CN108728022A - A kind of adhesive sticker novel adhesive - Google Patents
A kind of adhesive sticker novel adhesive Download PDFInfo
- Publication number
- CN108728022A CN108728022A CN201810664017.5A CN201810664017A CN108728022A CN 108728022 A CN108728022 A CN 108728022A CN 201810664017 A CN201810664017 A CN 201810664017A CN 108728022 A CN108728022 A CN 108728022A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive
- modified epoxy
- emulsifier
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 45
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 44
- 239000004593 Epoxy Substances 0.000 claims abstract description 22
- -1 hydroxyethyl saponin Chemical class 0.000 claims abstract description 22
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims abstract description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 13
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 13
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 12
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 12
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 12
- 229930182490 saponin Natural products 0.000 claims abstract description 12
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005751 Copper oxide Substances 0.000 claims abstract description 10
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 10
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 229920000647 polyepoxide Polymers 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical class OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical class [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 3
- 239000010949 copper Substances 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 239000001913 cellulose Substances 0.000 claims 2
- 229920002678 cellulose Polymers 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 abstract description 9
- 239000001863 hydroxypropyl cellulose Substances 0.000 abstract description 9
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000002688 persistence Effects 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 239000004568 cement Substances 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 238000004078 waterproofing Methods 0.000 abstract description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 241000931143 Gleditsia sinensis Species 0.000 description 1
- 206010036590 Premature baby Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004826 Synthetic adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of adhesive sticker novel adhesive is made of following parts by weight raw material：6-12 parts of isomerous tridecanol polyoxyethylene ether, 30-40 parts of dibutyl phthalate, 40-50 parts of 15% polyvinyl formal, 20-24 parts of copper oxide, 18-22 parts of aluminium hydroxide, 8-14 parts of calgon, 20-30 parts of modified epoxy, 10-12 parts of hydroxyethyl saponin gum, 8-12 parts of hydroxypropyl cellulose, 30-38 parts of emulsifier op-10.Beneficial effects of the present invention are：(1) this adhesive component is environmentally friendly, and harmless in production process, caking property is strong, not easily to fall off, and persistence is excellent；(2) adhesive has good water proofing property, heat-resisting quantity, applied widely, is applicable not only to the use of paper labels, while being also applied for the use of timber, film plastic cement.
Description
Technical field
The invention belongs to adhesive sticker fields, and in particular to a kind of adhesive sticker novel adhesive.
Background technology
Adhesive sticker, i.e. self-adhesive label material are using paper, film or special material as fabric, and the back side is coated with adhesive, with
Apply a kind of composite material that silicon protection sheet is base stock.
Due to there are many coating techniques, adhesive material is caused to be formed with different class, current developing direction is by passing
The print roll coating of system, blade coating develop to high pressure cast coat direction, to ensure the uniform perception of coating to greatest extent, avoid
The generation of bubble and pinprick ensures coating quality, and is cast cloth and is coated on domestic technique also prematurity, it is domestic mainly using
Conventional roller-type is coated with.
It refers to homogeneity or the skill that heterogeneous body surface is linked together with adhesive to be glued (bonding, bonding, cementing, gluing)
Art has stress distribution continuous, it is light-weight, or sealing, most technological temperatures are low the features such as.It is glued especially suitable for different materials
The connection of matter, different-thickness, ultra-thin specification and complex component.Splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide, and to high-new section
Learning technological progress and people's daily life improvement has significant impact.Therefore, it is very heavy to study, develop and produce all kinds of adhesive
It wants.Synthetic adhesive is made of host agent and auxiliary agent, and host agent is also known as major ingredient, base-material or sizing；Auxiliary agent have curing agent, diluent,
Plasticizer, filler, coupling agent, initiator, thickener, anti-aging agent, polymerization inhibitor, stabilizer, complexing agent, emulsifier etc., according to wanting
It can also includes the ingredients such as fire retardant, foaming agent, antifoaming agent, colorant and mould inhibitor to ask with purposes.
The adhesive sticker that existing adhesive is prepared will appear poor waterproof properties in use, and high temperature resistance is poor,
Not environmentally, easy do harm to huamn body in production, adhesion strength is low, is easy to fall off, and persistence is poor for cost；The final scope of application
Also smaller.
