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CN108729244A - The silicon rubber synthetic leather and its manufacturing technology of outdoor furniture - Google Patents

The silicon rubber synthetic leather and its manufacturing technology of outdoor furniture Download PDF

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Publication number
CN108729244A
CN108729244A CN201810769616.3A CN201810769616A CN108729244A CN 108729244 A CN108729244 A CN 108729244A CN 201810769616 A CN201810769616 A CN 201810769616A CN 108729244 A CN108729244 A CN 108729244A
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CN
China
Prior art keywords
parts
outdoor furniture
synthetic leather
vinyl
silicon
Prior art date
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Withdrawn
Application number
CN201810769616.3A
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Chinese (zh)
Inventor
陶玉红
胥晓群
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Tian Yue New Material Ltd By Share Ltd
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Guangdong Tian Yue New Material Ltd By Share Ltd
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Application filed by Guangdong Tian Yue New Material Ltd By Share Ltd filed Critical Guangdong Tian Yue New Material Ltd By Share Ltd
Priority to CN201810769616.3A priority Critical patent/CN108729244A/en
Publication of CN108729244A publication Critical patent/CN108729244A/en
Priority to PCT/CN2019/085749 priority patent/WO2020010909A1/en
Withdrawn legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D06N3/106Elastomers
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
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    • D06N2201/00Chemical constitution of the fibres, threads or yarns
    • D06N2201/04Vegetal fibres
    • D06N2201/042Cellulose fibres, e.g. cotton
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    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/045Vinyl (co)polymers
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    • D06N2209/00Properties of the materials
    • D06N2209/08Properties of the materials having optical properties
    • D06N2209/0807Coloured
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    • D06N2209/0846Matt, dull surface
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    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/146Soilproof, soil repellent
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    • D06N2211/12Decorative or sun protection articles
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    • D06N2211/00Specially adapted uses
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    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth is coated with the silastic-layer of outdoor furniture on the base material cloth, outdoor furniture matt handfeel pasta layer is coated on the silastic-layer;It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, 100-200 parts of vinylsiloxane rubber base rubber, 5-10 parts of high-vinyl silicone oil, 10-20 parts of vinyl MQ resin, 5-15 parts of methyl MQ resins, 5-20 parts of containing hydrogen silicone oil, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor.The present invention prepares the outdoor synthetic leather used using fluid silicone rubber, the synthetic leather can meet requirement of the outdoor furniture to synthetic leather well, have many advantages, such as ageing-resistant, hydrolysis, color inhibition, while the characteristics of the silicon rubber synthetic leather also possesses waterproof and breathable, easy to clean, asepsis environment-protecting.

Description

The silicon rubber synthetic leather and its manufacturing technology of outdoor furniture
Technical field
The present invention relates to silicon rubber leathers, and in particular to a kind of the silicon rubber synthetic leather and the outdoor furniture of outdoor furniture The manufacturing technology of silicon rubber synthetic leather.
Background technology
With the development of modern high technology, artificial leather, synthetic leather all realize quickly in product quality, kind and yield Increase, appearance is splendid colorful, and performance becomes closer to natural leather, and the performance of some aspects is even more than natural leather.
Artificial leather used at present, synthetic leather are based on polyvinyl chloride (PVC), polyurethanes (PU), in order to obtain Good comfort level, PVC artificial leather can add a large amount of benzoate plasticizer in use;PU synthetic leather can discharge People and environment are caused prodigious injury by a large amount of DMF waste water and discarded.Simultaneously these products that there is also ageing properties is poor, Not hydrolysis, not color inhibition the problems such as, cannot use outdoors for a long time.
In order to avoid the above problem, there is part of the manufacturer to be asked by using Thermoplastic polyurethane elastomer material to solve this Topic.Such as in the Chinese invention patent of Publication No. CN 103541228A, application discloses a kind of environment-friendlyoutdoor outdoor sofa leather Preparation method, which prepares sofa artificial leather using thermoplastic polyurethane elastomer as raw material, and this method solve tradition The problem of producing problem of environmental pollution present in synthetic leather, but aging and hydrolysis still remained by the sofa artificial leather of its making, no Can meet the needs of outdoor sofa very well.
