CN108949207A - A kind of internal-combustion and-heating type biomass continuously carbonizing system and its production technology - Google Patents
A kind of internal-combustion and-heating type biomass continuously carbonizing system and its production technology Download PDFInfo
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Abstract
Description
技术领域technical field
本发明属于生物质炭化技术领域,具体涉及一种内燃内热式生物质连续炭化系统及其生产工艺。The invention belongs to the technical field of biomass carbonization, and in particular relates to an internal combustion and internal heating type biomass continuous carbonization system and a production process thereof.
背景技术Background technique
生物质炭化是指利用热化学反应原理,将生物质原料(秸秆:棉花、篦麻、向日葵等植物秆,林业三生物:林业废弃物和木材加工剩余物以及其它)通过一定的工艺加工、化学反应生成产品及副产品的过程。在炭化过程中,生物质原料中多余的水分及挥发物被脱除,纤维素、半纤维素、木质素等被部分分解,不仅可以得到生物炭,同时还能产出可燃气体、可冷凝液体(木焦油和木醋液)等产物。Biomass carbonization refers to the use of thermochemical reaction principles to process biomass raw materials (straw: cotton, castor, sunflower and other plant stalks, forestry three biology: forestry waste and wood processing residues and others) through certain process, chemical The process by which a reaction produces products and by-products. During the carbonization process, the excess water and volatiles in the biomass raw materials are removed, and the cellulose, hemicellulose, lignin, etc. are partially decomposed, not only biochar can be obtained, but also combustible gas and condensable liquid can be produced (wood tar and wood vinegar) and other products.
中国专利:授权公告号CN205740890、授权公告日2016年11月30日的实用新型专利公开了一种连续式生物质炭气联产装置,炉体顶部设置有进料口,底部设置有出料口及卸料斗,炉体内腔从上至下依次设置有干燥室和炭化室,在炭化室顶部的炉体侧壁上设置有与炉体内腔相连通的气体进口,气体进口通过进气管与燃烧室的出气口相连通,在卸料斗侧壁上设置有与炉体内腔相连通的气体出口,气体出口通过抽气管道与喷嘴相连接,喷嘴的喷嘴头密封穿过燃烧室上的通孔后伸入燃烧室内,在抽气管道上设置有抽气装置,炭化室底部设置有筛孔板,炭化室与出料口之间通过筛孔板分隔,筛孔板由驱动装置驱动。虽然其得到的可燃气体热值高达1250kcal/m3,但仍然存在以下缺陷:Chinese patent: Authorized announcement number CN205740890, the utility model patent of authorized announcement date on November 30, 2016 discloses a continuous biomass charcoal gas cogeneration device, the top of the furnace body is provided with a feed port, and the bottom is provided with a discharge port And the unloading hopper, the inner cavity of the furnace is provided with a drying chamber and a carbonization chamber in sequence from top to bottom, and a gas inlet connected with the inner cavity of the furnace is arranged on the side wall of the furnace body at the top of the carbonization chamber, and the gas inlet is connected to the combustion chamber through the air intake pipe. The gas outlet of the discharge hopper is connected to the gas outlet, and the gas outlet connected to the inner cavity of the furnace is provided on the side wall of the unloading hopper. Into the combustion chamber, an air extraction device is installed on the air extraction pipe, and a sieve plate is installed at the bottom of the carbonization chamber. The carbonization chamber and the discharge port are separated by a sieve plate, and the sieve plate is driven by a driving device. Although the calorific value of combustible gas obtained by it is as high as 1250kcal/m 3 , the following defects still exist:
1、该装置为外燃内热式炭化炉,结构复杂,需单独设置燃烧室、燃烧器,加热点火困难;1. The device is an external-combustion and internal-heating carbonization furnace with a complex structure, which requires a separate combustion chamber and burner, making it difficult to heat and ignite;
2、该装置仅适用于较大颗粒(粒径大于30mm)的生物质原料,对于粒径小于30mm的生物质原料,由于堆积密实,间隙小,透气性极差,高温烟气很难穿透物料层,从而导致中间部分原料难以炭化,影响生物炭的产量和质量。2. This device is only suitable for biomass raw materials with larger particles (particle size greater than 30mm). For biomass raw materials with a particle size of less than 30mm, due to dense accumulation, small gaps, poor air permeability, high-temperature flue gas is difficult to penetrate The material layer makes it difficult to carbonize the middle part of the raw material, which affects the yield and quality of biochar.
发明内容Contents of the invention
本发明的目的是克服现有技术中存在的上述问题,提供一种适用于小颗粒生物质原料炭化的内燃内热式生物质连续炭化系统及其生产工艺。The purpose of the present invention is to overcome the above-mentioned problems existing in the prior art, and provide an internal combustion and internal heat continuous biomass carbonization system and its production process, which are suitable for the carbonization of small particle biomass raw materials.
为实现以上目的,本发明的技术方案如下:For realizing above object, technical scheme of the present invention is as follows:
一种内燃内热式生物质连续炭化系统,包括内燃内热式直立炉,所述内燃内热式直立炉的内部包括由上至下依次相通的进料段、干燥段、干馏炭化段、冷却段,所述冷却段内设置有花墙,所述花墙的两侧径向设置有多个位于花墙的导气孔下方的布气栅,所述布气栅近导气孔布置,且与导气孔之间形成多个分气道。An internal combustion and internal heating type biomass continuous carbonization system, comprising an internal combustion and internal heating type vertical furnace, the interior of the internal combustion and internal heating type vertical furnace includes a feeding section, a drying section, a dry distillation carbonization section, and a cooling section connected in sequence from top to bottom. A flower wall is arranged in the cooling section, and a plurality of air distribution grids located below the air guide holes of the flower wall are arranged radially on both sides of the flower wall. The air distribution grids are arranged near the air guide holes, and a plurality of Divide the airway.
