effectively reduce the loss of battery liquid, improve the service life of accumulator.
Description
Technical field
The present invention relates to field of battery production, be specifically related to the production technology of a kind of accumulator.
Background technology
At present, conventional accumulator mainly has following three classes:
Conventional accumulators;The pole plate of conventional accumulators is to be made up of plumbous and plumbous oxide, and electrolyte is sulfur aqueous acid;It has the advantages that voltage stabilization, low price;Shortcoming be than can low (i.e. the electric energy of per kilogram accumulators store), service life is short and regular maintenance is frequent.
Dry storage battery: full name dry battery unit lead-acid accumulator, its negative plate that is mainly characterized by has higher charge storage ability, under completely dried state, can preserve obtained electricity in two years, during use, only need to add electrolyte, wait within 20~30 minutes, just can use.
Maintenance-free battery: maintenance-free battery is due to the advantage in self structure, and the consumption of electrolyte is very little, substantially need not supplement distilled water within service life;It also has feature shatter-proof, high temperature resistant, that volume is little, self discharge is little;It is generally the twice of conventional accumulators service life.
Lead-acid accumulator is formed by positive/negative plate, dividing plate, housing, electrolyte and wiring pile are first-class, and the chemical reaction of its electric discharge is dependent on positive plate active substance and positive and negative pole active matter to carry out under the effect of electrolyte.But the imbibition ability that tradition assembles the accumulator median septum prepared is low, and the life-span of accumulator is short.
Summary of the invention
It is an object of the invention to provide the production technology of a kind of accumulator, the accumulator liquid gasification speed that it obtains is low, can effectively reduce the loss of electrolyte, improves the service life of accumulator.
For achieving the above object, the present invention by the following technical solutions: the production technology of a kind of accumulator, specifically include Hydrocerussitum (Ceruse) manufacture, grid casting, diaphragm manufacture, pole plate manufacture, pole plate chemical conversion and assemble operation;
Wherein, Hydrocerussitum (Ceruse) manufacturing process: electrolytic lead is made Hydrocerussitum (Ceruse) in the screening of flour mill internal oxidition stand-by;
Grid casting process: lead, stannum and calloy are cast as grid stand-by;
Pole plate manufacturing process: with dilute sulfuric acid and additive mixing, prepared Hydrocerussitum (Ceruse) is prepared into lead plaster, prepares green plate after then lead plaster is coated on prepared grid surface dry solidification stand-by;
Diaphragm manufacture operation: glass fibre, the polyacrylonitrile resin of inflatable microcapsule state, PAMC are made colloid solution according to adding water after mass ratio 85~90:9~14:1 mixing, then being dried by colloid solution and make dividing plate, glass fiber average diameter used is 1.0~1.2um.
Pole plate formation process: by prepared green plate under the effect of DC source with dilute sulfuric acid generation redox reaction, green plate is carried out after terminating by redox reaction, can be prepared by the positive/negative plate used for battery assembling after drying;
Assemble operation: undertaken the positive/negative plate of preparation, dividing plate, housing, electrolyte and wiring pile crown assembling, weld, rush nitrogen and Mi Kou after can be prepared by finished battery.
The concrete operations of aluminium powder manufacturing process are: undertaken electrolytic lead broken being placed in flour mill and making Hydrocerussitum (Ceruse), then Hydrocerussitum (Ceruse) is carried out oxidation processes, and leady oxide processes after being placed in powder-storage bin to stand Ageing Treatment 2~3d stand-by.
The concrete operations of grid casting process are:
A1: put into respectively in smelting furnace after plumbous, aluminum and kalzium metal are weighed according to the mass ratio of 99.35:0.5:0.15 and carry out melting at 680 DEG C, wherein aluminum in kalzium metal, calcium constituent mass ratio be 1:1.5, melting terminates to add slag-cleaning agent under rear stirring and removes scum silica frost, is then cooled under 450 DEG C of conditions and carries out watering building up ingot;
A2: by ingot through rolling, milling, anneal, cut out process after prepare grid stand-by.
The concrete operations of pole plate manufacturing process are:
B1: prepared aluminium powder and additive are added water and mix, adds sulfuric acid solution and stirs mixing 40min under 65 DEG C of conditions, be subsequently cooled to the lead plaster of room temperature after mixing;
B2: after prepared grid surface one layer of carbon film of spraying, then the lead plaster of the above-mentioned preparation of surface-coated at grid, prepare green plate after lead plaster dry solidification;
Wherein, additive is fiber, and aluminium powder, fiber, water and sulfuric acid solution weigh mixing respectively according to mass ratio 20:0.05:2:2, and the concentration of sulfuric acid solution is 1.25g/ml.
