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CN109133858A - A kind of blackspot blue chun glaze and the method for preparing pottery using it - Google Patents

A kind of blackspot blue chun glaze and the method for preparing pottery using it Download PDF

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Publication number
CN109133858A
CN109133858A CN201811116882.2A CN201811116882A CN109133858A CN 109133858 A CN109133858 A CN 109133858A CN 201811116882 A CN201811116882 A CN 201811116882A CN 109133858 A CN109133858 A CN 109133858A
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Prior art keywords
parts
glaze
blackspot
blue
slurry
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Pending
Application number
CN201811116882.2A
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Inventor
杨珊珊
帅强
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Henan Junyi Lighting Lighting Co Ltd
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Henan Junyi Lighting Lighting Co Ltd
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Priority to CN201811116882.2A priority Critical patent/CN109133858A/en
Publication of CN109133858A publication Critical patent/CN109133858A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • C03C1/06Opacifiers, e.g. fluorides or phosphates; Pigments to produce non-uniformly pigmented, e.g. speckled, marbled, or veined products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/16Lean materials, e.g. grog, quartz
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Vascular Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The present invention relates to a kind of blackspot blue chun glaze and the methods for preparing pottery using it, blackspot copper red color chun glaze, including glaze outside glaze in copper red color and blackspot, glaze is made of the raw material of following weight ratio in the copper red color: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 parts of titanium ores, 9 parts of iron ores, 2 parts of yellow cash and 12 parts of Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of graphite sheets, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores;Carcass raw material is crushed into plasticity and fires modeling tire, then tire will be moulded and immerse glazing in the slurry of glaze in copper red color, slurry wait mould glaze in tire surface attachment copper red color is dipped in glazing in the slurry of glaze outside blackspot after drying again, slurry wait mould glaze outside tire surface attachment blackspot is put into kiln after drying and fires to get blackspot copper red color pottery.