所述布气栅为锯齿状结构或由多个不锈钢栅条按5~10mm的等间距竖直排列而成,且相邻的所述布气栅之间的距离为100~300mm。The air distribution grid has a zigzag structure or is formed by a plurality of stainless steel grid bars vertically arranged at equal intervals of 5 to 10 mm, and the distance between adjacent air distribution grids is 100 to 300 mm.
所述系统还包括煤气净化装置,所述干燥段的顶部设置有集气伞阵,所述集气伞阵的排气口依次通过桥管、煤气净化装置、回炉煤气管路与气体混合器的进气外管相通,所述进气外管内部同轴设置的进气内管与空气管路相通,气体混合器的排气口依次通过花墙的主气道、导气孔与分气道的进口相通。The system also includes a gas purification device, the top of the drying section is provided with a gas collection umbrella array, and the exhaust port of the gas collection umbrella array passes through the bridge pipe, the gas purification device, the return gas pipeline and the gas mixer in sequence. The air intake outer pipe is connected, the air intake inner pipe coaxially arranged inside the air intake outer pipe is connected with the air pipeline, and the exhaust port of the gas mixer passes through the main air channel of the flower wall, the air guide hole and the inlet of the air distribution channel in turn. connected.
所述煤气净化装置包括水封集气箱、文氏塔、旋流板塔、煤气风机、旋风除雾器,所述水封集气箱的进气端与桥管的排气端相通,水封集气箱的排气端依次经由文氏塔、旋流板塔、煤气风机、旋风除雾器与回炉煤气管路的进气端相通。The gas purification device includes a water-sealed gas collection box, a Venturi tower, a swirl plate tower, a gas blower, and a cyclone demister. The exhaust end of the sealed gas box communicates with the inlet end of the furnace gas pipeline through the Venturi tower, the swirl plate tower, the gas fan, and the cyclone demister in turn.
所述水封集气箱、文氏塔的排液口均通过一号回收管路与木醋和木焦油澄清分离热槽相通,所述旋流板塔、煤气风机、旋风除雾器的排液口均通过二号回收管路与木醋和木焦油澄清分离冷槽相通。The liquid outlets of the water-sealed gas collection box and the Venturi tower are all communicated with the wood vinegar and wood tar clarification and separation heat tank through No. 1 recovery pipeline, and the discharge outlets of the swirl plate tower, gas blower, and cyclone demister The liquid ports are all communicated with the clarification and separation cold tank of wood vinegar and wood tar through the No. 2 recovery pipeline.
所述干馏炭化段设置有若干个测温热电偶,所述测温热电偶由内燃内热式直立炉的炉壁延伸至相邻布气栅的中垂线与花墙的顶面的交接处附近;The dry distillation and carbonization section is provided with several temperature-measuring thermocouples, and the temperature-measuring thermocouples extend from the furnace wall of the internal-combustion and internal-heating vertical furnace to the vicinity of the junction between the vertical line of the adjacent gas distribution grid and the top surface of the flower wall;
所述内燃内热式直立炉的底部设置有与冷却段的底部相通的木醋液封出焦槽。The bottom of the internal-combustion and internal-heating vertical furnace is provided with a wood vinegar liquid that communicates with the bottom of the cooling section to seal out the coke groove.
一种内燃内热式生物质连续炭化系统的生产工艺,依次包括以下步骤:A production process of an internal combustion and internal heat type biomass continuous carbonization system comprises the following steps in sequence:
干燥:先将原料由进料段送入内燃内热式直立炉内,然后原料进入干燥段与气体热载体换热以完成干燥,其中,所述原料为农林废弃物、生活垃圾RDF中的至少一种;Drying: first feed the raw material into the internal combustion internal heating type vertical furnace from the feeding section, and then the raw material enters the drying section to exchange heat with the gas heat carrier to complete the drying, wherein the raw material is at least one of agricultural and forestry waste and domestic garbage RDF kind;
干馏炭化和冷却:首先,干燥后的原料在自身重力的作用下进入干馏炭化段被气体热载体干馏炭化以得到干馏煤气以及干馏料,然后干馏料经由冷却段后排出炉外,同时干馏煤气随着气体热载体流向干燥段,与干燥段的原料换热后依次经集气伞阵、桥管进入煤气净化装置内进行净化冷却处理,净化冷却后的部分煤气通过回炉煤气管路后由进气外管进入气体混合器内部,与经由进气内管进入气体混合器的空气按所需比例混合均匀形成混合气,混合气再依次通过主气道、导气孔、分气道、布气栅后与冷却段内的炭化料换热,随后上升至干馏炭化段的料层间进行半无焰燃烧,形成气体热载体对干馏炭化段的干燥原料进行干馏炭化,其中,所述煤气与空气的体积比为1.7~2.1∶1。Dry distillation carbonization and cooling: firstly, the dried raw material enters the dry distillation carbonization section under the action of its own gravity and is carbonized by gas heat carrier to obtain dry distillation gas and dry distillation material, and then the dry distillation material passes through the cooling section and is discharged out of the furnace. The gas heat carrier flows to the drying section, and after exchanging heat with the raw materials in the drying section, it enters the gas purification device through the gas collection umbrella array and the bridge tube for purification and cooling treatment. Part of the purified and cooled gas passes through the furnace gas pipeline and is fed into the The outer tube enters the gas mixer, and mixes with the air entering the gas mixer through the inlet inner tube according to the required ratio to form a mixed gas, and then the mixed gas passes through the main air channel, air guide hole, sub-air channel, and air distribution grid in turn. Exchange heat with the carbonized material in the cooling section, then rise to the material layer of the carbonization and carbonization section for semi-flameless combustion, and form a gas heat carrier to carry out carbonization and carbonization of the dry raw material in the carbonization and carbonization section, wherein the volume of the gas and air The ratio is 1.7~2.1:1.
