CN108749244B - Optical high-flexibility conductive glass film and preparation method thereof - Google Patents
Optical high-flexibility conductive glass film and preparation method thereof Download PDFInfo
- Publication number
- CN108749244B CN108749244B CN201810581923.9A CN201810581923A CN108749244B CN 108749244 B CN108749244 B CN 108749244B CN 201810581923 A CN201810581923 A CN 201810581923A CN 108749244 B CN108749244 B CN 108749244B
- Authority
- CN
- China
- Prior art keywords
- layer
- parts
- conductive
- film
- metal grid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0038—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving application of liquid to the layers prior to lamination, e.g. wet laminating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/28—Multiple coating on one surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Non-Insulated Conductors (AREA)
Abstract
The invention discloses an optical high-flexibility conductive glass film, which sequentially comprises an upper protective layer, an upper adhesive layer, a scratch-resistant layer, a conductive composite layer, a release adhesive layer and a release layer from outside to inside, wherein the conductive composite layer sequentially comprises a conductive film layer and a conductive adhesive layer from outside to inside, the conductive film layer comprises a main conductive film and a metal grid layer embedded into the main conductive film, the main conductive film is formed by coating conductive paste, and the conductive paste comprises the following raw materials in parts by weight: 70-80 parts of silver nanowire dispersoid, 3-5 parts of alkylphenol polyoxyethylene, 1-3 parts of ethylene glycol phenyl ether, 8-12 parts of acrylic resin monomer, 1.5-4 parts of diethylenetriamine, 0.1-0.4 part of cyano phosphate, 12-20 parts of oligosaccharide, 1-2.5 parts of sodium carboxymethylcellulose, 20-30 parts of mixed solvent and 0.2-1 part of thickening agent. The conductive paste and the conductive adhesive have unique formulas, and are good at combining the advantages of the nano silver wires and the metal grid layer to carry out architectural design, so that the square resistance is greatly reduced, and the application value of the scheme of replacing the conductive film by the ITO is improved.
Description
Technical Field
The invention relates to a glass film, in particular to an optical high-flexibility conductive glass film and a preparation method thereof.
Background
A glass film is a film with optical or other functional effects that is applied over glass. With the development of the electronic industry, the transparent conductive film glass film is a thin film with good conductivity and high light transmittance in a visible light band, and the transparent conductive film is widely applied to the fields of flat panel display, photovoltaic devices, touch panels, electromagnetic shielding and the like at present, and has extremely wide application prospects. Generally, the optical transmission performance and the electrical conductivity of the transparent conductive glass film are two main properties of the transparent conductive glass film.
At present, a transparent conductive film includes a transparent substrate and a conductive layer disposed on the transparent substrate, and an ITO (indium tin oxide) layer is a main material of the conductive layer in the transparent conductive film, however, a conventional ITO film cannot be used for flexible applications, and essential problems such as conductivity and light transmittance are not easily overcome, and many panel manufacturers are beginning to research a substitute for ITO.
The novel technologies of the nano silver wire, the graphene, the metal grid and the like are in the development stage at present, for example, the transparency of the nano silver wire can be improved, the preparation and adhesion difficulty of a specific interface of the graphene is high, and the metal grid has the problem of interference ripple.
In view of the above problems, the present invention has been made to overcome the above problems by developing an optically highly flexible conductive glass film having excellent electrical conductivity and optical transparency.
Disclosure of Invention
The purpose of the invention is as follows: the invention provides an optical high-flexibility conductive glass film, which aims to obtain a conductive glass film with good optical performance and conductivity and flexible mechanical property, and solves the problems in the prior art.
The invention content is as follows: the utility model provides a high flexible electrically conductive glass membrane of optics includes protective layer, last glue film, scratch-resistant layer, electrically conductive composite bed in proper order, from the type glue film, from the type layer from outside to inside, electrically conductive composite bed includes electrically conductive rete, electrically conductive glue film in proper order from outside to inside, and electrically conductive rete includes main part conducting film and the metal grid layer of embedding in the main part conducting film, the main part conducting film is formed by electrically conductive thick liquid coating, the raw materials of electrically conductive thick liquid contain the component of following part by weight:
preferably, the upper glue layer is made of silica gel glue. The silica gel glue has the characteristics of strong adhesive force, good wettability with each interface and the like, and has high universality value when being used as high-quality glue for adhering a tearing layer.
