CN108726980A - A kind of hydrophobic self-cleaning magnesite wallboard - Google Patents
A kind of hydrophobic self-cleaning magnesite wallboard Download PDFInfo
- Publication number
- CN108726980A CN108726980A CN201810729099.7A CN201810729099A CN108726980A CN 108726980 A CN108726980 A CN 108726980A CN 201810729099 A CN201810729099 A CN 201810729099A CN 108726980 A CN108726980 A CN 108726980A
- Authority
- CN
- China
- Prior art keywords
- parts
- magnesite
- cleaning
- ultralight
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000001095 magnesium carbonate Substances 0.000 title claims abstract description 51
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 title claims abstract description 51
- 235000014380 magnesium carbonate Nutrition 0.000 title claims abstract description 51
- 229910000021 magnesium carbonate Inorganic materials 0.000 title claims abstract description 51
- 238000004140 cleaning Methods 0.000 title claims abstract description 28
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 24
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 26
- 230000003075 superhydrophobic effect Effects 0.000 claims abstract description 21
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940070527 tourmaline Drugs 0.000 claims abstract description 11
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 11
- 239000011032 tourmaline Substances 0.000 claims abstract description 11
- 235000019362 perlite Nutrition 0.000 claims abstract description 10
- 239000011083 cement mortar Substances 0.000 claims abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 7
- 239000011777 magnesium Substances 0.000 claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 3
- 239000010451 perlite Substances 0.000 claims abstract description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 46
- 239000003795 chemical substances by application Substances 0.000 claims description 46
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- 239000003638 chemical reducing agent Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 24
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 23
- 239000002002 slurry Substances 0.000 claims description 21
- 238000004078 waterproofing Methods 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000003365 glass fiber Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 238000007605 air drying Methods 0.000 claims description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 230000002787 reinforcement Effects 0.000 claims description 8
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 8
- 229920000877 Melamine resin Polymers 0.000 claims description 7
- 230000001476 alcoholic effect Effects 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000009423 ventilation Methods 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 239000011152 fibreglass Substances 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 claims description 5
- 239000005046 Chlorosilane Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 4
- 229910001923 silver oxide Inorganic materials 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 239000004111 Potassium silicate Substances 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 238000005034 decoration Methods 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 239000010702 perfluoropolyether Substances 0.000 claims description 3
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- -1 siloxanes Chemical class 0.000 claims description 3
- 239000005315 stained glass Substances 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 230000003467 diminishing effect Effects 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims 2
- BVPWJMCABCPUQY-UHFFFAOYSA-N 4-amino-5-chloro-2-methoxy-N-[1-(phenylmethyl)-4-piperidinyl]benzamide Chemical compound COC1=CC(N)=C(Cl)C=C1C(=O)NC1CCN(CC=2C=CC=CC=2)CC1 BVPWJMCABCPUQY-UHFFFAOYSA-N 0.000 claims 1
- 229920001732 Lignosulfonate Polymers 0.000 claims 1
- 235000003283 Pachira macrocarpa Nutrition 0.000 claims 1
- 241001083492 Trapa Species 0.000 claims 1
- 235000014364 Trapa natans Nutrition 0.000 claims 1
- 235000009165 saligot Nutrition 0.000 claims 1
- 150000001450 anions Chemical class 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 2
- 230000036541 health Effects 0.000 abstract description 2
- 239000002086 nanomaterial Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 36
- 238000003756 stirring Methods 0.000 description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- NYNKCGWJPNZJMI-UHFFFAOYSA-N Clebopride malate Chemical compound [O-]C(=O)C(O)CC(O)=O.COC1=CC(N)=C(Cl)C=C1C(=O)NC1CC[NH+](CC=2C=CC=CC=2)CC1 NYNKCGWJPNZJMI-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/04—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
- E04C2/044—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres of concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2069—Self-cleaning materials, e.g. using lotus effect
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
A kind of hydrophobic self-cleaning magnesite wallboard, including architectural surface made of decorative magnesia cement mortar(1), ultralight filled layer made of plant fiber and perlite composite magnesite cement mortar(2), chopped strand activeness and quietness magnesia cement mortar structure layer(3)And super-hydrophobic layer(4).Product is coated in magnesite surfaces of wall by micro-nano structure coating, the sandwich construction of ultralight filled layer is wrapped up in conjunction with decorative layer and structure sheaf, effectively improve the intensity and water resistance of glass magnesium board, use nano-tourmaline in formula simultaneously, its anion discharged can purify air, be conducive to health.
