[go: up one dir, main page]

CN108511815B - A method and system for evaluating the consistency of lithium-ion batteries - Google Patents

A method and system for evaluating the consistency of lithium-ion batteries Download PDF

Info

Publication number
CN108511815B
CN108511815B CN201810170001.9A CN201810170001A CN108511815B CN 108511815 B CN108511815 B CN 108511815B CN 201810170001 A CN201810170001 A CN 201810170001A CN 108511815 B CN108511815 B CN 108511815B
Authority
CN
China
Prior art keywords
lithium
battery
temperature
ion battery
consistency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201810170001.9A
Other languages
Chinese (zh)
Other versions
CN108511815A (en
Inventor
姚丹
彭文
李亚金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gotion High Tech Co Ltd
Original Assignee
Gotion High Tech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gotion High Tech Co Ltd filed Critical Gotion High Tech Co Ltd
Priority to CN201810170001.9A priority Critical patent/CN108511815B/en
Publication of CN108511815A publication Critical patent/CN108511815A/en
Application granted granted Critical
Publication of CN108511815B publication Critical patent/CN108511815B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/3644Constructional arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)

Abstract

The invention discloses a lithium ion battery consistency evaluation method and a lithium ion battery consistency evaluation system, which belong to the field of power battery detection technology and comprise the steps of carrying out formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries; carrying out alternating current impedance spectrum test on the lithium ion battery subjected to preliminary grading at low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to preliminary grading; and according to the magnitude of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery. According to the invention, the alternating current impedance test of the battery at low temperature is added to solve the problems that the consistency of the electrical property of the battery at normal temperature is better and the consistency of the battery at low temperature is poorer, so that the reasonable matching of the battery is realized, and the excellent performance of the battery pack during low-temperature and normal-temperature charging and discharging is ensured.

Description

Method and system for evaluating consistency of lithium ion battery
Technical Field
The invention relates to the technical field of power battery detection, in particular to a method for evaluating consistency of a lithium ion battery.
Background
Lithium ion batteries have been successfully used in electric road vehicles because of their high specific energy, high specific power, long service life, wide working range, and the like. Lithium ion batteries for electric road vehicles generally require a plurality of small-capacity low-voltage single batteries to be combined into a high-capacity high-voltage battery pack in a parallel or series connection manner. It is well known that the uniformity of the individual cells within a battery pack is critical to maintaining the performance of the battery pack, and the quality of the uniformity is directly related to the performance and the life of the battery pack.
The method for detecting the consistency of each single battery in the battery industry generally comprises two methods: one method is to classify by detecting the static data of capacity difference, alternating current internal resistance difference and initial voltage difference after the formation and capacity grading of all the single batteries, and then match and screen. The other is a dynamic method, namely, the consistency characteristic of the battery is evaluated by observing the charging and discharging processes.
However, both of the above-described detection methods are intended for detection and evaluation of the consistency of the battery in a normal temperature state, and are not suitable for consistency detection of the battery pack in various environments, particularly in a low-temperature environment. In a low-temperature environment, the conductivity of the important components such as organic electrolyte, active substances, a diaphragm and the like in the battery is greatly reduced, and the battery voltage is possibly reduced to a cut-off voltage at the moment of discharging, so that the battery cannot be discharged and cannot be detected by a dynamic method. Moreover, the internal resistance of each component in the battery is affected by the processing and manufacturing processes, and the inconsistency of the discharge capacity is reflected, so that the internal resistance, the pressure difference and the like at normal temperature cannot be effectively detected.
Therefore, in order to better detect and ensure the consistency of the lithium ion battery pack for the electric road vehicle in a low temperature environment, patent document No. 201010241411.1 discloses testing the consistency of the battery by low temperature direct current internal resistance. Although the mode is simple, large-current charging and discharging equipment is needed, the occupied area of the equipment is large, the price is high, the cost of consistency detection of the single batteries is increased, and the method is not suitable for consistency detection of a large number of single batteries.
