CN108716042A - A kind of preparation method of functionality heavy twist color spot silk - Google Patents
A kind of preparation method of functionality heavy twist color spot silk Download PDFInfo
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- CN108716042A CN108716042A CN201810471472.3A CN201810471472A CN108716042A CN 108716042 A CN108716042 A CN 108716042A CN 201810471472 A CN201810471472 A CN 201810471472A CN 108716042 A CN108716042 A CN 108716042A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 89
- -1 polyethylene Polymers 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 21
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003086 colorant Substances 0.000 claims abstract description 12
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims description 34
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims description 34
- 238000009987 spinning Methods 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 22
- 238000012545 processing Methods 0.000 claims description 16
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 16
- 239000004677 Nylon Substances 0.000 claims description 14
- 229920001778 nylon Polymers 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000004043 dyeing Methods 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- 239000012860 organic pigment Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910017623 MgSi2 Inorganic materials 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 239000006166 lysate Substances 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 6
- 238000011002 quantification Methods 0.000 claims description 6
- 238000003836 solid-state method Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- 238000009960 carding Methods 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019082 Osmanthus Nutrition 0.000 claims description 3
- 241000333181 Osmanthus Species 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 230000001112 coagulating effect Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000006184 cosolvent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- GEZAXHSNIQTPMM-UHFFFAOYSA-N dysprosium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Dy+3].[Dy+3] GEZAXHSNIQTPMM-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 230000008929 regeneration Effects 0.000 claims description 3
- 238000011069 regeneration method Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 1
- 239000001095 magnesium carbonate Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 26
- 230000008569 process Effects 0.000 abstract description 10
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 239000004698 Polyethylene Substances 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 5
- 229920000573 polyethylene Polymers 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 4
- 238000011161 development Methods 0.000 abstract description 3
- 238000002513 implantation Methods 0.000 abstract description 3
- 229920000297 Rayon Polymers 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000037303 wrinkles Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 229910001940 europium oxide Inorganic materials 0.000 description 2
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
- D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/02—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
- D01F2/04—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts from cuprammonium solutions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/20—Physical properties optical
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of preparation method of functional heavy twist color spot silk, the color spot silk that is prepared in the present invention is silk in twisting process, and interruption implantation color fiber forms intermittent section coloured silk color spot shape, rugosity, the length of color spot can control on filament surface.Color spot silk has more variations on the color of yarn, and the three-dimensional sense of yarn is stronger, and more variations are assigned in the style of fabric, the kind of long filament is enriched, promotes the progress and development of long filament technology.In the color spot silk prepared in the present invention, long filament uses copper ammonia fiber long filament and superhigh molecular weight polyethylene fibers long filament, after heavy twist, have the performances such as nice and cool, ventilative, moisture absorption, high-strength, wear-resisting, the luminous fiber color spot of two kinds of colors is added in twisting process, luminous fiber can shine at daytime, night, different colors is presented, property and three-dimensional sense rich in color are increased for high twist yarn, through the invention, the application of functional fibre is promoted, enriches textile product design.
Description
Technical field
The invention belongs to the fields of spinning, and in particular to a kind of preparation method of functionality heavy twist color spot silk.
Background technology
Cuprammonium viscose glue raw material is refined by the down of cottonseed in cotton, cuprammonium rayon bacterium easily in by soil and water
It decomposes, natural environment will not be destroyed, be to meet current environmentally friendly trend " green even if burning there will not be poisonous gas appearance
Fiber ".
Cuprammonium viscose glue has good humidity absorption and release effect, feels tender careful with skin contact.In addition with anti-quiet
The function of electricity exists, and has good sense of touch, can avoid generating sultry discomfort.Cuprammonium viscose rayon have can breathe,
Clearly, antistatic, the good four big function of pendant property of hanging down.Its most attracting characteristic is tool moisture absorption, wet putting, belongs to breathing, salubrious fibre
Dimension.The section of copper ammonia fiber is rounded, no skin-core structure, and fiber can bear high elongation, and monofilament obtained is thinner.So fabric
Soft, gloss is soft, there is silky touch.The hygroscopicity of copper ammonia fiber is close with viscose rayon, official regain 11%,
Regain can reach 12-13% under the conditions of general atmosphere, under identical dyeing condition, the dyeing affinity of copper ammonia fiber
Big compared with viscose rayon, colouring is deeper.