Description
Technical field
The present invention relates to a kind of hydrophobic self-cleaning magnesite wallboards, are suitable for the necks such as building roof, building curtain wall, wall decoration
Domain.
Background technology
China's magnesite resource is abundant, and abundant raw material are provided to prepare magnesite product.Magnesite product is by active oxygen
Change magnesium and aqueous salt brine mixes and stirs magnesium gelatinous material made of molding, maintenance hardening.It has many excellent performances, belongs to environmental protection
Building materials, fireproof building material are good substitute for wood.It is popular in American-European and Japan, there have been a considerable amount of systems in China
Row products export.But it since the article water resistance is poor, easily makes moist and returns halogen, influence construction quality, cause the application of magnesite product
It is restricted, also directly affects the outlet of product.Therefore, can the scumming that solve magnesite product become its development and application
Key.
Invention content
In view of the above-mentioned problems, using nano-tourmaline for anion releasable material, carry out low-surface-energy to it changes the present invention
Property, in the magnesite board product surface constructing super-drainage self-cleaning coat with decoration functions, make with negative ion releasing function
Self-cleaning magnesite wallboard.
Technical scheme is as follows:
The hydrophobic self-cleaning magnesite wallboard of one kind includes architectural surface, ultralight filled layer, structure sheaf and super-hydrophobic layer;The decorative cover
Layer is made of decorative magnesia cement mortar;The ultralight filled layer is using plant fiber, perlite composite magnesite cement
Mortar is made;The structure sheaf is made of chopped strand activeness and quietness magnesia cement mortar;The architectural surface one side
Ultralight filled layer is coated between structure sheaf, 1-5 layers of fiber glass reinforcement are equipped in ultralight filled layer, and architectural surface is another
It is connected on one side with super-hydrophobic layer by resin adhesive backers.
The fiber glass reinforcement is alkali-resistant glass fibre felt, alkali-resistant glass fibre enhancing grid cloth, three-dimensional glass
One kind in glass fibrous braid.
The resin adhesive backers is the organic resin dispersion liquid that solid content is 3-15%.
The invention also discloses a kind of preparation methods of hydrophobic self-cleaning magnesite wallboard, are prepared using following steps:
(1)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 3-5 parts of decorative fillers, 1-3 parts
Modifying agent, 1-3 part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and the slurry mixed is equal
Even paving is scattered to die surface, and control thickness is rolled in 3-5mm, and preparation forms architectural surface.
(2)By 30-50 parts of magnesia, 10-30 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3
Part waterproofing agent, 1-3 parts of water-reducing agents, 10-20 parts of perlites, 10-20 parts of plant fibers are mixed evenly, the slurry that will be mixed
Successively uniform paving is scattered on the architectural surface that step 1 prepares, and is laid with 1-5 layers of fiber glass reinforcement, and control is ultralight to fill out
Layer thickness is filled in 10-520mm, and rolling is closely knit.
(3)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3
Part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and by the slurry mixed, uniformly paving is scattered to
On the ultralight filled layer that step 2 prepares, control thickness is completed magnesite wallboard and is prepared in 3-5mm.
(4)The magnesite wallboard made is placed in 25-40 DEG C of temperature, after being conserved for 24 hours under conditions of humidity 70-100%
Demoulding, then conserved 7 days under the conditions of being placed in 40-60 DEG C,
(5)8-10 parts of nano-tourmaline powders, 1-3 parts of alcoholic solutions, 0.1-0.5 parts of low-surface-energy modifying agent are uniformly mixed and are carried out
30-60min is ground, the mixture after grinding is scattered in alcoholic solution, control powder content is 10-30%, in 8000-
High speed shear is carried out in the blender of 10000r/min and disperses 30-60min, and 3-5 parts of electric conductivity dispersion liquids are added plus alcoholic solution is dilute
It releases to powder content and is stirred evenly for 0.1-1%, super hydrophobic coating is made after 72h under conditions of being placed in 30-50 DEG C.
(6)The product surface that evenly dispersed resin gluing material spraying is prepared in step 4, natural air drying or air blast are dry
After dry, super hydrophobic coating prepared by spraying process 5 conserves for 24 hours under the conditions of room ventilation, completes the hydrophobic of negative ion releasing function
It is prepared by self-cleaning magnesite wallboard.