Disclosure of Invention
The invention aims to provide a lithium ion battery consistency evaluation method capable of detecting consistency of a large number of single batteries at low temperature.
In order to realize the purpose, the invention adopts the technical scheme that:
on one hand, the method for evaluating the consistency of the lithium ion battery comprises the following steps:
carrying out formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries;
carrying out alternating current impedance spectrum test on the lithium ion battery subjected to the preliminary grading at a low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to the preliminary grading;
and according to the magnitude of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery.
Preferably, the alternating current impedance spectrum test at low temperature is performed on the preliminarily graded lithium ion battery to obtain the charge transfer impedance of the preliminarily graded lithium ion battery, and the method specifically includes:
charging the lithium ion battery subjected to primary grading to the same charge state at normal temperature;
placing the lithium ion batteries with the same charge state in a low-temperature environment until the internal and external parts of the batteries reach preset temperatures;
and carrying out low-temperature alternating current impedance spectrum test on the batteries with the internal and external temperatures reaching the preset temperature to obtain the charge transfer impedance of the batteries.
Preferably, according to the magnitude of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery, specifically including:
taking the average value of the charge transfer impedances of all the lithium ion batteries with the difference values of the charge transfer impedances within the difference standard range as a grading standard;
and according to the grading standard, a plurality of lithium ion batteries in the same gear form a battery pack.
Preferably, the temperature range of the low-temperature environment is-20 ℃ to 0 ℃.
Preferably, the step of performing formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain the lithium ion batteries after preliminary grading specifically includes:
carrying out formation treatment on a plurality of lithium ion batteries with the same nominal capacity, carrying out voltage detection on the formed batteries, and screening out the batteries with qualified voltage values;
and (3) aging the battery with a qualified voltage value at a high temperature, grading and standing, and grading the lithium ion battery according to the voltage reduction value, the internal resistance value and the capacity value to obtain the preliminarily graded lithium ion battery.
Preferably, the high-temperature aging temperature of the battery with qualified voltage value is 40-45 ℃, and the standing time is 12-13h in the capacity grading and standing treatment.
Preferably, in the lithium ion battery subjected to the primary grading treatment according to the voltage reduction value, the internal resistance difference standard and the capacity difference standard, the grading conditions are specifically as follows:
the value of the capacity difference standard is 10-20% of the nominal capacity of the single battery, the value of the internal resistance difference standard is 10-20% of the nominal internal resistance of the single battery,
and the voltage reduction value is the voltage difference delta V measured twice before and after the same battery is placed still, and the delta V is less than 30 mV.
In another aspect, a system for evaluating lithium ion battery consistency includes:
the formation and capacity grading processing module is used for carrying out formation and capacity grading processing on a plurality of lithium ion batteries with the same nominal capacity to obtain the lithium ion batteries subjected to primary grading;
the alternating current impedance spectrum testing module is used for carrying out alternating current impedance spectrum testing on the lithium ion battery subjected to the preliminary grading at a low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to the preliminary grading;
and the consistency evaluation module is used for carrying out consistency evaluation on the lithium ion battery subjected to the preliminary grading according to the size of the charge transfer impedance.
Preferably, the alternating current impedance spectrum testing module specifically includes:
the charging unit is used for charging the lithium ion battery subjected to the preliminary grading to the same charge state at normal temperature;
the low-temperature processing unit is used for placing the lithium ion batteries with the same charge state in a low-temperature environment until the internal and external parts of the batteries reach preset temperatures;
and the test unit is used for carrying out low-temperature alternating current impedance spectrum test on the batteries with the inside and the outside reaching the preset temperature to obtain the charge transfer impedance of the batteries.