Preferably, the release layer and the scratch-resistant layer are made of one of a PET film and a PC film. The PET film and the PC film have high transparency, are suitable as release layers needing to be peeled, and have a certain scratch-resistant protection effect as scratch-resistant layers.
Preferably, the silver nanowire dispersion is a dispersion of silver nanowires in water, ethanol or isopropanol, the diameter of the silver nanowires is 30-100nm, and the length of the silver nanowires is 5-100 μm. The silver nanowire dispersoid has non-trivial effects, has high conductivity, and plays a role in conducting the film layer and mixing the film layer with other components of the conductive paste to form a film; the length and the diameter of the conductive material enable the conductive performance of the conductive material to be fully exerted.
Preferably, the material of the metal grid layer is one of copper, silver, gold, chromium-gold, titanium-palladium-gold, titanium-platinum-gold and titanium-copper-gold. The metal grid layer is made of a material with the characteristics of high conductivity, mechanical flexibility in class bending and the like.
Preferably, the mixed solvent includes a combination of at least two of saturated alcohols, ketones, and esters having 4 to 9 carbon atoms. The mixed solvent enables the system of the conductive paste to be mixed and homogenized.
Preferably, the conductive adhesive layer is formed by coating conductive adhesive, and the raw materials of the conductive adhesive comprise the following components in parts by weight:
a preparation method of an optical high-flexibility conductive glass film comprises the following steps:
(1) adding the silver nanowire dispersion, alkylphenol ethoxylates, ethylene glycol phenyl ether, acrylic resin monomer, diethylenetriamine, oligosaccharide, sodium carboxymethylcellulose and a mixed solvent into a vacuum stirrer according to a formula ratio, defoaming in vacuum, and uniformly stirring to obtain a solution A, placing the solution A into a high-speed stirrer, adding cyano phosphate and a thickening agent into the solution A, stirring at 500-800rpm for 5-15min to obtain conductive paste, wherein the concentration of silver nanowires in the conductive paste is 15-60mg/m L;
(2) coating the prepared conductive paste on the anti-scraping layer, drying, coating again and drying, repeating the steps for 2-4 times, temporarily not drying after the last coating, pressing by using a grid graver to form a metal grid groove, and drying to form a main conductive film with the thickness of 20-400 mu m in total;
(3) at 3 to 5 × 10-3Plating a metal material used for the metal grid at the position of a groove of the metal grid by adopting an evaporation method under the vacuum degree of Pa, and filling the groove of the metal grid to form a metal grid layer, wherein the total thickness of the metal grid layer is slightly larger than the depth of the groove of the metal grid, and the width of a grid metal line of the metal grid layer is not more than 3 mu m; repairing the surfaces of the metal grid layer and the main conductive film to be flat;
(4) preparing a conductive adhesive according to a formula, coating the conductive adhesive on the surfaces of the main conductive film and the metal grid layer, and forming a conductive adhesive layer with the coating thickness of 50-500 mu m;
(5) coating a prepared release adhesive on the conductive adhesive layer, and attaching a release film; and similarly, coating the silica gel glue of the glue coating layer on the anti-scraping layer and then pasting the protective layer to obtain the anti-scraping glue.
The invention has the beneficial effects that: the optical high-flexibility conductive glass film disclosed by the invention is fine and reasonable in formula, obvious in structural hierarchy and excellent in conductivity. The upper protective layer, the upper adhesive layer, the release adhesive layer and the release layer are used for uncovering the protective layer of the main body layer and play an important role in protection and sealing; the scratch-resistant layer plays the most basic protection role, the conductive composite layer has a special structure and comprises a main framework conductive film layer and a conductive adhesive layer in contact with an application surface, and the combination of the nano silver wire formula of the conductive film layer and the metal grid layer is uniquely combined with the current optional path of the high-efficiency conductive film for replacing ITO, so that the conductivity is fully improved. The conductive paste and the conductive adhesive have unique formulas, and are good at combining the advantages of the nano silver wires and the metal grid layer to carry out architectural design, so that the square resistance is greatly reduced, and the application value of the scheme of replacing the conductive film by the ITO is improved.