Invention content
It is an object of the present invention to provide a kind of silicon rubber synthetic leather of outdoor furniture regarding to the issue above, meet family Requirement of the outer furniture to synthetic leather has many advantages, such as ageing-resistant, hydrolysis, color inhibition, while also having waterproof and breathable, Yi Qing The characteristics of clean, asepsis environment-protecting.
The present invention also aims to provide the manufacturing technology of the silicon rubber synthetic leather of above-mentioned outdoor furniture.
Present invention technical solution used for the above purpose is:
A kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth is coated with outdoor family on the base material cloth The silastic-layer of tool is coated with outdoor furniture matt handfeel pasta layer on the silastic-layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 100-200 parts, 5-10 parts of high-vinyl silicone oil, 10-20 parts of vinyl MQ resin, 5-15 parts of methyl MQ resins, containing hydrogen silicone oil 5- 20 parts, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor.
It is figured by mass parts, the outdoor furniture is made of following raw material with matt handfeel pasta layer:Vinyl silicone oil 100-120 parts, 30-50 parts of vinyl MQ resin, 30-50 parts of Vinylphenyl silicon resin, 20-30 parts of hydrogeneous MQ resins, silicon it is micro- 10-20 parts of powder, 3-5 parts of flatting silica, 0.1-0.5 parts of platinum catalyst, 0.02-0.1 parts of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
Vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
The vinyl MQ resin medium vinyl content is 2-3%.
The tackifier are polyether-modified dimethyl silicone polymer.
The mesh number of the silicon powder is 5000-6000 mesh;
The containing hydrogen silicone oil hydrogen content is 0.55-1.2%;
Hydrogen content is 0.8%-1.0% in the hydrogeneous MQ resins;
The platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution;
The inhibitor is the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
A kind of manufacturing technology of the silicon rubber synthetic leather of aforementioned outdoor furniture, which is characterized in that it includes the following steps:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
In step 1, by 100-200 parts of vinylsiloxane rubber base rubber, 5-10 parts of high-vinyl silicone oil, vinyl MQ resin 10-20 parts, 5-15 parts of methyl MQ resins, 5-20 parts of containing hydrogen silicone oil, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, color 5-20 parts of pigment, 0.02-0.1 parts of inhibitor are put into planet dispersator, and cooling water is led to, and open vacuum equipment, dispersion Stirring 10 minutes.
In step 2, by 100-120 parts of vinyl silicone oil, 30-50 parts of vinyl MQ resin, Vinylphenyl silicon resin 30-50 parts, 20-30 parts of hydrogeneous MQ resins, 10-20 parts of silicon powder, 3-5 parts of flatting silica, 0.1-0.5 parts of platinum catalyst, inhibit 0.02-0.1 parts of agent disperses 10 minutes in dispersion machine.
In step 3, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then pass through Coated silicon rubber is transmitted to continuous tunnel furnace by conveyer belt, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C, and outdoor family is formed Tool matt handfeel pasta layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and with base material cloth Fitting, then passes to continuous tunnel furnace, vulcanizes 5-10 minutes at a temperature of 100-140 DEG C, and release paper or leather paper are removed, obtained To the silicon rubber synthetic leather of outdoor furniture.
Beneficial effects of the present invention are:The present invention prepares the outdoor synthetic leather used, the synthesis using fluid silicone rubber Leather can meet requirement of the outdoor furniture to synthetic leather well, have many advantages, such as ageing-resistant, hydrolysis, color inhibition, simultaneously should Silicon rubber synthetic leather also possesses the characteristics of waterproof and breathable, easy to clean, asepsis environment-protecting.
Specific implementation mode
Embodiment present embodiments provides a kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth, the base It is coated with the silastic-layer of outdoor furniture on material cloth, outdoor furniture matt handfeel pasta is coated on the silastic-layer Layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 100-200 parts, 5-10 parts of high-vinyl silicone oil, 10-20 parts of vinyl MQ resin, 5-15 parts of methyl MQ resins, containing hydrogen silicone oil 5- 20 parts, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor.