In another aspect, a system for evaluating lithium ion battery consistency is provided, comprising:
a memory for storing a plurality of program instructions;
a processor for loading a plurality of program instructions stored in memory to perform:
carrying out formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries;
carrying out alternating current impedance spectrum test on the lithium ion battery subjected to the preliminary grading at a low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to the preliminary grading;
and according to the magnitude of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery.
Compared with the prior art, the invention has the following technical effects: the invention adds the alternating current impedance test of the battery under the specific charging State (SOC) at low temperature in addition to the conventional screening detection of the consistency of voltage, internal resistance, capacity, storage voltage drop and the like at normal temperature, so as to solve the problems of better electrical property consistency of the battery under the normal temperature condition and poorer consistency under the low temperature condition, realize reasonable matching of the battery and ensure that the battery pack has excellent performance at low temperature and normal temperature charging and discharging.
Drawings
The following detailed description of embodiments of the invention refers to the accompanying drawings in which:
FIG. 1 is a schematic flow chart of a method for evaluating lithium ion battery consistency;
FIG. 2 is an EIS spectrum of 8 cells tested at-10 ℃;
FIG. 3 is a schematic diagram of a system for evaluating lithium ion battery consistency;
fig. 4 is a comparative graph illustrating the discharge of batteries leased using the method of the present invention and the prior art method at a rate of 0.5C at a low temperature of-10C.
Detailed Description
To further illustrate the features of the present invention, refer to the following detailed description of the invention and the accompanying drawings. The drawings are for reference and illustration purposes only and are not intended to limit the scope of the present disclosure.
As shown in fig. 1, the present embodiment discloses a method for evaluating lithium ion battery consistency, which includes the following steps S101 to S103:
s101, carrying out formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries;
s102, carrying out alternating current impedance spectrum test on the lithium ion battery subjected to preliminary grading at a low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to preliminary grading;
and S103, according to the size of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery.
As a further preferable scheme, the step S101 specifically includes:
(1) voltage screening: charging and discharging multiple lithium ion batteries with nominal capacity of 16.5Ah for the first time to obtain a battery state of 3.2 + -0.02V, standing at room temperature for 1 day, measuring the voltage of the battery, and recording as V1. According to the voltage of the measuring cell, V1The single lithium ion battery A with the battery of more than or equal to 3.2V qualified by judgment1
(2) Capacity grading treatment: after the battery with qualified size and appearance is judged, the battery is subjected to capacity grading and standing treatment, and the lithium ion battery A is subjected to capacity grading and standing treatment1Aging in a high temperature aging room with the high temperature aging condition set at 40-45 deg.C for 12-13 h.
(3) Sorting the batteries: and grading the single lithium ion battery according to the obtained discharge capacity C value, the voltage reduction value and the internal resistance value of the battery. The specific screening conditions are as follows:
a. the voltage reduction value is that delta V is less than or equal to 30mV, wherein the delta V is the voltage difference measured twice before and after the same battery is placed still;
b. the value of the standard deviation of the capacity is 10 to 20 percent of the nominal capacity of the single battery;
c. the value of the standard deviation of the internal resistance is 10 to 20 percent of the nominal internal resistance of the single battery.
Screening the lithium ion batteries according to the three standards, wherein the selected battery is Ac1
Specifically, in practical application, an automatic voltage and internal resistance sorting device may be adopted to sequentially sort the voltage and internal resistance of the batteries of each grade according to the capacity grading identification, and perform grading according to the standard that the voltage difference is less than 30mV and the alternating current internal resistance difference is less than 0.5 mohm.
More preferably, in step S102: the lithium ions A after the preliminary grading are carried outc1The method comprises the following steps of testing alternating current impedance spectrum of a battery at low temperature to obtain charge transfer impedance of the lithium ion battery after primary grading, and specifically comprises the following steps:
(1) a is to bec1The battery is charged to the same state of charge, requiring a state of charge of 25-75%.
(2) Battery A after the preliminary gradingc1And standing the battery in a constant-temperature environment bin for more than 5 hours to ensure that the inside and the outside of the battery reach the temperature set in the environment bin in advance.