The concrete operations of pole plate formation process are:
C1: green plate is loaded battery case and seals, dilute sulfuric acid is poured in battery case;
C2: undertaken after redox reaction terminates, green plate being carried out, can be prepared by the positive/negative plate used for battery assembling after drying by logical for green plate unidirectional current.
Utilize the accumulator liquid gasification speed that the dividing plate being mixed by glass fibre, the polyacrylonitrile resin of inflatable microcapsule state and PAMC prepares through above-mentioned operation low, can effectively reduce the loss of battery liquid, improve the service life of accumulator.In the present invention, accumulator assembly process is consistent with the battery assembly process operation preparing accumulator in prior art, slag-cleaning agent used and additive are also common product sold on market, those of ordinary skill in the art can according to its in scheme disclosed by the invention role and commercially choose the product with corresponding function and be commercially available.The polyacrylonitrile resin of inflatable microcapsule state refers to that acrylic resin is to be made up of inflatable microcapsule state fine powder body.
Detailed description of the invention
Below by way of specific embodiment, the invention will be further described.
Embodiment 1
Hydrocerussitum (Ceruse) manufacturing process:
Being undertaken electrolytic lead broken being placed in flour mill and making Hydrocerussitum (Ceruse), then Hydrocerussitum (Ceruse) is carried out oxidation processes, leady oxide processes after being placed in powder-storage bin to stand Ageing Treatment 2.5d stand-by.
Diaphragm manufacture operation:
Glass fibre, the polyacrylonitrile resin of inflatable microcapsule state, PAMC being added water after mixing according to mass ratio 88:11:1 and make colloid solution, then dried by colloid solution and make dividing plate, glass fiber average diameter used is 1.1um.
Grid casting process:
A1: put into respectively in smelting furnace after plumbous, aluminum and kalzium metal are weighed according to the mass ratio of 99.35:0.5:0.15 and carry out melting at 680 DEG C, wherein aluminum in kalzium metal, calcium constituent mass ratio be 1:1.5, melting terminates to add slag-cleaning agent under rear stirring and removes scum silica frost, is then cooled under 450 DEG C of conditions and carries out watering building up ingot;
A2: by ingot through rolling, milling, anneal, cut out process after prepare grid stand-by.
Pole plate manufacturing process:
B1: prepared aluminium powder and additive are added water and mix, adds sulfuric acid solution and stirs mixing 40min under 65 DEG C of conditions, be subsequently cooled to the lead plaster of room temperature after mixing;
B2: after prepared grid surface one layer of carbon film of spraying, then the lead plaster of the above-mentioned preparation of surface-coated at grid, prepare green plate after lead plaster dry solidification;
Wherein, additive is fiber, and aluminium powder, fiber, water and sulfuric acid solution weigh mixing respectively according to mass ratio 20:0.05:2:2, and the concentration of sulfuric acid solution is 1.25g/ml.
Pole plate formation process:
C1: green plate is loaded battery case and seals, dilute sulfuric acid is poured in battery case;
C2: undertaken after redox reaction terminates, green plate being carried out, can be prepared by the positive/negative plate used for battery assembling after drying by logical for green plate unidirectional current.
Assemble operation: undertaken the positive/negative plate of preparation, dividing plate, housing, electrolyte and wiring pile crown assembling, weld, rush nitrogen and Mi Kou after can be prepared by finished battery.
Embodiment 2
Hydrocerussitum (Ceruse) manufacturing process:
Being undertaken electrolytic lead broken being placed in flour mill and making Hydrocerussitum (Ceruse), then Hydrocerussitum (Ceruse) is carried out oxidation processes, leady oxide processes after being placed in powder-storage bin to stand Ageing Treatment 2d stand-by.
Diaphragm manufacture operation:
Glass fibre, the polyacrylonitrile resin of inflatable microcapsule state, PAMC being added water after mixing according to mass ratio 85:14:1 and make colloid solution, then dried by colloid solution and make dividing plate, glass fiber average diameter used is 1.0um.
Grid casting process:
A1: put into respectively in smelting furnace after plumbous, aluminum and kalzium metal are weighed according to the mass ratio of 99.35:0.5:0.15 and carry out melting at 680 DEG C, wherein aluminum in kalzium metal, calcium constituent mass ratio be 1:1.5, melting terminates to add slag-cleaning agent under rear stirring and removes scum silica frost, is then cooled under 450 DEG C of conditions and carries out watering building up ingot;
A2: by ingot through rolling, milling, anneal, cut out process after prepare grid stand-by.