Copper ammonia fiber it is dry close with viscose rayon by force, but it is wet be higher than viscose rayon by force, wearability also superior to viscose rayon,
When skin contact is to it, meeting sensory surface is very smooth.Compared with other various fibers, its section is more round, this is also very heavy
A bit wanted.Because friction is good small, even if stimulation few absolutely if mutually wiping with skin.The characteristic of this softness does not allow easy damaged very thin
Sensitive skin.
Superhigh molecular weight polyethylene fibers are that specific strength and the highest fiber of specific modulus, molecular weight exist in the world at present
1000000~5,000,000 spun fiber of polyethylene institute.With following property：1, high specific strength, high ratio modulus.2, fiber
Density is low, and density is 0.97-0.98g/cm, can bubble through the water column.3, extension at break is low, work to break is big, has very strong absorption energy
The ability of amount, thus there is impact resistance outstanding and anti-cut.4, ultra-violet radiation resisting, anti-neutron and gamma-rays, than energy
Amount absorption is high, dielectric constant is low, electromagnetic wave tansmittivity is high.5, resistant to chemical etching, wearability has longer flex life.Its object
Rationality can be：Density：0.97~0.98g/cm, it is lower than the density of water, it can float on the water；Intensity：2.8~4N/tex；Mould
Amount：91~140N/tex；Ductility：3.5%~3.7%.Impact absorbing can be higher by about one time than contraposition aramid fiber, wearability
Good, friction coefficient is small, but fusing point only has 145~160 DEG C under stress.
Luminous fiber absorbs visible light 10 minutes, just can store luminous energy among storing in fiber, persistently send out in the dark state
Light 10 hours or more.When there is illumination, luminous fiber shows a variety of colors, such as red, yellow, green, blue.In dark
In, luminous fiber sends out various coloured light, such as feux rouges, yellow light, blue and green light.Luminous fiber is lucuriant in design, and is not required to dye,
It is the high-tech product of environment-friendly high-efficiency.
Invention content
Goal of the invention：In order to solve the deficiencies in the prior art, the present invention provides a kind of systems of functional heavy twist color spot silk
Preparation Method.
Technical solution：A kind of preparation method of functionality heavy twist color spot silk, includes the following steps：
Step 1: copper ammonia fiber long filament prepares dyeing processing：The natural cellulosic feedstocks such as cotton linter are dissolved in hydroxide
In copper or the liquor ammoniae fortis of alkaline cupric salt, be made into spinning solution, the spinning technique in the coagulating bath of water or dilute alkaline soln, then containing
So that copper ammonia fiber molecular chemistry object disintegrating and regeneration is gone out cellulose in second bath of 2-3% sulfuric acid solutions, generate hydrate cellulose,
Copper ammonia fiber is obtained through post-processing；And carry out dyeing processing；
Step 2: ultra-high molecular weight polyethylene long filament coloring treatment：
A, ultra-high molecular weight polyethylene lysate and the mixing of ultra-high molecular weight polyethylene swelling solution, it is poly- to obtain super high molecular weight
Vinyl fiber spinning solution；
The ultra-high molecular weight polyethylene lysate is ultra-high molecular weight polyethylene powder, spin solvent, antioxidant and breast
The mixed liquor of agent；The ultra-high molecular weight polyethylene swelling solution is the mixing of ultra-high molecular weight polyethylene powder and spin solvent