Invention content
Purpose of the invention is to overcome the shortcomings in the prior art, provides a kind of adhesive sticker novel adhesive.
In order to solve the above technical problems, the technical scheme is that：
A kind of adhesive sticker novel adhesive is made of following parts by weight raw material：Isomerous tridecanol polyoxyethylene ether 6-
12 parts, 30-40 parts of dibutyl phthalate, 40-50 parts of 15% polyvinyl formal, 20-24 parts of copper oxide, aluminium hydroxide
18-22 parts, 8-14 parts of calgon, 20-30 parts of modified epoxy, 10-12 parts of hydroxyethyl saponin gum, hydroxypropyl cellulose
8-12 parts, 30-38 parts of emulsifier op-10；
Wherein, the preparation method of the modified epoxy is：(1) 180mL deionized waters are added into four-hole bottle, then add
0.5mol sodium alkyl benzene sulfonates and 0.2mol potassium peroxydisulfates are passed through the air in nitrogen discharge four-hole bottle, are then stirred
50min obtains solution A；(2) 0.6mol epoxy resin and 0.2mol vinylacetates are added in the solution A into step (1), stirs
2h is mixed, then heats to 80 DEG C, 50min is reacted, then be cooled to 50 DEG C, obtains modified epoxy.
Preferably, it is made of following parts by weight raw material：6 parts of isomerous tridecanol polyoxyethylene ether, two fourth of phthalic acid
30 parts of ester, 40 parts of 15% polyvinyl formal, 20 parts of copper oxide, 18 parts of aluminium hydroxide, 8 parts of calgon, modified epoxy
20 parts of resin, 10 parts of hydroxyethyl saponin gum, 8 parts of hydroxypropyl cellulose, 30 parts of emulsifier op-10.
Preferably, it is made of following parts by weight raw material：12 parts of isomerous tridecanol polyoxyethylene ether, two fourth of phthalic acid
40 parts of ester, 50 parts of 15% polyvinyl formal, 24 parts of copper oxide, 22 parts of aluminium hydroxide, 14 parts of calgon, modified epoxy
30 parts of resin, 12 parts of hydroxyethyl saponin gum, 12 parts of hydroxypropyl cellulose, 38 parts of emulsifier op-10.
Preferably, it is made of following parts by weight raw material：9 parts of isomerous tridecanol polyoxyethylene ether, two fourth of phthalic acid
35 parts of ester, 45 parts of 15% polyvinyl formal, 22 parts of copper oxide, 20 parts of aluminium hydroxide, 11 parts of calgon, modified epoxy
25 parts of resin, 11 parts of hydroxyethyl saponin gum, 10 parts of hydroxypropyl cellulose, 34 parts of emulsifier op-10.
Beneficial effects of the present invention are：(1) this adhesive component is environmentally friendly, and harmless in production process, caking property is strong,
Not easily to fall off, persistence is excellent；(2) adhesive has good water proofing property, heat-resisting quantity, applied widely, is applicable not only to
The use of paper labels, while being also applied for the use of timber, film plastic cement.
Specific implementation mode
The effect of to make to structure feature of the invention and being reached, has a better understanding and awareness, to preferable
Embodiment cooperation detailed description, is described as follows：
Embodiment 1
A kind of adhesive sticker novel adhesive is made of following parts by weight raw material：Isomerous tridecanol polyoxyethylene ether 6
Part, 30 parts of dibutyl phthalate, 40 parts of 15% polyvinyl formal, 20 parts of copper oxide, 18 parts of aluminium hydroxide, six inclined phosphorus
8 parts of sour sodium, 20 parts of modified epoxy, 10 parts of hydroxyethyl saponin gum, 8 parts of hydroxypropyl cellulose, 30 parts of emulsifier op-10.
Wherein, the preparation method of the modified epoxy is：(1) 180mL deionized waters are added into four-hole bottle, then add
0.5mol sodium alkyl benzene sulfonates and 0.2mol potassium peroxydisulfates are passed through the air in nitrogen discharge four-hole bottle, are then stirred
50min obtains solution A；(2) 0.6mol epoxy resin and 0.2mol vinylacetates are added in the solution A into step (1), stirs
2h is mixed, then heats to 80 DEG C, 50min is reacted, then be cooled to 50 DEG C, obtains modified epoxy.
