CN108659941A - A kind of cutting fluid and preparation method thereof - Google Patents
A kind of cutting fluid and preparation method thereof Download PDFInfo
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- CN108659941A CN108659941A CN201810806874.4A CN201810806874A CN108659941A CN 108659941 A CN108659941 A CN 108659941A CN 201810806874 A CN201810806874 A CN 201810806874A CN 108659941 A CN108659941 A CN 108659941A
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- cutting fluid
- good
- fungicide
- diethanol amine
- raw material
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229940043237 diethanolamine Drugs 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 18
- 239000003784 tall oil Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 claims abstract description 15
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004327 boric acid Substances 0.000 claims abstract description 15
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 15
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 15
- 239000000417 fungicide Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000001294 propane Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 229920002545 silicone oil Polymers 0.000 claims abstract description 15
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 14
- 150000007513 acids Chemical class 0.000 claims abstract description 13
- AWJGUDCJLBHALH-UHFFFAOYSA-N [Na].C(CCCCCCCC)C=1C(=C(C2=CC=CC=C2C1)S(=O)(=O)O)CCCCCCCCC Chemical compound [Na].C(CCCCCCCC)C=1C(=C(C2=CC=CC=C2C1)S(=O)(=O)O)CCCCCCCCC AWJGUDCJLBHALH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 18
- KTJPWDKOKGANNX-UHFFFAOYSA-N [2-methoxy-3-(octadecanoylamino)propyl] 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCC(OC)COP([O-])(=O)OCC[N+](C)(C)C KTJPWDKOKGANNX-UHFFFAOYSA-N 0.000 claims description 16
- 229940049964 oleate Drugs 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 13
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 12
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- JYUMIEPRMBLLEI-UHFFFAOYSA-N C1(=CC=CC2=CC=CC=C12)S(=O)(=O)O.C(CCCCCCCC)[Na] Chemical compound C1(=CC=CC2=CC=CC=C12)S(=O)(=O)O.C(CCCCCCCC)[Na] JYUMIEPRMBLLEI-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000004458 analytical method Methods 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 6
- 238000012797 qualification Methods 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- -1 hydroxyl Oleate Chemical compound 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 239000008233 hard water Substances 0.000 abstract description 4
- 239000004519 grease Substances 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000013256 coordination polymer Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 238000005555 metalworking Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- FZRJLAPPFMJMCZ-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene;sodium Chemical compound [Na].C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 FZRJLAPPFMJMCZ-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000008234 soft water Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XOGODJOZAUTXDH-UHFFFAOYSA-M (N-methylanilino)methanesulfonate Chemical compound CN(CS([O-])(=O)=O)c1ccccc1 XOGODJOZAUTXDH-UHFFFAOYSA-M 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- FMNZBNCPTJEVDS-KVVVOXFISA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;(z)-octadec-9-enoic acid Chemical compound CCC(CO)(CO)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O FMNZBNCPTJEVDS-KVVVOXFISA-N 0.000 description 1
- BVPWJMCABCPUQY-UHFFFAOYSA-N 4-amino-5-chloro-2-methoxy-N-[1-(phenylmethyl)-4-piperidinyl]benzamide Chemical compound COC1=CC(N)=C(Cl)C=C1C(=O)NC1CCN(CC=2C=CC=CC=2)CC1 BVPWJMCABCPUQY-UHFFFAOYSA-N 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/18—Tall oil acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/26—Waterproofing or water resistance
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention relates to chemical technology field, especially a kind of cutting fluid and preparation method thereof, raw material includes following components by weight percentage：2 ~ 3% dodecanedicarboxylic acid, 4 ~ 5%CP, 50 ternary acids, 2 ~ 4% boric acid, 1.5 ~ 3.5% fungicide, 0.3 ~ 1% organic silicone oil, 15 ~ 20% diethanol amine, 5 ~ 10% tricarboxymethyl propane oleates, 5 ~ 10 dinonylnaphthalene sulfonic acid sodium, 3 ~ 5% tall oils, 1 ~ 5% fatty alcohol polyoxyethylene ether and surplus are pure water.Inventive formulation is scientific and reasonable, and containing less amount of grease, relatively existing cutting fluid is more environmentally friendly；And the advantages that greasy property is remarkable, rust-preventing characteristic is good, cleaning performance is excellent, hard water resistance property is good, biological stability is good, the preparation method of the present invention mixes hydrophilic raw material, then lipophilic raw material is mixed, finally the two is mixed, the cutting fluid transparency height come is blended, condition is good.
