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CN108726980A - A kind of hydrophobic self-cleaning magnesite wallboard - Google Patents

A kind of hydrophobic self-cleaning magnesite wallboard Download PDF

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Publication number
CN108726980A
CN108726980A CN201810729099.7A CN201810729099A CN108726980A CN 108726980 A CN108726980 A CN 108726980A CN 201810729099 A CN201810729099 A CN 201810729099A CN 108726980 A CN108726980 A CN 108726980A
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CN
China
Prior art keywords
parts
magnesite
cleaning
ultralight
hydrophobic
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Application number
CN201810729099.7A
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Chinese (zh)
Inventor
熊吉如
王猛
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NANJING BEILIDA
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Nanjing Beilida Oulu Decoration Art Engineering Co Ltd
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Priority to CN201810729099.7A priority Critical patent/CN108726980A/en
Publication of CN108726980A publication Critical patent/CN108726980A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/044Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres of concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • C04B2111/2069Self-cleaning materials, e.g. using lotus effect
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

A kind of hydrophobic self-cleaning magnesite wallboard, including architectural surface made of decorative magnesia cement mortar(1), ultralight filled layer made of plant fiber and perlite composite magnesite cement mortar(2), chopped strand activeness and quietness magnesia cement mortar structure layer(3)And super-hydrophobic layer(4).Product is coated in magnesite surfaces of wall by micro-nano structure coating, the sandwich construction of ultralight filled layer is wrapped up in conjunction with decorative layer and structure sheaf, effectively improve the intensity and water resistance of glass magnesium board, use nano-tourmaline in formula simultaneously, its anion discharged can purify air, be conducive to health.

Description

A kind of hydrophobic self-cleaning magnesite wallboard
Technical field
The present invention relates to a kind of hydrophobic self-cleaning magnesite wallboards, are suitable for the necks such as building roof, building curtain wall, wall decoration Domain.
Background technology
China's magnesite resource is abundant, and abundant raw material are provided to prepare magnesite product.Magnesite product is by active oxygen Change magnesium and aqueous salt brine mixes and stirs magnesium gelatinous material made of molding, maintenance hardening.It has many excellent performances, belongs to environmental protection Building materials, fireproof building material are good substitute for wood.It is popular in American-European and Japan, there have been a considerable amount of systems in China Row products export.But it since the article water resistance is poor, easily makes moist and returns halogen, influence construction quality, cause the application of magnesite product It is restricted, also directly affects the outlet of product.Therefore, can the scumming that solve magnesite product become its development and application Key.
Invention content
In view of the above-mentioned problems, using nano-tourmaline for anion releasable material, carry out low-surface-energy to it changes the present invention Property, in the magnesite board product surface constructing super-drainage self-cleaning coat with decoration functions, make with negative ion releasing function Self-cleaning magnesite wallboard.
Technical scheme is as follows:
The hydrophobic self-cleaning magnesite wallboard of one kind includes architectural surface, ultralight filled layer, structure sheaf and super-hydrophobic layer;The decorative cover Layer is made of decorative magnesia cement mortar;The ultralight filled layer is using plant fiber, perlite composite magnesite cement Mortar is made;The structure sheaf is made of chopped strand activeness and quietness magnesia cement mortar;The architectural surface one side Ultralight filled layer is coated between structure sheaf, 1-5 layers of fiber glass reinforcement are equipped in ultralight filled layer, and architectural surface is another It is connected on one side with super-hydrophobic layer by resin adhesive backers.
The fiber glass reinforcement is alkali-resistant glass fibre felt, alkali-resistant glass fibre enhancing grid cloth, three-dimensional glass One kind in glass fibrous braid.
The resin adhesive backers is the organic resin dispersion liquid that solid content is 3-15%.
The invention also discloses a kind of preparation methods of hydrophobic self-cleaning magnesite wallboard, are prepared using following steps:
(1)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 3-5 parts of decorative fillers, 1-3 parts Modifying agent, 1-3 part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and the slurry mixed is equal Even paving is scattered to die surface, and control thickness is rolled in 3-5mm, and preparation forms architectural surface.