It is figured by mass parts, the outdoor furniture is made of following raw material with matt handfeel pasta layer:Vinyl silicone oil 100-120 parts, 30-50 parts of vinyl MQ resin, 30-50 parts of Vinylphenyl silicon resin, 20-30 parts of hydrogeneous MQ resins, silicon it is micro- 10-20 parts of powder, 3-5 parts of flatting silica, 0.1-0.5 parts of platinum catalyst, 0.02-0.1 parts of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
Vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
The vinyl MQ resin medium vinyl content is 2-3%.
The tackifier are polyether-modified dimethyl silicone polymer.
The mesh number of the silicon powder is 5000-6000 mesh;
The containing hydrogen silicone oil hydrogen content is 0.55-1.2%;
Hydrogen content is 0.8%-1.0% in the hydrogeneous MQ resins;
The platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution;
The inhibitor is the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
A kind of manufacturing technology of the silicon rubber synthetic leather of aforementioned outdoor furniture, which is characterized in that it includes the following steps:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
In step 1, by 100-200 parts of vinylsiloxane rubber base rubber, 5-10 parts of high-vinyl silicone oil, vinyl MQ resin 10-20 parts, 5-15 parts of methyl MQ resins, 5-20 parts of containing hydrogen silicone oil, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, color 5-20 parts of pigment, 0.02-0.1 parts of inhibitor are put into planet dispersator, and cooling water is led to, and open vacuum equipment, dispersion Stirring 10 minutes.
In step 2, by 100-120 parts of vinyl silicone oil, 30-50 parts of vinyl MQ resin, Vinylphenyl silicon resin 30-50 parts, 20-30 parts of hydrogeneous MQ resins, 10-20 parts of silicon powder, 3-5 parts of flatting silica, 0.1-0.5 parts of platinum catalyst, inhibit 0.02-0.1 parts of agent disperses 10 minutes in dispersion machine.
In step 3, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then pass through Coated silicon rubber is transmitted to continuous tunnel furnace by conveyer belt, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C, and outdoor family is formed Tool matt handfeel pasta layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and with base material cloth Fitting, then passes to continuous tunnel furnace, vulcanizes 5-10 minutes at a temperature of 100-140 DEG C, and release paper or leather paper are removed, obtained To the silicon rubber synthetic leather of outdoor furniture.
The present invention prepares the outdoor synthetic leather used using fluid silicone rubber, which can meet open air well Requirement of the furniture to synthetic leather, has many advantages, such as ageing-resistant, hydrolysis, color inhibition, at the same the silicon rubber synthetic leather also possess it is anti- The characteristics of water is ventilative, easy to clean, asepsis environment-protecting.
Embodiment 1 present embodiments provides a kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth, it should It is coated with the silastic-layer of outdoor furniture on base material cloth, outdoor furniture matt handfeel pasta is coated on the silastic-layer Layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 100 parts, 5 parts of high-vinyl silicone oil, 10 parts of vinyl MQ resin, 5 parts of methyl MQ resins, 5 parts of containing hydrogen silicone oil, 1 part of tackifier, platinum 0.1 part of Au catalyst, 5 parts of color pigment, 0.02 part of inhibitor.
It is figured by mass parts, the outdoor furniture is made of following raw material with matt handfeel pasta layer:Vinyl silicone oil 100 Part, 30 parts of vinyl MQ resin, 30 parts of Vinylphenyl silicon resin, 20 parts of hydrogeneous MQ resins, 10 parts of silicon powder, 3 parts of flatting silica, 0.1 part of platinum catalyst, 0.02 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
Vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
The vinyl MQ resin medium vinyl content is 2-3%.
The tackifier are polyether-modified dimethyl silicone polymer.
