CN109180055A - A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof - Google Patents
A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof Download PDFInfo
- Publication number
- CN109180055A CN109180055A CN201811194032.4A CN201811194032A CN109180055A CN 109180055 A CN109180055 A CN 109180055A CN 201811194032 A CN201811194032 A CN 201811194032A CN 109180055 A CN109180055 A CN 109180055A
- Authority
- CN
- China
- Prior art keywords
- tertiary amine
- grinding aid
- cement grinding
- polyhydroxy tertiary
- polyether polyhydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000003512 tertiary amines Chemical class 0.000 title claims abstract 23
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract 22
- 239000004568 cement Substances 0.000 title claims abstract 21
- 229920000570 polyether Polymers 0.000 title claims abstract 21
- 238000002360 preparation method Methods 0.000 title claims abstract 4
- 229920005906 polyester polyol Polymers 0.000 claims abstract 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract 6
- 150000001875 compounds Chemical class 0.000 claims abstract 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 4
- 241000555268 Dendroides Species 0.000 claims abstract 2
- 125000003368 amide group Chemical group 0.000 claims abstract 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims 4
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 claims 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- 239000004970 Chain extender Substances 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 125000003916 ethylene diamine group Chemical group 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 abstract 1
- 150000002632 lipids Chemical class 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/32—Polyethers, e.g. alkylphenol polyglycolether
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
Abstract
The invention discloses a kind of polyether polyhydroxy tertiary amine cement grinding aids, the branch of main chain and low hydroxyl value polyester polyol including aminated compounds, the main chain and the branch form the polyether polyhydroxy tertiary amine cement grinding aid molecular structure of " pectination " or " dendroid ", active function groups are the synthetic of amido, contain ehter bond in the ether polyhydroxy tertiary amine cement grinding aid molecular structure.The invention also discloses a kind of preparation methods of polyether polyhydroxy tertiary amine cement grinding aid.Polyether polyhydroxy tertiary amine cement grinding aid of the invention is provided with stronger absorption dispersibility and electrostatic screening effect, more powerful to the grinding-aid effect of cement, is better than the substances such as alcohol, hydramine, lipid to the grinding-aid effect of cement.
Description
Technical field
The present invention relates to polyether polyhydroxy tertiary amine cement grinding aid technical fields, specifically, being related to a kind of polyethers polyhydroxy
Base tertiary amine cement grinding aid and preparation method thereof.
Background technique
In order to improve cement grinding, improve production efficiency and what is mixed plays grind -aiding effect and not in cement pulverizing course
The technique additive of damage cement performance is known as grinding aid, and the purpose for adding grinding aid is grindability in order to improve material, subtracts
Adhesive aggregation conglomeration effect between light particle eliminates subparticle paste ball and pastes liner plate phenomenon, improves the mobility of material in grinding machine, from
And realize the target of ball grinder saving energy high yield.
Existing cement, which helps, touches agent by state when using point, can be divided into: solid, liquids and gases grinding aid.Solid
Grinding aid has: stearates, colloidal silicon dioxide, aquadag, carbon black, flyash, gypsum etc.；Liquid grinding aid has: having
Machine silicon, triethanolamine, ethylene glycol；Propylene glycol, polyacrylate, polycarboxylate etc.；Gas grinding aid has: the polar object of vaporous
Matter (acetone, nitromethane, methanol, vapor) and apolar substance (carbon tetrachloride) etc..It can be with by chemical structure grinding aid
It is divided into three classes: polymer-inorganic salt, polymerization organic salt and complex chemical compound.It is very universal in the application of external grinding aid, 95%
Cement mill all uses grinding aid.Some cement plants at home also used grinding aid in the past, such as: triethanolamine, ethylene glycol,
The one kind such as propylene glycol, petroleum acids soda soap chemical plant leftover bits and pieces, but since source shortage, price increase, it deactivates gradually.