Embodiment 2
A kind of adhesive sticker novel adhesive is made of following parts by weight raw material：Isomerous tridecanol polyoxyethylene ether 12
Part, 40 parts of dibutyl phthalate, 50 parts of 15% polyvinyl formal, 24 parts of copper oxide, 22 parts of aluminium hydroxide, six inclined phosphorus
14 parts of sour sodium, 30 parts of modified epoxy, 12 parts of hydroxyethyl saponin gum, 12 parts of hydroxypropyl cellulose, emulsifier op-10 38
Part.
Wherein, the preparation method of the modified epoxy is：(1) 180mL deionized waters are added into four-hole bottle, then add
0.5mol sodium alkyl benzene sulfonates and 0.2mol potassium peroxydisulfates are passed through the air in nitrogen discharge four-hole bottle, are then stirred
50min obtains solution A；(2) 0.6mol epoxy resin and 0.2mol vinylacetates are added in the solution A into step (1), stirs
2h is mixed, then heats to 80 DEG C, 50min is reacted, then be cooled to 50 DEG C, obtains modified epoxy.
Embodiment 3
A kind of adhesive sticker novel adhesive is made of following parts by weight raw material：Isomerous tridecanol polyoxyethylene ether 9
Part, 35 parts of dibutyl phthalate, 45 parts of 15% polyvinyl formal, 22 parts of copper oxide, 20 parts of aluminium hydroxide, six inclined phosphorus
11 parts of sour sodium, 25 parts of modified epoxy, 11 parts of hydroxyethyl saponin gum, 10 parts of hydroxypropyl cellulose, emulsifier op-10 34
Part.
Wherein, the preparation method of the modified epoxy is：(1) 180mL deionized waters are added into four-hole bottle, then add
0.5mol sodium alkyl benzene sulfonates and 0.2mol potassium peroxydisulfates are passed through the air in nitrogen discharge four-hole bottle, are then stirred
50min obtains solution A；(2) 0.6mol epoxy resin and 0.2mol vinylacetates are added in the solution A into step (1), stirs
2h is mixed, then heats to 80 DEG C, 50min is reacted, then be cooled to 50 DEG C, obtains modified epoxy.
Comparative example 1 (for ordinary epoxy resin)
It is made of following parts by weight raw material：9 parts of isomerous tridecanol polyoxyethylene ether, 35 parts of dibutyl phthalate,
15% 45 parts of polyvinyl formal, 22 parts of copper oxide, 20 parts of aluminium hydroxide, 11 parts of calgon, 25 parts of epoxy resin, hydroxyl
11 parts of ethyl Chinese honey locust glue, 10 parts of hydroxypropyl cellulose, 34 parts of emulsifier op-10.
Above-described embodiment and comparative example products obtained therefrom performance indicator are as shown in the table：
By above-mentioned as it can be seen that forming simultaneously adhesive obtained according to parts by weight raw material in embodiment 3 has good bonding
Intensity, waterproof ability, and hardening time are short, and high temperature resistant cryogenic property is excellent.Belong to best parts by weight of raw materials array into option.
Epoxy resin has preferable adhesive strength and chemical-resistance, but in production is reacted, is not easy and other objects
Its advantage is preferably reacted and played to matter, by embodiment 1-3 and 1 data of comparative example it is found that passing through the asphalt mixtures modified by epoxy resin after being modified
Fat not only increases the high temperature resistant cryogenic property of entire adhesive, water resistance, the solidification speed for having also speeded up adhesive itself
Degree.
Beneficial effects of the present invention are：(1) this adhesive component is environmentally friendly, and harmless in production process, caking property is strong,
Not easily to fall off, persistence is excellent；(2) adhesive has good water proofing property, heat-resisting quantity, applied widely, is applicable not only to
The use of paper labels, while being also applied for the use of timber, film plastic cement.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention
Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and
Improvement is both fallen in the range of claimed invention.The present invention claims protection domain by appended claims and its
Equivalent defines.