Drawings
Fig. 1 is a schematic structural level diagram of the present invention, and fig. 2 is a schematic structural level diagram of the main conductive film, the metal mesh layer, and the conductive adhesive layer of the present invention.
In the figure: 1-upper protective layer, 2-upper adhesive layer, 3-anti-scratch layer, 4-conductive composite layer, 41-main conductive film, 42-metal grid layer, 43-conductive adhesive layer, 5-release adhesive layer and 6-release layer.
Detailed Description
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the following briefly introduces the embodiments.
Examples 1 to 5
As shown in fig. 1-2, an optical high-flexibility conductive glass film, in which the right side is outside and the left side is inside, the right side and the left side are inside, the upper protective layer 1, the upper adhesive layer 2, the scratch-resistant layer 3, the conductive composite layer 4, the release layer 5 and the release layer 6 are sequentially included from outside to inside, the upper adhesive layer 2 adopts silica gel glue, the release layer 5 and the scratch-resistant layer 3 are made of one of PET films and PC films, preferably PET films, the conductive composite layer 4 sequentially includes a conductive film layer and a conductive adhesive layer 43 from outside to inside, the conductive film layer includes a main conductive film 41 and a metal mesh layer 42 embedded in the main conductive film 41, the main conductive film 41 is formed by coating conductive paste, and the conductive adhesive layer 43 is formed by coating conductive adhesive;
the metal grid layer 42 is made of one of copper, silver, gold, chromium-gold, titanium-palladium-gold, titanium-platinum-gold and titanium-copper-gold;
the raw materials of the conductive paste and the raw materials of the conductive adhesive comprise the components in parts by weight according to the examples in the table 1.
TABLE 1 Components of the examples (unit: parts by weight)
The silver nanowire dispersion is a dispersion liquid of silver nanowires in water, ethanol or isopropanol, the diameters of the silver nanowires are 80nm in example 1, 67nm in example 2, 88nm in example 3, 90nm in example 4, 71nm in example 5, and the lengths of the silver nanowires are 80, 70, 90, 100 and 75 micrometers in examples 1-5 respectively; the mixed solvent comprises at least two component combinations of saturated alcohols, ketones and esters with 4-9 carbon atoms, and the best component combination is the combination of three components.
A preparation method of an optical high-flexibility conductive glass film comprises the following steps:
(1) adding the silver nanowire dispersion, alkylphenol ethoxylates, ethylene glycol phenyl ether, acrylic resin monomer, diethylenetriamine, oligosaccharide, sodium carboxymethylcellulose and a mixed solvent into a vacuum stirrer according to a formula ratio, defoaming in vacuum, and uniformly stirring to obtain a solution A, placing the solution A into a high-speed stirrer, adding cyano phosphate and a thickening agent into the solution A, stirring at 500-800rpm for 5-15min to obtain conductive paste, wherein the concentration of silver nanowires in the conductive paste is 15-60mg/m L;
(2) coating the prepared conductive paste on the anti-scraping layer, drying, coating again and drying, repeating the steps for 2-4 times, temporarily not drying after the last coating, pressing by using a grid graver to form a metal grid groove, and drying to form a main conductive film with the thickness of 20-400 mu m in total; the thicknesses of the main body conductive films in the embodiments 1 to 5 are respectively 201, 176, 127, 165 and 230 μm;
(3) at 3 to 5 × 10-3Under the vacuum degree of Pa, plating the metal material for the metal grid on the groove position of the metal grid by adopting an evaporation plating method, and filling the groove of the metal grid to form the metal gridThe total thickness of the metal grid layer is slightly larger than the depth of the metal grid groove, and the grid metal line width of the metal grid layer is not more than 3 mu m; repairing the surfaces of the metal grid layer and the main conductive film to be flat;
(4) preparing a conductive adhesive according to a formula, coating the conductive adhesive on the surfaces of the main conductive film and the metal grid layer, and forming a conductive adhesive layer with the coating thickness of 50-500 mu m; the coating thicknesses of the conductive adhesive in the embodiments 1 to 5 are respectively 131 μm, 152 μm, 205 μm, 172 μm and 98 μm;
(5) coating a prepared release adhesive on the conductive adhesive layer, and attaching a release film; and similarly, coating the silica gel glue of the glue coating layer on the anti-scraping layer and then pasting the protective layer to obtain the anti-scraping glue.