The mesh number of the silicon powder is 5000-6000 mesh;
The containing hydrogen silicone oil hydrogen content is 0.55%;
Hydrogen content is 0.8%-1.0% in the hydrogeneous MQ resins;
The platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution;
The inhibitor is the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
A kind of manufacturing technology of the silicon rubber synthetic leather of aforementioned outdoor furniture, which is characterized in that it includes the following steps:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
In step 1, by 100 parts of vinylsiloxane rubber base rubber, 5 parts of high-vinyl silicone oil, 10 parts of vinyl MQ resin, first 0.02 part of 5 parts of base MQ resins, 5 parts of containing hydrogen silicone oil, 1 part of tackifier, 0.1 part of platinum catalyst, 5 parts of color pigment, inhibitor throwing Enter into planet dispersator, lead to cooling water, opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 100 parts of vinyl silicone oil, 30 parts of vinyl MQ resin, 30 parts of Vinylphenyl silicon resin, hydrogeneous 20 parts of MQ resins, 10-20 parts of silicon powder, 3-5 parts of flatting silica, 0.1 part of platinum catalyst, 0.02 part of inhibitor, in dispersion machine Dispersion 10 minutes.
In step 3, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then pass through Coated silicon rubber is transmitted to continuous tunnel furnace by conveyer belt, is vulcanized 5 minutes at a temperature of 100 DEG C, forms outdoor furniture with mute Light feel pasta layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and with base material cloth Fitting, then passes to continuous tunnel furnace, vulcanizes 5 minutes at a temperature of 100 DEG C, and release paper or leather paper are removed, open air is obtained The silicon rubber synthetic leather of furniture.
The present invention prepares the outdoor synthetic leather used using fluid silicone rubber, which can meet open air well Requirement of the furniture to synthetic leather, has many advantages, such as ageing-resistant, hydrolysis, color inhibition, at the same the silicon rubber synthetic leather also possess it is anti- The characteristics of water is ventilative, easy to clean, asepsis environment-protecting.
Embodiment 2 present embodiments provides a kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth, it should It is coated with the silastic-layer of outdoor furniture on base material cloth, outdoor furniture matt handfeel pasta is coated on the silastic-layer Layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 200 parts, 10 parts of high-vinyl silicone oil, 20 parts of vinyl MQ resin, 15 parts of methyl MQ resins, 20 parts of containing hydrogen silicone oil, tackifier 2 Part, 0.5 part of platinum catalyst, 20 parts of color pigment, 0.1 part of inhibitor.
It is figured by mass parts, the outdoor furniture is made of following raw material with matt handfeel pasta layer:Vinyl silicone oil 120 Part, 50 parts of vinyl MQ resin, 50 parts of Vinylphenyl silicon resin, 30 parts of hydrogeneous MQ resins, 20 parts of silicon powder, 5 parts of flatting silica, 0.5 part of platinum catalyst, 0.1 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
Vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
The vinyl MQ resin medium vinyl content is 2-3%.
The tackifier are polyether-modified dimethyl silicone polymer.
The mesh number of the silicon powder is 5000-6000 mesh;
The containing hydrogen silicone oil hydrogen content is 1.2%;
Hydrogen content is 0.8%-1.0% in the hydrogeneous MQ resins;
The platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution;
The inhibitor is the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
A kind of manufacturing technology of the silicon rubber synthetic leather of aforementioned outdoor furniture, which is characterized in that it includes the following steps:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
In step 1, by 200 parts of vinylsiloxane rubber base rubber, 10 parts of high-vinyl silicone oil, 20 parts of vinyl MQ resin, first 15 parts of base MQ resins, 20 parts of containing hydrogen silicone oil, 2 parts of tackifier, 0.5 part of platinum catalyst, 20 parts of color pigment, 0.1 part of inhibitor It puts into planet dispersator, leads to cooling water, open vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 120 parts of vinyl silicone oil, 50 parts of vinyl MQ resin, 50 parts of Vinylphenyl silicon resin, hydrogeneous 30 parts of MQ resins, 20 parts of silicon powder, 5 parts of flatting silica, 0.5 part of platinum catalyst, 0.1 part of inhibitor, disperse 10 in dispersion machine Minute.
In step 3, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then pass through Coated silicon rubber is transmitted to continuous tunnel furnace by conveyer belt, is vulcanized 10 minutes at a temperature of 140 DEG C, forms outdoor furniture with mute Light feel pasta layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and with base material cloth Fitting, then passes to continuous tunnel furnace, vulcanizes 10 minutes at a temperature of 140 DEG C, and release paper or leather paper are removed, open air is obtained The silicon rubber synthetic leather of furniture.