Description

A kind of blackspot blue chun glaze and the method for preparing pottery using it
Technical field
The side of pottery is prepared the invention belongs to pottery technical field more particularly to a kind of blackspot blue chun glaze and using it Method.
Background technique
Pottery category northern celadon system.Chinese celadon is with a long history, Tang Yiqian, and celadon is always the mainstream of Production of Ceramics. Pottery is different from other porcelain kinds with its unique natural transmutation art, and the transmutation phenomenon of " enter kiln is of the same colour, kiln discharge ten thousand is color " constitutes an ancient unit of weight The special aesthetic feeling and artistic effect of porcelain have very high artistic charm.As soon as it comes out, valued by common people, and enters name Among kiln ranks.The outstanding technique achievement of an ancient unit of weight kiln, is reasonably controlled in sintering process on the basis of science prepares tire, glaze The variation of flame atmosphere is become deep mixed transmutation color by same glaze glaze colours using oxidation and reducing atmosphere.
Pottery in the production process, from sorting to finished product is fired, during which at least wants ten processes, typically burns raw material Modeling tire is made, then glazing is sintered again on plain tire, finally obtains pottery product, and the pottery finished product quality produced is tight It is close, any surface finish, or even occur lines in sintering procedure, ornamental value is enhanced, but this is often appeared in sintering procedure The drawbacks of, high temperature leads to glaze paint damage and crack, this needs the control of low-priceder accurately temperature, it has taken difficulty to firing, main cause It is that ingredient thermal shock resistance in glaze is reported to the leadship after accomplishing a task, if temperature is unstable under high temperature environment, mutation will lead to volume increasing Greatly, it cracks, and finds that graphite powder has good thermal shock resistance and lubricity, can not only be perfectly combined with former glaze, Also it can enhance the thermal shock resistance in sintering procedure.
Summary of the invention
In view of the deficiencies of the prior art, a kind of method which provides blackspot blue chun glaze and prepare pottery using it, Chun glaze is divided into interior glaze and outer glaze, the glazing twice on plain tire, wherein graphite powder is added in the raw material of outer glaze, due to graphite powder With very high thermal shock resistance, it can guarantee pottery Surface Creation blackspot that is cracked in sintering procedure, and firing, add Its big ornamental value.
To achieve the goals above, which provides a kind of blackspot blue chun glaze, including glaze, institute outside glaze and blackspot in blue It states glaze in blue to be made of the raw material of following weight ratio: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 Part titanium ore, 9 parts of iron ores, 2 parts of yellow cash and 12 parts of Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of graphite sheets, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores.
As the method that blackspot blue chun glaze of the present invention prepares pottery, carcass raw material is crushed into plasticity first and fires modeling Then tire will mould tire and immerse glazing in the slurry of glaze in blue, the slurry wait mould glaze in tire surface attachment blue again will after drying Glazing in its slurry for immersing the outer glaze of blackspot, the slurry wait mould glaze outside tire surface attachment blackspot are put into kiln after drying and fire, Up to blackspot blue pottery.
The further improvements in methods of pottery are prepared as blackspot blue chun glaze of the present invention: the following weight of carcass raw material The raw material of ratio forms: the western temple soil of 50 ~ 60 parts of mind Hou, 20 ~ 25 parts of quartz sands and 20 ~ 25 parts of lime stones.
The further improvements in methods of pottery are prepared as blackspot blue chun glaze of the present invention: the carcass raw material according to The weight ratio of the sub- 1:1.2:1.2 of water, ball milling, which is added in ball mill, to be ground, then carries out modeling tire.
The further improvements in methods of pottery are prepared as blackspot blue chun glaze of the present invention: the slurry of glaze is in the blue Glaze, water, ball milling are added to according to the weight ratio of 1:1:1.2 in blue ground in ball mill made of.
The further improvements in methods of pottery are prepared as blackspot blue chun glaze of the present invention: the slurry of glaze is outside the blackspot The outer glaze of blackspot, water, ball milling are added to made of grinding in ball mill according to the weight ratio of 1:1.4:1.2.
Prepare the further improvements in methods of pottery as blackspot blue chun glaze of the present invention: the density of the graphite sheet is 1.07g/cm3。
Beneficial effect
A kind of blackspot blue chun glaze of the invention, is divided into interior glaze and outer glaze for chun glaze, applies interior glaze and outer glaze backward on plain tire, wherein Glaze paint of the interior glaze to generate blue, and stone is also added in the raw material of outer glaze other than containing the raw material to generate blue glaze paint Ink powder, graphite powder have good lubricity and thermal shock resistance, can not only melt with the raw material perfection to generate blue glaze paint It closes, and increases whole thermal shock resistance, will not be cracked during firing, but graphite blackspot is generated, increase an ancient unit of weight The ornamental value of porcelain entirety.
Specific embodiment
Further technical solution of the present invention is illustrated below in conjunction with specific embodiment.
Embodiment 1
A kind of blackspot blue chun glaze includes glaze and the outer glaze of blackspot in blue, in the blue glaze by following weight ratio raw material group At: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 parts of titanium ores, 9 parts of iron ores, 2 parts of yellow cash and 12 parts Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of graphite sheets, 15 parts of white length Stone, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores.
The method that blackspot blue chun glaze prepares pottery: crushing plasticity for carcass raw material first and fire modeling tire, then will modeling Tire immerses glazing in the slurry of glaze in blue, and the slurry wait mould glaze in tire surface attachment blue is dipped in outside blackspot again after drying Glazing in the slurry of glaze, the slurry wait mould glaze outside tire surface attachment blackspot are put into kiln after drying and fire to get blackspot blue Pottery.
Wherein the raw material of the following weight ratio of carcass raw material forms: the western temple soil of 55 parts of mind Hou, 22 parts of quartz sands and 23 Part lime stone;Carcass raw material is added in ball mill according to the weight ratio with water, the sub- 1:1.2:1.2 of ball milling and grinds, then is moulded Tire;And the slurry of glaze is that glaze in blue, water, ball milling are added in ball mill according to the weight ratio of 1:1:1.2 and grind in blue Made of system;The slurry of the outer glaze of blackspot is that blackspot outer glaze, water, ball milling according to the weight ratio of 1:1.4:1.2 are added to ball mill In grind made of;The density for the graphite sheet selected simultaneously is 1.07g/cm3.
Embodiment 2
A kind of blackspot blue chun glaze includes glaze and the outer glaze of blackspot in blue, in the blue glaze by following weight ratio raw material group At: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 parts of titanium ores, 9 parts of iron ores, 2 parts of yellow cash and 12 parts Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of graphite sheets, 15 parts of white length Stone, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores.
The method that blackspot blue chun glaze prepares pottery: crushing plasticity for carcass raw material first and fire modeling tire, then will modeling Tire immerses glazing in the slurry of glaze in blue, and the slurry wait mould glaze in tire surface attachment blue is dipped in outside blackspot again after drying Glazing in the slurry of glaze, the slurry wait mould glaze outside tire surface attachment blackspot are put into kiln after drying and fire to get blackspot blue Pottery.
Wherein the raw material of the following weight ratio of carcass raw material forms: the western temple soil of 50 parts of mind Hou, 25 parts of quartz sands and 25 Part lime stone;Carcass raw material is added in ball mill according to the weight ratio with water, the sub- 1:1.2:1.2 of ball milling and grinds, then is moulded Tire;And the slurry of glaze is that glaze in blue, water, ball milling are added in ball mill according to the weight ratio of 1:1:1.2 and grind in blue Made of system;The slurry of the outer glaze of blackspot is that blackspot outer glaze, water, ball milling according to the weight ratio of 1:1.4:1.2 are added to ball mill In grind made of;The density for the graphite sheet selected simultaneously is 1.07g/cm3.
Embodiment 3
A kind of blackspot blue chun glaze includes glaze and the outer glaze of blackspot in blue, in the blue glaze by following weight ratio raw material group At: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 parts of titanium ores, 9 parts of iron ores, 2 parts of yellow cash and 12 parts Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of graphite sheets, 15 parts of white length Stone, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores.
The method that blackspot blue chun glaze prepares pottery: crushing plasticity for carcass raw material first and fire modeling tire, then will modeling Tire immerses glazing in the slurry of glaze in blue, and the slurry wait mould glaze in tire surface attachment blue is dipped in outside blackspot again after drying Glazing in the slurry of glaze, the slurry wait mould glaze outside tire surface attachment blackspot are put into kiln after drying and fire to get blackspot blue Pottery.
Wherein the raw material of the following weight ratio of carcass raw material forms: the western temple soil of 60 parts of mind Hou, 20 parts of quartz sands and 20 Part lime stone;Carcass raw material is added in ball mill according to the weight ratio with water, the sub- 1:1.2:1.2 of ball milling and grinds, then is moulded Tire;And the slurry of glaze is that glaze in blue, water, ball milling are added in ball mill according to the weight ratio of 1:1:1.2 and grind in blue Made of system;The slurry of the outer glaze of blackspot is that blackspot outer glaze, water, ball milling according to the weight ratio of 1:1.4:1.2 are added to ball mill In grind made of;The density for the graphite sheet selected simultaneously is 1.07g/cm3.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though So the present invention has been disclosed as a preferred embodiment, and however, it is not intended to limit the invention, any technology people for being familiar with this profession Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification It is right according to the technical essence of the invention for the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention Any simple modification, equivalent change and modification made by above embodiments, all of which are still within the scope of the technical scheme of the invention.