It should be noted that the low temperature range in the environmental chamber is any temperature point in the range of-20 ℃ to 0 ℃.
(3) The cells were subjected to alternating current impedance (EIS) testing using an electrochemical workstation. Wherein the set parameters are as follows: frequency of 10-2~105The amplitude was 5 mV. An EIS curve graph is obtained, and the electrochemical transfer impedance value is obtained after Zview fitting, as shown in FIG. 2, the EIS curve graph of the batteries No. 1 and No. 2 in the sequence along the arrow direction in FIG. 2 is the EIS curve graph of the battery No. 8.
More preferably, in step S103: according to the magnitude of the charge transfer impedance, consistency evaluation is carried out on the lithium ion battery subjected to preliminary grading, and the method specifically comprises the following steps:
selecting a value, such as 10%, between the range of the standard deviation of the internal resistance of 10-20%, and taking the average value of the impedance with the difference standard of the charge transfer impedance of 10% (namely 10% of the nominal internal resistance of the single battery) as the grading standard. And grading the plurality of single batteries subjected to the test according to the grading standard.
The scheme increases the charge transfer impedance test of the battery at low temperature, effectively solves the problems that each single battery has good electrical property consistency under the condition of normal temperature and the electrical properties of each single battery have large difference under the condition of low temperature, is suitable for detecting large-scale batteries, realizes reasonable battery matching and ensures that the battery pack has excellent performance during low-temperature and normal-temperature charging and discharging.
As shown in fig. 2, a 0.5C constant current discharge at a temperature of-10 ℃ was performed, and discharge capacity data were collected as shown in table 1:
TABLE 1
Figure BDA0001585311780000061
Figure BDA0001585311780000071
The test results in table 1 show that the grading of the conventional capacity internal resistance test at normal temperature does not reflect the consistency of the low-temperature discharging capacity of the battery, and the low-temperature charge transfer resistance value is very consistent with the low-temperature discharging capacity of the battery.
As shown in fig. 4, according to the method of the present invention, the tested low temperature transfer impedance value is used as a grading standard, the batteries are graded according to the standard of the average value of the direct current low temperature charge transfer impedance of all the batteries with the difference of the low temperature charge transfer impedance of each battery being less than 10%, the battery is combined by 7S2P by using the single batteries with the same grade to obtain a 22.4V16Ah battery pack, and fig. 4 is a graph of the battery pack discharging at 0.5C rate at the low temperature of-10 ℃. The battery pack numbered 1-1 in the figure is obtained by sorting and matching by adopting the method of the invention, the battery pack numbered 2-1 is obtained by screening the voltage difference, the internal resistance difference and the capacity difference by adopting a common method, and as can be seen from the figure 4, the battery pack obtained by adopting the method of the invention has small voltage reduction at the moment of heavy current discharge at low temperature, high discharge capacity and good consistency among the battery packs.
In addition to conventional screening detection of consistency such as voltage, internal resistance, capacity, storage voltage drop and the like at normal temperature, the charge transfer impedance detection at low temperature is added for evaluating the electrochemical characteristics of the battery at low temperature, so that the consistency of the electrical performance of each single battery at low temperature is ensured, reasonable matching of the battery is realized, and the battery pack has excellent performance during low-temperature and normal-temperature high-rate charge and discharge. The method can quickly, comprehensively and effectively evaluate the consistency of the electrical properties of the batteries, particularly evaluate the characteristics of the batteries in a special low-temperature use environment, effectively solve the common problems that each single battery shows good consistency at normal temperature and the electrical properties greatly differ at low temperature, and can be popularized and applied to detection of large-batch batteries and screening of battery matching.