(2)By 30-50 parts of magnesia, 10-30 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 Part waterproofing agent, 1-3 parts of water-reducing agents, 10-20 parts of perlites, 10-20 parts of plant fibers are mixed evenly, the slurry that will be mixed Successively uniform paving is scattered on the architectural surface that step 1 prepares, and is laid with 1-5 layers of fiber glass reinforcement, and control is ultralight to fill out Layer thickness is filled in 10-520mm, and rolling is closely knit.
(3)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 Part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and by the slurry mixed, uniformly paving is scattered to On the ultralight filled layer that step 2 prepares, control thickness is completed magnesite wallboard and is prepared in 3-5mm.
(4)The magnesite wallboard made is placed in 25-40 DEG C of temperature, after being conserved for 24 hours under conditions of humidity 70-100% Demoulding, then conserved 7 days under the conditions of being placed in 40-60 DEG C,
(5)8-10 parts of nano-tourmaline powders, 1-3 parts of alcoholic solutions, 0.1-0.5 parts of low-surface-energy modifying agent are uniformly mixed and are carried out 30-60min is ground, the mixture after grinding is scattered in alcoholic solution, control powder content is 10-30%, in 8000- High speed shear is carried out in the blender of 10000r/min and disperses 30-60min, and 3-5 parts of electric conductivity dispersion liquids are added plus alcoholic solution is dilute It releases to powder content and is stirred evenly for 0.1-1%, super hydrophobic coating is made after 72h under conditions of being placed in 30-50 DEG C.
(6)The product surface that evenly dispersed resin gluing material spraying is prepared in step 4, natural air drying or air blast are dry After dry, super hydrophobic coating prepared by spraying process 5 conserves for 24 hours under the conditions of room ventilation, completes the hydrophobic of negative ion releasing function It is prepared by self-cleaning magnesite wallboard.
A concentration of 15-30% of the magnesium chloride solution;Magnesium sulfate concentration is 15-30%.
The decorative fillers are one kind in inorganic toner, color sand, stone, stained glass clast, shell, mica flake Or it is a variety of.
The modifying agent is that silica, magnesium silicate, sodium metasilicate, potassium silicate, phosphate, aluminate etc. are a kind of or more Kind.
The waterproofing agent be organic silicon emulsion, acrylic emulsion, polyaminoester emulsion, one kind in epoxy resin latex or It is a variety of.
The water-reducing agent be polycarboxylate water-reducer, how based water reducer, melamine system, sulfamate system, lignin sulfonic acid It is one or more in salt.
The chopped strand is using one or more in PP fibers, PVA fibers, nylon fiber, glass fibre.
The alcoholic solution selects one kind in methanol, ethyl alcohol, propyl alcohol or isopropanol.
The low-surface-energy modifying agent includes silicon fluoride modifying agent, perfluoropolyether glycol, chlorosilane, dealcoholized type siloxanes One or more of.
The electric conductivity dispersion liquid be micron order tin oxide sol, Sol silver oxide, one kind in zinc oxide colloidal sol or It is a variety of.
The beneficial effects of the present invention are:
1, the coating that nano-tourmaline powder, electric conductivity dispersion liquid are mixed with is coated in magnesite surfaces of wall and forms micro-nano knot Structure plays waterproof, surface halide accumulation resistance, self-cleaning action.
2, decorative layer and structure sheaf wrap up ultralight filled layer, can effectively improve the intensity of glass magnesium board, while playing into one Walk water proof anti-seepage effect.
3, nano-tourmaline is added in being formulated, the anion of release can purify air, be conducive to health.
Description of the drawings
Fig. 1 is a kind of hydrophobic self-cleaning magnesite wallboard with negative ion releasing function.
1- architectural surfaces;The ultralight filled layers of 2-;3- structure sheafs;4- super-hydrophobic layers;5- fiber glass reinforcements.
Specific implementation mode
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
(1)By 50 parts of magnesia, 30 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 3 parts of inorganic colors Powder, 1 part of silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of PP fiber, 0.1 part of polycarboxylate water-reducer are mixed evenly, will Uniformly paving is scattered to die surface to the slurry mixed, and control thickness is rolled in 3mm, and preparation forms architectural surface.
