CN109233142A - A kind of electroconductive glass fibre cloth and its processing method - Google Patents
A kind of electroconductive glass fibre cloth and its processing method Download PDFInfo
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- CN109233142A CN109233142A CN201810841883.7A CN201810841883A CN109233142A CN 109233142 A CN109233142 A CN 109233142A CN 201810841883 A CN201810841883 A CN 201810841883A CN 109233142 A CN109233142 A CN 109233142A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
- B29B15/14—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of electroconductive glass fibre cloth, it is made of by weight the following raw material: 30-40 parts of glass fabric, 20-30 parts of Corvic, 6-15 parts of epoxy resin, 13-16 parts of hollow quartz fiber, 4-8 parts of carbon nanotube, 15-20 parts of polytetrafluoroethylene (PTFE), 3-7 parts of acetylene black, 3-5 parts of silane coupling agent, 4-5 parts of polyethylene glycol, 0.8-1.5 parts of guar gum, 0.05-0.08 parts of sodium carboxymethyl starch, 12-16 parts of curing agent, 10-15 parts of amino silane, 6-8 parts of ethylene bis stearamide, 4-7 parts of dodecyl sodium sulfate, the present invention selects reasonable raw material and proportion, each raw material synergistic effect, it complements each other, with stronger conduction, acid and alkali-resistance, it is corrosion-resistant, ageing-resistant and impermeable feature, mechanical strength Height increases the service life of product;Processing method is simple, small to equipment requirement, can satisfy the industrial demand of serialization.
Description
Technical field
The present invention relates to glass fibre manufacture field, specifically a kind of electroconductive glass fibre cloth and its processing method.
Background technique
Glass fibre is the inorganic non-metallic material using silica as raw material, and main component includes silica, oxygen
Change aluminium, calcium oxide etc., be processed into finished product by techniques such as melting, wire drawing, woven fabrics, controlled diameter system more than ten micron with
Under;Glass fibre has the characteristics that good insulating, heat resistance are strong, corrosion resistance is good, high mechanical strength, is widely used in compound
Property the industrial circles such as material, insulating materials, thermal insulation material and circuit substrate, but glass fibre existence is crisp and wearability is poor
The characteristics of, excellent insulation performance prevents glass fibre from using in conductive material application field.
Summary of the invention
The purpose of the present invention is to provide a kind of electroconductive glass fibre cloth and its processing methods, to solve above-mentioned background technique
The problem of middle proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
30-40 parts of glass fabric, 20-30 parts of Corvic, 6-15 parts of epoxy resin, hollow quartz fiber 13-
16 parts, 4-8 parts of carbon nanotube, 15-20 parts of polytetrafluoroethylene (PTFE), 3-7 parts of acetylene black, 3-5 parts of silane coupling agent, polyethylene glycol 4-5
Part, 0.8-1.5 parts of guar gum, 0.05-0.08 parts of sodium carboxymethyl starch, 12-16 parts of curing agent, 10-15 parts of amino silane, ethylene
6-8 parts of bis-stearamides, 4-7 parts of dodecyl sodium sulfate.
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
30 parts of glass fabric, 20 parts of Corvic, 6 parts of epoxy resin, 13 parts of hollow quartz fiber, carbon nanotube
4 parts, 15 parts of polytetrafluoroethylene (PTFE), 3 parts of acetylene black, 3 parts of silane coupling agent, 4 parts of polyethylene glycol, 0.8 part of guar gum, carboxymethyl starch
0.05 part of sodium, 12 parts of curing agent, 10 parts of amino silane, 6 parts of ethylene bis stearamide, 4 parts of dodecyl sodium sulfate.
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
40 parts of glass fabric, 30 parts of Corvic, 15 parts of epoxy resin, 16 parts of hollow quartz fiber, carbon nanometer
8 parts of pipe, 20 parts of polytetrafluoroethylene (PTFE), 7 parts of acetylene black, 5 parts of silane coupling agent, 5 parts of polyethylene glycol, 1.5 parts of guar gum, carboxymethyl form sediment
0.08 part of powder sodium, 16 parts of curing agent, 15 parts of amino silane, 8 parts of ethylene bis stearamide, 7 parts of dodecyl sodium sulfate.