干燥步骤中,所述原料的粒度为3~120mm,其含水量为25%以下,所述干燥温度为150~200℃;In the drying step, the particle size of the raw material is 3-120mm, the water content thereof is below 25%, and the drying temperature is 150-200°C;
干馏炭化和冷却步骤中,所述干馏炭化的温度为250~650℃。In the dry distillation carbonization and cooling steps, the temperature of the carbonization carbonization is 250-650°C.
所述干馏炭化和冷却步骤还包括木醋和木焦油回收的操作;The dry distillation carbonization and cooling steps also include the recovery of wood vinegar and wood tar;
所述木醋和木焦油回收是指:在净化冷却处理过程中,所述水封集气箱、文氏塔内部产生的木醋和木焦油的混合物经由一号回收管路进入木醋和木焦油澄清分离热槽内,所述旋流板塔、煤气风机、旋风除雾器内部产生的木醋和木焦油的混合物经由二号回收管路进入木醋和木焦油澄清分离冷槽内,分离得到木醋、木焦油。The recovery of wood vinegar and wood tar refers to: during the purification and cooling process, the mixture of wood vinegar and wood tar produced in the water-sealed gas collection box and Venturi tower enters the wood vinegar and wood tar through No. 1 recovery pipeline. In the tar clarification and separation hot tank, the mixture of wood vinegar and wood tar produced in the swirl plate tower, gas fan, and cyclone demister enters the wood vinegar and wood tar clarification and separation cold tank through the No. 2 recovery pipeline, and separates Get wood vinegar, wood tar.
所述干馏炭化和冷却步骤还包括干馏料的初加工操作;The dry distillation carbonization and cooling step also includes the preliminary processing operation of the dry distillation material;
所述干馏料的初加工是指:干馏料由冷却段排出后进入木醋液封出焦槽,经其中的木醋液浸渍后作为炭基肥初产品使用。The primary processing of the retort material refers to: the retort material is discharged from the cooling section, enters the wood vinegar liquid to seal out the coke groove, and is used as the primary product of carbon-based fertilizer after being impregnated in the wood vinegar liquid.
与现有技术相比,本发明的有益效果为:Compared with prior art, the beneficial effect of the present invention is:
1、本发明一种内燃内热式生物质连续炭化系统包括内燃内热式直立炉,内燃内热式直立炉的内部包括由上至下依次相通的进料段、干燥段、干馏炭化段、冷却段,冷却段内设置有花墙,花墙的两侧径向设置有多个位于花墙的导气孔下方的布气栅,布气栅近导气孔布置,且与导气孔之间形成多个分气道,该设计通过在花墙两侧布置布气栅,并与导气孔之间形成多个分气道,不仅实现了布气的均匀,而且使得由导气孔排出的气体沿水平方向穿透小颗粒物料层,从而解决小颗粒物料的透气性问题,保证了本内燃内热式直立炉能够适用于粒度在3~120mm的生物质物料的干馏炭化。因此,本发明适用于粒度在3~120mm的生物质物料的干馏炭化。1. An internal combustion and internal heating type biomass continuous carbonization system of the present invention includes an internal combustion and internal heating type vertical furnace, and the interior of the internal combustion and internal heating type vertical furnace includes a feeding section, a drying section, a dry distillation carbonization section, and a cooling section connected in sequence from top to bottom, There is a flower wall in the cooling section. On both sides of the flower wall, there are a plurality of air distribution grids located below the air guide holes of the flower wall. The design arranges air distribution grids on both sides of the flower wall and forms multiple air distribution channels with the air guide holes, which not only achieves uniform air distribution, but also makes the gas discharged from the air guide holes penetrate the small particle material layer in the horizontal direction. Therefore, the air permeability problem of small particle materials is solved, and the internal combustion and internal heating type vertical furnace is guaranteed to be suitable for dry distillation and carbonization of biomass materials with particle sizes ranging from 3 to 120 mm. Therefore, the present invention is suitable for dry distillation and carbonization of biomass materials with a particle size of 3-120 mm.