Liquid；Organic pigment solution converges with the spinning solution of ultra-high molecular weight polyethylene fiber, and double screw extruder is entered after confluence
Blending extrusion carries out spinning and forms frozen glue precursor；
B, the frozen glue precursor obtains ultra-high molecular weight polyethylene colored fibers after extraction, drying and hot-stretch；
Step 3: simultaneously plying：By ultra-high molecular weight polyethylene long filament and copper ammonia fiber long filament carries out and silk；
Step 4: the preparation of noctilucence nylon fibre：Using spinning material as matrix, using the luminous material of long afterglow rare earth aluminate
Material, luminous fiber is made through extraordinary spinning；Wherein, the noctilucence nylon fibre of two kinds of colors of A, B is prepared：
Rare earth silicate luminous fiber is using high polymers such as polyester, polyamide, polypropylene as base material, and addition has good hair
Functional fibre is prepared through extraordinary spinning technique in the rare earth silicate long-afterglow material and several functions auxiliary agent of optical property
Dimension；Rare earth silicate Sr is prepared using high temperature solid-state method2MgSi2O7:Eu2+,Dy3+Long-afterglow material；
The concrete operation step that the high temperature solid-state method prepares rare earth silicate long-afterglow material is：
(1) according to chemical composition Sr2-x-yMgSi2O7:xEu2+,yDy3+,zB3+Accurate calculate weighs strontium carbonate, basic carbonate
The raw materials such as magnesium, europium oxide, dysprosia, titanium dioxide osmanthus, boric acid (cosolvent)；
(2) raw material is put into agate mortar and is ground；Grinding method can there are two types of：First, directly grinding, milling time
It will be more than half an hour to ensure to mix fully between raw material；Second is that absolute ethyl alcohol assisted milling is added in mortar, then will mixing
Liquid is put into for being dried in case；
(3) powder is fitted into aluminium oxide Noah's ark, Noah's ark be put into oneself heat up in advance dehumidifying vacuum tube furnace in, use carbon dust
In the CO gas that high temperature generates as reducing atmosphere, it is warming up to 1200-1400 DEG C with the rate of 10 DEG C/10min, high temperature
Calcination is 2-4 hours；
(4) calcining terminates, and tube furnace is naturally cooling to that oneself is formed block-like sample taking-up after room temperature, by attrition grinding
After can be obtained target product；
Step 5: the noctilucence nylon fibre of two kinds of colors of A, B is spinned respectively, the processing of rove processing flow is carried out：Clearly
Connection, drafting (two), rove are combed, wherein：Blowing carding：Quantification of 20-25g/5m, drafting (two)：End quantitative is 18-22g/
5m, rove：Quantification of 3.5-6.5g/10m, ingot speed 800-1000r/min；
Step 6: simultaneously plying and noctilucence nylon fibre are carried out to the processing of spun yarn, dead twist, winder, wherein：Spun yarn：Ingot speed
For 12500-15000r/min, twist factor 450-700；Color spot is distributed as：A color spots：Length is：60,70,50,35mm, rugosity
It is 80%；B color spots：Length is：55,45,50,70mm, rugosity 80%；A, B color spots spacing：150,230,300,180,140,
180,200,200mm；Dead twist temperature be：80-90 DEG C, the time is：3.5-8.0h；Winder：Speed is 800-1200m/min.
As an optimization：The ultra-high molecular weight polyethylene long filament is：144dtex/72f is red.
As an optimization：The copper ammonia fiber long filament is：144dtex/72f is red.
As an optimization：The noctilucence nylon fibre is：1.67dtex*38mm, blue, yellow.