Description
Technical field
The present invention relates to chemical technology field, especially a kind of cutting fluid and preparation method thereof.
Background technology
In mechanical processing industry, lubricating oil is substantially added to carry out cutting lubrication using lubricating oil or using radix bupleuri oil
With cooling.In process, oil product waste is extremely serious, and causes prodigious injury to environment and operating personnel；And it is difficult
Obtain ideal finished surface.And radiating rate is slow when processing, and after workpieces processing, very easily upper rust.Cutting fluid should have good
Cooling performance, greasy property, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.Cutting fluid can be divided at present
Two classes, oil-soluble cutting fluid and water-soluble metalworking liquid.General oil-soluble cutting fluid lubrication performance is good, but poor cooling performance, and contains
There is large amount of organic, pollutes environment.Although some water-soluble metalworking liquid cooling performances are good, and there are lubricity and rust-proof effect are poor
The problem of, thus research and development have both lubricity, cooling, rust-preventing characteristic, easy cleaning, environmental protection, it is biodegradable, non-stimulated to human body,
Just seem critically important to the non-staining cutting fluid of environment.
Invention content
The purpose of the present invention is to solve traditional oils soluble cutting fluid pollute environment, and water-soluble metalworking liquid lubricity and
The problem of rust-proof effect difference, and provide it is a kind of it is environmentally friendly, biodegradable, non-stimulated to human body, to the non-staining water solubility of environment
Cutting fluid.
The technical solution adopted by the present invention is：A kind of cutting fluid, raw material include following components by weight percentage：2~3%
Dodecanedicarboxylic acid, 4 ~ 5%CP-50 ternary acids, 2 ~ 4% boric acid, 1.5 ~ 3.5% fungicide, 0.3 ~ 1% organic silicone oil, 15 ~ 20% 2
Ethanol amine, 5 ~ 10% tricarboxymethyl propane oleates, 5 ~ 10 dinonylnaphthalene sulfonic acid sodium, 3 ~ 5% tall oils, 1 ~ 5% fatty alcohol polyoxy second
Alkene ether and surplus are pure water.
Further, raw material includes following components by weight percentage：2.5% dodecanedicarboxylic acid, 4.4%CP-50 tri-
First acid, 3% boric acid, 2% fungicide, 0.6% organic silicone oil, 17% diethanol amine, 8% tricarboxymethyl propane oleate, 8% dinonyl naphthalene
Sodium sulfonate, 4% tall oil, 2.7% fatty alcohol polyoxyethylene ether and surplus are pure water.
Further, fungicide is Bit20 or accounts for total weight ratio to be 1 ~ 1.5% morpholine and 0.5 ~ 2% pyridine.