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
35 parts of glass fabric, 25 parts of Corvic, 10 parts of epoxy resin, 15 parts of hollow quartz fiber, carbon nanometer
6 parts of pipe, 18 parts of polytetrafluoroethylene (PTFE), 5 parts of acetylene black, 4 parts of silane coupling agent, 4.5 parts of polyethylene glycol, 1.2 parts of guar gum, carboxymethyl
0.06 part of sodium starch, 14 parts of curing agent, 13 parts of amino silane, 7 parts of ethylene bis stearamide, 6 parts of dodecyl sodium sulfate.
A kind of processing method of electroconductive glass fibre cloth, comprising the following steps:
(1) roughening treatment is carried out to glass fabric surface using NaOH solution, wherein NaOH solution concentration 40g/L;Slightly
Change temperature 60 C;Glass fabric taking-up after roughening treatment, is washed till glass fabric table with clear water by coarsening time 30-40min
After face is neutral, by glass fabric, continuous mode enters baking oven, and control oven temperature is 200-300 degrees Celsius, keeps
The speed of 20-30m/min is run, then cooled to room temperature;This roughening condition can make the specific surface area of glass fabric with
Surface-active is increased to improve the caking property between glass fabric matrix and resin layer.
(2) slurry prepare: by Corvic, epoxy resin, hollow quartz fiber, carbon nanotube, polytetrafluoroethylene (PTFE),
Acetylene black, silane coupling agent, polyethylene glycol, guar gum, sodium carboxymethyl starch, curing agent, amino silane, ethylene stearic bicine diester
Amine, dodecyl sodium sulfate are uniformly mixed, and 100 parts of deionized water is added, after mixing evenly, then ultrasound 30 minutes, slurry is made
Material;Glass fibre is arranged in slurry and is impregnated 2-3 hours;
(3) it impregnates: slurry being put into dipping tank, processed glass fabric in step (1) is impregnated into dipping tank,
So that glass fabric is at the uniform velocity passed through dipping tank, is then fed into solidifying pool and solidifies 20-40min, so that glass fibre layer surface is covered
It is stamped resin layer;The glass fabric of completion of cure is sent into baking oven drying, and cooled to room temperature;
(4) it winds, pack: winding the glass fabric that processing is completed to obtain finished product.
Compared with prior art, the beneficial effects of the present invention are:
Glass fabric of the invention, selects reasonable raw material and proportion, and each raw material synergistic effect complements each other, has
Stronger conduction, acid and alkali-resistance, corrosion-resistant, ageing-resistant and impermeable feature, high mechanical strength, increase product uses the longevity
Life;Glass fabric flat appearance produced by the invention, color uniformity can be suitable for well various post-processings and manufacture work
Skill.And processing method is simple, small to equipment requirement, can satisfy the industrial demand of serialization.
Specific embodiment
Embodiment 1
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
30 parts of glass fabric, 20 parts of Corvic, 6 parts of epoxy resin, 13 parts of hollow quartz fiber, carbon nanotube
4 parts, 15 parts of polytetrafluoroethylene (PTFE), 3 parts of acetylene black, 3 parts of silane coupling agent, 4 parts of polyethylene glycol, 0.8 part of guar gum, carboxymethyl starch
0.05 part of sodium, 12 parts of curing agent, 10 parts of amino silane, 6 parts of ethylene bis stearamide, 4 parts of dodecyl sodium sulfate.
A kind of processing method of electroconductive glass fibre cloth, comprising the following steps:
(1) roughening treatment is carried out to glass fabric surface using NaOH solution, wherein NaOH solution concentration 40g/L;Slightly
Change temperature 60 C;Glass fabric taking-up after roughening treatment, is washed till glass fabric table with clear water by coarsening time 30-40min
After face is neutral, by glass fabric, continuous mode enters baking oven, and control oven temperature is 200-300 degrees Celsius, keeps
The speed of 20-30m/min is run, then cooled to room temperature;This roughening condition can make the specific surface area of glass fabric with
Surface-active is increased to improve the caking property between glass fabric matrix and resin layer.
