CN108888570A - A kind of mild emulsifier that salt resistant character is good - Google Patents
A kind of mild emulsifier that salt resistant character is good Download PDFInfo
- Publication number
- CN108888570A CN108888570A CN201810855573.0A CN201810855573A CN108888570A CN 108888570 A CN108888570 A CN 108888570A CN 201810855573 A CN201810855573 A CN 201810855573A CN 108888570 A CN108888570 A CN 108888570A
- Authority
- CN
- China
- Prior art keywords
- propylene glycol
- emulsifier
- good
- resistant character
- salt resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 38
- 150000003839 salts Chemical class 0.000 title claims abstract description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 24
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 11
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 11
- 235000009566 rice Nutrition 0.000 claims abstract description 11
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940031569 diisopropyl sebacate Drugs 0.000 claims abstract description 9
- XFKBBSZEQRFVSL-UHFFFAOYSA-N dipropan-2-yl decanedioate Chemical compound CC(C)OC(=O)CCCCCCCCC(=O)OC(C)C XFKBBSZEQRFVSL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 claims abstract description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 33
- 150000002148 esters Chemical class 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 9
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical group CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- ONQPZWUHTAWFSN-UHFFFAOYSA-N 1-hydroxybutyl docosanoate Chemical compound C(CCCCCCCCCCCCCCCCCCCCC)(=O)OC(CCC)O ONQPZWUHTAWFSN-UHFFFAOYSA-N 0.000 claims description 2
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 claims description 2
- FGYZAECYNNGYAN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;propane-1,2-diol Chemical compound CC(O)CO.OC(=O)CC(O)(C(O)=O)CC(O)=O FGYZAECYNNGYAN-UHFFFAOYSA-N 0.000 claims description 2
- SGRCVQDBWHCTIS-UHFFFAOYSA-N 2-nonanoyloxypropyl nonanoate Chemical compound CCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCC SGRCVQDBWHCTIS-UHFFFAOYSA-N 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 229940116422 propylene glycol dicaprate Drugs 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims 2
- BJRXGOFKVBOFCO-UHFFFAOYSA-N 2-hydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(C)O BJRXGOFKVBOFCO-UHFFFAOYSA-N 0.000 claims 1
- HTNFLUQQANUSLR-UHFFFAOYSA-N 2-octanoyloxyethyl octanoate Chemical compound CCCCCCCC(=O)OCCOC(=O)CCCCCCC HTNFLUQQANUSLR-UHFFFAOYSA-N 0.000 claims 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims 1
- GIIJTDXSACMUEI-UHFFFAOYSA-N carbonic acid;propane-1,1-diol Chemical compound OC(O)=O.CCC(O)O GIIJTDXSACMUEI-UHFFFAOYSA-N 0.000 claims 1
- 235000013372 meat Nutrition 0.000 claims 1
- 229940105132 myristate Drugs 0.000 claims 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 description 18
- 235000019198 oils Nutrition 0.000 description 17
- 239000000839 emulsion Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 12
- 239000002537 cosmetic Substances 0.000 description 11
- 230000001804 emulsifying effect Effects 0.000 description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 10
- 239000006210 lotion Substances 0.000 description 10
- 241000209094 Oryza Species 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000012071 phase Substances 0.000 description 7
- 239000002211 L-ascorbic acid Substances 0.000 description 5
- 235000000069 L-ascorbic acid Nutrition 0.000 description 5
- 229960005070 ascorbic acid Drugs 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 4
- 102000003886 Glycoproteins Human genes 0.000 description 4
- 108090000288 Glycoproteins Proteins 0.000 description 4
- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004519 grease Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- -1 propylene, propylene Chemical group 0.000 description 3
- FYGDTMLNYKFZSV-URKRLVJHSA-N (2s,3r,4s,5s,6r)-2-[(2r,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5r,6s)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1[C@@H](CO)O[C@@H](OC2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-URKRLVJHSA-N 0.000 description 2
- 229920002498 Beta-glucan Polymers 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 2
- 206010067482 No adverse event Diseases 0.000 description 2
- 108010055615 Zein Proteins 0.000 description 2