The present invention prepares the outdoor synthetic leather used using fluid silicone rubber, which can meet open air well Requirement of the furniture to synthetic leather, has many advantages, such as ageing-resistant, hydrolysis, color inhibition, at the same the silicon rubber synthetic leather also possess it is anti- The characteristics of water is ventilative, easy to clean, asepsis environment-protecting.
Embodiment 3 present embodiments provides a kind of silicon rubber synthetic leather of outdoor furniture comprising base material cloth, it should It is coated with the silastic-layer of outdoor furniture on base material cloth, outdoor furniture matt handfeel pasta is coated on the silastic-layer Layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 150 parts, 7.5 parts of high-vinyl silicone oil, 15 parts of vinyl MQ resin, 10 parts of methyl MQ resins, 12.5 parts of containing hydrogen silicone oil, tackifier 1.5 parts, 0.3 part of platinum catalyst, 12.5 parts of color pigment, 0.06 part of inhibitor.
It is figured by mass parts, the outdoor furniture is made of following raw material with matt handfeel pasta layer:Vinyl silicone oil 110 Part, 40 parts of vinyl MQ resin, 40 parts of Vinylphenyl silicon resin, 25 parts of hydrogeneous MQ resins, 15 parts of silicon powder, 4 parts of flatting silica, 0.3 part of platinum catalyst, 0.06 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
Vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
The vinyl MQ resin medium vinyl content is 2-3%.
The tackifier are polyether-modified dimethyl silicone polymer.
The mesh number of the silicon powder is 5000-6000 mesh;
The containing hydrogen silicone oil hydrogen content is 0.75%, in some other embodiment, it is also an option that hydrogen content is 1%;
Hydrogen content is 0.8%-1.0% in the hydrogeneous MQ resins;
The platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution;
The inhibitor is the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
A kind of manufacturing technology of the silicon rubber synthetic leather of aforementioned outdoor furniture, which is characterized in that it includes the following steps:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
In step 1, by 150 parts of vinylsiloxane rubber base rubber, 7.5 parts of high-vinyl silicone oil, 15 parts of vinyl MQ resin, 10 parts of methyl MQ resins, 1.5 parts of tackifier, 0.3 part of platinum catalyst, 12.5 parts of color pigment, inhibit 12.5 parts of containing hydrogen silicone oil 0.06 part of agent is put into planet dispersator, and cooling water is led to, and opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 110 parts of vinyl silicone oil, 40 parts of vinyl MQ resin, 40 parts of Vinylphenyl silicon resin, hydrogeneous 25 parts of MQ resins, 15 parts of silicon powder, 4 parts of flatting silica, 0.3 part of platinum catalyst, 0.06 part of inhibitor, disperse 10 in dispersion machine Minute.
In step 3, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then pass through Coated silicon rubber is transmitted to continuous tunnel furnace by conveyer belt, is vulcanized 7.5 minutes at a temperature of 120 DEG C, is formed outdoor furniture and is used Matt handfeel pasta layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and with base material cloth Fitting, then passes to continuous tunnel furnace, vulcanizes 7.5 minutes at a temperature of 120 DEG C, and release paper or leather paper are removed, family is obtained The silicon rubber synthetic leather of outer furniture.
The present invention prepares the outdoor synthetic leather used using fluid silicone rubber, which can meet open air well Requirement of the furniture to synthetic leather, has many advantages, such as ageing-resistant, hydrolysis, color inhibition, at the same the silicon rubber synthetic leather also possess it is anti- The characteristics of water is ventilative, easy to clean, asepsis environment-protecting.
The above described is only a preferred embodiment of the present invention, being not intended to limit the present invention in any form.Appoint What those skilled in the art, without departing from the scope of the technical proposal of the invention, all using the skill of the disclosure above Art means and technology contents make many possible changes and modifications to technical solution of the present invention, or be revised as equivalent variations etc. Imitate embodiment.Therefore every content without departing from technical solution of the present invention, made by shape according to the present invention, construction and principle etc. Effect variation, should all be covered by protection scope of the present invention.