Claims (4)
1. a kind of adhesive sticker novel adhesive, it is characterised in that：It is made of following parts by weight raw material：Isomerous tridecanol polyoxy
6-12 parts of vinethene, 30-40 parts of dibutyl phthalate, 40-50 parts of 15% polyvinyl formal, 20-24 parts of copper oxide,
18-22 parts of aluminium hydroxide, 8-14 parts of calgon, 20-30 parts of modified epoxy, 10-12 parts of hydroxyethyl saponin gum, hydroxypropyl
8-12 parts of base cellulose, 30-38 parts of emulsifier op-10；
Wherein, the preparation method of the modified epoxy is：(1) 180mL deionized waters are added into four-hole bottle, then add
0.5mol sodium alkyl benzene sulfonates and 0.2mol potassium peroxydisulfates are passed through the air in nitrogen discharge four-hole bottle, are then stirred
50min obtains solution A；(2) 0.6mol epoxy resin and 0.2mol vinylacetates are added in the solution A into step (1), stirs
2h is mixed, then heats to 80 DEG C, 50min is reacted, then be cooled to 50 DEG C, obtains modified epoxy.
2. a kind of adhesive sticker novel adhesive according to claim 1, it is characterised in that：By following parts by weight raw material
Composition：6 parts of isomerous tridecanol polyoxyethylene ether, 30 parts of dibutyl phthalate, 40 parts of 15% polyvinyl formal, oxidation
20 parts of copper, 18 parts of aluminium hydroxide, 8 parts of calgon, 20 parts of modified epoxy, 10 parts of hydroxyethyl saponin gum, hydroxypropyl are fine
Dimension plain 8 parts, 30 parts of emulsifier op-10.
3. a kind of adhesive sticker novel adhesive according to claim 1, it is characterised in that：By following parts by weight raw material
Composition：12 parts of isomerous tridecanol polyoxyethylene ether, 40 parts of dibutyl phthalate, 50 parts of 15% polyvinyl formal, oxygen
Change 24 parts of copper, 22 parts of aluminium hydroxide, 14 parts of calgon, 30 parts of modified epoxy, 12 parts of hydroxyethyl saponin gum, hydroxypropyl
12 parts of cellulose, 38 parts of emulsifier op-10.
4. a kind of adhesive sticker novel adhesive according to claim 1, it is characterised in that：By following parts by weight raw material
Composition：9 parts of isomerous tridecanol polyoxyethylene ether, 35 parts of dibutyl phthalate, 45 parts of 15% polyvinyl formal, oxidation
22 parts of copper, 20 parts of aluminium hydroxide, 11 parts of calgon, 25 parts of modified epoxy, 11 parts of hydroxyethyl saponin gum, hydroxypropyl are fine
Dimension plain 10 parts, 34 parts of emulsifier op-10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810664017.5A CN108728022A (en) | 2018-06-25 | 2018-06-25 | A kind of adhesive sticker novel adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810664017.5A CN108728022A (en) | 2018-06-25 | 2018-06-25 | A kind of adhesive sticker novel adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108728022A true CN108728022A (en) | 2018-11-02 |
Family
ID=63930564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810664017.5A Pending CN108728022A (en) | 2018-06-25 | 2018-06-25 | A kind of adhesive sticker novel adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108728022A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109913152A (en) * | 2019-01-21 | 2019-06-21 | 桐城市桐佳装饰有限公司 | Preparation method for coating is used in a kind of fitting of family's wallpaper |
| CN115100943A (en) * | 2022-06-30 | 2022-09-23 | 上海芳辉印刷有限公司 | Adhesive label and production process thereof |
| CN115232571A (en) * | 2022-08-19 | 2022-10-25 | 珠海腾佳印务有限公司 | Novel environment-friendly adhesive sticker |
| CN115322722A (en) * | 2022-08-22 | 2022-11-11 | 珠海腾佳印务有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083842A (en) * | 1993-07-22 | 1994-03-16 | 浙江大学 | Emulsion type adhesive for sticking paper to plastics and preparation method thereof |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
| CN102964535A (en) * | 2012-11-22 | 2013-03-13 | 上海涂料有限公司技术中心 | Preparation method and application of composite emulsion for alkali-resistant wine label coating |