A concentration of 15-30% of the magnesium chloride solution;Magnesium sulfate concentration is 15-30%.
The decorative fillers are one kind in inorganic toner, color sand, stone, stained glass clast, shell, mica flake
Or it is a variety of.
The modifying agent is that silica, magnesium silicate, sodium metasilicate, potassium silicate, phosphate, aluminate etc. are a kind of or more
Kind.
The waterproofing agent be organic silicon emulsion, acrylic emulsion, polyaminoester emulsion, one kind in epoxy resin latex or
It is a variety of.
The water-reducing agent be polycarboxylate water-reducer, how based water reducer, melamine system, sulfamate system, lignin sulfonic acid
It is one or more in salt.
The chopped strand is using one or more in PP fibers, PVA fibers, nylon fiber, glass fibre.
The alcoholic solution selects one kind in methanol, ethyl alcohol, propyl alcohol or isopropanol.
The low-surface-energy modifying agent includes silicon fluoride modifying agent, perfluoropolyether glycol, chlorosilane, dealcoholized type siloxanes
One or more of.
The electric conductivity dispersion liquid be micron order tin oxide sol, Sol silver oxide, one kind in zinc oxide colloidal sol or
It is a variety of.
The beneficial effects of the present invention are:
1, the coating that nano-tourmaline powder, electric conductivity dispersion liquid are mixed with is coated in magnesite surfaces of wall and forms micro-nano knot
Structure plays waterproof, surface halide accumulation resistance, self-cleaning action.
2, decorative layer and structure sheaf wrap up ultralight filled layer, can effectively improve the intensity of glass magnesium board, while playing into one
Walk water proof anti-seepage effect.
3, nano-tourmaline is added in being formulated, the anion of release can purify air, be conducive to health.
Description of the drawings
Fig. 1 is a kind of hydrophobic self-cleaning magnesite wallboard with negative ion releasing function.
1- architectural surfaces;The ultralight filled layers of 2-;3- structure sheafs;4- super-hydrophobic layers;5- fiber glass reinforcements.
Specific implementation mode
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
(1)By 50 parts of magnesia, 30 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 3 parts of inorganic colors
Powder, 1 part of silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of PP fiber, 0.1 part of polycarboxylate water-reducer are mixed evenly, will
Uniformly paving is scattered to die surface to the slurry mixed, and control thickness is rolled in 3mm, and preparation forms architectural surface.
(2)By 30 parts of magnesia, 10 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 1 part two
Silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of polycarboxylate water-reducer, 10 parts of perlites, 10 parts of plant fibers are mixed equal
Even, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 1 layer of alkali-resistant glass fibre
Felt controls ultralight filling layer thickness in 10mm, and rolling is closely knit.
(3)By 50 parts of magnesia, 30 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 1 part two
Silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of PP fiber, 0.1 part of polycarboxylate water-reducer are mixed evenly, by what is mixed
Uniformly paving is scattered on the ultralight filled layer that step 2 prepares slurry, and control thickness is completed magnesite wallboard and prepared in 3mm.
(4)The magnesite wallboard made is placed in 25 DEG C of temperature, is conserved under conditions of humidity 70% and is demoulded afterwards for 24 hours, then
It is conserved 7 days under the conditions of being placed in 40 DEG C.
(5)8 parts of nano-tourmaline powders, 1 part of methanol solution, 0.1 part of silicon fluoride modifying agent are uniformly mixed and are ground
Mixture after grinding is scattered in methanol solution by 30min, and control powder content is 10%, in the blender of 8000r/min
Middle progress high speed shear disperses 30min, and 3 parts of micron order tin oxide sols of addition plus methanol solution are diluted to powder content and are
0.1% stirs evenly, and super hydrophobic coating is made after 72h under conditions of being placed in 30 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 3% is sprayed at product surface prepared by step 4, from
So air-dry or forced air drying after, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes anion
It is prepared by the hydrophobic self-cleaning magnesite wallboard of release function.
Embodiment 2
(1)By 80 parts of magnesia, 50 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 3 parts of color sands, 2
Part stone, 2 parts of magnesium silicates, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts of PVA fibers, 1.5 parts how based water reducer mixes
It stirs evenly, by the slurry mixed, uniformly paving is scattered to die surface, and control thickness is rolled in 5mm, prepares and form dress
Finish coat.