(2)By 30 parts of magnesia, 10 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 1 part two Silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of polycarboxylate water-reducer, 10 parts of perlites, 10 parts of plant fibers are mixed equal Even, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 1 layer of alkali-resistant glass fibre Felt controls ultralight filling layer thickness in 10mm, and rolling is closely knit.
(3)By 50 parts of magnesia, 30 parts of a concentration of 15% magnesium chloride solutions, 2 parts of a concentration of 15% Adlerikas, 1 part two Silica, 1 part of organic silicon emulsion waterproofing agent, 1 part of PP fiber, 0.1 part of polycarboxylate water-reducer are mixed evenly, by what is mixed Uniformly paving is scattered on the ultralight filled layer that step 2 prepares slurry, and control thickness is completed magnesite wallboard and prepared in 3mm.
(4)The magnesite wallboard made is placed in 25 DEG C of temperature, is conserved under conditions of humidity 70% and is demoulded afterwards for 24 hours, then It is conserved 7 days under the conditions of being placed in 40 DEG C.
(5)8 parts of nano-tourmaline powders, 1 part of methanol solution, 0.1 part of silicon fluoride modifying agent are uniformly mixed and are ground Mixture after grinding is scattered in methanol solution by 30min, and control powder content is 10%, in the blender of 8000r/min Middle progress high speed shear disperses 30min, and 3 parts of micron order tin oxide sols of addition plus methanol solution are diluted to powder content and are 0.1% stirs evenly, and super hydrophobic coating is made after 72h under conditions of being placed in 30 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 3% is sprayed at product surface prepared by step 4, from So air-dry or forced air drying after, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes anion It is prepared by the hydrophobic self-cleaning magnesite wallboard of release function.
Embodiment 2
(1)By 80 parts of magnesia, 50 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 3 parts of color sands, 2 Part stone, 2 parts of magnesium silicates, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts of PVA fibers, 1.5 parts how based water reducer mixes It stirs evenly, by the slurry mixed, uniformly paving is scattered to die surface, and control thickness is rolled in 5mm, prepares and form dress Finish coat.
(2)By 50 parts of magnesia, 30 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 2 parts of silicon Sour magnesium, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts how based water reducer, 20 parts of perlites, the mixing of 20 parts of plant fibers It stirs evenly, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 5 layers of alkaline-resisting glass Glass fiber reinforcement grid cloth controls ultralight filling layer thickness in 520mm, and rolling is closely knit.
(3)By 80 parts of magnesia, 50 parts of a concentration of 30% magnesium chloride solutions, 10 parts of a concentration of 30% Adlerikas, 2 parts of silicon Sour magnesium, 1 part of sodium metasilicate, 3 parts of acrylic emulsion waterproofing agents, 3 parts of PVA fibers, 1.5 parts how based water reducer is mixed evenly, will Uniformly paving is scattered on the ultralight filled layer that step 2 prepares the slurry mixed, and control thickness completes magnesite wallboard in 5mm It prepares.
(4)The magnesite wallboard made is placed in 40 DEG C of temperature, is conserved under conditions of humidity 100% and is demoulded afterwards for 24 hours, It is conserved 7 days under the conditions of being placed in 60 DEG C again.
(5)10 parts of nano-tourmaline powders, 3 parts of ethanol solutions, 0.5 part of perfluoropolyether glycol low-surface-energy modifying agent are mixed Conjunction is uniformly ground 60min, and the mixture after grinding is scattered in ethanol solution, and control powder content is 30%, High speed shear is carried out in the blender of 10000r/min and disperses 60min, and 5 parts of micron-sized silver oxide colloidal sols plus ethanol solution is added It is diluted to powder content to stir evenly for 1%, super hydrophobic coating is made after 72h under conditions of being placed in 50 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 15% is sprayed at product surface prepared by step 4, After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 3
(1)By 60 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of stones, 2 Part stained glass clast, 2 parts of potassium silicate modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of nylon fibers, 1 part of melamine system diminishing Agent is mixed evenly, and by the slurry mixed, uniformly paving is scattered to die surface, and control thickness is rolled in 4mm, prepared Form architectural surface.