Advantageous effect：The color spot silk prepared in the present invention is silk in twisting process, interruption implantation color fiber, in long filament
Intermittent section coloured silk color spot shape is formed on surface, rugosity, the length of color spot can control.This color spot silk is in surface structure, color
A variety of new variations are all showed in color feature, fabric style, and more more options are provided for new textile product exploitation.Color spot silk exists
There are more variations, the three-dimensional sense of yarn is stronger, and more variations are assigned in the style of fabric, are enriched on the color of yarn
The kind of long filament, promotes the progress and development of long filament technology.In the color spot silk prepared in the present invention, long filament uses cuprammonium
Fiber filament has nice and cool, ventilative, moisture absorption, high-strength, wear-resisting etc. with superhigh molecular weight polyethylene fibers long filament after heavy twist
Performance is added to the luminous fiber color spot of two kinds of colors in twisting process, and luminous fiber can shine at daytime, night,
Different colors is presented, increase property and three-dimensional sense rich in color for high twist yarn promotes answering for functional fibre through the invention
With, enrich textile product design.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, so that the technology of this field
Personnel can be better understood from advantages and features of the invention, to make apparent boundary to protection scope of the present invention
It is fixed.Embodiment described in the invention is only a part of the embodiment of the present invention, instead of all the embodiments, based on the present invention
In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work
Example, shall fall within the protection scope of the present invention.
Embodiment
A kind of preparation method of functionality heavy twist color spot silk, includes the following steps：
Step 1: copper ammonia fiber long filament prepares dyeing processing：The natural cellulosic feedstocks such as cotton linter are dissolved in hydroxide
In copper or the liquor ammoniae fortis of alkaline cupric salt, be made into spinning solution, the spinning technique in the coagulating bath of water or dilute alkaline soln, then containing
So that copper ammonia fiber molecular chemistry object disintegrating and regeneration is gone out cellulose in second bath of 2-3% sulfuric acid solutions, generate hydrate cellulose,
Copper ammonia fiber is obtained through post-processing；And carry out dyeing processing.
Step 2: ultra-high molecular weight polyethylene long filament coloring treatment：
This method is total in double screw extruder by organic pigment solution and spinning solution of ultra-high molecular weight polyethylene fiber
Mixed to squeeze out, since the internal temperature of double screw extruder is higher, and the mixture of spinning solution and organic pigment solution is located always
In flow regime, accordingly it is possible to prevent solidification and residual of the organic pigment inside equipment, effectively prevent organic pigment to spinning
The pollution of silk equipment, reduces the cleaning difficulty of spinning equipment.Meanwhile the pigment that the present invention uses is organic pigment, with spinning
The intersolubility of stoste is good, and the colored fibre color of preparation is uniform.
A, ultra-high molecular weight polyethylene lysate and the mixing of ultra-high molecular weight polyethylene swelling solution, it is poly- to obtain super high molecular weight
Vinyl fiber spinning solution；
The ultra-high molecular weight polyethylene lysate is ultra-high molecular weight polyethylene powder, spin solvent, antioxidant and breast
The mixed liquor of agent；The ultra-high molecular weight polyethylene swelling solution is the mixing of ultra-high molecular weight polyethylene powder and spin solvent
Liquid；Organic pigment solution converges with the spinning solution of ultra-high molecular weight polyethylene fiber, and double screw extruder is entered after confluence
Blending extrusion carries out spinning and forms frozen glue precursor；
B, the frozen glue precursor obtains ultra-high molecular weight polyethylene colored fibers after extraction, drying and hot-stretch.
Step 3: simultaneously plying：By ultra-high molecular weight polyethylene long filament and copper ammonia fiber long filament carries out and silk.
Step 4: the preparation of noctilucence nylon fibre：Using spinning material as matrix, using the luminous material of long afterglow rare earth aluminate
Material, luminous fiber is made through extraordinary spinning；Wherein, the noctilucence nylon fibre of two kinds of colors of A, B is prepared；It refers specifically in spinning
A kind of functional fiber that long-afterglow material can shine in the dark is added in journey.Southern Yangtze University and the limited public affairs of Wuxi Hong Yuan chemical fibres
The rare earth silicate luminous fiber for taking charge of cooperation, is a kind of high performance functional fiber.Rare earth silicate noctilucence is fine
Dimension is to add the rare earth silicate long afterglow with good luminous performance using high polymers such as polyester, polyamide, polypropylene as base material
Material and several functions auxiliary agent, the functional fiber being prepared through extraordinary spinning technique, as long as receive artificial light source or
Natural light irradiation for a period of time, can in the dark shine ten hours or more, be a kind of pollution-free, "dead", green energy conservation
And the accumulating type functional fibre that can be recycled.