Claims (7)

1. a kind of blackspot blue chun glaze, it is characterised in that: including glaze outside glaze in blue and blackspot, glaze is by following heavy in the blue The raw material of amount ratio forms: 40 parts of melilites, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites, 7 parts of titanium ores, 9 parts of iron ores Stone, 2 parts of yellow cash and 12 parts of Copper Ores;The outer glaze of the blackspot is made of the raw material of following weight ratio: 40 parts of melilites, 20 parts of stones Black plate, 15 parts of white feldspars, 10 parts of quartz, 8 parts of calcites and 7 parts of titanium ores.
2. the method that blackspot blue chun glaze prepares pottery according to claim 1, it is characterised in that: first by carcass raw material powder Broken plasticity simultaneously fires modeling tire, then will mould tire and immerses glazing in the slurry of glaze in blue, glaze in attachment blue in tire surface to be moulded Slurry is dipped in glazing in the slurry of the outer glaze of blackspot again after drying, the slurry wait mould glaze outside tire surface attachment blackspot will after drying It is put into kiln and fires to get blackspot blue pottery.
3. the method that blackspot blue chun glaze prepares pottery according to claim 2, it is characterised in that: below the carcass raw material The raw material of weight ratio forms: the western temple soil of 50 ~ 60 parts of mind Hou, 20 ~ 25 parts of quartz sands and 20 ~ 25 parts of lime stones.
4. the method that blackspot blue chun glaze prepares pottery according to claim 2, it is characterised in that: the carcass raw material according to It is added in ball mill and grinds with the weight ratio of water, the sub- 1:1.2:1.2 of ball milling, then carry out modeling tire.
5. the method that blackspot blue chun glaze prepares pottery according to claim 2, it is characterised in that: the material of the blue chun glaze Slurry is that blue chun glaze, water, ball milling are added to made of grinding in ball mill according to the weight ratio of 1:1:1.2.
6. the method that blackspot blue chun glaze prepares pottery according to claim 2, it is characterised in that: the material of the outer glaze of the blackspot Slurry is that glaze, water, ball milling are added to made of grinding in ball mill blackspot according to the weight ratio of 1:1.4:1.2 outside.
7. the method that blackspot blue chun glaze prepares pottery according to claim 2, it is characterised in that: the graphite sheet it is close Degree is 1.07g/cm3.
CN201811116882.2A 2018-09-25 2018-09-25 A kind of blackspot blue chun glaze and the method for preparing pottery using it Pending CN109133858A (en)

Priority Applications (1)

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Publication number Priority date Publication date Assignee Title
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CN106116152A (en) * 2016-06-30 2016-11-16 安徽省德邦瓷业有限公司 A kind of ceramic utensil glaze and preparation method thereof
CN106316123A (en) * 2016-08-18 2017-01-11 温书强 Compound blue-bottom red-spot jun porcelain glaze material
CN106396408A (en) * 2016-08-31 2017-02-15 福建省德化佳诚陶瓷有限公司 Antiqued copper craft ceramic and manufacturing process thereof
CN107673618A (en) * 2017-11-02 2018-02-09 禹州市华盛钧窑有限公司 A kind of compound glaze of pottery of blue down payment spot
CN109052960A (en) * 2018-09-19 2018-12-21 杨鹏飞 A kind of red glaze glaze and its enameling method prepared using titanium ore and Copper Ores

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* Cited by examiner, † Cited by third party
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林彬荫等: "《耐火材料原料》", 31 October 2015, 冶金工业出版社 *
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