2、本发明一种内燃内热式生物质连续炭化系统中干燥段的顶部设置有集气伞阵,该集气伞阵的排气口依次通过桥管、煤气净化装置、回炉煤气管路与气体混合器的进气外管相通,进气外管内部同轴设置的进气内管与空气管路相通,气体混合器的排气口依次通过花墙的主气道、导气孔与分气道的进口相通,在生产过程中,干馏炭化过程中产生的干馏煤气会经由桥管进入煤气净化装置中进行净化处理,净化后的部分干馏煤气作为干馏炭化的热源,通过回炉煤气管路进入气体混合器中与空气按特定的比例混合后上升至干馏炭化段的料层间进行半无焰燃烧,形成气体热载体对干馏炭化段的干燥原料进行干馏炭化,该设计利用炉内煤气不完全燃烧的控氧加热方式以及煤气和空气先混合再燃烧的方式,不仅保证了加热均匀、控温方便,而且使得干馏煤气的热值大于1500kcal/m3,超过常规生物质气化煤气热值的40%左右,得到的生物质炭的产率高达30%~40%,远高于常规生物质气化多联产的15%~25%,同时将炭化周期缩短至6~8小时。因此,本发明不仅提高了干馏煤气的热值以及生物质炭的产率,而且缩短了炭化周期。2. The top of the drying section in the internal combustion and internal heat type biomass continuous carbonization system of the present invention is provided with a gas-collecting umbrella array, and the exhaust port of the gas-collecting umbrella array passes through the bridge pipe, the gas purification device, the furnace gas pipeline and the gas The air intake outer pipe of the mixer is connected, the air intake inner pipe coaxially arranged inside the air intake outer pipe is connected with the air pipeline, and the exhaust port of the gas mixer passes through the main air channel of the flower wall, the air guide hole and the air distribution channel in turn. The inlet is connected. During the production process, the dry distillation gas generated during the dry distillation and carbonization process will enter the gas purification device through the bridge pipe for purification treatment. Part of the purified dry distillation gas will be used as a heat source for dry distillation and carbonization, and enter the gas mixer through the furnace gas pipeline. After being mixed with air in a specific ratio, it rises to the material layer of the carbonization section for semi-flameless combustion, forming a gas heat carrier to carbonize the dry raw material in the carbonization section. This design utilizes the control of incomplete combustion of gas in the furnace. The oxygen heating method and the method of mixing gas and air before burning not only ensure uniform heating and convenient temperature control, but also make the calorific value of dry distillation gas greater than 1500kcal/m 3 , which is about 40% higher than the calorific value of conventional biomass gasification gas , The yield of the obtained biochar is as high as 30% to 40%, which is much higher than the 15% to 25% of conventional biomass gasification polygeneration, and the carbonization cycle is shortened to 6 to 8 hours. Therefore, the invention not only improves the calorific value of dry distillation gas and the yield of biomass charcoal, but also shortens the carbonization cycle.
附图说明Description of drawings
图1为本发明的结构框图。Fig. 1 is a structural block diagram of the present invention.
图2为本发明实施例1中内燃内热式直立炉的结构示意图。Fig. 2 is a schematic structural view of an internal-combustion and internal-heating vertical furnace in Example 1 of the present invention.
图3为图2的侧视图。FIG. 3 is a side view of FIG. 2 .
图4为实施例6中布气栅的结构示意图。FIG. 4 is a schematic structural diagram of the gas distribution grid in Example 6. FIG.
图中:In the picture:
内燃内热式直立炉1、进料段11、干燥段12、干馏炭化段13、冷却段14、花墙15、主气道151、分气道152、布气栅153、导气孔154、集气伞阵16、煤气净化装置2、水封集气箱21、文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25、桥管3、回炉煤气管路4、气体混合器5、进气外管51、进气内管52、一号回收管路61、二号回收管路62、木醋和木焦油澄清分离热槽71、木醋和木焦油澄清分离冷槽72、木醋液封出焦槽8、测温热电偶9;Internal combustion and internal heating type vertical furnace 1, feeding section 11, drying section 12, dry distillation and carbonization section 13, cooling section 14, flower wall 15, main air passage 151, sub-air passage 152, air distribution grid 153, air guide hole 154, gas collection umbrella Array 16, gas purification device 2, water-sealed gas collection box 21, Venturi tower 22, swirl plate tower 23, gas fan 24, cyclone demister 25, bridge pipe 3, return gas pipeline 4, gas mixer 5 , air intake outer pipe 51, air intake inner pipe 52, No. 1 recovery pipeline 61, No. 2 recovery pipeline 62, wood vinegar and wood tar clarification and separation hot tank 71, wood vinegar and wood tar clarification and separation cold tank 72, wood Vinegar liquid seals out the coke groove 8, temperature measuring thermocouple 9;
实线所指方向为气流走向,虚线所指方向为液体的走向。The direction indicated by the solid line is the direction of the airflow, and the direction indicated by the dotted line is the direction of the liquid.
具体实施方式Detailed ways
下面结合附图说明和具体实施方式对本发明作进一步详细的说明。The present invention will be described in further detail below in conjunction with the accompanying drawings and specific embodiments.
参见图1至图4,一种内燃内热式生物质连续炭化系统,包括内燃内热式直立炉1,所述内燃内热式直立炉1的内部包括由上至下依次相通的进料段11、干燥段12、干馏炭化段13、冷却段14,所述冷却段14内设置有花墙15,所述花墙15的两侧径向设置有多个位于花墙15的导气孔154下方的布气栅153,所述布气栅153近导气孔154布置,且与导气孔154之间形成多个分气道152。Referring to Fig. 1 to Fig. 4, an internal combustion and internal heating type biomass continuous carbonization system includes an internal combustion and internal heating type vertical furnace 1, and the interior of the internal combustion and internal heating type vertical furnace 1 includes a feed section 11, a drying Section 12, dry distillation and carbonization section 13, cooling section 14, the cooling section 14 is provided with a flower wall 15, and the two sides of the flower wall 15 are radially provided with a plurality of air distribution grids 153 below the air guide holes 154 of the flower wall 15, The air distribution grid 153 is arranged close to the air guide holes 154 , and a plurality of air distribution channels 152 are formed between the air guide holes 154 .