- 229920002494 Zein Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003335 steric effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 150000003700 vitamin C derivatives Chemical class 0.000 description 2
- CZKPBCHPLNOUSJ-UHFFFAOYSA-N 1-octadecoxyperoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOOOCCCCCCCCCCCCCCCCCC CZKPBCHPLNOUSJ-UHFFFAOYSA-N 0.000 description 1
- BYQPMKXSZDJZAW-UHFFFAOYSA-N 1-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OC(CCC)OC(=O)CCCCCCC BYQPMKXSZDJZAW-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- NPAXBRSUVYCZGM-UHFFFAOYSA-N carbonic acid;propane-1,2-diol Chemical compound OC(O)=O.CC(O)CO NPAXBRSUVYCZGM-UHFFFAOYSA-N 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000007933 dermal patch Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229960003943 hypromellose Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 125000005473 octanoic acid group Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- JOVGBHDAFFAOMV-YSMBQZINSA-N propane-1,2-diol (Z)-tetradec-9-enoic acid Chemical compound CC(O)CO.CCCC\C=C/CCCCCCCC(O)=O JOVGBHDAFFAOMV-YSMBQZINSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/676—Ascorbic acid, i.e. vitamin C
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/33—Free of surfactant
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Botany (AREA)
- Biotechnology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of good mild emulsifiers of salt resistant character, it is characterised in that：It is grouped as by the group of following mass percent：30-70% diisopropyl sebacate, 25-65% wetting agent, 1-5% hydroxypropyl methyl cellulose tristearin oxygen ether, 1-5% rice chaff extract.The present invention has many advantages, such as that salt resistant character is good, does not stimulate skin mildly.
Description
Technical field
The present invention relates to emulsifying agent for cosmetics technical field, in particular to the good mild emulsifier of a kind of salt resistant character.
Background technique
In recent years, requirement of the people to cosmetic industry is higher and higher, and consumer wishes that cosmetics can provide really
Remarkable efficacy.In order to reach more preferable effect, then need to increase the additive amount of efficacy active component in cosmetics, functional component is big
Polyion is stronger, is such as used for the L-Ascorbic Acid L-O-Phosphate of whitening, and the Sodium Hyaluronate etc. for moisturizing is all strong ionic
Ingredient, however current most emulsifiers are lower to the tolerance degree of salt, after the active constituent of high additive amount will lead to emulsification
Product there is the unstable phenomenon such as water-oil separation.
In addition, most emulsifiers on current market, chemically belong to surfactant in structure, they are applied to
After on skin, because of HLB higher, the natural oil of skin can be generally also emulsified, the sebum in skin can be then taken away after cleaning, is passed through
The reuse of perseverance can destroy sebum film instead, and skin is caused to be easy to appear the feelings such as redness, dehydration, scytitis, allergy
The sensitivity of skin is further aggravated in condition.
Non-surface-active agent structure but the emulsifier with emulsification function at present, are often referred to polymer emulsifier, as road is rich
CARBOPOL TR-1, the TR-2 of profit company are to reach emulsifying effectiveness by space steric effect, but these polymer poles are not
Salt tolerant, usual salt content is no more than 0.3%（Mass ratio）, otherwise polymer will be unable to fully trail and lose emulsification effect
Fruit.
Another is pickering emulsion, with solia particles such as zeins or bentonite in powder, is adsorbed onto two-phase
The stable emulsion of the formation at interface, pickering emulsion have the characteristic of high salt tolerant.But because of zeins, bentonite is all
It is coarse solids powder, it is very puckery to apply skin sense on the skin for the pickering emulsion of formation, and solid powder is easy to be rubbed, and is changing
Cosmetic industry has commonly known as been easy mud；And pickering emulsion interfacial film is not strong, can not usually pass through cosmetic industry
- 10 DEG C to 50 DEG C of the environmental stability requirement usually required, therefore pickering emulsion is impracticable in cosmetic industry, almost
It is not adopted.