As shown in fig. 3, the present embodiment discloses a system for evaluating lithium ion battery consistency, which includes:
a formation and grading processing module 10, configured to perform formation and grading processing on multiple lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries;
an ac impedance spectrum testing module 20, configured to perform an ac impedance spectrum test at a low temperature on the preliminarily graded lithium ion battery to obtain a charge transfer impedance of the preliminarily graded lithium ion battery;
and the consistency evaluation module 30 is configured to perform consistency evaluation on the preliminarily graded lithium ion batteries according to the magnitude of the charge transfer impedance.
Preferably, the ac impedance spectrum testing module 20 specifically includes:
the charging unit is used for charging the lithium ion battery subjected to the preliminary grading to the same charge state at normal temperature;
the low-temperature processing unit is used for placing the lithium ion batteries with the same charge state in a low-temperature environment until the internal and external parts of the batteries reach preset temperatures;
and the test unit is used for carrying out low-temperature alternating current impedance spectrum test on the batteries with the inside and the outside reaching the preset temperature to obtain the charge transfer impedance of the batteries.
On the other hand, this embodiment also discloses an evaluation system for lithium ion battery consistency, which includes:
a memory for storing a plurality of program instructions;
a processor for loading a plurality of program instructions stored in memory to perform:
carrying out formation and grading treatment on a plurality of lithium ion batteries with the same nominal capacity to obtain preliminarily graded lithium ion batteries;
carrying out alternating current impedance spectrum test on the lithium ion battery subjected to the preliminary grading at a low temperature to obtain the charge transfer impedance of the lithium ion battery subjected to the preliminary grading;
and according to the magnitude of the charge transfer impedance, performing consistency evaluation on the preliminarily graded lithium ion battery.
It should be understood that the consistency evaluation system in this embodiment corresponds to the consistency evaluation method, and the above and other operations and/or functions of each module in the consistency evaluation system respectively implement corresponding processes of each method in fig. 1, and are not described herein again for brevity.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (8)

1.一种锂离子电池一致性的评价方法,其特征在于,包括:1. an evaluation method of lithium ion battery consistency, is characterized in that, comprises: 对多个具有相同标称容量的锂离子电池进行化成分容处理,得到初步分档后的锂离子电池;Carry out chemical composition treatment on a plurality of lithium-ion batteries with the same nominal capacity, and obtain the lithium-ion batteries after preliminary classification; 对所述初步分档后的锂离子电池进行低温下的交流阻抗谱测试,得到该初步分档后的锂离子电池的电荷转移阻抗,包括:Carry out the AC impedance spectrum test at low temperature on the lithium-ion battery after the preliminary classification, and obtain the charge transfer impedance of the lithium-ion battery after the preliminary classification, including: 将所述初步分档后的锂离子电池充电至同一荷电状态,要求的荷电状态为25-75%,然后搁置于恒温环境仓中静置5h以上,使电池内外部均达到环境仓预先设定的温度,所述环境仓中的低温范围为-20℃~0℃;Charge the lithium-ion battery after the preliminary classification to the same state of charge, the required state of charge is 25-75%, and then place it in a constant temperature environment for more than 5 hours, so that both the inside and outside of the battery reach the pre-condition of the environment. The set temperature, the low temperature