Summary of the invention
Gather the first technical problem to be solved by the present invention is: the grinding-aid effect for providing a kind of pair of cement is more powerful
Ether polyhydroxy tertiary amine cement grinding aid.
Second technical problem to be solved by this invention is: providing a kind of above-mentioned polyether polyhydroxy tertiary amine cement grinding aid
Preparation method.
In order to solve the first technical problem mentioned above, the technical scheme is that
Polyether polyhydroxy tertiary amine cement grinding aid, the branch of main chain and low hydroxyl value polyester polyol including aminated compounds, institute
It states main chain and the branch forms the polyether polyhydroxy tertiary amine cement grinding aid molecular structure of " pectination " or " dendroid ", activity
Functional group is the synthetic of amido, contains ehter bond in the ether polyhydroxy tertiary amine cement grinding aid molecular structure.
Preferably, the aminated compounds is polyether polyhydroxy tertiary amine.
Preferably, the aminated compounds further includes diethanol monoisopropanolamine.
Preferably, the low hydroxyl value polyester polyol is benzoic anhydride polyester polyol.
Preferably, the weight of the polyether polyhydroxy tertiary amine, the diethanol monoisopropanolamine, the benzoic anhydride polyester polyol
Amount ratio are as follows:
30~80 parts of polyether polyhydroxy tertiary amine；
0~20 part of diethanol monoisopropanolamine；
10~20 parts of benzoic anhydride polyester polyol.
To solve above-mentioned second technical problem, the technical scheme is that
A kind of above-mentioned polyether polyhydroxy tertiary amine cement grinding aid preparation method, it is characterised in that: the following steps are included:
A, aminated compounds and low hydroxyl value polyester polyol addition water are mixed, is stirred evenly；
B, chain extender, crosslinking agent and catalyst is added, stirs evenly；
C, 80~120 DEG C are heated to and is maintained, is chemically reacted 1~3 hour, polyether polyhydroxy tertiary amine cement grinding aid liquid is generated
Body.
Preferably, the aminated compounds is polyether polyhydroxy tertiary amine or is polyether polyhydroxy tertiary amine and diethanol Dan Yi
The mixture of Propanolamine.
Preferably, the low hydroxyl value polyester polyol is benzoic anhydride polyester polyol.
Preferably, the chain extender is ethylenediamine or N- dihydroxy aniline, and the crosslinking agent is N- methylene bisacrylamide acyl
Amine or divinylbenzene.
Preferably, the catalyst is iron oxide Fe2O3.
By adopting the above-described technical solution, the beneficial effects of the present invention are:
Polyether polyhydroxy tertiary amine cement grinding aid of the invention is a kind of novel cement grinding aid, be chain extender, crosslinking agent,
Under the action of catalyst, using diethanol monoisopropanolamine as main chain, using low hydroxyl value polyester polyol as branch, by artificially dividing
Son design forms the macromolecule new material with " pectination " or " dendroid " molecular structure, contains ehter bond in molecular structure,
Active function groups are the synthetic of amido.It has the advantage that
1, there is stronger absorption dispersibility and electrostatic screening effect, therefore more powerful to the grinding-aid effect of cement, to water
The grinding-aid effect of mud is better than substances such as alcohol, hydramine, lipids.
2, have diethanol monoisopropanolamine to strength of cement value added later strength high-performance.In the base of identical addition content
On plinth, intensity value added reaches 4-10Mpa within 28 days, is higher than diethanol monoisopropanolamine.
3, because of the substances such as polyether polyhydroxy tertiary amine and triethanolamine, diethanol monoisopropanolamine and other alcohol, hydramine, lipid
There is good compatibility, when making cement grinding aid, diethanol monoisopropanolamine can be replaced to be used alone completely, it can also be with
The matching of other substances uses.
4, due to the special construction of strand, there is good compatibility with each Series Admixtures of concrete, can also make
It is directly used for concrete admixture.
