CN108752925A - A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof - Google Patents
A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof Download PDFInfo
- Publication number
- CN108752925A CN108752925A CN201810517371.5A CN201810517371A CN108752925A CN 108752925 A CN108752925 A CN 108752925A CN 201810517371 A CN201810517371 A CN 201810517371A CN 108752925 A CN108752925 A CN 108752925A
- Authority
- CN
- China
- Prior art keywords
- parts
- materials
- mixture
- wear
- resisting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 63
- 239000000463 material Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 37
- 239000005061 synthetic rubber Substances 0.000 claims abstract description 36
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 25
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 25
- 239000005361 soda-lime glass Substances 0.000 claims abstract description 25
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- LNDKRVOOYMEYTC-UHFFFAOYSA-N buta-1,3-dien-1-ol Chemical compound OC=CC=C LNDKRVOOYMEYTC-UHFFFAOYSA-N 0.000 claims abstract description 11
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 2
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 claims 1
- 239000005368 silicate glass Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RABLWSNOVBIRIU-UHFFFAOYSA-N [Na].[Ca].[Si](O)(O)(O)O Chemical compound [Na].[Ca].[Si](O)(O)(O)O RABLWSNOVBIRIU-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- FSWDLYNGJBGFJH-UHFFFAOYSA-N n,n'-di-2-butyl-1,4-phenylenediamine Chemical compound CCC(C)NC1=CC=C(NC(C)CC)C=C1 FSWDLYNGJBGFJH-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof, are made of the raw material below according to parts by weight：98 parts of PA66 materials, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, 58 parts of soda lime glass, 27 parts of molybdenum disulfide.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is dialkyl diphenylamine and Isooctyl acrylate monomer 1:1 mixture.PA66 materials and synthetic rubber are added, compatilizer mixing is added, obtains first group of mixture；Be added soda lime glass into first group of mixture, and stirred with 500 revs/min of mixing speed, second group of mixture；It is slowly added to molybdenum disulfide into second group of mixture, and is at the uniform velocity stirred, is placed 2.5 hours.Wear-resisting and waterproof solution PA66 materials of the present invention, water resistance is high, and wearability is high, and properties of product are stablized, and manufacture craft is simple, at low cost.
Description
Technical field
The present invention relates to a kind of PA66 materials and preparation method thereof, specifically a kind of wear-resisting and waterproof solution PA66 materials and its system
Preparation Method.
Background technology
PA66 (polyamide 66 or nylon66 fiber), compared with PA6, PA66 broader applications in auto industry, Instrument shell with
And other products for needing impact resistance and high intensity and requiring.It is widely used in manufacture machinery, automobile, chemistry and electric device
Part, as impeller in gear, roller, pulley, roll shaft, the pump housing, fan blade, high pressure sealing are enclosed, valve seat, gasket, bushing, various
Handle, supporting rack, electric wire packet internal layer etc..Synthetic rubber is by artificial synthesized strong flexible polymer.Also referred to as synthetic elastomer is
One of three big synthetic materials, yield are only below synthetic resin (or plastics), synthetic fibers.
But common PA66 domestic at present adds fiber material there is wear-resistant strengths that not high, performance erratic fluctuations is big, resistance to
The disadvantages such as conservation rate is low are hydrolyzed, the application in this field is seriously limited.
Invention content
The purpose of the present invention is to provide a kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of wear-resisting and waterproof solution PA66 materials, including below according to the raw material of parts by weight：85-105 parts of PA66 materials, synthesis
55-75 parts of rubber, 18-25 parts of novel antioxidant, 25-35 parts of compatilizer, 50-65 parts of soda lime glass, molybdenum disulfide 22-
30 parts.
As a further solution of the present invention：The wear-resisting and waterproof solution PA66 materials, including below according to the original of parts by weight
Material：95-100 parts of PA66 materials, 60-70 parts of synthetic rubber, 20-23 parts of novel antioxidant, 29-33 parts of compatilizer, sodium calcium silicic acid
57-62 parts of salt glass, 25-29 parts of molybdenum disulfide.
As further scheme of the invention：The wear-resisting and waterproof solution PA66 materials, including below according to weight
The raw material of part：98 parts of PA66 materials, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, soda lime glass 58
Part, 27 parts of molybdenum disulfide.
As further scheme of the invention：The synthetic rubber is end hydroxy butadiene.
As further scheme of the invention：The novel antioxidant is dialkyl diphenylamine and Isooctyl acrylate monomer 1:
1 mixture.