Therefore exploitation salt resistant character is good, mild low-stimulation, and the good emulsifier of final products use feeling, produces in cosmetics
Industry has a extensive future.
Summary of the invention
The technical problem to be solved by the present invention is to, a kind of emulsifier is provided, the emulsifier have salt resistant character it is good, it is mild not
The advantages that stimulating skin.
In order to solve the above technical problems, the present invention provides a kind of mild emulsifier that salt resistant character is good, it is characterised in that：By
The composition of following mass percent：30-70% diisopropyl sebacate, 25-65% wetting agent, 1-5% hydroxypropyl methyl cellulose are hard
Rouge oxygen ether, 1-5% rice chaff extract.
The wetting agent is two octanoic acids of butanediol/dicaprate, butanediol behenate, butanediol cocounut oil acid esters, the third two
Alcohol dicaprate, propylene glycol dipelargonate, propylene, propylene/dicaprate, two cocounut oil of propylene glycol
Acid esters, propylene glycol citrate, propylene glycol myristinate, Capmul PG-8, propylene glycol cocounut oil acid esters, the different tristearin of propylene glycol
One of acid esters, propylene glycol oleate, propylene glycol carbonate or their mixture.
Hydroxypropyl methyl cellulose tristearin oxygen ether of the present invention（HYDROXYPROPYL METHYLCELLULOSE
STEAROXY ETHER）, it is a kind of hydrophobic derivatives of hypromellose, in China《Cosmetic material name is used
Claim catalogue（2015 editions）》There are Japanese DAIDO Chemical Corporation company in middle serial number 05230, commercial product
Sangelose 60L,Sangelose 90L.Hydroxypropyl methyl cellulose tristearin oxygen ether has parents' thickened gel characteristic, to oil
There is gelatification with to water, phase and water external phase in oil can be thickened simultaneously, therefore oil droplet in emulsion may be implemented
Stable emulsifying effect.
Rice chaff extract of the present invention（ORYZA SATIVA (RICE) BRAN EXTRACT）, in China《It has used
Cosmetic material Names Catalogue（2015 editions）》There are the OZ-300U of OZEKI Co., Ltd. in middle serial number 01874, commercial product, rich
Containing beta glucan, chitin, yeast mannose glycoprotein etc., beta glucan, chitin, yeast mannose glycoprotein etc. are cell membranes
Substance is constituted, wherein yeast mannose glycoprotein is macromolecular natural products, can be adsorbed on by hydroxypropyl methyl cellulose tristearin oxygen
It on the oil-water interfaces of oil droplet after the thickening of base ether, further avoids oil droplet and collides with each other and form larger oil droplet and cause to separate, rise
It is acted on to stable emulsion.
The present invention is acted on using the stable emulsion of yeast mannose glycoprotein in rice chaff extract, modified with hydrophobic cellulose
Parents' thickened gel characteristic of object is realized and is acted on the stable emulsifying of different greases.The emulsifier does not contain traditional high HLB table
Face activating agent, irritation is low, it is main using the space steric effect in emulsion between oil droplet and water phase come to different type grease into
Row emulsification, stablizing effect is good, has a wide range of application, and lotion obtained is strong to the tolerance of electrolyte.
To test emulsifying capacity, irritation and salt resistant character of the invention, following experiment has been carried out.
1. Emulsion Stability Test
The mild emulsifier of the preparation of embodiment 1 is chosen as emulsifier A, remaining B-E each group emulsifier concrete composition such as 1 institute of table
Show.
1 emulsifier component table of table
It is formulated preparation lotion according to table 2, investigates mentioned emulsifier dialogue pond flower seed oil, ethylhexyl palmitate, dormant oil emulsifying power
Power.
2 emulsion formulations table of table
A heat phase is uniformly mixed, addition, which is uniformly dispersed, to be preheated in mutually synthermal B phase, is stirred simultaneously homogeneous, is added after cooling
C phase stirs evenly obtained lotion, which is placed 1 hour in 38 DEG C of baking ovens, then 3000rpm is centrifuged 30min, observation
Emulsion state, test result are as shown in table 3.