Pole plate manufacturing process:
B1: prepared aluminium powder and additive are added water and mix, adds sulfuric acid solution and stirs mixing 40min under 65 DEG C of conditions, be subsequently cooled to the lead plaster of room temperature after mixing;
B2: after prepared grid surface one layer of carbon film of spraying, then the lead plaster of the above-mentioned preparation of surface-coated at grid, prepare green plate after lead plaster dry solidification;
Wherein, additive is fiber, and aluminium powder, fiber, water and sulfuric acid solution weigh mixing respectively according to mass ratio 20:0.05:2:2, and the concentration of sulfuric acid solution is 1.25g/ml.
Pole plate formation process:
C1: green plate is loaded battery case and seals, dilute sulfuric acid is poured in battery case;
C2: undertaken after redox reaction terminates, green plate being carried out, can be prepared by the positive/negative plate used for battery assembling after drying by logical for green plate unidirectional current.
Assemble operation: undertaken the positive/negative plate of preparation, dividing plate, housing, electrolyte and wiring pile crown assembling, weld, rush nitrogen and Mi Kou after can be prepared by finished battery.
Embodiment 3
Hydrocerussitum (Ceruse) manufacturing process:
Being undertaken electrolytic lead broken being placed in flour mill and making Hydrocerussitum (Ceruse), then Hydrocerussitum (Ceruse) is carried out oxidation processes, leady oxide processes after being placed in powder-storage bin to stand Ageing Treatment 3d stand-by.
Diaphragm manufacture operation:
Glass fibre, the polyacrylonitrile resin of inflatable microcapsule state, PAMC being added water after mixing according to mass ratio 90:9:1 and make colloid solution, then dried by colloid solution and make dividing plate, glass fiber average diameter used is 1.2um.
Grid casting process:
A1: put into respectively in smelting furnace after plumbous, aluminum and kalzium metal are weighed according to the mass ratio of 99.35:0.5:0.15 and carry out melting at 680 DEG C, wherein aluminum in kalzium metal, calcium constituent mass ratio be 1:1.5, melting terminates to add slag-cleaning agent under rear stirring and removes scum silica frost, is then cooled under 450 DEG C of conditions and carries out watering building up ingot;
A2: by ingot through rolling, milling, anneal, cut out process after prepare grid stand-by.
Pole plate manufacturing process:
B1: prepared aluminium powder and additive are added water and mix, adds sulfuric acid solution and stirs mixing 40min under 65 DEG C of conditions, be subsequently cooled to the lead plaster of room temperature after mixing;
B2: after prepared grid surface one layer of carbon film of spraying, then the lead plaster of the above-mentioned preparation of surface-coated at grid, prepare green plate after lead plaster dry solidification;
Wherein, additive is fiber, and aluminium powder, fiber, water and sulfuric acid solution weigh mixing respectively according to mass ratio 20:0.05:2:2, and the concentration of sulfuric acid solution is 1.25g/ml.
Pole plate formation process:
C1: green plate is loaded battery case and seals, dilute sulfuric acid is poured in battery case;
C2: undertaken after redox reaction terminates, green plate being carried out, can be prepared by the positive/negative plate used for battery assembling after drying by logical for green plate unidirectional current.
Assemble operation: undertaken the positive/negative plate of preparation, dividing plate, housing, electrolyte and wiring pile crown assembling, weld, rush nitrogen and Mi Kou after can be prepared by finished battery.
In a word, the liquid gasification speed of accumulator prepared by accumulator green production. art provided by the invention is low, can effectively reduce the loss of battery liquid, improves the service life of accumulator.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all any amendment, equivalent replacement and improvement etc. made within the spirit and principles in the present invention, should be included within protection scope of the present invention.