range in the environmental chamber is -20 ℃ ~ 0 ℃; 利用电化学工作站对电池进行交流阻抗测试,其中,设置的参数为:频率为10-2~105,振幅为5mV,得到EIS曲线图,并用Zview拟合后求得电化学转移阻抗值;The AC impedance test of the battery was carried out by using an electrochemical workstation. The parameters were set as follows: the frequency was 10 -2 to 10 5 , the amplitude was 5mV, the EIS curve was obtained, and the electrochemical transfer impedance value was obtained after fitting with Zview; 根据所述电荷转移阻抗的大小,对所述初步分档后的锂离子电池进行一致性评价,具体包括:According to the size of the charge transfer impedance, the consistency evaluation of the lithium-ion battery after the preliminary classification is carried out, which specifically includes: 将电荷转移阻抗的差值在差别标准范围内的所有锂离子电池的电荷转移阻抗平均值作为分档标准;The average value of charge transfer impedance of all lithium-ion batteries whose difference in charge transfer impedance is within the range of the difference standard is used as the classification standard; 按照该分档标准,将同一个档位的多个锂离子电池组成电池组。According to this grading standard, multiple lithium-ion batteries in the same notch form a battery pack. 2.如权利要求1所述的锂离子电池一致性的评价方法,其特征在于,对所述初步分档后的锂离子电池进行低温下的交流阻抗谱测试,得到该初步分档后的锂离子电池的电荷转移阻抗,具体包括:2. The method for evaluating the consistency of lithium ion batteries as claimed in claim 1, wherein the lithium ion battery after the preliminary classification is subjected to an AC impedance spectrum test at low temperature to obtain the lithium ion battery after the preliminary classification. The charge transfer impedance of the ion battery, including: 将所述初步分档后的锂离子电池常温充电至同一荷电状态;charging the lithium-ion battery after the preliminary classification to the same state of charge at room temperature; 将同一荷电状态的锂离子电池放置在低温环境中直至电池内外部均达到预先设定的温度;Place the lithium-ion battery of the same state of charge in a low temperature environment until the inside and outside of the battery reach the preset temperature; 对内外部均达到预先设定温度的电池进行低温交流阻抗谱测试,得到该电池的电荷转移阻抗。The low-temperature AC impedance spectrum test was performed on the battery whose internal and external temperature reached the preset temperature, and the charge transfer impedance of the battery was obtained. 3.如权利要求1-2任一项所述的锂离子电池一致性的评价方法,其特征在于,所述对多个具有相同标称容量的锂离子电池进行化成分容处理,得到初步分档后的锂离子电池,具体包括:3. The method for evaluating the consistency of lithium ion batteries according to any one of claims 1 to 2, wherein the multiple lithium ion batteries with the same nominal capacity are subjected to chemical composition and volumetric treatment to obtain a preliminary score. The lithium-ion battery after the file, specifically includes: 对多个具有相同标称容量的锂离子电池进行化成处理,并对化成后的电池进行电压检测,筛选出电压值合格的电池;Perform chemical formation treatment on multiple lithium-ion batteries with the same nominal capacity, and perform voltage detection on the formed batteries to screen out batteries with qualified voltage values; 对电压值合格的电池采用高温老化并分容静置处理,并根据电压降低值、内阻值和容量值对锂离子电池分档处理得到初步分档后的锂离子电池。The batteries with qualified voltage values are subjected to high temperature aging and stand-by treatment, and the lithium-ion batteries are graded according to the voltage reduction value, internal resistance value and capacity value to obtain the preliminary graded lithium-ion batteries. 4.如权利要求3所述的锂离子电池一致性的评价方法,其特征在于,所述对电压值合格的电池采用高温老化并分容静置处理中,高温老化温度为40-45℃,静置时间为12-13h。4. The method for evaluating the consistency of lithium ion batteries according to claim 3, characterized in that the high temperature aging temperature is 40-45° C. for the battery with a qualified voltage value and is subjected to high-temperature aging and capacity-distributed standing treatment. The standing time is 12-13h. 5.