3 emulsifying capacity test result of table
As seen from the above table, diisopropyl sebacate and wetting agent are almost without emulsifying capacity, hydroxypropyl methyl cellulose tristearin oxygen
If both base ether and rice chaff extract, without cooperation, emulsifying capacity is somebody's turn to do also not as good as mild emulsifier provided by the invention
Emulsifier has preferable stable emulsifying ability to polarity, nonpolarity and vegetable fat, and 1 part of salt resistant character of the present invention is good
Mild emulsifier can stable emulsifying be no less than 6 parts of greases.
2. electrolyte resistance test
Mild emulsifier prepared by Example 1 emulsifies white pond flower seed oil, ethylhexyl palmitate and mine as emulsifier respectively
Oil, it is 12% that fat content, which is made,（Mass ratio）Stable emulsion, aforementioned stable lotion is divided into 15 groups, is separately added into 1.5% chlorine
Change sodium, 3.0% sodium chloride, 4.5% sodium chloride, 2% L-Ascorbic Acid L-O-Phosphate tests its electrolyte tolerance performance, specific test result
Such as table 4.
4 emulsifier electrolyte tolerance test result of table
As shown in Table 4, it is not less than 3.0% so that the lotion of mild emulsifier preparation provided by the invention is tolerable（Mass ratio）Electricity
Xie Zhi, and do not limited by grease；When adding 2% L-Ascorbic Acid L-O-Phosphate, emulsion viscosity variation was little, through 4 weeks by a definite date height
Temperature stability experiment still keeps stablizing non-discolouring, illustrates the system also and have protection vitamin C derivatives L-Ascorbic Acid L-O-Phosphate
Effect.
3. irritation test
Volunteer 32 of selection 18-60 years old, reference《Cosmetics safety technical specification 2015 editions》Human skin patch into
The test of row irritation.
Mild emulsifier prepared by Example 1 emulsifies white pond flower seed oil, ethylhexyl palmitate as emulsifier respectively
And dormant oil, it is 12% that fat content, which is made,（Mass ratio）Stable emulsion, respectively as sample A, B, C be added spot tester in, then
The back of subject will be pasted on non-stimulated adhesive tape added with the spot tester of sample, be gently pressed with palm and be allowed to equably be pasted on skin
On skin, continue for 24 hours；Tested material spot tester is removed, is remained with the tested material that wet rayon balls gently wipes test position,
After 30min, dermoreaction is observed after impression disappearance.If result is feminine gender, observed again for 24 hours after throwing off patch primary.By point
Grade standard records reaction result, and effectively the results are shown in Table 5.
5 irritation test test result of table
Sample A is white pond flower seed oil lotion, sample B is ethylhexyl palmitate lotion, and sample C is dormant oil lotion.
As seen from the above table, the lotion of mild emulsifier preparation provided by the invention has no adverse reaction to human skin, has
Have the characteristics that mild non-stimulated.
In conclusion mild emulsifier provided by the invention has stable emulsifying effect, 1 part of emulsifier is emulsifiable to stablize 6
Part（Mass ratio）Above grease, and do not limited by fat type, lotion obtained tolerable no less than 3.0%（Mass ratio）'s
Electrolyte, while also having the function of protecting vitamin C derivatives L-Ascorbic Acid L-O-Phosphate, it has no adverse reaction to human skin,
It is mild non-stimulated.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below.
Embodiment 1：
A kind of mild emulsifier and preparation method thereof with high salt resistance ability, it is characterised in that：Using following steps,
Raw material, diisopropyl sebacate 60%, butanediol cocounut oil acid esters 33%, hydroxypropyl methyl fiber are weighed by following mass ratio
Plain tristearin oxygen ether 4%, rice chaff extract 3%, 90-95 DEG C dissolves by heating to clear, is cooled to room temperature to obtain the final product.
Embodiment 2：
A kind of mild emulsifier and preparation method thereof with high salt resistance ability, it is characterised in that：Using following steps,
Raw material, diisopropyl sebacate 30%, propylene glycol cocounut oil acid esters 62%, hydroxypropyl methyl cellulose are weighed by following mass ratio
Stearic oxygen ether 5%, rice chaff extract 3%, 90-95 DEG C dissolves by heating to clear, is cooled to room temperature to obtain the final product.