The results of the basic performance tests on the conductive composite layer of the obtained optical high-flexibility conductive glass film are shown in table 2.
TABLE 2 basic Performance index of the examples
In conclusion, the optical high-flexibility conductive glass film has excellent visible light transmittance and small sheet resistance.
The above embodiments are only intended to illustrate the preferred embodiments of the present invention, and it should be noted that, for those skilled in the art, various modifications and equivalent substitutions can be made without departing from the principle of the present invention, and the scope of the present invention is still covered by the claims.
Claims (7)
1. The utility model provides a high flexible electrically conductive glass membrane of optics, its characterized in that includes protective layer, last glue film, scratch-resistant layer, electrically conductive composite bed in proper order, leaves the glue film, leaves the type layer from outside to inside, electrically conductive composite bed includes electrically conductive rete, electrically conductive glue film in proper order from outside to inside, and electrically conductive rete includes main part conducting film and the metal grid layer that imbeds in the main part conducting film, the main part conducting film is formed by electrically conductive thick liquid coating, the raw materials of electrically conductive thick liquid contain the component of following parts by weight:
70-80 parts of silver nanowire dispersion
3-5 parts of alkylphenol polyoxyethylene
1-3 parts of ethylene glycol phenyl ether
8-12 parts of acrylic resin monomer
1.5-4 parts of diethylenetriamine
0.1-0.4 part of cyano phosphate
12-20 parts of oligosaccharide
Sodium carboxymethylcellulose 1-2.5 parts
20-30 parts of mixed solvent
0.2-1 part of thickening agent;
the conductive adhesive layer is formed by coating conductive adhesive, and the raw materials of the conductive adhesive comprise the following components in parts by weight:
15-25 parts of epoxy resin
22-35 parts of isopropanol
5-7 parts of diethylenetriamine
6-9 parts of polyvinyl alcohol
3-5 parts of methyl vinyl polysiloxane
5-10 parts of waterborne polyurethane emulsion
55-70 parts of electrolytic silver powder
15-22 parts of graphite powder
3-8 parts of toughening agent
1.5-3.5 parts of curing agent.
2. The optical highly flexible conductive glass film according to claim 1, wherein said glue layer is a silicone glue.
3. The optical high-flexibility conductive glass film as claimed in claim 1, wherein the release layer and the scratch-resistant layer are made of one of a PET film and a PC film.
4. The optical high-flexibility conductive glass film according to claim 1, wherein the silver nanowire dispersion is a dispersion of silver nanowires in water, ethanol or isopropanol, the diameter of the silver nanowires is 30-100nm, and the length of the silver nanowires is 5-100 μm.
5. The optical high-flexibility conductive glass film according to claim 1, wherein the metal mesh layer is made of one of copper, silver, gold, chromium-gold, titanium-palladium-gold, titanium-platinum-gold, and titanium-copper-gold.
6. The optical high-flexibility conductive glass film according to claim 1, wherein the mixed solvent comprises a combination of at least two of saturated alcohols, ketones, and esters having 4 to 9 carbon atoms.