It is a further object of the present invention to provide a kind of preparation methods of wear-resisting and waterproof solution PA66 materials, include the following steps：
PA66 materials and synthetic rubber are added, compatilizer mixing is added, obtains first group of mixture；
Soda lime glass is added into first group of mixture, and stirs, second group of mixture；
It is slowly added to molybdenum disulfide into second group of mixture, and is at the uniform velocity stirred, is placed 2-3 hours.
As further scheme of the invention：The mixing speed of the step (2) is set as 500 revs/min.
As further scheme of the invention：In the step (3), place 2.5 hours.
Compared with prior art, the beneficial effects of the invention are as follows：
Wear-resisting and waterproof solution PA66 materials of the present invention, for end hydroxy butadiene synthetic rubber addition improve it is hydrophobic
Property, water resistance is high, and the addition of molybdenum disulfide and soda lime glass improves wearability, and properties of product are stablized, manufacture craft
Simply, at low cost.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
85 parts of material, 55 parts of synthetic rubber, 18 parts of novel antioxidant, 25 parts of compatilizer, 50 parts of soda lime glass, molybdenum disulfide 22
Part.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different pungent
Ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 2 hours.
Embodiment 2
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
105 parts of material, 75 parts of synthetic rubber, 25 parts of novel antioxidant, 35 parts of compatilizer, 65 parts of soda lime glass, molybdenum disulfide
30 parts.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different
Monooctyl ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 3 hours.
Embodiment 3
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
95 parts of material, 60 parts of synthetic rubber, 20 parts of novel antioxidant, 29 parts of compatilizer, 57 parts of soda lime glass, molybdenum disulfide 25
Part.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different pungent
Ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 2 hours.
Embodiment 4
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
100 parts of material, 70 parts of synthetic rubber, 23 parts of novel antioxidant, 33 parts of compatilizer, 62 parts of soda lime glass, molybdenum disulfide
29 parts.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different
Monooctyl ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 3 hours.
Embodiment 5
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
98 parts of material, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, 58 parts of soda lime glass, molybdenum disulfide 27
Part.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different pungent
Ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 2.5 hours.
Embodiment 6
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
98 parts of material, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, 58 parts of soda lime glass, molybdenum disulfide 27
Part.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different pungent
Ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 2 hours.
Embodiment 7
In the embodiment of the present invention, a kind of wear-resisting and waterproof solution PA66 materials are made of the raw material below according to parts by weight：PA66
98 parts of material, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, 58 parts of soda lime glass, molybdenum disulfide 27
Part.The wherein described synthetic rubber is end hydroxy butadiene；The novel antioxidant is that dialkyl diphenylamine and acrylic acid are different pungent
Ester 1:1 mixture.
(1) PA66 materials and synthetic rubber are added, add compatilizer mixing, obtains first group of mixture；
(2) soda lime glass is added into first group of mixture, and is stirred with 500 revs/min of mixing speed,
Second group of mixture；
(3) it is slowly added to molybdenum disulfide into second group of mixture, and at the uniform velocity stirred, placed 3 hours.
Comparative example 1
A kind of wear-resisting and waterproof solution PA66 materials, are made of the raw material below according to parts by weight：It is 98 parts of PA66 materials, novel anti-
22 parts of oxygen agent, 30 parts of compatilizer, 58 parts of soda lime glass, 27 parts of molybdenum disulfide.
Comparative example 2
A kind of wear-resisting and waterproof solution PA66 materials, are made of the raw material below according to parts by weight：98 parts of PA66 materials, synthesis rubber
65 parts of glue, 22 parts of novel antioxidant, 30 parts of compatilizer.
The formula composition of above-described embodiment 1-5 such as the following table 1：
Table 1
Formula composition such as the following table 2 of above-mentioned comparative example 1,2：
Table 2
| Comparative example 1 | Comparative example 2 | |
| PA66 materials | 98 | 98 |
| Synthetic rubber | 0 | 65 |
| Novel antioxidant | 22 | 22 |
| Compatilizer | 30 | 30 |
| Soda lime glass | 58 | 0 |
| Molybdenum disulfide | 27 | 0 |
According to GB/T3960 testing standard to embodiment 1-5 and comparative example 1,2 gained composite materials carry out abrasion and
The measurement of friction coefficient.Concrete outcome is shown in Table 3：
Table 3
For the wear-resisting and waterproof solution PA66 materials prepared by Examples 1 to 5 relative to comparative example 2, performance is higher, stablizes and meets often
The test of state isostatic pressing strength is more than 50Mpa, and anti-hydrolytic performance is good, and detonation pressure intensity is more than 30Mpa after 100 DEG C of boilings 24 hours, resistance to
It is aqueous good, by Examples 1 to 5 prepare wear-resisting and waterproof solution PA66 materials relative to comparative example 1 have lower friction coefficient and
Abrasion, wear-resisting property obtain bigger raising.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (8)
1. a kind of wear-resisting and waterproof solution PA66 materials, which is characterized in that including below according to the raw material of parts by weight：PA66 materials 85-
105 parts, 55-75 parts of synthetic rubber, 18-25 parts of novel antioxidant, 25-35 parts of compatilizer, 50-65 parts of soda lime glass,
22-30 parts of molybdenum disulfide.