所述布气栅153为锯齿状结构或由多个不锈钢栅条按5~10mm的等间距竖直排列而成,且相邻的布气栅153之间的距离为100~300mm。The air distribution grid 153 is a zigzag structure or a plurality of stainless steel grid bars vertically arranged at equal intervals of 5-10 mm, and the distance between adjacent air distribution grids 153 is 100-300 mm.
所述系统还包括煤气净化装置2,所述干燥段12的顶部设置有集气伞阵16,所述集气伞阵16的排气口依次通过桥管3、煤气净化装置2、回炉煤气管路4与气体混合器5的进气外管51相通,所述进气外管51内部同轴设置的进气内管52与空气管路相通,气体混合器5的排气口依次通过花墙15的主气道151、导气孔154与分气道152的进口相通。The system also includes a gas purification device 2, the top of the drying section 12 is provided with a gas collection umbrella array 16, and the exhaust port of the gas collection umbrella array 16 passes through the bridge pipe 3, the gas purification device 2, and the furnace gas pipe in turn. The road 4 communicates with the air intake outer pipe 51 of the gas mixer 5, and the air intake inner pipe 52 coaxially arranged inside the air intake outer pipe 51 communicates with the air pipeline, and the exhaust port of the gas mixer 5 passes through the flower wall 15 in turn. The main air passage 151, the air guide hole 154 communicate with the inlet of the air distribution passage 152.
所述煤气净化装置2包括水封集气箱21、文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25,所述水封集气箱21的进气端与桥管3的排气端相通,水封集气箱21的排气端依次经由文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25与回炉煤气管路4的进气端相通。The gas purification device 2 includes a water-sealed gas collection box 21, a Venturi tower 22, a swirl plate tower 23, a gas blower 24, and a cyclone demister 25. The exhaust ends of 3 are connected, and the exhaust end of the water-sealed gas collection box 21 is connected with the inlet end of the furnace gas pipeline 4 through the Venturi tower 22, the swirl plate tower 23, the gas fan 24, and the cyclone demister 25. .
所述水封集气箱21、文氏塔22的排液口均通过一号回收管路61与木醋和木焦油澄清分离热槽71相通,所述旋流板塔23、煤气风机24、旋风除雾器25的排液口均通过二号回收管路62与木醋和木焦油澄清分离冷槽72相通。The drain outlets of the water-sealed gas collection box 21 and the Venturi tower 22 are all communicated with wood vinegar and wood tar clarification and separation heat tank 71 through No. 1 recovery pipeline 61, and the swirl plate tower 23, gas blower 24, The liquid outlets of the cyclone eliminator 25 communicate with the clarification and separation cold tank 72 of wood vinegar and wood tar through No. 2 recovery pipeline 62 .
所述干馏炭化段13设置有若干个测温热电偶9,所述测温热电偶9由内燃内热式直立炉1的炉壁延伸至相邻布气栅153的中垂线与花墙15的顶面的交接处附近;The dry distillation and carbonization section 13 is provided with several temperature-measuring thermocouples 9, and the temperature-measuring thermocouples 9 extend from the furnace wall of the internal-combustion and internal-heating vertical furnace 1 to the vertical line of the adjacent gas distribution grid 153 and the top of the flower wall 15. Near the intersection of faces;
所述内燃内热式直立炉1的底部设置有与冷却段14的底部相通的木醋液封出焦槽8。The bottom of the internal-combustion and internal-heating vertical furnace 1 is provided with a coke groove 8 communicated with the bottom of the cooling section 14 by wood vinegar liquid.
一种内燃内热式生物质连续炭化系统的生产工艺,依次包括以下步骤:A production process of an internal combustion and internal heat type biomass continuous carbonization system comprises the following steps in sequence:
干燥:先将原料由进料段11送入内燃内热式直立炉1内,然后原料进入干燥段12与气体热载体换热以完成干燥,其中,所述原料为农林废弃物、生活垃圾RDF中的至少一种;Drying: first feed the raw materials into the internal combustion and internal heating vertical furnace 1 from the feeding section 11, and then the raw materials enter the drying section 12 to exchange heat with the gas heat carrier to complete the drying. at least one of
干馏炭化和冷却:首先,干燥后的原料在自身重力的作用下进入干馏炭化段13被气体热载体干馏炭化以得到干馏煤气以及干馏料,然后干馏料经由冷却段14后排出炉外,同时干馏煤气随着气体热载体流向干燥段12,与干燥段12的原料换热后依次经集气伞阵16、桥管3进入煤气净化装置2内进行净化冷却处理,净化冷却后的部分煤气通过回炉煤气管路4后由进气外管51进入气体混合器5内部,与经由进气内管52进入气体混合器5的空气按所需比例混合均匀形成混合气,混合气再依次通过主气道151、导气孔154、分气道152、布气栅153后与冷却段14内的干馏料换热,随后上升至干馏炭化段13的料层间进行半无焰燃烧,形成气体热载体对干馏炭化段13的干燥原料进行干馏炭化,其中,所述煤气与空气的体积比为1.7~2.1∶1。Dry distillation carbonization and cooling: firstly, the dried raw material enters the carbonization carbonization section 13 under the action of its own gravity and is carbonized by gas heat carrier to obtain carbonization gas and carbonization material, and then the carbonization material passes through the cooling section 14 and is discharged out of the furnace. The gas flows to the drying section 12 along with the gas heat carrier, and after exchanging heat with the raw material in the drying section 12, it enters the gas purification device 2 through the gas collection umbrella array 16 and the bridge tube 3 in turn for purification and cooling treatment, and part of the purified and cooled gas passes through the furnace The gas pipeline 4 enters the interior of the gas mixer 5 through the outer intake pipe 51, and mixes evenly with the air entering the gas mixer 5 through the inner intake pipe 52 to form a mixed gas according to the required ratio, and then the mixed gas passes through the main air channel in turn 151. Air guide holes 154, gas distribution channels 152, and gas distribution grid 153 exchange heat with the carbonization material in the cooling section 14, and then rise to the carbonization section 13 for semi-flameless combustion to form a gas heat carrier for the carbonization The dry raw material in the carbonization section 13 is carbonized by dry distillation, wherein the volume ratio of the gas to air is 1.7-2.1:1.