(2)By 40 parts of magnesia, 20 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of silicon Sour potassium modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of melamine based water reducers, 15 parts of perlites, 15 parts of plant fiber mixing are stirred It mixes uniformly, by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 2 layers of three-dimensional glass Fibrous braid controls ultralight filling layer thickness in 100mm, and rolling is closely knit.
(3)By 60 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of silicon Sour potassium modifying agent, 2 parts of polyaminoester emulsion waterproofing agents, 2 parts of nylon fibers, 1 part of melamine based water reducer are mixed evenly, and will mix Uniformly paving is scattered on the ultralight filled layer that step 2 prepares good slurry, and control thickness is completed magnesite wallboard and prepared in 4mm.
(4)The magnesite wallboard made is placed in 30 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)9 parts of nano-tourmaline powders, 2 parts of propanol solutions, 0.2 part of chlorosilane low-surface-energy modifying agent are uniformly mixed It is ground 40min, the mixture after grinding is scattered in propanol solution, control powder content is 20%, in 9000r/min Blender in carry out high speed shear disperse 40min, be added 4 parts of micron order zinc oxide colloidal sols, plus propanol solution be diluted to powder Content stirs evenly for 0.5%, and super hydrophobic coating is made after 72h under conditions of being placed in 40 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 10% is sprayed at product surface prepared by step 4, After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 4
(1)By 70 parts of magnesia, 35 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of inorganic colors Powder, 2 parts of shells, 1 part of mica flake, 2 parts phosphate-modified dose, 1 part of epoxy resin latex waterproofing agent, 1 part of acrylic emulsion it is anti- Aqua, 1.5 parts of glass fibres, 1.5 parts of PP fibers, 1.2 parts of sulfamate based water reducers are mixed evenly, by what is mixed Uniformly paving is scattered to die surface to slurry, and control thickness is rolled in 4mm, and preparation forms architectural surface.
(2)By 45 parts of magnesia, 25 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of phosphorus Sulfonate modified dose, 1 part of epoxy resin latex waterproofing agent, 1.2 parts of sulfamate based water reducers, 18 parts of perlites, 16 portions of plants Fiber is mixed evenly, and by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 3 Layer alkali-resistant glass fibre felt controls ultralight filling layer thickness in 220mm, and rolling is closely knit.
(3)By 70 parts of magnesia, 35 parts of a concentration of 25% magnesium chloride solutions, 6 parts of a concentration of 25% Adlerikas, 2 parts of phosphorus Sulfonate modified dose, 1 part of epoxy resin latex waterproofing agent, 1.5 parts of glass fibres, the mixing of 1.2 parts of sulfamate based water reducers stir It mixes uniformly, by the slurry mixed, uniformly paving is scattered on the ultralight filled layer that step 2 prepares, and control thickness is completed in 4mm It is prepared by magnesite wallboard.
(4)The magnesite wallboard made is placed in 35 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)8 parts of nano-tourmaline powders, 1.5 parts of aqueous isopropanols, 0.3 part of dealcoholized type siloxanes low-surface-energy are modified Agent is uniformly mixed and is ground 50min, and the mixture after grinding is scattered in aqueous isopropanol, and control powder content is 25%, High speed shear is carried out in the blender of 8000r/min and disperses 50min, and 4 parts of micron order tin oxide sols are added plus isopropanol is molten Liquid is diluted to powder content and is stirred evenly for 0.6%, and super hydrophobic coating is made after 72h under conditions of being placed in 40 DEG C.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 10% is sprayed at product surface prepared by step 4, After natural air drying or forced air drying, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completion bear from It is prepared by the hydrophobic self-cleaning magnesite wallboard of sub- release function.
Embodiment 5
(1)80 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 7 parts of a concentration of 20% Adlerikas, 3 parts of micas are broken Piece, 2 parts of aluminate modifying agent, 3 parts of acrylic emulsion waterproofing agents, 1 part of PP fiber, 0.15 part of ligno-sulfate based plasticizer, 0.15 part of melamine based water reducer is mixed evenly, and by the slurry mixed, uniformly paving is scattered to die surface, and control thickness exists 3mm is rolled, and preparation forms architectural surface.