2. a kind of wear-resisting and waterproof solution PA66 materials according to claim 1, which is characterized in that including below according to parts by weight
Raw material：95-100 parts of PA66 materials, 60-70 parts of synthetic rubber, 20-23 parts of novel antioxidant, 29-33 parts of compatilizer, sodium calcium
57-62 parts of silicate glass, 25-29 parts of molybdenum disulfide.
3. a kind of wear-resisting and waterproof solution PA66 materials according to claim 1, which is characterized in that including below according to parts by weight
Raw material：98 parts of PA66 materials, 65 parts of synthetic rubber, 22 parts of novel antioxidant, 30 parts of compatilizer, soda lime glass 58
Part, 27 parts of molybdenum disulfide.
4. according to a kind of any wear-resisting and waterproof solution PA66 materials of claim 1-3, which is characterized in that the synthetic rubber is
End hydroxy butadiene.
5. according to a kind of any wear-resisting and waterproof solution PA66 materials of claim 1-3, which is characterized in that the novel antioxidant
For dialkyl diphenylamine and Isooctyl acrylate monomer 1:1 mixture.
6. a kind of preparation method of the wear-resisting and waterproof solution PA66 materials as described in claim 1-3 is any, which is characterized in that including with
Lower step：
（1）PA66 materials and synthetic rubber are added, compatilizer mixing is added, obtains first group of mixture；
（2）Soda lime glass is added into first group of mixture, and stirs, second group of mixture；
（3）It is slowly added to molybdenum disulfide into second group of mixture, and is at the uniform velocity stirred, is placed 2-3 hours.
7. a kind of preparation method of wear-resisting and waterproof solution PA66 materials according to claim 6, which is characterized in that the step
（2）Mixing speed be set as 500 revs/min.
8. a kind of preparation method of wear-resisting and waterproof solution PA66 materials according to claim 6, which is characterized in that the step
（3）In, it places 2.5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810517371.5A CN108752925A (en) | 2018-05-25 | 2018-05-25 | A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810517371.5A CN108752925A (en) | 2018-05-25 | 2018-05-25 | A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108752925A true CN108752925A (en) | 2018-11-06 |
Family
ID=64006112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810517371.5A Pending CN108752925A (en) | 2018-05-25 | 2018-05-25 | A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108752925A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796757A (en) * | 2019-01-16 | 2019-05-24 | 上海塑锐达复合材料有限公司 | A kind of wear-resisting and waterproof solution PA66 material and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098840A (en) * | 1974-08-21 | 1978-07-04 | Japan Atomic Energy Research Institute | Thermosetting resin composition |
| CN102585495A (en) * | 2012-01-06 | 2012-07-18 | 聚威工程塑料(上海)有限公司 | Hydrolysis-resistant glass fiber reinforced polyamide 66 (PA66) composite material and preparation method thereof |
| CN103304994A (en) * | 2013-06-21 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | Wearable and hydrolysis-resistant enhanced nylon 66 composite material |
| CN103976508A (en) * | 2014-05-24 | 2014-08-13 | 浙江奥康鞋业股份有限公司 | Abrasion-resistant hydrolysis-resistant insole |
| CN104004346A (en) * | 2014-05-22 | 2014-08-27 | 广州市南方尼龙制品有限公司 | Super-tough anti-abrasion MC (Monomer Casting) nylon composite material and preparation method thereof |
| CN104589748A (en) * | 2015-02-04 | 2015-05-06 | 上海铱塑科技有限公司 | Enhanced TPO (thermoplastic polyolefin) automobile instrument skin material and manufacturing method thereof |
| CN104610736A (en) * | 2015-02-03 | 2015-05-13 | 上海日之升新技术发展有限公司 | Nylon composite material with high transparency and low temperature cracking resistance and preparation method thereof |
| CN107778857A (en) * | 2017-11-17 | 2018-03-09 | 江门市荣龙新材料科技有限公司 | Anti- nylon 66 composite material of UV hydrolysis nylon 6/ of warp resistance and preparation method thereof |
-
2018
- 2018-05-25 CN CN201810517371.5A patent/CN108752925A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098840A (en) * | 1974-08-21 | 1978-07-04 | Japan Atomic Energy Research Institute | Thermosetting resin composition |