Rare earth silicate Sr is prepared using high temperature solid-state method2MgSi2O7:Eu2+,Dy3+Long-afterglow material.
The concrete operation step that high temperature solid-state method prepares rare earth silicate long-afterglow material is：
(1) according to chemical composition Sr2-x-yMgSi2O7:xEu2+,yDy3+,zB3+Accurate calculate weighs strontium carbonate, basic carbonate
The raw materials such as magnesium, europium oxide, dysprosia, titanium dioxide osmanthus, boric acid (cosolvent).
(2) raw material is put into agate mortar and is ground.There are two types of grinding method：First, directly grinding, milling time will surpass
In half an hour to ensure to mix fully between raw material；Second is that absolute ethyl alcohol assisted milling is added in mortar, then mixed liquor is put
Enter for being dried in case, the powder that this method obtains hook degree is high but elapsed time is longer.
(3) powder is fitted into aluminium oxide Noah's ark, Noah's ark be put into oneself heat up in advance dehumidifying vacuum tube furnace in, use carbon dust
In the CO gas that high temperature generates as reducing atmosphere, target temperature (1200- is warming up to the rate of 10 DEG C/10min
1400 DEG C) high-temperature calcination 2-4 hours.
(4) calcining terminates, and tube furnace is naturally cooling to that oneself is formed block-like sample taking-up after room temperature, by attrition grinding
After can be obtained target product.
Step 5: the noctilucence nylon fibre of two kinds of colors of A, B is spinned respectively, the processing of rove processing flow is carried out：Clearly
Connection, drafting (two), rove are combed, wherein：Blowing carding：Quantification of 20-25g/5m, drafting (two)：End quantitative is 18-22g/
5m, rove：Quantification of 3.5-6.5g/10m, ingot speed 800-1000r/min；
Step 6: simultaneously plying and noctilucence nylon fibre are carried out to the processing of spun yarn, dead twist, winder, wherein：Spun yarn：Ingot speed
For 12500-15000r/min, twist factor 450-700；Color spot is distributed as：A color spots：Length is：60,70,50,35mm, rugosity
It is 80%；B color spots：Length is：55,45,50,70mm, rugosity 80%；A, B color spots spacing：150,230,300,180,140,
180,200,200mm；Dead twist temperature be：80-90 DEG C, the time is：3.5-8.0h；Winder：Speed is 800-1200m/min.
In the present embodiment, the ultra-high molecular weight polyethylene long filament is：144dtex/72f is red.The cuprammonium is fine
Tieing up long filament is：144dtex/72f is red.The noctilucence nylon fibre is：1.67dtex*38mm, blue, yellow.
The color spot silk prepared in the present invention is silk in twisting process, interruption implantation color fiber, the shape on filament surface
At intermittent section coloured silk color spot shape, rugosity, the length of color spot can control.This color spot silk is in surface structure, color character, face
A variety of new variations are all showed in material style, more more options are provided for new textile product exploitation.Color of the color spot silk in yarn
There are more variations, the three-dimensional sense of yarn is stronger, and more variations are assigned in the style of fabric, enrich long filament on coloured silk
Kind promotes the progress and development of long filament technology.In the color spot silk prepared in the present invention, long filament uses copper ammonia fiber long filament
Have the performances such as nice and cool, ventilative, moisture absorption, high-strength, wear-resisting after heavy twist with superhigh molecular weight polyethylene fibers long filament, adding
The luminous fiber color spot of two kinds of colors is added to during twisting, luminous fiber can shine at daytime, night, present different
Color increases property and three-dimensional sense rich in color for high twist yarn, through the invention, promotes the application of functional fibre, enriches
Textile product designs.
