CN108976866A - A kind of bamboo rattan material wide spectrum mildew resistant paint - Google Patents
A kind of bamboo rattan material wide spectrum mildew resistant paint Download PDFInfo
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- CN108976866A CN108976866A CN201810883175.XA CN201810883175A CN108976866A CN 108976866 A CN108976866 A CN 108976866A CN 201810883175 A CN201810883175 A CN 201810883175A CN 108976866 A CN108976866 A CN 108976866A
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- parts
- resistant paint
- mildew resistant
- wide spectrum
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- 239000003973 paint Substances 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 title claims abstract description 23
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 22
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 22
- 241001330002 Bambuseae Species 0.000 title claims abstract description 22
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 22
- 239000011425 bamboo Substances 0.000 title claims abstract description 22
- 241000345998 Calamus manan Species 0.000 title claims abstract description 21
- 235000012950 rattan cane Nutrition 0.000 title claims abstract description 21
- 238000001228 spectrum Methods 0.000 title claims abstract description 18
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000006210 lotion Substances 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002635 polyurethane Polymers 0.000 claims abstract description 12
- 239000004814 polyurethane Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 9
- 229910021538 borax Inorganic materials 0.000 claims abstract description 6
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- -1 acrylic ester Chemical class 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 15
- 244000046101 Sophora japonica Species 0.000 claims description 14
- 235000010586 Sophora japonica Nutrition 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims description 10
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 125000002346 iodo group Chemical group I* 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 7
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 150000001409 amidines Chemical class 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 125000005442 diisocyanate group Chemical group 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 150000002334 glycols Chemical class 0.000 claims description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 5
- 239000001095 magnesium carbonate Substances 0.000 claims description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical group OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003112 inhibitor Substances 0.000 abstract description 4
- 238000003672 processing method Methods 0.000 abstract description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 8
- KGAZPXNFWZDYHC-UHFFFAOYSA-N azane;butyl formate Chemical compound N.CCCCOC=O KGAZPXNFWZDYHC-UHFFFAOYSA-N 0.000 description 7
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical group CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical group ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 description 4
- 230000000855 fungicidal effect Effects 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000460 chlorine Chemical group 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 230000000721 bacterilogical effect Effects 0.000 description 2
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical group [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- JCIIKRHCWVHVFF-UHFFFAOYSA-N 1,2,4-thiadiazol-5-amine;hydrochloride Chemical compound Cl.NC1=NC=NS1 JCIIKRHCWVHVFF-UHFFFAOYSA-N 0.000 description 1
- VUZHZDBMVSHDRE-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.OCCCOC(=O)C=C VUZHZDBMVSHDRE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940096826 phenylmercuric acetate Drugs 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6484—Polysaccharides and derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to bamboo rattan material processing method technical fields, more particularly to a kind of bamboo rattan material wide spectrum mildew resistant paint, the raw material including following parts by weight: 55-65 parts of polymerization of acrylic modified polyurethane lotion, 2-8 parts of borax, modifying agent 12-16 parts mould proof, 1-2 parts of emulsifier, 1-3 parts of stabilizer, 0.4-0.8 parts of pH adjusting agent.The present invention is had the advantage that in the present invention compared with prior art through the mould proof modifying agent of rational proportion, mould inhibitor is set effectively to be combined with polymerization of acrylic modified polyurethane lotion, improve the homogenieity of coating, make it have preferable compactness and film forming, coating has stronger broad spectrum activity, suitable for different use environments.
Description
Technical field
The invention belongs to bamboo rattan material processing method technical fields, and in particular to a kind of bamboo rattan material wide spectrum mildew resistant paint.
Background technique
Bamboo rattan material is the no-wood forest resource for integrating economic benefit, ecological benefits and social benefit, is that timber is short
It is main instead of type resource in scarce situation, considerable status, but starch, sugar in bamboo rattan material are occupied in world forest resources
Class, protein content are higher than timber, and fibr tissue is mostly longitudinal arrangement, thus are easier the erosion by various moulds,
Existing mildew-proof treatment method generally includes phenols and organic heavy metal compound, such as benzene mercury naphthenate, phenylmercuric acetate etc., with
There is formaldehyde release-type fungicide again afterwards, but contains phenols, organic heavy metal compound and first in these mildew resistant paint formulas
The severe toxicity such as aldehyde or high toxic material have biggish toxic side effect to human body and environment, have stopped using at present；Developed now
The mould inhibitor to get up is mostly based on the lower substance of nontoxic or toxicity, such as heterocyclic compound, organo-tin compound, organic chloride
Object, organocopper compound etc., but mildew resistant paint currently on the market are closed, exists mostly or fungicidal spectrum is narrow or validity period is short, or is applied
The property covered is poor, or the problems such as be more toxic or be expensive.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of bamboo rattan material wide spectrum mildew resistant paint is provided.