A kind of preparation method of cutting fluid, includes the following steps：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, fungicide and organic silicone oil, stirring are mixed for 0.5 ~ 1.5 hour
Close A material；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 0.5 ~ 1.5 hour；
(3) mixture A is slowly added into mixture B, stirs 0.5 ~ 1 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
Beneficial effects of the present invention：
1, inventive formulation is scientific and reasonable, containing less amount of grease, and using tall oil and trimethylolpropane oleic acid
This kind of degradable grease of ester, relatively existing cutting fluid are more environmentally friendly；
2, cutting fluid lubrication performance of the invention is remarkable, enables workpiece obtain splendid surface smoothness and effectively extends making for cutter
With the service life, it is very suitable for and high progress and high-speed cutting and grinding；
3, rust-preventing characteristic is good, using rust-inhibiting additives such as CP-50 ternary acids, reaches good rust prevention during manufacture effect；
4, cleaning performance is excellent, water-base cutting fluid cut and Grinding Process in, can effectively surface cleaning process generate
Clast ensures that board sticks with product surface cleaning nothing；
5, hard water resistance property is good, and the emulsifiers such as diethanol amine are added and have good emulsibility and low bubble, no matter in hard water or
The good performance in place can be showed in soft water；
6, biological stability is good, and special fungicide is added, and effectively antagonizes bacterium and mould, and cutting fluid service life is long, maximum
Limit reduces discharge；
7, preparation method of the invention mixes hydrophilic raw material, then mixes lipophilic raw material, finally
The two is mixed, the cutting fluid transparency height come is blended, condition is good.
Specific implementation mode
The cutting fluid of the present invention, raw material include following components by weight percentage：2 ~ 3% dodecanedicarboxylic acid, 4 ~ 5%
CP-50 ternary acids, 2 ~ 4% boric acid, 1.5 ~ 3.5% fungicide, 0.3 ~ 1% organic silicone oil, 15 ~ 20% diethanol amine, 5 ~ 10% 3 hydroxyl first
Base propane oleate, 5 ~ 10 dinonylnaphthalene sulfonic acid sodium, 3 ~ 5% tall oils, 1 ~ 5% fatty alcohol polyoxyethylene ether and surplus are pure water.
Fungicide is the Bit20 of low toxic and environment-friendly or accounts for total weight ratio to be 1 ~ 1.5% morpholine and 0.5 ~ 2% pyridine, though morpholine and pyridine have
There is certain toxicity but accounting is seldom, and itself is alkalinity, it can be substantially reduced with other acid reactions in cutting fluid
Toxicity, and it is at low cost.
The tricarboxymethyl propane oleate that the cutting fluid of the present invention is added have excellent greasy property, viscosity index (VI) it is high,
Flame resistance is good, hydrolytic stability is good, high-flash, it is low volatilization, low-temperature characteristics it is good and environment friendly and pollution-free；CP-50 ternary acids etc. are added
Rust-inhibiting additive reaches good rust prevention during manufacture effect；The emulsifiers such as diethanol amine are added and have good emulsibility and low
Bubble property, no matter the good performance in place can be showed in hard water or soft water；Special fungicide is added, valence can be used in fungicide
The Bit20 or the relatively low morpholine of price and pyridine of the higher low toxic and environment-friendly of lattice, effectively antagonize bacterium and mould, and cutting fluid uses the longevity
Life length, reduces discharge to greatest extent.
The preparation method of cutting fluid of the present invention, includes the following steps：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, fungicide and organic silicone oil, stirring are mixed for 0.5 ~ 1.5 hour
Close A material；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 0.5 ~ 1.5 hour；
(3) mixture A is slowly added into mixture B, stirs 0.5 ~ 1 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
First hydrophilic raw material is mixed in the preparation method of the present invention, then mixes lipophilic raw material
It closes, finally mixes the two, blend the cutting fluid transparency height come, condition is good.
Specific embodiment 1.
A kind of cutting fluid, raw material include following components by weight percentage：2.5% dodecanedicarboxylic acid, 4.4%CP-50
Ternary acid, 3% boric acid, 2% Bit20,0.6% organic silicone oil, 17% diethanol amine, 8% tricarboxymethyl propane oleate, 8% dinonyl
Sodium naphthalene sulfonate, 4% tall oil, 2.7% fatty alcohol polyoxyethylene ether and surplus are pure water.
Preparation method includes the following steps：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, Bit20 and organic silicone oil, stirring obtain mixing A material for 1 hour；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 1 hour；
(3) mixture A is slowly added into mixture B, stirs 0.8 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
Specific embodiment 2.