干燥步骤中,所述原料的粒径为3~120mm,其含水量为25%以下,所述干燥温度为150~200℃;In the drying step, the particle size of the raw material is 3-120mm, the water content thereof is below 25%, and the drying temperature is 150-200°C;
干馏炭化和冷却步骤中,所述干馏炭化的温度为250~650℃。In the dry distillation carbonization and cooling steps, the temperature of the carbonization carbonization is 250-650°C.
所述干馏炭化和冷却步骤还包括木醋和木焦油回收的操作;The dry distillation carbonization and cooling steps also include the recovery of wood vinegar and wood tar;
所述木醋和木焦油回收是指:在净化冷却处理过程中,所述水封集气箱21、文氏塔22内部产生的木醋和木焦油的混合物经由一号回收管路61进入木醋和木焦油澄清分离热槽71内,所述旋流板塔23、煤气风机24、旋风除雾器25内部产生的木醋和木焦油的混合物经由二号回收管路62进入木醋和木焦油澄清分离冷槽72内,分离得到木醋、木焦油。The recovery of wood vinegar and wood tar refers to: during the purification and cooling process, the mixture of wood vinegar and wood tar produced inside the water-sealed gas collecting box 21 and the Venturi tower 22 enters the wood via No. 1 recovery pipeline 61. Vinegar and wood tar are clarified and separated in the hot tank 71, and the mixture of wood vinegar and wood tar produced inside the swirl plate tower 23, gas blower 24, and cyclone demister 25 enters the wood vinegar and wood tar through No. 2 recovery pipeline 62. Tar is clarified and separated in the cold tank 72, and separated to obtain wood vinegar and wood tar.
所述干馏炭化和冷却步骤还包括干馏料的初加工操作;The dry distillation carbonization and cooling step also includes the preliminary processing operation of the dry distillation material;
所述干馏料的初加工是指:干馏料由冷却段14排出后进入木醋液封出焦槽8,经其中的木醋液浸渍后作为炭基肥初产品使用。The primary processing of the retort material refers to: the retort material is discharged from the cooling section 14 and enters the wood vinegar liquid to seal out the coke tank 8, and is used as the primary product of carbon-based fertilizer after being impregnated in the wood vinegar liquid therein.
本发明内容说明如下:Contents of the present invention are described as follows:
本发明所述原料可以是秸秆、稻壳、花生壳、杂木、废竹料等农林废弃物和/或生活垃圾RDF,其形状可以是颗粒、压块或片状(如木片、竹片等),可提高原料的利用率,降低生产成本。同时,本发明装置对物料的水分适应范围较大,可实现小于25%含水量的原料直接入炉。The raw material of the present invention can be straw, rice husk, peanut shell, miscellaneous wood, waste bamboo and other agricultural and forestry waste and/or domestic garbage RDF, and its shape can be granule, briquette or sheet (such as wood chips, bamboo chips, etc. ), which can improve the utilization rate of raw materials and reduce production costs. At the same time, the device of the present invention has a wide range of adaptability to the moisture content of materials, and can realize that raw materials with a moisture content of less than 25% can be directly fed into the furnace.
本发明得到的干馏煤气部分作为内加热源,剩余的煤气可用于点火燃烧或煤气发电。干馏料可直接用于燃煤电厂,亦可加工成机制木炭、活性炭,或经木醋液封出焦槽8浸渍后作为炭基肥初产品使用。经澄清分离后的木醋可供水封集气箱21、文氏塔22、旋流板塔23以及木醋液封出焦槽8循环使用,也可作为叶面肥等使用。Part of the dry distillation gas obtained in the present invention is used as an internal heat source, and the remaining gas can be used for ignition combustion or gas power generation. The retort material can be directly used in coal-fired power plants, and can also be processed into machine-made charcoal, activated carbon, or used as the primary product of carbon-based fertilizer after being impregnated in the coke tank 8 sealed with wood vinegar. The wood vinegar after clarification and separation can be used for recycling in the water-sealed gas collecting box 21, the Venturi tower 22, the swirl plate tower 23 and the wood vinegar liquid sealing out the coke tank 8, and can also be used as foliar fertilizer.
分气道152:本发明将相邻的分气道152之间的距离设定在100~300mm,保证了混合气沿水平方向获得更优的穿透效果,实际应用时可根据物料粒度的分布确定。Air distribution channel 152: The present invention sets the distance between adjacent air distribution channels 152 at 100-300mm, which ensures a better penetration effect of the mixed gas along the horizontal direction, and can be used according to the distribution of material particle size in practical application. Sure.