(2)By 50 parts of magnesia, 30 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 2 parts of silicon
Sour magnesium, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts how based water reducer, 20 parts of perlites, the mixing of 20 parts of plant fibers
It stirs evenly, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 5 layers of alkaline-resisting glass
Glass fiber reinforcement grid cloth controls ultralight filling layer thickness in 520mm, and rolling is closely knit.
(3)By 80 parts of magnesia, 50 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 2 parts of silicon
Sour magnesium, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts of PVA fibers, 1.5 parts how based water reducer is mixed evenly, will
Uniformly paving is scattered on the ultralight filled layer that step 2 prepares the slurry mixed, and control thickness completes magnesite wallboard in 5mm
It prepares.
(4)The magnesite wallboard made is placed in 40 DEG C of temperature, is conserved under conditions of humidity 100% and is demoulded afterwards for 24 hours,
It is conserved 7 days under the conditions of being placed in 60 DEG C again.
(5)10 parts of nano-tourmaline powders, 3 parts of ethanol solutions, 0.5 part of perfluoropolyether glycol low-surface-energy modifying agent are mixed
Conjunction is uniformly ground 60min, and the mixture after grinding is scattered in ethanol solution, and control powder content is 30%,
High speed shear is carried out in the blender of 10000r/min and disperses 60min, and 5 parts of micron-sized silver oxide colloidal sols plus ethanol solution is added
It is diluted to powder content to stir evenly for 1%, super hydrophobic coating is made after 72h under conditions of being placed in 50 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 15% is sprayed at product surface prepared by step 4,
After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from
It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 3
(1)By 60 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of stones, 2
Part stained glass clast, 2 parts of potassium silicate modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of nylon fibers, 1 part of melamine system diminishing
Agent is mixed evenly, and by the slurry mixed, uniformly paving is scattered to die surface, and control thickness is rolled in 4mm, prepared
Form architectural surface.
(2)By 40 parts of magnesia, 20 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of silicon
Sour potassium modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of melamine based water reducers, 15 parts of perlites, 15 parts of plant fiber mixing are stirred
It mixes uniformly, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 2 layers of three-dimensional glass
Fibrous braid controls ultralight filling layer thickness in 100mm, and rolling is closely knit.
(3)By 60 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of silicon
Sour potassium modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of nylon fibers, 1 part of melamine based water reducer are mixed evenly, and will mix
Uniformly paving is scattered on the ultralight filled layer that step 2 prepares good slurry, and control thickness is completed magnesite wallboard and prepared in 4mm.
(4)The magnesite wallboard made is placed in 30 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then
It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)9 parts of nano-tourmaline powders, 2 parts of propanol solutions, 0.2 part of chlorosilane low-surface-energy modifying agent are uniformly mixed
It is ground 40min, the mixture after grinding is scattered in propanol solution, control powder content is 20%, in 9000r/min
Blender in carry out high speed shear disperse 40min, be added 4 parts of micron order zinc oxide colloidal sols, plus propanol solution be diluted to powder
Content stirs evenly for 0.5%, and super hydrophobic coating is made after 72h under conditions of being placed in 40 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 10% is sprayed at product surface prepared by step 4,
After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from
It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 4
(1)By 70 parts of magnesia, 35 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of inorganic colors
Powder, 2 parts of shells, 1 part of mica flake, 2 parts phosphate-modified dose, 1 part of epoxy resin latex waterproofing agent, 1 part of acrylic emulsion it is anti-
Aqua, 1.5 parts of glass fibres, 1.5 parts of PP fibers, 1.2 parts of sulfamate based water reducers are mixed evenly, by what is mixed
Uniformly paving is scattered to die surface to slurry, and control thickness is rolled in 4mm, and preparation forms architectural surface.
(2)By 45 parts of magnesia, 25 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of phosphorus
Sulfonate modified dose, 1 part of epoxy resin latex waterproofing agent, 1.2 parts of sulfamate based water reducers, 18 parts of perlites, 16 portions of plants
Fiber is mixed evenly, and by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 3
Layer alkali-resistant glass fibre felt controls ultralight filling layer thickness in 220mm, and rolling is closely knit.