Claims (1)
1. a production technology for accumulator, specifically includes Hydrocerussitum (Ceruse) manufacture, grid casting, diaphragm manufacture, pole plate manufacture, pole plate chemical conversion and assemble operation;
Wherein, Hydrocerussitum (Ceruse) manufacturing process: electrolytic lead is made Hydrocerussitum (Ceruse) in the screening of flour mill internal oxidition stand-by;
Grid casting process: lead, stannum and calloy are cast as grid stand-by;
Pole plate manufacturing process: with dilute sulfuric acid and additive mixing, prepared Hydrocerussitum (Ceruse) is prepared into lead plaster, prepares green plate after then lead plaster is coated on prepared grid surface dry solidification stand-by;
Diaphragm manufacture operation: glass fibre, the polyacrylonitrile resin of inflatable microcapsule state, PAMC are made colloid solution according to adding water after mass ratio 85~90:9~14:1 mixing, then being dried by colloid solution and make dividing plate, glass fiber average diameter used is 1.0~1.2um;
Pole plate formation process: by prepared green plate under the effect of DC source with dilute sulfuric acid generation redox reaction, green plate is carried out after terminating by redox reaction, can be prepared by the positive/negative plate used for battery assembling after drying;
Assemble operation: undertaken the positive/negative plate of preparation, dividing plate, housing, electrolyte and wiring pile crown assembling, weld, rush nitrogen and Mi Kou after can be prepared by finished battery;
The concrete operations of Hydrocerussitum (Ceruse) manufacturing process are: undertaken electrolytic lead broken being placed in flour mill and making Hydrocerussitum (Ceruse), then Hydrocerussitum (Ceruse) is carried out oxidation processes, and leady oxide processes after being placed in powder-storage bin to stand Ageing Treatment 2~3d stand-by;
The concrete operations of grid casting process are:
A1: put into respectively in smelting furnace after plumbous, stannum and kalzium metal are weighed according to the mass ratio of 99.35:0.5:0.15 and carry out melting at 680 DEG C, wherein aluminum in kalzium metal, calcium constituent mass ratio be 1:1.5, melting terminates to add slag-cleaning agent under rear stirring and removes scum silica frost, is then cooled under 450 DEG C of conditions and carries out watering building up ingot;
A2: by ingot through rolling, milling, anneal, cut out process after prepare grid stand-by;
The concrete operations of pole plate manufacturing process are:
B1: prepared Hydrocerussitum (Ceruse) and additive are added water and mix, adds sulfuric acid solution and stirs mixing 40min under 65 DEG C of conditions, be subsequently cooled to room temperature after mixing;
B2: after prepared grid surface one layer of carbon film of spraying, then the lead plaster of the above-mentioned preparation of surface-coated at grid, prepare green plate after lead plaster dry solidification;
Wherein, additive is fiber, and the Hydrocerussitum (Ceruse) of gained, fiber, water and sulfuric acid solution weigh mixing respectively according to mass ratio 20:0.05:2:2, and the concentration of sulfuric acid solution is 1.25g/ml;
The concrete operations of pole plate formation process are:
C1: green plate is loaded battery case and seals, dilute sulfuric acid is poured in battery case;
C2: undertaken after redox reaction terminates, green plate being carried out, can be prepared by the positive/negative plate used for battery assembling after drying by logical for green plate unidirectional current.
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CN104157846B (en) * | 2014-08-07 | 2016-06-08 | 深圳市海涛投资管理有限公司 | A kind of accumulator pole plate structure and production method thereof |
CN107863565A (en) * | 2017-08-30 | 2018-03-30 | 合肥新文远信息技术有限公司 | A kind of production technology of the special lead-acid accumulator of solar energy |
CN107768594A (en) * | 2017-10-19 | 2018-03-06 | 广州倬粤动力新能源有限公司 | A kind of storage battery production technological process |
CN109609881A (en) * | 2018-10-29 | 2019-04-12 | 骆驼集团蓄电池研究院有限公司 | A kind of high intensity battery. g., lead tape and preparation method thereof |
CN110635114B (en) * | 2019-10-30 | 2020-11-17 | 英德奥克莱电源有限公司 | Processing technology of lead-acid storage battery pole plate |
CN112038712A (en) * | 2020-09-11 | 2020-12-04 | 重庆神驰电池有限责任公司 | High-efficiency nano colloid storage battery |
CN114430025A (en) * | 2022-01-26 | 2022-05-03 | 宁夏瑞银铅资源再生有限公司 | Environment-friendly process for preparing high-energy-storage battery plate by using secondary lead |
CN114497927A (en) * | 2022-02-08 | 2022-05-13 | 安徽文达信息工程学院 | Lead-acid storage battery assembly |
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CN1185046A (en) * | 1996-12-13 | 1998-06-17 | 徐恒涛 | Large capacity high starting perfermence lead-acid acumulator |
EP1596448B1 (en) * | 2003-02-18 | 2011-04-13 | Nippon Sheet Glass Company, Limited | Separator for storage battery, storage battery, and method for manufacturing storage battery |
CN101702427B (en) * | 2009-11-23 | 2011-07-20 | 中材科技股份有限公司 | Preparation method of battery diaphragm resisting penetration of lead dendritic crystal |
CN101807723B (en) * | 2010-03-24 | 2015-04-08 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
CN101859901B (en) * | 2010-06-10 | 2012-05-23 | 赵恒祥 | Lead alloy composition for positive plate of lead-acid storage battery and preparation method thereof |
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