Embodiment 3：
A kind of mild emulsifier and preparation method thereof with high salt resistance ability, it is characterised in that：Using following steps,
Raw material, diisopropyl sebacate 70%, propylene glycol dicaprate 26%, hydroxypropyl methyl fiber are weighed by following mass ratio
Plain tristearin oxygen ether 3%, rice chaff extract 1%, 90-95 DEG C dissolves by heating to clear, is cooled to room temperature to obtain the final product.
Embodiment 4：
A kind of mild emulsifier and preparation method thereof with high salt resistance ability, it is characterised in that：Using following steps,
Raw material, diisopropyl sebacate 50%, butanediol dicaprylate 25%, two coconut oil of propylene glycol are weighed by following mass ratio
Ester 20%, hydroxypropyl methyl cellulose tristearin oxygen ether 1%, rice chaff extract 4%, 90-95 DEG C dissolves by heating to clear, cold
But to room temperature to obtain the final product.
Embodiment 5：
A kind of mild emulsifier and preparation method thereof with high salt resistance ability, it is characterised in that：Using following steps,
Raw material, diisopropyl sebacate 65%, propylene/dicaprate 10%, propylene glycol are weighed by following mass ratio
Isostearate 18%, hydroxypropyl methyl cellulose tristearin oxygen ether 2%, rice chaff extract 5%, 90-95 DEG C dissolves by heating to clarification
It is transparent, it is cooled to room temperature to obtain the final product.
The above description of disclosed embodiment of this invention makes professional and technical personnel in the field can be realized or use this hair
It is bright.Various modifications to these embodiments will be readily apparent to those skilled in the art, and determine herein
The General Principle of justice can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, originally
Invention is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein
Consistent widest scope.
Claims (2)
1. a kind of good mild emulsifier of salt resistant character, it is characterised in that：It is grouped as by the group of following mass percent：30-70%
Diisopropyl sebacate, 25-65% wetting agent, 1-5% hydroxypropyl methyl cellulose tristearin oxygen ether, 1-5% rice chaff extract.
2. the good mild emulsifier of salt resistant character according to claim 1, it is characterised in that：The wetting agent is butanediol two
Octanoic acid/dicaprate, butanediol behenate, butanediol cocounut oil acid esters, propylene glycol dicaprate, propylene glycol dipelargonate, third
Glycol dicaprylate, propylene/dicaprate, two cocounut oil acid esters of propylene glycol, propylene glycol citrate, propylene glycol meat
Myristate, Capmul PG-8, propylene glycol cocounut oil acid esters, propylene glycol isostearate, propylene glycol oleate, carbonate propanediol
One of ester or their mixture.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849597A (en) * | 2020-08-04 | 2020-10-30 | 中山华明泰科技股份有限公司 | Preparation method and application of paraffin coal-based oil synthetic lubricant |
| CN112089682A (en) * | 2020-09-30 | 2020-12-18 | 花安堂生物科技集团有限公司 | Lip jelly and preparation method thereof |
| CN116710041A (en) * | 2020-12-22 | 2023-09-05 | Lvmh研究公司 | Aqueous emulsion |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106029049A (en) * | 2013-10-31 | 2016-10-12 | 德比Ip有限公司 | Stable multiple emulsions as skin protection products |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106029049A (en) * | 2013-10-31 | 2016-10-12 | 德比Ip有限公司 | Stable multiple emulsions as skin protection products |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849597A (en) * | 2020-08-04 | 2020-10-30 | 中山华明泰科技股份有限公司 | Preparation method and application of paraffin coal-based oil synthetic lubricant |
| CN112089682A (en) * | 2020-09-30 | 2020-12-18 | 花安堂生物科技集团有限公司 | Lip jelly and preparation method thereof |
| CN116710041A (en) * | 2020-12-22 | 2023-09-05 | Lvmh研究公司 | Aqueous emulsion |
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