干燥步骤:本步骤将干燥温度控制在150~200℃,可保证物料能够脱水的同时不会发生化学反应。Drying step: In this step, the drying temperature is controlled at 150-200°C to ensure that the material can be dehydrated without chemical reaction.
实施例1:Example 1:
参见图1至图3,一种内燃内热式生物质连续炭化系统,包括内燃内热式直立炉1、煤气净化装置2,所述内燃内热式直立炉1的内部包括由上至下依次相通的进料段11、干燥段12、干馏炭化段13、冷却段14,所述干燥段12的顶部设置有集气伞阵16,所述干馏炭化段13设置有若干个测温热电偶9,所述冷却段14内设置有花墙15,所述煤气净化装置2包括水封集气箱21、文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25,所述花墙15的两侧径向设置有多个位于花墙15的导气孔154下方的布气栅153,所述布气栅153为锯齿状结构,相邻的布气栅153之间的距离为200mm,其近导气孔154布置,且与导气孔154之间形成多个分气道152,所述集气伞阵16的排气口依次通过桥管3、水封集气箱21、文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25、回炉煤气管路4与气体混合器5的进气外管51相通,所述进气外管51内部同轴设置的进气内管52与空气管路相通,气体混合器5的排气口依次通过花墙15的主气道151、导气孔154与分气道152的进口相通,所述水封集气箱21、文氏塔22的排液口均通过一号回收管路61与木醋和木焦油澄清分离热槽71相通,所述水封集气箱21、文氏塔22的排液口均通过一号回收管路61与木醋和木焦油澄清分离热槽71相通,所述旋流板塔23、煤气风机24、旋风除雾器25的排液口均通过二号回收管路62与木醋和木焦油澄清分离冷槽72相通,所述测温热电偶9由内燃内热式直立炉1的炉壁延伸至相邻布气栅153的中垂线与花墙15的顶面的交接处附近,所述内燃内热式直立炉1的底部还设置有与冷却段14的底部相通的木醋液封出焦槽8。Referring to Figures 1 to 3, an internal combustion and internal heating type biomass continuous carbonization system includes an internal combustion and internal heating type vertical furnace 1 and a gas purification device 2. Material section 11, drying section 12, carbonization and carbonization section 13, and cooling section 14, the top of the drying section 12 is provided with an air-collecting umbrella array 16, and the dry distillation and carbonization section 13 is provided with several temperature-measuring thermocouples 9, the A flower wall 15 is arranged in the cooling section 14, and the gas purification device 2 includes a water-sealed gas collecting box 21, a Venturi tower 22, a swirl plate tower 23, a gas blower 24, and a cyclone demister 25. A plurality of air distribution grids 153 located below the air guide holes 154 of the flower wall 15 are provided in the lateral radial direction. The air distribution grids 153 are in a zigzag structure, and the distance between adjacent air distribution grids 153 is 200 mm, which is close to the air guide holes. 154, and form a plurality of air distribution passages 152 between the air guide hole 154, the exhaust port of the air collection umbrella array 16 passes through the bridge pipe 3, the water-sealed air collection box 21, the Venturi tower 22, the swirl plate The tower 23, the gas fan 24, the cyclone demister 25, the furnace gas pipeline 4 communicate with the air intake outer pipe 51 of the gas mixer 5, and the air intake inner pipe 52 coaxially arranged inside the air intake outer pipe 51 is connected with the air The pipelines are connected, and the exhaust port of the gas mixer 5 communicates with the inlet of the gas distribution channel 152 through the main air channel 151 and the air guide hole 154 of the flower wall 15 successively, and the liquid discharge of the water-sealed gas collecting box 21 and the Venturi tower 22 The outlets are all communicated with wood vinegar and wood tar clarification and separation heat tank 71 through No. 1 recovery pipeline 61, and the liquid outlets of the water-sealed gas collecting box 21 and Venturi tower 22 are all connected with wood vinegar through No. 1 recovery pipeline 61. It communicates with the wood tar clarification and separation heat tank 71, and the liquid outlets of the swirl plate tower 23, the gas blower 24, and the cyclone demister 25 are all connected to wood vinegar and wood tar clarification and separation cold tank 72 through the No. 2 recovery pipeline 62 In the same way, the temperature-measuring thermocouple 9 extends from the furnace wall of the internal-combustion and internal-heating type vertical furnace 1 to the vicinity of the junction between the vertical line of the adjacent gas distribution grid 153 and the top surface of the flower wall 15, and the internal-combustion and internal-heating type vertical furnace 1 The bottom of the bottom is also provided with the wood vinegar liquid that communicates with the bottom of the cooling section 14 to seal out the coke groove 8.