A kind of cutting fluid, raw material include following components by weight percentage：2% dodecanedicarboxylic acid, 4%CP-50 ternarys
Acid, 4% boric acid, 1.5% Bit20,1% organic silicone oil, 20% diethanol amine, 5% tricarboxymethyl propane oleate, 10% dinonyl naphthalene
Sodium sulfonate, 3% tall oil, 1% fatty alcohol polyoxyethylene ether and surplus are pure water.
Preparation method includes the following steps：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, Bit20 and organic silicone oil, stirring obtain mixing A for 0.5 hour
Material；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 1.5 hours；
(3) mixture A is slowly added into mixture B, stirs 1 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
Specific embodiment 3.
A kind of cutting fluid, raw material include following components by weight percentage：3% dodecanedicarboxylic acid, 5%CP-50 ternarys
Acid, 2% boric acid, 1% morpholine, 0.5% pyridine, 0.3% organic silicone oil, 15% diethanol amine, 10% tricarboxymethyl propane oleate, 5% 2
Nonyl sodium naphthalene sulfonate, 5% tall oil, 5% fatty alcohol polyoxyethylene ether and surplus are pure water.
Preparation method includes the following steps：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, Bit20 and organic silicone oil, stirring obtain mixing A for 1.5 hours
Material；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 0.5 hour；
(3) mixture A is slowly added into mixture B, stirs 0.5 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
The present invention is suitable for the processing of the various materials such as cast iron, steel, steel alloy, mould steel, copper, titanium alloy, and can be used
In a variety of processing technologys such as vehicle, milling, brill, hinge, saw, mill, it can be widely applied to machining center, numerically-controlled machine tool, building-block machine etc. and add
Construction equipment.
The cutting fluid of the present invention reaches following technology requirement through overtesting：
Claims (4)
1. a kind of cutting fluid, it is characterised in that：Raw material includes following components by weight percentage：2 ~ 3% dodecanedicarboxylic acid, 4 ~
5%CP-50 ternary acids, 2 ~ 4% boric acid, 1.5 ~ 3.5% fungicide, 0.3 ~ 1% organic silicone oil, 15 ~ 20% diethanol amine, 5 ~ 10% 3 hydroxyl
Oleate, 5 ~ 10 dinonylnaphthalene sulfonic acid sodium, 3 ~ 5% tall oils, 1 ~ 5% fatty alcohol polyoxyethylene ether and surplus are pure
Water.
2. a kind of cutting fluid according to claim 1, it is characterised in that：Raw material includes following components by weight percentage：
2.5% dodecanedicarboxylic acid, 4.4%CP-50 ternary acids, 3% boric acid, 2% fungicide, 0.6% organic silicone oil, 17% diethanol amine, 8%
Tricarboxymethyl propane oleate, 8% dinonylnaphthalene sulfonic acid sodium, 4% tall oil, 2.7% fatty alcohol polyoxyethylene ether and surplus are pure
Water.
3. a kind of cutting fluid according to claim 1, it is characterised in that：The fungicide is Bit20 or accounts for total weight
Than for 1 ~ 1.5% morpholine and 0.5 ~ 2% pyridine.
4. a kind of preparation method preparing a kind of cutting fluid as described in claim 1-3, it is characterised in that：Including walking as follows
Suddenly：
(1) water of formula ratio is added in the reaction kettle cleaned up, starts blender, then sequentially adds formula ratio
Diethanol amine, dodecanedicarboxylic acid, CP-50 ternary acids, boric acid, fungicide and organic silicone oil, stirring are mixed for 0.5 ~ 1.5 hour
Close A material；
(2) start blender, then sequentially add the diethanol amine of formula ratio, tall oil, tricarboxymethyl propane oleate, two
Nonyl sodium naphthalene sulfonate and fatty alcohol polyoxyethylene ether, stirring obtain mixing B material for 0.5 ~ 1.5 hour；
(3) mixture A is slowly added into mixture B, stirs 0.5 ~ 1 hour to obtain the final product；
(4) blowing is packed after sampling analysis qualification.
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Application publication date: 20181016 |