Specific embodiment
The polyether polyhydroxy tertiary amine cement grinding aid preparation method of the present embodiment, main chain and low hydroxyl including aminated compounds
It is worth the branch of polyester polyol, the polyether polyhydroxy tertiary amine cement that main chain and the branch form " pectination " or " dendroid " helps
Grinding agent molecular structure, active function groups are the synthetic of amido, contain ether in ether polyhydroxy tertiary amine cement grinding aid molecular structure
Key.
Aminated compounds is polyether polyhydroxy tertiary amine.
Aminated compounds further includes diethanol monoisopropanolamine.
Low hydroxyl value polyester polyol is benzoic anhydride polyester polyol.
The weight ratio of polyether polyhydroxy tertiary amine, diethanol monoisopropanolamine, benzoic anhydride polyester polyol are as follows:
30~80 parts of polyether polyhydroxy tertiary amine；
0~20 part of diethanol monoisopropanolamine；
10~20 parts of benzoic anhydride polyester polyol.
Above-mentioned polyether polyhydroxy tertiary amine cement grinding aid can be made by following preparation method, and preparation method includes following step
It is rapid:
A, aminated compounds and low hydroxyl value polyester polyol addition water are mixed, is stirred evenly；
B, chain extender, crosslinking agent and catalyst is added, stirs evenly；
C, 80~120 DEG C are heated to and is maintained, is chemically reacted 1~3 hour, polyether polyhydroxy tertiary amine cement grinding aid liquid is generated
Body.
Wherein, aminated compounds can be used polyether polyhydroxy tertiary amine or be polyether polyhydroxy tertiary amine and diethanol list isopropyl
The mixture of hydramine.
Benzoic anhydride polyester polyol can be used in low hydroxyl value polyester polyol.
Ethylenediamine or N- dihydroxy aniline etc. can be used in chain extender, and N- methylene-bisacrylamide or two can be used in crosslinking agent
Vinyl benzene etc..
Iron oxide Fe2O3 etc. can be used in catalyst.
Polyether polyhydroxy tertiary amine cement grinding aid of the invention is a kind of novel cement grinding aid, is in chain extender, hands over
Under the action of joining agent, catalyst, pass through using diethanol monoisopropanolamine as main chain using low hydroxyl value polyester polyol as branch
Artificial MOLECULE DESIGN forms the macromolecule new material with " pectination " or " dendroid " molecular structure, contains in molecular structure
Ehter bond, active function groups are the synthetic of amido.It is more powerful to the grinding-aid effect of cement, the grinding-aid effect of cement is better than
The substances such as alcohol, hydramine, lipid.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. polyether polyhydroxy tertiary amine cement grinding aid, it is characterised in that: main chain and low hydroxyl value polyester including aminated compounds are more
The branch of first alcohol, the main chain and the branch form the polyether polyhydroxy tertiary amine cement grinding aid of " pectination " or " dendroid "
Molecular structure, active function groups are the synthetic of amido, contain ether in the ether polyhydroxy tertiary amine cement grinding aid molecular structure
Key.
2. polyether polyhydroxy tertiary amine cement grinding aid as described in claim 1, it is characterised in that: the aminated compounds is poly-
Ether polyhydroxy tertiary amine.
3. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 2, it is characterised in that: the aminated compounds also wraps
Include diethanol monoisopropanolamine.
4. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 3, it is characterised in that: the low hydroxyl value polyester polyols
Alcohol is benzoic anhydride polyester polyol.
5. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 3, it is characterised in that: the polyether polyhydroxy uncle
The weight ratio of amine, the diethanol monoisopropanolamine, the benzoic anhydride polyester polyol are as follows:
30~80 parts of polyether polyhydroxy tertiary amine；
0~20 part of diethanol monoisopropanolamine；
10~20 parts of benzoic anhydride polyester polyol.
6. a kind of polyether polyhydroxy tertiary amine cement grinding aid preparation method described in any one of claim 1 to 5, feature exist
In: the following steps are included:
A, aminated compounds and low hydroxyl value polyester polyol addition water are mixed, is stirred evenly；
B, chain extender, crosslinking agent and catalyst is added, stirs evenly；
C, 80~120 DEG C are heated to and is maintained, is chemically reacted 1~3 hour, polyether polyhydroxy tertiary amine cement grinding aid liquid is generated
Body.