The purpose for reinforcing twisting in the present invention is to meet the requirement of Fabric Style and dress ornament performance, and high twist yarn is stored due to itself
Larger untwisting power, fabric practice contaminate during, strand is made fabric generate larger by hyther, the enhancing of untwisting power
It shrinks, the wrinkle effect of thousand money different expressions and various different-styles is presented in fabric, increases the elasticity, wrinkle resistance, drapability of fabric
Etc. wearability.
Setting process：Setting process is a key in entire heavy twist process of producing product.The quality that shapes is direct
Influence product quality and weaving efficiency.Setting is insufficient, and twisted filament fails volt and twists, no matter doing through or doing latitude, all can reversely be turned round because of silk thread
Knot influences production and stops platform and product quality.If fixing time is long or temperature is excessively high, although weaving is smooth, finished product wrinkle effect is influenced
It answers, feel is hardened, and stylistic effects expected from fabric are not achieved.The parameter of most crux is temperature and time in setting process,
According to different silk kinds, line density, twist value etc. because of usually reasonable set thermosetting process parameter, that is, reaches setting and only twist and be conducive to knit
The purpose made, and the best effect of fabric silk fabric face wrinkle effect can be obtained.
Generally in silk of the same race, same to line density, under the conditions such as the twist, long filament is lower than the setting temperature of textured filament.
Fixing time can be set according to silk kind, line density, the twist and purposes.Fine twisting silk setting mixed to plurality of raw materials ingredient is to answer
Notice mixing that the raw material types of fibre, setting temperature generally consider to set with base glass temperature low one kind.
The characteristics of heavy twist silk fabrics is：The gas permeability and wearability of heavy twist silk fabrics are better than common silk fabrics, cloth cover line
Clear it is clear, therefore yarn twist system than more demanding.It is very big to be made into cloth after-contraction, is somewhat like elastic force, cloth cover corrugation, relatively light
Clean, feel slightly hardboard needs to shape after resultant yarn, and dress is relatively more nice and cool, has more dry and comfortable feeling, relative to having preferably for low twist
Gas permeability.Heavy twist silk fabrics is more thick and stiff, with linen feeling, ventilating, since the twist is larger, moisture pick-up properties compared with
Difference, it is thick and stiff, it is not easy to paste on the skin after summer perspiration.
Heavy twist：Ventilative, good heat-transfer, cool and comfortable, high-strength wearable, feel is coarse, has dimity sense.High twist yarn is made
The knitting fabric of nice and cool linen look not only there is dimity sense, but also nice and cool good hygroscopicity, especially long filament are twisted, and are a kind of comparisons
Ideal knitting fabric, other than the excellent performance with long filament, fabric hand feel is more plentiful, and relatively stiffening has body bone, size
Stability is good, has preferable anti-craping character, is the ideal fabric of business wear, easy dress.The Bali voile of high twist yarn manufacture, is plain weave
Bimbisara fabric, due to using heavy twist, to achieve the effect that clear cloth hole, good permeability, feel are smooth, well-pressed.