(2)By 35 parts of magnesia, 20 parts of a concentration of 20% magnesium chloride solutions, 5 parts of a concentration of 20% Adlerikas, 2 parts of aluminium Sulfonate modified dose, 3 parts of acrylic emulsion waterproofing agents, 0.15 part of ligno-sulfate based plasticizer, 12 parts of perlites, 12 parts of plant fibres Dimension is mixed evenly, and by the slurry mixed, successively uniformly paving is scattered on the architectural surface that step 1 prepares, and is laid with 4 layers Alkali-resistant glass fibre enhances grid cloth, controls ultralight filling layer thickness in 370mm, rolling is closely knit.
(3)By 80 parts of magnesia, 40 parts of a concentration of 20% magnesium chloride solutions, 7 parts of a concentration of 20% Adlerikas, 2 parts of aluminium Sulfonate modified dose, 3 parts of acrylic emulsion waterproofing agents, 1 part of PP fiber, 0.15 part of ligno-sulfate based plasticizer, 0.15 part of melamine Based water reducer is mixed evenly, and by the slurry mixed, uniformly paving is scattered on the ultralight filled layer that step 2 prepares, and controls Thickness is completed magnesite wallboard and is prepared in 3mm.
(4)The magnesite wallboard made is placed in 30 DEG C of temperature, is conserved under conditions of humidity 80% and is demoulded afterwards for 24 hours, then It is conserved 7 days under the conditions of being placed in 50 DEG C.
(5)By 8 parts of nano-tourmaline powders, 2 parts of methanol solutions, 0.2 part of silicon fluoride modifying agent, the low table of 0.1 part of chlorosilane Face energy modifying agent, which is uniformly mixed, is ground 40min, and the mixture after grinding is scattered in methanol solution, powder content is controlled It is 20%, high speed shear is carried out in the blender of 9000r/min and disperses 50min, 4 parts of micron order zinc oxide colloidal sols and 1 part is added It is 0.6% to stir evenly that Sol silver oxide plus methanol solution, which are diluted to powder content, is made after 72h under conditions of being placed in 40 DEG C super Hydrophobic coating.
(6)The organic resin dispersion liquid that evenly dispersed solid content is 8% is sprayed at product surface prepared by step 4, from So air-dry or forced air drying after, super hydrophobic coating prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes anion It is prepared by the hydrophobic self-cleaning magnesite wallboard of release function.
After testing, the hydrophobic self-cleaning magnesite wallboard of the present invention with negative ion releasing function:It is super-hydrophobic >=140 °;It is anti- Aqueous >=70%;Stain resistance is surface no-pollution;Nothing returns halogen phenomenon.
Protection scope of the present invention is not limited to above example, other technical solutions substantially identical with the present invention belong to The scope of the present invention.

Claims (10)

1. a kind of hydrophobic self-cleaning magnesite wallboard, which is characterized in that including architectural surface(1), ultralight filled layer(2), structure sheaf(3) And super-hydrophobic layer(4);The architectural surface(1)It is made of decorative magnesia cement mortar;The ultralight filled layer(2) It is made of plant fiber, perlite composite magnesite cement mortar;The structure sheaf(3)Using chopped strand activeness and quietness water chestnut Magnesium cement mortar is made;The architectural surface(1)On one side with structure sheaf(3)Between coat ultralight filled layer(2), described ultralight to fill out Fill layer(2)In be equipped with 1-5 layers of fiber glass reinforcement(5), the architectural surface(1)Another side passes through resin adhesive backers With super-hydrophobic layer(4)It is connected.
2. the hydrophobic self-cleaning magnesite wallboard of one kind according to claim 1, which is characterized in that the glass fiber reinforcement material Material(5)Enhance one kind in grid cloth, three-dimensional glass fibrous braid for alkali-resistant glass fibre felt, alkali-resistant glass fibre.
3. the hydrophobic self-cleaning magnesite wallboard of one kind according to claim 1, which is characterized in that the resin adhesive backers is Solid content is the organic resin dispersion liquid of 3-15%.
4. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard, which is characterized in that be prepared using following steps:
(1)By 50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 3-5 parts of decorative fillers, 1-3 parts Modifying agent, 1-3 part waterproofing agent, 1-3 parts of chopped strands, 0.1-1.5 parts of water-reducing agents are mixed evenly, and the slurry mixed is equal Even paving is scattered to die surface, and control thickness is rolled in 3-5mm, and preparation forms architectural surface;
(2)30-50 parts of magnesia, 10-30 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 parts are prevented Aqua, 1-3 part water-reducing agent, 10-20 parts of perlites, 10-20 parts of plant fibers are mixed evenly, successively by the slurry mixed Uniform paving is scattered on the architectural surface that step 1 prepares, and is laid with 1-5 layers of fiber glass reinforcement and forms ultralight filled layer, Ultralight filling layer thickness is controlled in 10-520mm, rolling is closely knit;
(3)50-80 parts of magnesia, 30-50 parts of magnesium chloride solutions, 2-10 parts of Adlerikas, 1-3 parts of modifying agent, 1-3 parts are prevented Aqua, 1-3 part chopped strand, 0.1-1.5 parts of water-reducing agents are mixed evenly, and by the slurry mixed, uniformly paving is scattered to step On the 2 ultralight filled layers prepared, control thickness is completed magnesite wallboard and is prepared in 3-5mm, as structure sheaf;
(4)The magnesite wallboard made is placed in 25-40 DEG C of temperature, is conserved under conditions of humidity 70-100% and is taken off afterwards for 24 hours Mould, then conserved 7 days under the conditions of being placed in 40-60 DEG C;
(5)8-10 parts of nano-tourmaline powders, 1-3 parts of alcoholic solutions, 0.1-0.5 parts of low-surface-energy modifying agent are uniformly mixed and are carried out 30-60min is ground, the mixture after grinding is scattered in alcoholic solution, control powder content is 10-30%, in 8000- High speed shear is carried out in the blender of 10000r/min and disperses 30-60min, and 3-5 parts of electric conductivity dispersion liquids are added plus alcoholic solution is dilute It releases to powder content and is stirred evenly for 0.1-1%, super hydrophobic coating is made after 72h under conditions of being placed in 30-50 DEG C;
(6)The product surface that evenly dispersed resin gluing material spraying is prepared in step 4, natural air drying or forced air drying Afterwards, the super hydrophobic coating that prepared by spraying process 5 conserves under the conditions of room ventilation for 24 hours, completes dredging with negative ion releasing function The preparation of the self-cleaning magnesite wallboard of water.
5. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that each step A concentration of 15-30% of middle magnesium chloride solution;A concentration of 15-30% of Adlerika.
6. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the decoration Filler is one or more in inorganic toner, color sand, stone, stained glass clast, shell, mica flake.
7. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that each step Middle modifying agent is one or more in silica, magnesium silicate, sodium metasilicate, potassium silicate, phosphate, aluminate;Described is anti- Aqua is one or more in organic silicon emulsion, acrylic emulsion, polyaminoester emulsion, epoxy resin latex;The diminishing Agent is polycarboxylate water-reducer, how one or more in based water reducer, melamine system, sulfamate system, lignosulfonates;Institute The chopped strand stated is using one or more in PP fibers, PVA fibers, nylon fiber, glass fibre.
8. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the alcohol is molten Liquid selects one kind in methanol, ethyl alcohol, propyl alcohol or isopropanol.
9. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that the low table Face energy modifying agent includes one or more in silicon fluoride modifying agent, perfluoropolyether glycol, chlorosilane, dealcoholized type siloxanes.
10. a kind of preparation method of hydrophobic self-cleaning magnesite wallboard according to claim 4, which is characterized in that described leads Electrical dispersion liquid is one or more in micron order tin oxide sol, Sol silver oxide, zinc oxide colloidal sol.
CN201810729099.7A 2018-07-05 2018-07-05 A kind of hydrophobic self-cleaning magnesite wallboard Pending CN108726980A (en)

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