7. The method for preparing an optical high-flexibility conductive glass film according to any one of claims 1 to 6, comprising the steps of:
(1) adding the silver nanowire dispersion, alkylphenol ethoxylates, ethylene glycol phenyl ether, acrylic resin monomer, diethylenetriamine, oligosaccharide, sodium carboxymethylcellulose and a mixed solvent into a vacuum stirrer according to a formula ratio, defoaming in vacuum, and uniformly stirring to obtain a solution A, placing the solution A into a high-speed stirrer, adding cyano phosphate and a thickening agent into the solution A, stirring at 500-800rpm for 5-15min to obtain conductive paste, wherein the concentration of silver nanowires in the conductive paste is 15-60mg/m L;
(2) coating the prepared conductive paste on the anti-scraping layer, drying, coating again and drying, repeating the steps for 2-4 times, temporarily not drying after the last coating, pressing by using a grid graver to form a metal grid groove, and drying to form a main conductive film with the thickness of 20-400 mu m in total;
(3) at 3 to 5 ×10-3Plating a metal material used for the metal grid at the position of a groove of the metal grid by adopting an evaporation method under the vacuum degree of Pa, and filling the groove of the metal grid to form a metal grid layer, wherein the total thickness of the metal grid layer is slightly larger than the depth of the groove of the metal grid, and the width of a grid metal line of the metal grid layer is not more than 3 mu m; repairing the surfaces of the metal grid layer and the main conductive film to be flat;
(4) preparing a conductive adhesive according to a formula, coating the conductive adhesive on the surfaces of the main conductive film and the metal grid layer, and forming a conductive adhesive layer with the coating thickness of 50-500 mu m;
(5) coating a prepared release adhesive on the conductive adhesive layer, and attaching a release film; and similarly, coating the silica gel glue of the glue coating layer on the anti-scraping layer and then pasting the protective layer to obtain the anti-scraping glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810581923.9A CN108749244B (en) | 2018-06-07 | 2018-06-07 | Optical high-flexibility conductive glass film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810581923.9A CN108749244B (en) | 2018-06-07 | 2018-06-07 | Optical high-flexibility conductive glass film and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108749244A CN108749244A (en) | 2018-11-06 |
| CN108749244B true CN108749244B (en) | 2020-07-14 |
Family
ID=64000472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810581923.9A Active CN108749244B (en) | 2018-06-07 | 2018-06-07 | Optical high-flexibility conductive glass film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108749244B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109240015A (en) * | 2018-11-08 | 2019-01-18 | 揭阳市宏光镀膜玻璃有限公司 | A kind of production method of electrochomeric glass |
| CN112078196A (en) * | 2020-09-09 | 2020-12-15 | 武汉华星光电半导体显示技术有限公司 | Composite film layer and display device |
| CN113409991B (en) * | 2021-06-18 | 2022-12-02 | 江苏纳美达光电科技有限公司 | Flexible composite conductive film and preparation method and application thereof |
| CN114927260A (en) * | 2022-03-16 | 2022-08-19 | 苏州六材新材料科技有限公司 | Conductive film and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106003947A (en) * | 2016-06-30 | 2016-10-12 | 广东新视野薄膜有限公司 | Safety film and preparation method thereof |
| CN106128563A (en) * | 2016-08-15 | 2016-11-16 | 东莞市纳利光学材料有限公司 | A kind of conductive heat conduction film and preparation method thereof |
| CN106601382A (en) * | 2016-12-15 | 2017-04-26 | 华南理工大学 | Flexible transparent conductive film preparation method |
| CN106990857A (en) * | 2016-01-21 | 2017-07-28 | 王干 | A kind of composite nano silver wire flexible and transparent conductive electrode structure and preparation method |
| CN107964111A (en) * | 2017-12-05 | 2018-04-27 | 浙江欧仁新材料有限公司 | Flexible conductive film based on conductive nano silver wire |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW555790B (en) * | 2000-12-26 | 2003-10-01 | Matsushita Electric Ind Co Ltd | Conductive organic thin film, process for producing the same, and organic photoelectronic device, electric wire, and electrode aech employing the same |
| EP2396375B1 (en) * | 2009-02-16 | 2017-05-17 | Cytec Technology Corp. | Conductive surfacing films for lightning strike and electromagnetic interference shielding of thermoset composite materials |
| US20140120356A1 (en) * | 2012-06-18 | 2014-05-01 | Ormet Circuits, Inc. | Conductive film adhesive |
| CN103436197B (en) * | 2013-09-02 | 2015-11-11 | 南京萨特科技发展有限公司 | A kind of overtemperature and overcurrent protection element conductive resin and preparation method thereof |