| CN104277752A (en) * | 2014-10-20 | 2015-01-14 | 常熟市鑫磊木业制造厂 | Wood adhesive |
| CN107779109A (en) * | 2016-08-24 | 2018-03-09 | 南京禾文化创意有限公司 | A kind of environment-friendly adhesive |
-
2018
- 2018-06-25 CN CN201810664017.5A patent/CN108728022A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083842A (en) * | 1993-07-22 | 1994-03-16 | 浙江大学 | Emulsion type adhesive for sticking paper to plastics and preparation method thereof |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
| CN102964535A (en) * | 2012-11-22 | 2013-03-13 | 上海涂料有限公司技术中心 | Preparation method and application of composite emulsion for alkali-resistant wine label coating |
| CN104277752A (en) * | 2014-10-20 | 2015-01-14 | 常熟市鑫磊木业制造厂 | Wood adhesive |
| CN107779109A (en) * | 2016-08-24 | 2018-03-09 | 南京禾文化创意有限公司 | A kind of environment-friendly adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 张丽: ""环氧-醋酸乙烯酯共聚物乳液的制备与性能研究"", 《沈阳理工大学学报》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109913152A (en) * | 2019-01-21 | 2019-06-21 | 桐城市桐佳装饰有限公司 | Preparation method for coating is used in a kind of fitting of family's wallpaper |
| CN115100943A (en) * | 2022-06-30 | 2022-09-23 | 上海芳辉印刷有限公司 | Adhesive label and production process thereof |
| CN115232571A (en) * | 2022-08-19 | 2022-10-25 | 珠海腾佳印务有限公司 | Novel environment-friendly adhesive sticker |
| CN115322722A (en) * | 2022-08-22 | 2022-11-11 | 珠海腾佳印务有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108728022A (en) | A kind of adhesive sticker novel adhesive | |
| CN113004494B (en) | Modified epoxy resin, preparation method and emulsion preparation method thereof, and application of waterproof coating | |
| US12152170B2 (en) | Resin modified starch adhesive and preparation method thereof | |
| CN101619201B (en) | Underwater epoxy adhesive and preparation method thereof | |
| CN103193426B (en) | Preparation method of graphene oxide modified polymer cement waterproof coating | |
| CN102382552B (en) | Low temperature cured solvent-free epoxy anticorrosion paint and its preparation method | |
| CN102876240A (en) | High-performance building adhesive | |
| CN108285763B (en) | A kind of preparation method of environmental protection building adhesive | |
| CN104263292A (en) | Water-based laminated adhesive and preparation method thereof | |
| CN113717591B (en) | Single-component water-based waterproof coating and preparation method thereof | |
| CN101423420B (en) | Flexible waterproof putty and using method | |
| CN101701138A (en) | Adhesive for flexible decorative tiles and manufacturing method thereof | |
| CN108676496A (en) | A kind of novel environment friendly water-repellent paint and preparation method thereof | |
| CN108192079A (en) | A kind of high strength epoxy resin water phase curing agent and its preparation method and application | |
| CN117683498A (en) | Steel-bonding structural adhesive and preparation method thereof | |
| CN106753094A (en) | A kind of aqueous high-strength nail-free glue | |
| CN102585234B (en) | Macromolecular coupling agent, preparation method and application thereof | |
| CN104944874A (en) | Cold water quick-soluble composite rubber powder for building | |
| CN104877063A (en) | Polyvinyl acetate emulsion and preparation method thereof | |
| CN104532672B (en) | Reverse gloss resistant glue | |
| CN107312480A (en) | A kind of water dilution type aerodux and preparation method thereof | |
| CN107011785A (en) | A kind of wear-resistant polyester mirror surface coating of hard and preparation method thereof | |
| CN113308158A (en) | Quick-drying type interface agent for wall surface base layer and preparation method thereof | |
| CN101012359A (en) | Environment-friendly type multifunctional self-adhesive and preparing method thereof | |
| CN111393653A (en) | Modified epoxy resin composition, adhesive film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181102 |