The present invention is achieved by the following technical solutions: a kind of bamboo rattan material wide spectrum mildew resistant paint, including following weight
The raw material of part: 55-65 parts of polymerization of acrylic modified polyurethane lotion, 2-8 parts of borax, modifying agent 12-16 parts mould proof, emulsifier 1-2
Part, 1-3 parts of stabilizer, 0.4-0.8 parts of pH adjusting agent；
The polymerization of acrylic modified polyurethane lotion the preparation method comprises the following steps: polyurethane prepolymer is heated to 55-60 DEG C after, stirring
20-30 minutes, basic magnesium carbonate, the 2.5- of the acrylic ester polymerization liquid, 1-3% that are equivalent to its weight 20-30% is then added
The C of 3.6% N- bromo-succinimide, 0.2-0.6%6The fatty acid sorbitan alcohol of-O- sulfated chitosan, 0.1-0.3%
Ester, 200% solvent, temperature be 65-75 DEG C under conditions of be stirred 3-4 hour, revolving removing solvent to get；
The mould proof modifying agent includes the raw material of following parts by weight: 6-10 parts of Chinese scholartree bark extract, iodo propinyl ammonia formic acid fourth
4-6 parts of ester, 6-10 parts of diene monomers, 12-18 parts of hydroxyethyl methacrylate, 3-5 parts of 4- hydroxybutyl acrylate, versatic acid
1-3 parts of vinyl acetate, 2-4 parts of ammonium chloride.
As further improvement of these options, the polyurethane prepolymer the preparation method comprises the following steps: by polyether Glycols,
Diisocyanate with weight ratio 5:1.1-1.3 mixing, temperature be 75-85 DEG C under conditions of stir 2-3 hours to get；It is described
Acrylic ester polymerization liquid is by (methyl) hydroxypropyl acrylate, acrylic acid 4- hydroxybutyl, (methyl) butyl acrylate with weight ratio
12-16:4-6:1 mixing, adds the azo diisobutyl amidine hydrochloride and 0.3-0.5% for being equivalent to its total weight 1.2-1.8 %
Potassium peroxydisulfate, after mixing temperature be 80-85 DEG C under conditions of be mixed 6-8 hours after obtain.
As further improvement of these options, the solvent is glycol monoethyl ether.
As further improvement of these options, the Chinese scholartree bark extract the preparation method comprises the following steps: secondary Cortex sophorae is dried
It does to water content lower than pulverizing after 3%, sieves with 100 mesh sieve, and be equivalent to 30-40 times of its weight, mass concentration as 80-90%'s
Ethanol solution is ultrasonically treated 20-30 minutes under conditions of 20-24kHz, filters after the completion, is added in filter residue and is equivalent to it
10-20 times of weight, the ethanol solution that mass concentration is 55-65%, are handled 30-40 hours under conditions of temperature is 45-55 DEG C,
Filtering merges filtrate twice, dry to aqueous under conditions of temperature is 50 DEG C after 0.22 μm of filter membrane carries out hyperfiltration
It measures as 1-3% to obtain the final product.
As further improvement of these options, the emulsifier is dodecyl trimethyl ammonium bromide, cetyl
One of trimethylammonium bromide or the organic functions polysiloxanes containing quaternary ammonium group.
As further improvement of these options, the stabilizer is benzene sulfonyl chloride.
As further improvement of these options, the pH adjusting agent is one of sodium bicarbonate, ammonium hydroxide.
As further improvement of these options, the pH value of the mildew resistant paint is 7.6-7.8.
The mould proof better performances of iodo propinyl ammonia butyl formate, bacteriological protection performance is relatively poor, is illuminated by the light and easily divides
Solution influences anti-mold effect, is acted in the present invention by Chinese scholartree bark extract conjunction with which, guarantee to mention while its mould proof performance
Its high bacteriological protection performance, cooperates the reasonable preparation of other raw materials of modifying agent, can prevent iodo propinyl ammonia butyl formate light
According to decomposition, its weatherability and mould proof stability are improved.
The present invention is had the advantage that in the present invention compared with prior art through the mould proof modifying agent of rational proportion, is made mould proof
Agent can effectively be combined with polymerization of acrylic modified polyurethane lotion, improve the homogenieity of coating, make it have preferable compactness
And film forming, coating has stronger broad spectrum activity, suitable for different use environments.