| CN102585495A (en) * | 2012-01-06 | 2012-07-18 | 聚威工程塑料(上海)有限公司 | Hydrolysis-resistant glass fiber reinforced polyamide 66 (PA66) composite material and preparation method thereof |
| CN103304994A (en) * | 2013-06-21 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | Wearable and hydrolysis-resistant enhanced nylon 66 composite material |
| CN104004346A (en) * | 2014-05-22 | 2014-08-27 | 广州市南方尼龙制品有限公司 | Super-tough anti-abrasion MC (Monomer Casting) nylon composite material and preparation method thereof |
| CN103976508A (en) * | 2014-05-24 | 2014-08-13 | 浙江奥康鞋业股份有限公司 | Abrasion-resistant hydrolysis-resistant insole |
| CN104610736A (en) * | 2015-02-03 | 2015-05-13 | 上海日之升新技术发展有限公司 | Nylon composite material with high transparency and low temperature cracking resistance and preparation method thereof |
| CN104589748A (en) * | 2015-02-04 | 2015-05-06 | 上海铱塑科技有限公司 | Enhanced TPO (thermoplastic polyolefin) automobile instrument skin material and manufacturing method thereof |
| CN107778857A (en) * | 2017-11-17 | 2018-03-09 | 江门市荣龙新材料科技有限公司 | Anti- nylon 66 composite material of UV hydrolysis nylon 6/ of warp resistance and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 何曼君等: "《高分子物理》", 31 March 2007, 复旦大学出版社 * |
| 兰州化学工业公司组织编著: "《合成橡胶工业手册》", 31 December 1991, 化学工业出版社 * |
| 王珏 等: "《塑料改性实用技术与应用》", 30 June 2014, 印刷工业出版社 * |
| 赵亚平等: "《中国石油和化工行业发展研究报告》", 29 February 2008, 河南科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796757A (en) * | 2019-01-16 | 2019-05-24 | 上海塑锐达复合材料有限公司 | A kind of wear-resisting and waterproof solution PA66 material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106146906B (en) | A kind of preparation method and application of natural emulsion filler | |
| CN103059770B (en) | Starch adhesive, its preparation method and application | |
| CN103937428B (en) | A kind of preparation method of modified corn starch sizing agent | |
| CN107804979B (en) | Chopped basalt fiber impregnating compound for reinforced rubber and preparation method thereof | |
| CN101928529B (en) | EVA composite emulsion type low-temperature-resistant environment-friendly all-purpose adhesive and preparation method thereof | |
| CN110387128B (en) | Self-adhesive single-component addition type silicone rubber and preparation method thereof | |
| CN103013133B (en) | A kind of automobile V-shaped circle sizing material and preparation method thereof | |
| CN110577747A (en) | room temperature vulcanized fluorosilicone rubber and preparation method thereof | |
| CN109054715B (en) | Modified silane sealant for LED backlight source and preparation method thereof | |
| CN110746771A (en) | High-flexibility flexible reinforced nylon material and preparation method thereof | |
| CN108752925A (en) | A kind of wear-resisting and waterproof solution PA66 materials and preparation method thereof | |
| CN108728022A (en) | A kind of adhesive sticker novel adhesive | |
| CN102382555A (en) | Solvent-free low-temperature solidified phenolic epoxy anticorrosive paint and preparation method thereof | |
| CN108384489B (en) | High-performance glass fiber adhesive tape adhesive and preparation method thereof | |
| CN110128999A (en) | A kind of fire-retardant bonded adhesives of one-component additional organosilicon and preparation method thereof | |
| CN114214025A (en) | Novel two-component silicone structural sealant and preparation method thereof | |
| CN103509253B (en) | A kind of rubber combination of electric cable of submersible pump rubber sheath | |
| CN108948436A (en) | A kind of preparation method of the modified composite membrane of sodium alginate-pectin | |
| CN105440975A (en) | Styrene-butadiene latex adhesive and preparation method thereof | |
| CN113234284A (en) | Glass fiber reinforced polypropylene composite material and preparation method thereof | |
| CN105001808A (en) | Universal environment-friendly building glue and preparation method thereof | |
| CN107804978B (en) | Basalt fiber impregnating compound for reinforcing rubber and preparation method thereof | |
| CN102676064A (en) | Matte adhesive and preparation method thereof | |
| CN106366649B (en) | A kind of glass fiber reinforced PA66 composite material and preparation method | |
| CN112063336B (en) | Novel formaldehyde-free waterproof white latex and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181106 |
|
| RJ01 | Rejection of invention patent application after publication |