(2) slurry prepare: by Corvic, epoxy resin, hollow quartz fiber, carbon nanotube, polytetrafluoroethylene (PTFE),
Acetylene black, silane coupling agent, polyethylene glycol, guar gum, sodium carboxymethyl starch, curing agent, amino silane, ethylene stearic bicine diester
Amine, dodecyl sodium sulfate are uniformly mixed, and 100 parts of deionized water is added, after mixing evenly, then ultrasound 30 minutes, slurry is made
Material;Glass fibre is arranged in slurry and is impregnated 2-3 hours;
(3) it impregnates: slurry being put into dipping tank, processed glass fabric in step (1) is impregnated into dipping tank,
So that glass fabric is at the uniform velocity passed through dipping tank, is then fed into solidifying pool and solidifies 20-40min, so that glass fibre layer surface is covered
It is stamped resin layer;The glass fabric of completion of cure is sent into baking oven drying, and cooled to room temperature;
(4) it winds, pack: winding the glass fabric that processing is completed to obtain finished product.
Embodiment 2
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
40 parts of glass fabric, 30 parts of Corvic, 15 parts of epoxy resin, 16 parts of hollow quartz fiber, carbon nanometer
8 parts of pipe, 20 parts of polytetrafluoroethylene (PTFE), 7 parts of acetylene black, 5 parts of silane coupling agent, 5 parts of polyethylene glycol, 1.5 parts of guar gum, carboxymethyl form sediment
0.08 part of powder sodium, 16 parts of curing agent, 15 parts of amino silane, 8 parts of ethylene bis stearamide, 7 parts of dodecyl sodium sulfate.
A kind of processing method of electroconductive glass fibre cloth, comprising the following steps:
(1) roughening treatment is carried out to glass fabric surface using NaOH solution, wherein NaOH solution concentration 40g/L;Slightly
Change temperature 60 C;Glass fabric taking-up after roughening treatment, is washed till glass fabric table with clear water by coarsening time 30-40min
After face is neutral, by glass fabric, continuous mode enters baking oven, and control oven temperature is 200-300 degrees Celsius, keeps
The speed of 20-30m/min is run, then cooled to room temperature;This roughening condition can make the specific surface area of glass fabric with
Surface-active is increased to improve the caking property between glass fabric matrix and resin layer.
(2) slurry prepare: by Corvic, epoxy resin, hollow quartz fiber, carbon nanotube, polytetrafluoroethylene (PTFE),
Acetylene black, silane coupling agent, polyethylene glycol, guar gum, sodium carboxymethyl starch, curing agent, amino silane, ethylene stearic bicine diester
Amine, dodecyl sodium sulfate are uniformly mixed, and 100 parts of deionized water is added, after mixing evenly, then ultrasound 30 minutes, slurry is made
Material;Glass fibre is arranged in slurry and is impregnated 2-3 hours;
(3) it impregnates: slurry being put into dipping tank, processed glass fabric in step (1) is impregnated into dipping tank,
So that glass fabric is at the uniform velocity passed through dipping tank, is then fed into solidifying pool and solidifies 20-40min, so that glass fibre layer surface is covered
It is stamped resin layer;The glass fabric of completion of cure is sent into baking oven drying, and cooled to room temperature;
(4) it winds, pack: winding the glass fabric that processing is completed to obtain finished product.
Embodiment 3
A kind of electroconductive glass fibre cloth is made of by weight the following raw material:
35 parts of glass fabric, 25 parts of Corvic, 10 parts of epoxy resin, 15 parts of hollow quartz fiber, carbon nanometer
6 parts of pipe, 18 parts of polytetrafluoroethylene (PTFE), 5 parts of acetylene black, 4 parts of silane coupling agent, 4.5 parts of polyethylene glycol, 1.2 parts of guar gum, carboxymethyl
0.06 part of sodium starch, 14 parts of curing agent, 13 parts of amino silane, 7 parts of ethylene bis stearamide, 6 parts of dodecyl sodium sulfate.
A kind of processing method of electroconductive glass fibre cloth, comprising the following steps:
(1) roughening treatment is carried out to glass fabric surface using NaOH solution, wherein NaOH solution concentration 40g/L;Slightly
Change temperature 60 C;Glass fabric taking-up after roughening treatment, is washed till glass fabric table with clear water by coarsening time 30-40min
After face is neutral, by glass fabric, continuous mode enters baking oven, and control oven temperature is 200-300 degrees Celsius, keeps
The speed of 20-30m/min is run, then cooled to room temperature;This roughening condition can make the specific surface area of glass fabric with
Surface-active is increased to improve the caking property between glass fabric matrix and resin layer.