7. polyether polyhydroxy tertiary amine cement grinding aid preparation method as claimed in claim 6, it is characterised in that: the amine
Close object be polyether polyhydroxy tertiary amine or be polyether polyhydroxy tertiary amine and diethanol monoisopropanolamine mixture.
8. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 7, it is characterised in that: the low hydroxyl value polyester polyols
Alcohol is benzoic anhydride polyester polyol.
9. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 7, it is characterised in that: the chain extender is ethylenediamine
Or N- dihydroxy aniline, the crosslinking agent are N- methylene-bisacrylamide or divinylbenzene.
10. polyether polyhydroxy tertiary amine cement grinding aid as claimed in claim 7, it is characterised in that: the catalyst is oxidation
Iron Fe2O3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811194032.4A CN109180055A (en) | 2018-10-15 | 2018-10-15 | A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811194032.4A CN109180055A (en) | 2018-10-15 | 2018-10-15 | A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109180055A true CN109180055A (en) | 2019-01-11 |
Family
ID=64944815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811194032.4A Pending CN109180055A (en) | 2018-10-15 | 2018-10-15 | A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109180055A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102159609A (en) * | 2009-06-29 | 2011-08-17 | Dic株式会社 | Two-pack urethane resin composite for use in an abrasive pad, polyurethane abrasive pad, and method for manufacturing a polyurethane abrasive pad |
| CN103819623A (en) * | 2014-02-12 | 2014-05-28 | 科之杰新材料集团有限公司 | Preparation method for cement auxiliary-grinding strengthener of polyethylene glycol amine ester carboxylic acid system |
| CN104446112A (en) * | 2014-11-18 | 2015-03-25 | 桂林华越环保科技有限公司 | Polyether composite cement grinding aid |
| CN104529229A (en) * | 2014-12-11 | 2015-04-22 | 山东宏艺科技股份有限公司 | Enhanced cement grinding aid |
| CN105271918A (en) * | 2015-11-06 | 2016-01-27 | 吴金文 | Cement grinding aid and preparation method thereof |
| CN108218286A (en) * | 2018-02-27 | 2018-06-29 | 铜仁学院 | A kind of cement grinding aid and preparation method thereof |
| CN110498927A (en) * | 2018-05-17 | 2019-11-26 | 山东鑫圭新材料科技有限公司 | A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof |
-
2018
- 2018-10-15 CN CN201811194032.4A patent/CN109180055A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102159609A (en) * | 2009-06-29 | 2011-08-17 | Dic株式会社 | Two-pack urethane resin composite for use in an abrasive pad, polyurethane abrasive pad, and method for manufacturing a polyurethane abrasive pad |
| CN103819623A (en) * | 2014-02-12 | 2014-05-28 | 科之杰新材料集团有限公司 | Preparation method for cement auxiliary-grinding strengthener of polyethylene glycol amine ester carboxylic acid system |
| CN104446112A (en) * | 2014-11-18 | 2015-03-25 | 桂林华越环保科技有限公司 | Polyether composite cement grinding aid |
| CN104529229A (en) * | 2014-12-11 | 2015-04-22 | 山东宏艺科技股份有限公司 | Enhanced cement grinding aid |
| CN105271918A (en) * | 2015-11-06 | 2016-01-27 | 吴金文 | Cement grinding aid and preparation method thereof |
| CN108218286A (en) * | 2018-02-27 | 2018-06-29 | 铜仁学院 | A kind of cement grinding aid and preparation method thereof |
| CN110498927A (en) * | 2018-05-17 | 2019-11-26 | 山东鑫圭新材料科技有限公司 | A kind of polyether polyhydroxy tertiary amine cement grinding aid and preparation method thereof |
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Application publication date: 20190111 |