Specific embodiment
Embodiment 1
A kind of bamboo rattan material wide spectrum mildew resistant paint, the raw material including following parts by weight: 60 parts of polymerization of acrylic modified polyurethane lotion,
5 parts of borax, 14 parts of mould proof modifying agent, 1.5 parts of emulsifier, 2 parts of stabilizer, 0.6 part of pH adjusting agent；
The polymerization of acrylic modified polyurethane lotion the preparation method comprises the following steps: polyurethane prepolymer is heated to 58 DEG C after, stirring 25
Minute, the acrylic ester polymerization liquid, 2% basic magnesium carbonate, 3.1% N- bromo fourth two for being equivalent to its weight 25% is then added
Acid imide, 0.4% C6- O- sulfated chitosan, 0.2% fatty acid loss water sorbit ester, 200% solvent are 70 in temperature
Be stirred under conditions of DEG C 3.5 hours, revolving remove solvent to get；
The mould proof modifying agent includes the raw material of following parts by weight: 8 parts of Chinese scholartree bark extract, iodo propinyl ammonia butyl formate 5
Part, 8 parts of diene monomers, 15 parts of hydroxyethyl methacrylate, 4 parts of 4- hydroxybutyl acrylate, 2 parts of tertiary ethylene carbonate, chlorine
Change 3 parts of ammonium.
Wherein, the polyurethane prepolymer the preparation method comprises the following steps: by polyether Glycols, diisocyanate with weight ratio 5:
1.2 mixing, temperature be 80 DEG C under conditions of stir 2.5 hours to get；The acrylic ester polymerization liquid is by (methyl) acrylic acid
Hydroxypropyl acrylate, acrylic acid 4- hydroxybutyl, (methyl) butyl acrylate are added with weight ratio 14:5:1 mixing and are equivalent to its gross weight
1.5% azo diisobutyl amidine hydrochloride and 0.4% potassium peroxydisulfate are measured, it is mixed under conditions of temperature is 82 DEG C after mixing
It is obtained after closing stirring 7 hours.
Wherein, the solvent is glycol monoethyl ether.
Wherein, the Chinese scholartree bark extract the preparation method comprises the following steps: secondary Cortex sophorae is dried to water content lower than grinding after 3%
Cheng Fen is sieved with 100 mesh sieve, ultrasonic under conditions of 22kHz with the ethanol solution for being equivalent to 35 times of its weight, mass concentration is 85%
Processing 25 minutes, is filtered after the completion, is added in filter residue and is equivalent to 15 times of its weight, the ethanol solution that mass concentration is 60%,
Temperature is handled 35 hours under conditions of being 50 DEG C, is filtered, and filtrate twice is merged, after 0.22 μm of filter membrane carries out hyperfiltration,
Being dried under conditions of temperature is 50 DEG C to water content is 2% to obtain the final product.
Wherein, the emulsifier is dodecyl trimethyl ammonium bromide；The stabilizer is benzene sulfonyl chloride；The pH is adjusted
Agent is sodium bicarbonate.
Wherein, the pH value of the mildew resistant paint is 7.7.
Embodiment 2
A kind of bamboo rattan material wide spectrum mildew resistant paint, the raw material including following parts by weight: 55 parts of polymerization of acrylic modified polyurethane lotion,
8 parts of borax, 12 parts of mould proof modifying agent, 2 parts of emulsifier, 1 part of stabilizer, 0.8 part of pH adjusting agent；
The polymerization of acrylic modified polyurethane lotion the preparation method comprises the following steps: polyurethane prepolymer is heated to 60 DEG C after, stirring 20
Minute, the acrylic ester polymerization liquid, 1% basic magnesium carbonate, 3.6% N- bromo fourth two for being equivalent to its weight 30% is then added
Acid imide, 0.6% C6- O- sulfated chitosan, 0.1% fatty acid loss water sorbit ester, 200% solvent are 75 in temperature
Be stirred under conditions of DEG C 4 hours, revolving remove solvent to get；
The mould proof modifying agent includes the raw material of following parts by weight: 6 parts of Chinese scholartree bark extract, iodo propinyl ammonia butyl formate 4
Part, 6 parts of diene monomers, 12 parts of hydroxyethyl methacrylate, 5 parts of 4- hydroxybutyl acrylate, 3 parts of tertiary ethylene carbonate, chlorine
Change 2 parts of ammonium.