| CN105612585B (en) * | 2013-09-30 | 2018-03-16 | 东洋纺株式会社 | Electrocondution slurry, conductive coating, galvanic circle, electric conductivity laminate and touch-screen |
| KR102220972B1 (en) * | 2014-06-30 | 2021-02-25 | 코오롱인더스트리 주식회사 | Polyester film and transparent electrode film using thereof |
| CN106574164A (en) * | 2014-08-29 | 2017-04-19 | 古河电气工业株式会社 | Electrically conductive adhesive composition |
| CN104893601B (en) * | 2015-05-19 | 2017-05-17 | 中国航空工业集团公司北京航空材料研究院 | Conductive adhesive film with two conductive structures and preparation method of conductive adhesive film |
| CN106413358A (en) * | 2015-07-28 | 2017-02-15 | 哈尔滨工业大学 | Electromagnetic shielding optical window based on graphene/transparent conductive film composite structure |
-
2018
- 2018-06-07 CN CN201810581923.9A patent/CN108749244B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106990857A (en) * | 2016-01-21 | 2017-07-28 | 王干 | A kind of composite nano silver wire flexible and transparent conductive electrode structure and preparation method |
| CN106003947A (en) * | 2016-06-30 | 2016-10-12 | 广东新视野薄膜有限公司 | Safety film and preparation method thereof |
| CN106128563A (en) * | 2016-08-15 | 2016-11-16 | 东莞市纳利光学材料有限公司 | A kind of conductive heat conduction film and preparation method thereof |
| CN106601382A (en) * | 2016-12-15 | 2017-04-26 | 华南理工大学 | Flexible transparent conductive film preparation method |
| CN107964111A (en) * | 2017-12-05 | 2018-04-27 | 浙江欧仁新材料有限公司 | Flexible conductive film based on conductive nano silver wire |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108749244A (en) | 2018-11-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108749244B (en) | Optical high-flexibility conductive glass film and preparation method thereof | |
| CN103187119B (en) | Conductive film, preparation method for conductive film and touch screen comprising conductive film | |
| CN104134484A (en) | Flexible transparent conductive film based on silver nanowires and preparation method | |
| CN106373664B (en) | A kind of high-performance metal grid method for preparing transparent conductive film and its product | |
| CN104916351A (en) | Flexible and transparent conductive film and preparation method thereof | |
| CN111128443B (en) | A kind of transparent conductive film and preparation method thereof | |
| CN109390080A (en) | A kind of silver nanowires and transparent conductive oxide composite transparent conductive film and its application | |
| CN113793883B (en) | Preparation method of solar cell electrode | |
| CN103760695B (en) | A kind of dimming glass using nano-silver conductive layer and manufacture method thereof | |
| TW202100671A (en) | Oxidation-resistant conductive copper paste, preparation method and use thereof | |
| CN108822649A (en) | A kind of doping silver nanowires and the flexible and transparent conductive coating of graphene and preparation method thereof | |
| CN113973488A (en) | Anti-electromagnetic interference film and method of making the same | |
| CN213844777U (en) | Nano-silver wire composite transparent conductive film | |
| CN108447617A (en) | A method of protection nano-silver thread transparent conductive film | |
| CN114038623A (en) | Silver nanowire-biological material composite transparent conductive film and preparation method and application thereof | |
| CN106328252A (en) | Silver nanowire conducting transparent film and manufacture method thereof | |
| CN104021845A (en) | Transparent conductor | |
| CN209343800U (en) | A double-layer transparent conductive film | |
| CN106775073A (en) | A sensor glass plus tempered glass structure touch screen and preparation method thereof | |
| CN110957059A (en) | Silver nanowire transparent conductive film and preparation method and application thereof | |
| CN206232658U (en) | A kind of antistatic silica gel diaphragm | |
| CN211591645U (en) | Composite film for alcohol-based nano silver wire ink coating and nano silver wire conductive film | |
| CN209568047U (en) | A kind of high intensity aluminium film | |
| CN109285639B (en) | Conductive film and preparation method thereof | |
| CN109698047B (en) | Preparation method of waterproof foldable flexible conductive film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200628 Address after: 321000 13 Chuang Chuang Road, Lanxi Economic Development Zone, Jinhua, Zhejiang Applicant after: ZHEJIANG XINLIN NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 215400, 8, Kai Xing Road, old gate area, pontoon bridge, Suzhou, Jiangsu, Taicang Applicant before: SUZHOU XILIN OPTOELECTRONICS TECHNOLOGY INDUSTRY Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An optical high flexibility conductive glass film and its preparation method Effective date of registration: 20230407 Granted publication date: 20200714 Pledgee: Zhejiang Lanxi Rural Commercial Bank Co.,Ltd. Pledgor: ZHEJIANG XINLIN NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2023980037594 |