Claims (4)
1. a kind of preparation method of functionality heavy twist color spot silk, it is characterised in that：Include the following steps：
Step 1: copper ammonia fiber long filament prepares dyeing processing：By the natural cellulosic feedstocks such as cotton linter be dissolved in Kocide SD or
In the liquor ammoniae fortis of person's alkaline cupric salt, it is made into spinning solution, the spinning technique in the coagulating bath of water or dilute alkaline soln, then containing 2-
So that copper ammonia fiber molecular chemistry object disintegrating and regeneration is gone out cellulose in second bath of 3% sulfuric acid solution, hydrate cellulose is generated, after
Processing obtains copper ammonia fiber；And carry out dyeing processing；
Step 2: ultra-high molecular weight polyethylene long filament coloring treatment：
A, ultra-high molecular weight polyethylene lysate and the mixing of ultra-high molecular weight polyethylene swelling solution, obtain ultra-high molecular weight polyethylene
Fiber spinning dope；
The ultra-high molecular weight polyethylene lysate is ultra-high molecular weight polyethylene powder, spin solvent, antioxidant and emulsifier
Mixed liquor；The ultra-high molecular weight polyethylene swelling solution is the mixed liquor of ultra-high molecular weight polyethylene powder and spin solvent；
Organic pigment solution converges with the spinning solution of ultra-high molecular weight polyethylene fiber, and double screw extruder is entered after confluence and is blended
It squeezes out, carries out spinning and form frozen glue precursor；
B, the frozen glue precursor obtains ultra-high molecular weight polyethylene colored fibers after extraction, drying and hot-stretch；
Step 3: simultaneously plying：By ultra-high molecular weight polyethylene long filament and copper ammonia fiber long filament carries out and silk；
Step 4: the preparation of noctilucence nylon fibre：Using spinning material as matrix, using long afterglow rare earth aluminate luminescent material,
Luminous fiber is made through extraordinary spinning；Wherein, the noctilucence nylon fibre of two kinds of colors of A, B is prepared：
Rare earth silicate luminous fiber is using high polymers such as polyester, polyamide, polypropylene as base material, and addition has good luminous property
The rare earth silicate long-afterglow material and several functions auxiliary agent of energy, functional fiber is prepared through extraordinary spinning technique；
Rare earth silicate Sr is prepared using high temperature solid-state method2MgSi2O7:Eu2+,Dy3+Long-afterglow material；
The concrete operation step that the high temperature solid-state method prepares rare earth silicate long-afterglow material is：
(1) according to chemical composition Sr2-x-yMgSi2O7:xEu2+,yDy3+,zB3+Accurate calculate weighs strontium carbonate, basic magnesium carbonate, oxygen
Change the raw materials such as europium, dysprosia, titanium dioxide osmanthus, boric acid (cosolvent)；
(2) raw material is put into agate mortar and is ground；Grinding method can there are two types of：First, directly grinding, milling time will surpass
In half an hour to ensure to mix fully between raw material；Second is that absolute ethyl alcohol assisted milling is added in mortar, then mixed liquor is put
Enter for being dried in case；
(3) powder is fitted into aluminium oxide Noah's ark, Noah's ark be put into oneself heat up in advance dehumidifying vacuum tube furnace in, with carbon dust in height
The CO gas that temperature generates is warming up to 1200-1400 DEG C, high-temperature calcination as reducing atmosphere with the rate of 10 DEG C/10min
It is 2-4 hours；
(4) calcining terminates, and tube furnace is naturally cooling to that oneself is formed block-like sample taking-up after room temperature, after attrition grinding i.e.
Target product can be obtained；
Step 5: the noctilucence nylon fibre of two kinds of colors of A, B is spinned respectively, the processing of rove processing flow is carried out：Blowing carding,
Drafting (two), rove, wherein：Blowing carding：Quantification of 20-25g/5m, drafting (two)：End quantitative is 18-22g/5m, slightly
Yarn：Quantification of 3.5-6.5g/10m, ingot speed 800-1000r/min；
Step 6: simultaneously plying and noctilucence nylon fibre are carried out to the processing of spun yarn, dead twist, winder, wherein：Spun yarn：Ingot speed is
12500-15000r/min, twist factor 450-700；Color spot is distributed as：A color spots：Length is：60,70,50,35mm, rugosity are
80%；B color spots：Length is：55,45,50,70mm, rugosity 80%；A, B color spots spacing：150,230,300,180,140,
180,200,200mm；Dead twist temperature be：80-90 DEG C, the time is：3.5-8.0h；Winder：Speed is 800-1200m/min.
2. the preparation method of functionality heavy twist color spot silk according to claim 1, it is characterised in that：The supra polymer
Weight northylen long filament is：144dtex/72f is red.
3. the preparation method of functionality heavy twist color spot silk according to claim 1, it is characterised in that：The copper ammonia fiber
Long filament is：144dtex/72f is red.
4. the preparation method of functionality heavy twist color spot silk according to claim 1, it is characterised in that：The noctilucence polyamide fibre
Fiber is：1.67dtex*38mm, blue, yellow.
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Application publication date: 20181030 |