Wherein, the polyurethane prepolymer the preparation method comprises the following steps: by polyether Glycols, diisocyanate with weight ratio 5:
1.3 mixing, temperature be 85 DEG C under conditions of stir 2 hours to get；The acrylic ester polymerization liquid is by (methyl) acrylic acid hydroxyl
Propyl ester, acrylic acid 4- hydroxybutyl, (methyl) butyl acrylate are added with weight ratio 16:4:1 mixing and are equivalent to its total weight
1.2% azo diisobutyl amidine hydrochloride and 0.5% potassium peroxydisulfate mix under conditions of temperature is 85 DEG C after mixing
Stirring obtains after 8 hours.
Wherein, the solvent is glycol monoethyl ether.
Wherein, the Chinese scholartree bark extract the preparation method comprises the following steps: secondary Cortex sophorae is dried to water content lower than grinding after 3%
Cheng Fen is sieved with 100 mesh sieve, ultrasonic under conditions of 24kHz with the ethanol solution for being equivalent to 30 times of its weight, mass concentration is 90%
Processing 30 minutes, is filtered after the completion, is added in filter residue and is equivalent to 20 times of its weight, the ethanol solution that mass concentration is 65%,
Temperature is handled 30 hours under conditions of being 55 DEG C, is filtered, and filtrate twice is merged, after 0.22 μm of filter membrane carries out hyperfiltration,
Being dried under conditions of temperature is 50 DEG C to water content is 3% to obtain the final product.
Wherein, the emulsifier is cetyl trimethylammonium bromide；The stabilizer is benzene sulfonyl chloride；The pH is adjusted
Agent is ammonium hydroxide.
Wherein, the pH value of the mildew resistant paint is 7.8.
Embodiment 3
A kind of bamboo rattan material wide spectrum mildew resistant paint, the raw material including following parts by weight: 65 parts of polymerization of acrylic modified polyurethane lotion,
2 parts of borax, 16 parts of mould proof modifying agent, 1 part of emulsifier, 3 parts of stabilizer, 0.4 part of pH adjusting agent；
The polymerization of acrylic modified polyurethane lotion the preparation method comprises the following steps: polyurethane prepolymer is heated to 55 DEG C after, stirring 30
Minute, the acrylic ester polymerization liquid, 3% basic magnesium carbonate, 2.5% N- bromo fourth two for being equivalent to its weight 20% is then added
Acid imide, 0.2% C6- O- sulfated chitosan, 0.3% fatty acid loss water sorbit ester, 200% solvent are 65 in temperature
Be stirred under conditions of DEG C 3 hours, revolving remove solvent to get；
The mould proof modifying agent includes the raw material of following parts by weight: 10 parts of Chinese scholartree bark extract, iodo propinyl ammonia butyl formate 6
Part, 10 parts of diene monomers, 18 parts of hydroxyethyl methacrylate, 3 parts of 4- hydroxybutyl acrylate, 1 part of tertiary ethylene carbonate, chlorine
Change 4 parts of ammonium.
Wherein, the polyurethane prepolymer the preparation method comprises the following steps: by polyether Glycols, diisocyanate with weight ratio 5:
1.1 mixing, temperature be 75 DEG C under conditions of stir 3 hours to get；The acrylic ester polymerization liquid is by (methyl) acrylic acid hydroxyl
Propyl ester, acrylic acid 4- hydroxybutyl, (methyl) butyl acrylate are added with weight ratio 12:6:1 mixing and are equivalent to its total weight
1.8% azo diisobutyl amidine hydrochloride and 0.3% potassium peroxydisulfate mix under conditions of temperature is 80 DEG C after mixing
Stirring obtains after 6 hours.
Wherein, the solvent is glycol monoethyl ether.
Wherein, the Chinese scholartree bark extract the preparation method comprises the following steps: secondary Cortex sophorae is dried to water content lower than grinding after 3%
Cheng Fen is sieved with 100 mesh sieve, ultrasonic under conditions of 20kHz with the ethanol solution for being equivalent to 40 times of its weight, mass concentration is 80%
Processing 20 minutes, is filtered after the completion, is added in filter residue and is equivalent to 10 times of its weight, the ethanol solution that mass concentration is 55%,
Temperature is handled 40 hours under conditions of being 45 DEG C, is filtered, and filtrate twice is merged, after 0.22 μm of filter membrane carries out hyperfiltration,
Being dried under conditions of temperature is 50 DEG C to water content is 1% to obtain the final product.
Wherein, the emulsifier is the organic functions polysiloxanes containing quaternary ammonium group；The stabilizer is benzene sulfonyl chloride；Institute
Stating pH adjusting agent is sodium bicarbonate.
Wherein, the pH value of the mildew resistant paint is 7.6.