Claims (10)

1. a kind of silicon rubber synthetic leather of outdoor furniture, it is characterised in that:It includes base material cloth, is coated on the base material cloth There is the silastic-layer of outdoor furniture, outdoor furniture matt handfeel pasta layer is coated on the silastic-layer;
It is figured by mass parts, the silastic-layer of the outdoor furniture is made of following raw material, vinylsiloxane rubber base rubber 100- 200 parts, 5-10 parts of high-vinyl silicone oil, 10-20 parts of vinyl MQ resin, 5-15 parts of methyl MQ resins, 5-20 parts of containing hydrogen silicone oil, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor.
2. the silicon rubber synthetic leather of outdoor furniture according to claim 1, which is characterized in that it is figured by mass parts, it is described Outdoor furniture is made of following raw material with matt handfeel pasta layer:100-120 parts of vinyl silicone oil, vinyl MQ resin 30-50 Part, 30-50 parts of Vinylphenyl silicon resin, 20-30 parts of hydrogeneous MQ resins, 10-20 parts of silicon powder, 3-5 parts of flatting silica, platinum are urged 0.1-0.5 parts of agent, 0.02-0.1 parts of inhibitor.
3. the silicon rubber synthetic leather of outdoor furniture according to claim 1, which is characterized in that the vinylsiloxane rubber base Glue hardness range 30-70A, contents of ethylene 0.2-2%;
High-vinyl silicon oil viscosity is 10000-30000cs, contents of ethylene 5-7%.
4. the silicon rubber synthetic leather of outdoor furniture according to claim 2, which is characterized in that vinyl silicone oil viscosity is 10000-30000cs, contents of ethylene 0.05%-0.1%;
Vinylphenyl silicon resin medium vinyl content is 2-3%.
5. the silicon rubber synthetic leather of outdoor furniture according to claim 1, which is characterized in that in the vinyl MQ resin Contents of ethylene is 2-3%.
6. the silicon rubber synthetic leather of outdoor furniture according to claim 1, which is characterized in that the tackifier change for polyethers Property dimethyl silicone polymer.
7. a kind of manufacturing technology of the silicon rubber synthetic leather of outdoor furniture described in claim 1, which is characterized in that it include with Lower step:
Step 1: the preparation of the silicone rubber material of outdoor furniture;
Step 2: the preparation of the matt handfeel oil of outdoor fixture;
Step 3: the manufacture of the silicon rubber synthetic leather of outdoor furniture.
8. the manufacturing technology of the silicon rubber synthetic leather of outdoor furniture according to claim 7, which is characterized in that step 1 In, by 100-200 parts of vinylsiloxane rubber base rubber, 5-10 parts of high-vinyl silicone oil, 10-20 parts of vinyl MQ resin, methyl MQ 5-15 parts of resin, 1-2 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, inhibits 5-20 parts of containing hydrogen silicone oil 0.02-0.1 parts of agent is put into planet dispersator, and cooling water is led to, and opens vacuum equipment, dispersion stirring 10 minutes.
9. the manufacturing technology of the silicon rubber synthetic leather of outdoor furniture according to claim 8, which is characterized in that step 2 In, by 100-120 parts of vinyl silicone oil, 30-50 parts of vinyl MQ resin, 30-50 parts of Vinylphenyl silicon resin, hydrogeneous MQ trees 20-30 parts of fat, 10-20 parts of silicon powder, 3-5 parts of flatting silica, 0.1-0.5 parts of platinum catalyst, 0.02-0.1 parts of inhibitor are dividing It dissipates and disperses 10 minutes in machine.
10. the manufacturing technology of the silicon rubber synthetic leather of outdoor furniture according to claim 9, which is characterized in that step 3 In, by the matt handfeel oil raw material of outdoor furniture in release paper or leather paper, then will be coated by conveyer belt Silicon rubber be transmitted to continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, formed outdoor furniture matt handfeel oil Face layer;
The silicone rubber material of outdoor furniture is coated on outdoor furniture on matt handfeel pasta layer, and is pasted with base material cloth It closes, then passes to continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, release paper or leather paper are removed, obtained The silicon rubber synthetic leather of outdoor furniture.
CN201810769616.3A 2018-07-13 2018-07-13 The silicon rubber synthetic leather and its manufacturing technology of outdoor furniture Withdrawn CN108729244A (en)

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