(2) slurry prepare: by Corvic, epoxy resin, hollow quartz fiber, carbon nanotube, polytetrafluoroethylene (PTFE),
Acetylene black, silane coupling agent, polyethylene glycol, guar gum, sodium carboxymethyl starch, curing agent, amino silane, ethylene stearic bicine diester
Amine, dodecyl sodium sulfate are uniformly mixed, and 100 parts of deionized water is added, after mixing evenly, then ultrasound 30 minutes, slurry is made
Material;Glass fibre is arranged in slurry and is impregnated 2-3 hours;
(3) it impregnates: slurry being put into dipping tank, processed glass fabric in step (1) is impregnated into dipping tank,
So that glass fabric is at the uniform velocity passed through dipping tank, is then fed into solidifying pool and solidifies 20-40min, so that glass fibre layer surface is covered
It is stamped resin layer;The glass fabric of completion of cure is sent into baking oven drying, and cooled to room temperature;
(4) it winds, pack: winding the glass fabric that processing is completed to obtain finished product.
Claims (5)
1. a kind of electroconductive glass fibre cloth, which is characterized in that be made of by weight the following raw material:
30-40 parts of glass fabric, 20-30 parts of Corvic, 6-15 parts of epoxy resin, 13-16 parts of hollow quartz fiber,
4-8 parts of carbon nanotube, 15-20 parts of polytetrafluoroethylene (PTFE), 3-7 parts of acetylene black, 3-5 parts of silane coupling agent, 4-5 parts of polyethylene glycol, melon
You have 0.8-1.5 parts of glue, and 0.05-0.08 parts of sodium carboxymethyl starch, 12-16 parts of curing agent, 10-15 parts of amino silane, ethylene are double hard
6-8 parts of acyl amine, 4-7 parts of dodecyl sodium sulfate.
2. electroconductive glass fibre cloth according to claim 1, which is characterized in that be made of by weight the following raw material:
30 parts of glass fabric, 20 parts of Corvic, 6 parts of epoxy resin, 13 parts of hollow quartz fiber, 4 parts of carbon nanotube,
15 parts of polytetrafluoroethylene (PTFE), 3 parts of acetylene black, 3 parts of silane coupling agent, 4 parts of polyethylene glycol, 0.8 part of guar gum, sodium carboxymethyl starch
0.05 part, 12 parts of curing agent, 10 parts of amino silane, 6 parts of ethylene bis stearamide, 4 parts of dodecyl sodium sulfate.
3. electroconductive glass fibre cloth according to claim 1, which is characterized in that be made of by weight the following raw material:
40 parts of glass fabric, 30 parts of Corvic, 15 parts of epoxy resin, 16 parts of hollow quartz fiber, carbon nanotube 8
Part, 20 parts of polytetrafluoroethylene (PTFE), 7 parts of acetylene black, 5 parts of silane coupling agent, 5 parts of polyethylene glycol, 1.5 parts of guar gum, carboxymethyl starch
0.08 part of sodium, 16 parts of curing agent, 15 parts of amino silane, 8 parts of ethylene bis stearamide, 7 parts of dodecyl sodium sulfate.
4. electroconductive glass fibre cloth according to claim 1, which is characterized in that be made of by weight the following raw material:
35 parts of glass fabric, 25 parts of Corvic, 10 parts of epoxy resin, 15 parts of hollow quartz fiber, carbon nanotube 6
Part, 18 parts of polytetrafluoroethylene (PTFE), 5 parts of acetylene black, 4 parts of silane coupling agent, 4.5 parts of polyethylene glycol, 1.2 parts of guar gum, carboxymethyl form sediment
0.06 part of powder sodium, 14 parts of curing agent, 13 parts of amino silane, 7 parts of ethylene bis stearamide, 6 parts of dodecyl sodium sulfate.