(3)By 70 parts of magnesia, 35 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of phosphorus
Sulfonate modified dose, 1 part of epoxy resin latex waterproofing agent, 1.5 parts of glass fibres, the mixing of 1.2 parts of sulfamate based water reducers stir
It mixes uniformly, by the slurry mixed, uniformly paving is scattered on the ultralight filled layer that step 2 prepares, and control thickness is completed in 4mm
It is prepared by magnesite wallboard.
(4)The magnesite wallboard made is placed in 35 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then
It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)8 parts of nano-tourmaline powders, 1.5 parts of aqueous isopropanols, 0.3 part of dealcoholized type siloxanes low-surface-energy are modified
Agent is uniformly mixed and is ground 50min, and the mixture after grinding is scattered in aqueous isopropanol, and control powder content is 25%,
High speed shear is carried out in the blender of 8000r/min and disperses 50min, and 4 parts of micron order tin oxide sols are added plus isopropanol is molten
Liquid is diluted to powder content and is stirred evenly for 0.6%, and super hydrophobic coating is made after 72h under conditions of being placed in 40 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 10% is sprayed at product surface prepared by step 4,
After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from
It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 5
(1)80 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 7 parts of a concentration of 20% Adlerikas, 3 parts of micas are broken
Piece, 2 parts of aluminate modifying agent, 3 parts of acrylic emulsion waterproofing agents, 1 part of PP fiber, 0.15 part of ligno-sulfate based plasticizer,
0.15 part of melamine based water reducer is mixed evenly, and by the slurry mixed, uniformly paving is scattered to die surface, and control thickness exists
3mm is rolled, and preparation forms architectural surface.
(2)By 35 parts of magnesia, 20 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of aluminium
Sulfonate modified dose, 3 parts of acrylic emulsion waterproofing agents, 0.15 part of ligno-sulfate based plasticizer, 12 parts of perlites, 12 parts of plant fibres
Dimension is mixed evenly, and by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 4 layers
Alkali-resistant glass fibre enhances grid cloth, controls ultralight filling layer thickness in 370mm, rolling is closely knit.
(3)By 80 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 7 parts of a concentration of 20% Adlerikas, 2 parts of aluminium
Sulfonate modified dose, 3 parts of acrylic emulsion waterproofing agents, 1 part of PP fiber, 0.15 part of ligno-sulfate based plasticizer, 0.15 part of melamine
Based water reducer is mixed evenly, and by the slurry mixed, uniformly paving is scattered on the ultralight filled layer that step 2 prepares, and controls
Thickness is completed magnesite wallboard and is prepared in 3mm.
(4)The magnesite wallboard made is placed in 30 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then
It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)By 8 parts of nano-tourmaline powders, 2 parts of methanol solutions, 0.2 part of silicon fluoride modifying agent, the low table of 0.1 part of chlorosilane
Face energy modifying agent, which is uniformly mixed, is ground 40min, and the mixture after grinding is scattered in methanol solution, powder content is controlled
It is 20%, high speed shear is carried out in the blender of 9000r/min and disperses 50min, 4 parts of micron order zinc oxide colloidal sols and 1 part is added
It is 0.6% to stir evenly that Sol silver oxide plus methanol solution, which are diluted to powder content, is made after 72h under conditions of being placed in 40 DEG C super
Hydrophobic coating.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 8% is sprayed at product surface prepared by step 4, from
So air-dry or forced air drying after, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes anion
It is prepared by the hydrophobic self-cleaning magnesite wallboard of release function.
After testing, the hydrophobic self-cleaning magnesite wallboard of the present invention with negative ion releasing function:It is super-hydrophobic >=140 °;It is anti-
Aqueous >=70%;Stain resistance is surface no-pollution;Nothing returns halogen phenomenon.
Protection scope of the present invention is not limited to above example, other technical solutions substantially identical with the present invention belong to
The scope of the present invention.
Claims (10)
1. a kind of hydrophobic self-cleaning magnesite wallboard, which is characterized in that including architectural surface(1), ultralight filled layer(2), structure sheaf(3)
And super-hydrophobic layer(4);The architectural surface(1)It is made of decorative magnesia cement mortar;The ultralight filled layer(2)
It is made of plant fiber, perlite composite magnesite cement mortar;The structure sheaf(3)Using chopped strand activeness and quietness water chestnut
Magnesium cement mortar is made;The architectural surface(1)On one side with structure sheaf(3)Between coat ultralight filled layer(2), described ultralight to fill out
Fill layer(2)In be equipped with 1-5 layers of fiber glass reinforcement(5), the architectural surface(1)Another side passes through resin adhesive backers
With super-hydrophobic layer(4)It is connected.