一种内燃内热式生物质连续炭化系统的生产工艺,依次按照以下步骤进行:A production process of an internal combustion and internal heat type biomass continuous carbonization system is carried out sequentially according to the following steps:
干燥:先将原料由进料段11送入内燃内热式直立炉1内,然后原料进入干燥段12与气体热载体换热以完成干燥,其中,所述原料为秸秆颗粒,其粒径为6~50mm,含水量为9%,所述干燥温度为200℃;Drying: first feed the raw material into the internal combustion and internal heating vertical furnace 1 from the feeding section 11, and then the raw material enters the drying section 12 to exchange heat with the gas heat carrier to complete the drying. The raw material is straw particles with a particle size of 6 ~50mm, the water content is 9%, and the drying temperature is 200°C;
干馏炭化和冷却:首先,干燥后的原料在自身重力的作用下进入干馏炭化段13被气体热载体干馏炭化以得到干馏煤气以及干馏料,然后干馏料由冷却段14排出后进入木醋液封出焦槽8,经其中的木醋液浸渍后作为炭基肥初产品使用,同时干馏煤气随着气体热载体流向干燥段12,与干燥段12的原料换热后依次经集气伞阵16、桥管3依次进入水封集气箱21、文氏塔22、旋流板塔23、煤气风机24、旋风除雾器25内进行净化冷却处理,净化冷却后的部分煤气通过回炉煤气管路4后由进气外管51进入气体混合器5内部,与经由进气内管52进入气体混合器5的空气按所需比例混合均匀形成混合气,混合气再依次通过主气道151、导气孔154、分气道152、布气栅153后与冷却段14内的干馏料换热,随后上升至干馏炭化段13的料层间进行半无焰燃烧,形成气体热载体对干馏炭化段13的干燥原料进行干馏炭化,水封集气箱21、文氏塔22内部产生的木醋和木焦油的混合物经由一号回收管路61进入木醋和木焦油澄清分离热槽71内,旋流板塔23、煤气风机24、旋风除雾器25内部产生的木醋和木焦油的混合物经由二号回收管路62进入木醋和木焦油澄清分离冷槽72内,分离得到木醋、木焦油,其中,所述干馏炭化的温度为550℃,所述煤气与空气的体积比为1.8∶1。Dry distillation carbonization and cooling: firstly, the dried raw material enters the dry distillation carbonization section 13 under the action of its own gravity and is carbonized by gas heat carrier to obtain dry distillation gas and dry distillation material, and then the dry distillation material is discharged from the cooling section 14 and enters the wood vinegar liquid seal The coke discharge tank 8 is used as the initial product of charcoal-based fertilizer after being impregnated with the wood vinegar liquid therein. At the same time, the dry distillation gas flows to the drying section 12 along with the gas heat carrier, and after exchanging heat with the raw material of the drying section 12, it passes through the gas-collecting umbrella array 16, The bridge pipe 3 enters the water-sealed gas collection box 21, the Venturi tower 22, the swirl plate tower 23, the gas blower 24, and the cyclone demister 25 for purification and cooling treatment, and part of the purified and cooled gas passes through the furnace gas pipeline 4 Afterwards, it enters the gas mixer 5 through the intake outer tube 51, and mixes evenly with the air that enters the gas mixer 5 through the intake inner tube 52 to form a mixed gas, and then the mixed gas passes through the main air channel 151 and the air guide hole in turn. 154. After the gas distribution channel 152 and the gas distribution grid 153, it exchanges heat with the dry distillation material in the cooling section 14, and then rises to the carbonization and carbonization section 13 for semi-flameless combustion to form a gas heat carrier for the carbonization and carbonization section 13. The dry raw material is carbonized by dry distillation, and the mixture of wood vinegar and wood tar produced in the water-sealed gas collection box 21 and the Venturi tower 22 enters the wood vinegar and wood tar clarification and separation heat tank 71 through the No. 1 recovery pipeline 61, and the swirl plate The mixture of wood vinegar and wood tar produced inside tower 23, gas blower 24, and cyclone demister 25 enters wood vinegar and wood tar clarification and separation cold tank 72 through No. 2 recovery pipeline 62, and separates wood vinegar and wood tar. Wherein, the carbonization temperature is 550° C., and the volume ratio of gas to air is 1.8:1.
实施例2:Example 2:
与实施例1的不同之处在于:The difference with Example 1 is:
所述原料为秸秆压块,其粒度为32mm,含水量为17%,所述干燥温度为190℃。The raw material is straw briquettes with a particle size of 32mm, a water content of 17%, and a drying temperature of 190°C.
实施例3:Example 3:
与实施例1的不同之处在于:The difference with Example 1 is:
所述原料为花生壳,其粒度为8~30mm,含水量为22%,所述干燥温度为188℃;The raw material is peanut shells, the particle size is 8-30mm, the water content is 22%, and the drying temperature is 188°C;
实施例4:Example 4:
与实施例1的不同之处在于:The difference with Example 1 is:
所述原料为竹片,其粒度为20~100mm,含水量为25%,所述干燥温度为180℃。The raw material is bamboo chips, the particle size is 20-100mm, the moisture content is 25%, and the drying temperature is 180°C.
实施例5:Example 5:
与实施例1的不同之处在于:The difference with Example 1 is:
所述原料为生活垃圾RDF,其粒度为6~50mm,含水量为12%,所述干燥温度为195℃。The raw material is domestic garbage RDF with a particle size of 6-50mm, a water content of 12%, and a drying temperature of 195°C.
实施例6:Embodiment 6:
参见图4,与实施例1的不同之处在于:Referring to Fig. 4, the difference with Embodiment 1 is:
所述布气栅153由多个不锈钢栅条按5mm的等间距竖直排列而成。The air distribution grid 153 is formed by a plurality of stainless steel grid bars vertically arranged at equal intervals of 5mm.
实施例7:Embodiment 7:
参见图4,与实施例6的不同之处在于:Referring to Fig. 4, the difference with embodiment 6 is:
所述干馏炭化的温度为500℃,所述木煤气与空气的体积比为2.0∶1。The carbonization temperature of the dry distillation is 500° C., and the volume ratio of the wood gas to air is 2.0:1.
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