5. a kind of processing method of electroconductive glass fibre cloth, which comprises the following steps:
(1) roughening treatment is carried out to glass fabric surface using NaOH solution, wherein NaOH solution concentration 40g/L;Roughening temperature
60 DEG C of degree;Coarsening time 30-40min, after roughening treatment, glass fabric taking-up, which is washed till glass fabric surface with clear water, is
After neutrality, by glass fabric, continuous mode enters baking oven, and control oven temperature is 200-300 degrees Celsius, keeps 20-
The speed of 30m/min is run, then cooled to room temperature;This roughening condition can make specific surface area and the surface of glass fabric
Activity is increased to improve the caking property between glass fabric matrix and resin layer;
(2) prepared by slurry: by Corvic, epoxy resin, hollow quartz fiber, carbon nanotube, polytetrafluoroethylene (PTFE), acetylene
Black, silane coupling agent, polyethylene glycol, guar gum, sodium carboxymethyl starch, curing agent, amino silane, ethylene bis stearamide, ten
Dialkyl sulfonates are uniformly mixed, and 100 parts of deionized water is added, after mixing evenly, then ultrasound 30 minutes, slurry is made;It will
Glass fibre, which is arranged in slurry, to be impregnated 2-3 hours;
(3) it impregnates: slurry being put into dipping tank, processed glass fabric in step (1) is impregnated into dipping tank, glass is made
Glass fiber cloth at the uniform velocity passes through dipping tank, is then fed into solidifying pool and solidifies 20-40min, so that glass fibre layer surface is covered with
Resin layer;The glass fabric of completion of cure is sent into baking oven drying, and cooled to room temperature;
(4) it winds, pack: winding the glass fabric that processing is completed to obtain finished product.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109777012A (en) * | 2019-01-30 | 2019-05-21 | 中国人民解放军国防科技大学 | Epoxy-based super-hydrophobic fiber reinforced composite material and preparation method thereof |
CN110761506A (en) * | 2019-11-29 | 2020-02-07 | 无锡富仕德高科特材制造有限公司 | Preparation method of glass fiber wall cloth base cloth |
CN115467173A (en) * | 2022-09-20 | 2022-12-13 | 广东硕成科技股份有限公司 | Anti-static surface cloth and preparation method thereof |
CN117344552A (en) * | 2023-10-13 | 2024-01-05 | 广东硕成科技股份有限公司 | High-wear-resistance high-hardness plain cloth, preparation method and application thereof, and preparation method of lamination cushion pad |
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WO2011144010A1 (en) * | 2010-05-18 | 2011-11-24 | 国家纳米科学中心 | Graphene based conductive material and preparation method thereof |
WO2014185330A1 (en) * | 2013-05-15 | 2014-11-20 | 日本写真印刷株式会社 | Transparent conductor |
CN106205862A (en) * | 2016-06-29 | 2016-12-07 | 西安工程大学 | A kind of preparation method of high-temperature electric conduction glass fabric |
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WO2011144010A1 (en) * | 2010-05-18 | 2011-11-24 | 国家纳米科学中心 | Graphene based conductive material and preparation method thereof |
CN101873729A (en) * | 2010-06-07 | 2010-10-27 | 刘忠耀 | Electric heating film and preparation method thereof |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109777012A (en) * | 2019-01-30 | 2019-05-21 | 中国人民解放军国防科技大学 | Epoxy-based super-hydrophobic fiber reinforced composite material and preparation method thereof |
CN109777012B (en) * | 2019-01-30 | 2021-08-13 | 中国人民解放军国防科技大学 | A kind of epoxy-based superhydrophobic fiber-reinforced composite material and preparation method thereof |
CN110761506A (en) * | 2019-11-29 | 2020-02-07 | 无锡富仕德高科特材制造有限公司 | Preparation method of glass fiber wall cloth base cloth |
CN115467173A (en) * | 2022-09-20 | 2022-12-13 | 广东硕成科技股份有限公司 | Anti-static surface cloth and preparation method thereof |
CN115467173B (en) * | 2022-09-20 | 2024-04-30 | 广东硕成科技股份有限公司 | Antistatic electric meter cloth and preparation method thereof |
CN117344552A (en) * | 2023-10-13 | 2024-01-05 | 广东硕成科技股份有限公司 | High-wear-resistance high-hardness plain cloth, preparation method and application thereof, and preparation method of lamination cushion pad |
CN117344552B (en) * | 2023-10-13 | 2024-05-24 | 广东硕成科技股份有限公司 | High-wear-resistance high-hardness plain cloth, preparation method and application thereof, and preparation method of lamination cushion pad |
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Application publication date: 20190118 |