2. the hydrophobic self-cleaning magnesite wallboard of one kind according to claim 1, which is characterized in that the glass fiber reinforcement material
Material(5)Enhance one kind in grid cloth, three-dimensional glass fibrous braid for alkali-resistant glass fibre felt, alkali-resistant glass fibre.
3. the hydrophobic self-cleaning magnesite wallboard of one kind according to claim 1, which is characterized in that the resin adhesive backers is
Solid content is the organic resin dispersion liquid of 3-15%.
4. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard, which is characterized in that be prepared using following steps:
(1)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 3-5 parts of decorative fillers, 1-3 parts
Modifying agent, 1-3 part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and the slurry mixed is equal
Even paving is scattered to die surface, and control thickness is rolled in 3-5mm, and preparation forms architectural surface;
(2)30-50 parts of magnesia, 10-30 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 parts are prevented
Aqua, 1-3 part water-reducing agent, 10-20 parts of perlites, 10-20 parts of plant fibers are mixed evenly, successively by the slurry mixed
Uniform paving is scattered on the architectural surface that step 1 prepares, and is laid with 1-5 layers of fiber glass reinforcement and forms ultralight filled layer,
Ultralight filling layer thickness is controlled in 10-520mm, rolling is closely knit;
(3)50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 parts are prevented
Aqua, 1-3 part chopped strand, 0.1-1.5 parts of water-reducing agents are mixed evenly, and by the slurry mixed, uniformly paving is scattered to step
On the 2 ultralight filled layers prepared, control thickness is completed magnesite wallboard and is prepared in 3-5mm, as structure sheaf;
(4)The magnesite wallboard made is placed in 25-40 DEG C of temperature, is conserved under conditions of humidity 70-100% and is taken off afterwards for 24 hours
Mould, then conserved 7 days under the conditions of being placed in 40-60 DEG C;
(5)8-10 parts of nano-tourmaline powders, 1-3 parts of alcoholic solutions, 0.1-0.5 parts of low-surface-energy modifying agent are uniformly mixed and are carried out
30-60min is ground, the mixture after grinding is scattered in alcoholic solution, control powder content is 10-30%, in 8000-
High speed shear is carried out in the blender of 10000r/min and disperses 30-60min, and 3-5 parts of electric conductivity dispersion liquids are added plus alcoholic solution is dilute
It releases to powder content and is stirred evenly for 0.1-1%, super hydrophobic coating is made after 72h under conditions of being placed in 30-50 DEG C;
(6)The product surface that evenly dispersed resin gluing material spraying is prepared in step 4, natural air drying or forced air drying
Afterwards, the super hydrophobic coating that prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes dredging with negative ion releasing function
The preparation of the self-cleaning magnesite wallboard of water.
5. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that each step
A concentration of 15-30% of middle magnesium chloride solution;A concentration of 15-30% of Adlerika.
6. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the decoration
Filler is one or more in inorganic toner, color sand, stone, stained glass clast, shell, mica flake.
7. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that each step
Middle modifying agent is one or more in silica, magnesium silicate, sodium metasilicate, potassium silicate, phosphate, aluminate;Described is anti-
Aqua is one or more in organic silicon emulsion, acrylic emulsion, polyaminoester emulsion, epoxy resin latex;The diminishing
Agent is polycarboxylate water-reducer, how one or more in based water reducer, melamine system, sulfamate system, lignosulfonates;Institute
The chopped strand stated is using one or more in PP fibers, PVA fibers, nylon fiber, glass fibre.
8. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the alcohol is molten
Liquid selects one kind in methanol, ethyl alcohol, propyl alcohol or isopropanol.
9. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the low table
Face energy modifying agent includes one or more in silicon fluoride modifying agent, perfluoropolyether glycol, chlorosilane, dealcoholized type siloxanes.
10. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that described leads
Electrical dispersion liquid is one or more in micron order tin oxide sol, Sol silver oxide, zinc oxide colloidal sol.
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CN113698171A (en) * | 2021-09-08 | 2021-11-26 | 山西大学 | Surface-hydrophobic modified magnesium-based fly ash porous sound absorption material and preparation method thereof |
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