Control group 1 is set, Chinese scholartree bark extract in embodiment 1 is removed, remaining content is constant；Control group 2 is set, it will be real
Apply Chinese scholartree bark extract in example 1, iodo propinyl ammonia butyl formate is made an addition in coating by corresponding proportion, remaining content is constant；
Above-mentioned coating is coated on bamboo material surface, coated weight 200-240g/m2, by GB/T18261- by contrived experiment in a manner of cold soaking
2000 " experimental methods that mould inhibitor prevents and treats timber mould and Stain fungi " carry out fungicidal properties test, that is, detect the suppression of various moulds
Rate processed obtains following result:
Table 1
It can be seen that Chinese scholartree bark extract in the present invention, iodo propinyl ammonia butyl formate synergistic effect by data in table 1,
Antibacterial effect can be enhanced.
After the corresponding coating of above-mentioned coating, is irradiated under the ultraviolet radiator of 500w 30 days, press GB/ again after the completion
T18261-2000 " experimental method that mould inhibitor prevents and treats timber mould and Stain fungi " carries out fungicidal properties test, obtains following knot
Fruit:
Table 2
It is preferable to can be seen that the ageing-resistant degree of mildew resistant paint in the present invention by data in table 2, be able to extend its use it is effective
Phase.
Claims (8)
1. a kind of bamboo rattan material wide spectrum mildew resistant paint, which is characterized in that the raw material including following parts by weight: acrylate modified poly-
55-65 parts of urethane lotion, 2-8 parts of borax, modifying agent 12-16 parts mould proof, 1-2 parts of emulsifier, 1-3 parts of stabilizer, pH adjusting agent
0.4-0.8 parts；
The polymerization of acrylic modified polyurethane lotion the preparation method comprises the following steps: polyurethane prepolymer is heated to 55-60 DEG C after, stirring
20-30 minutes, basic magnesium carbonate, the 2.5- of the acrylic ester polymerization liquid, 1-3% that are equivalent to its weight 20-30% is then added
The C of 3.6% N- bromo-succinimide, 0.2-0.6%6The fatty acid sorbitan alcohol of-O- sulfated chitosan, 0.1-0.3%
Ester, 200% solvent, temperature be 65-75 DEG C under conditions of be stirred 3-4 hour, revolving removing solvent to get；
The mould proof modifying agent includes the raw material of following parts by weight: 6-10 parts of Chinese scholartree bark extract, iodo propinyl ammonia formic acid fourth
4-6 parts of ester, 6-10 parts of diene monomers, 12-18 parts of hydroxyethyl methacrylate, 3-5 parts of 4- hydroxybutyl acrylate, versatic acid
1-3 parts of vinyl acetate, 2-4 parts of ammonium chloride.
2. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the polyurethane prepolymer
The preparation method comprises the following steps: polyether Glycols, diisocyanate are mixed with weight ratio 5:1.1-1.3, the condition for being 75-85 DEG C in temperature
Lower stirring 2-3 hours to get；The acrylic ester polymerization liquid by (methyl) hydroxypropyl acrylate, acrylic acid 4- hydroxybutyl,
(methyl) butyl acrylate adds the azo two for being equivalent to its total weight 1.2-1.8 % with weight ratio 12-16:4-6:1 mixing
The potassium peroxydisulfate of isobutyl amidine hydrochloride and 0.3-0.5% is mixed under conditions of temperature is 80-85 DEG C after mixing
It is obtained after 6-8 hours.
3. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the solvent is ethylene glycol list first
Ether.
4. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the system of the Chinese scholartree bark extract
Preparation Method are as follows: secondary Cortex sophorae is dried to water content lower than pulverizing after 3%, is sieved with 100 mesh sieve, and is equivalent to its weight 30-40
Again, mass concentration is the ethanol solution of 80-90%, is ultrasonically treated 20-30 minutes under conditions of 20-24kHz, filters after the completion,
It is added in filter residue and is equivalent to 10-20 times of its weight, the ethanol solution that mass concentration is 55-65%, be 45-55 DEG C in temperature
Under the conditions of handle 30-40 hours, filter, merge filtrate twice, be 50 in temperature after 0.22 μm of filter membrane carries out hyperfiltration
Under conditions of DEG C dry to water content be 1-3% to obtain the final product.
5. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the emulsifier is dodecyl
One of trimethylammonium bromide, cetyl trimethylammonium bromide or organic functions polysiloxanes containing quaternary ammonium group.
6. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the stabilizer is benzene sulfonyl
Chlorine.
7. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the pH adjusting agent is bicarbonate
One of sodium, ammonium hydroxide.
8. a kind of bamboo rattan material wide spectrum mildew resistant paint as described in claim 1, which is characterized in that the pH value of the mildew resistant paint is
7.6-7.8。
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Application publication date: 20181211 |