如权利要求3所述的锂离子电池一致性的评价方法,其特征在于,所述根据电压降低值、内阻差别标准和容量差别标准对锂离子电池分档处理得到初步分档后的锂离子电池中,分档条件具体为:5. The method for evaluating the consistency of lithium ion batteries as claimed in claim 3, characterized in that, according to the voltage reduction value, the internal resistance difference standard and the capacity difference standard, the lithium ion battery is graded and processed to obtain the initial grades. In lithium-ion batteries, the binning conditions are as follows: 容量差别标准的取值为10%~20% 的单体电池标称容量,内阻差别标准的取值为10%~20% 的单体电池标称内阻,The value of the capacity difference standard is 10%~20% of the nominal capacity of the single battery, and the value of the internal resistance difference standard is 10%~20% of the nominal internal resistance of the single battery, 以及,电压降低值为同一只电池静置前后两次测量的电压差△V且△V<30mV。And, the voltage reduction value is the voltage difference ΔV measured twice before and after the same battery is left standing, and ΔV<30mV. 6.一种锂离子电池一致性的评价系统,其特征在于,包括:6. A lithium-ion battery consistency evaluation system, characterized in that, comprising: 化成分容处理模块,其用于对多个具有相同标称容量的锂离子电池进行化成分容处理,得到初步分档后的锂离子电池;A chemical composition processing module, which is used for chemical composition processing of a plurality of lithium ion batteries with the same nominal capacity, and obtains a preliminary classified lithium ion battery; 交流阻抗谱测试模块,其用于对所述初步分档后的锂离子电池进行低温下的交流阻抗谱测试,得到该初步分档后的锂离子电池的电荷转移阻抗,包括:An AC impedance spectrum test module, which is used to perform an AC impedance spectrum test at a low temperature on the lithium-ion battery after the preliminary classification, and obtain the charge transfer impedance of the lithium-ion battery after the preliminary classification, including: 将所述初步分档后的锂离子电池充电至同一荷电状态,要求的荷电状态为25-75%,然后搁置于恒温环境仓中静置5h以上,使电池内外部均达到环境仓预先设定的温度,所述环境仓中的低温范围为-20℃~0℃;Charge the lithium-ion battery after the preliminary classification to the same state of charge, the required state of charge is 25-75%, and then place it in a constant temperature environment for more than 5 hours, so that both the inside and outside of the battery reach the pre-condition of the environment. The set temperature, the low temperature range in the environmental chamber is -20 ℃ ~ 0 ℃; 利用电化学工作站对电池进行交流阻抗测试,其中,设置的参数为:频率为10-2~105,振幅为5mV,得到EIS曲线图,并用Zview拟合后求得电化学转移阻抗值;The AC impedance test of the battery was carried out by using an electrochemical workstation. The parameters were set as follows: the frequency was 10 -2 to 10 5 , the amplitude was 5mV, the EIS curve was obtained, and the electrochemical transfer impedance value was obtained after fitting with Zview; 一致性评价模块,其用于根据所述电荷转移阻抗的大小,对所述初步分档后的锂离子电池进行一致性评价,具体包括:The consistency evaluation module is used to evaluate the consistency of the lithium-ion battery after the preliminary classification according to the size of the charge transfer impedance, and specifically includes: 将电荷转移阻抗的差值在差别标准范围内的所有锂离子电池的电荷转移阻抗平均值作为分档标准;The average value of charge transfer impedance of all lithium-ion batteries whose difference in charge transfer impedance is within the range of the difference standard is used as the classification standard; 按照该分档标准,将同一个档位的多个锂离子电池组成电池组。According to this grading standard, multiple lithium-ion batteries in the same notch form a battery pack. 7.如权利要求6所述的锂离子电池一致性的评价系统,其特征在于,所述交流阻抗谱测试模块,具体包括:7. The system for evaluating the consistency of lithium-ion batteries according to claim 6, wherein the AC impedance spectrum test module specifically comprises: 充电单元,其用于将所述初步分档后的锂离子电池常温充电至同一荷电状态;a charging unit, which is used to charge the preliminarily classified lithium-ion battery to the same state of charge at room temperature; 低温处理单元,其用于将同一荷电状态的锂离子电池放置在低温环境中直至电池内外部均达到预先设定的温度;A low-temperature processing unit, which is used to place the lithium-ion battery of the same state of charge in a low-temperature environment until the inside and outside of the battery reach a preset temperature; 测试单元,其用于对内外部均达到预先设定温度的电池进行低温交流阻抗谱测试,得到该电池的电荷转移阻抗。The test unit is used to perform a low-temperature AC impedance spectrum test on a battery whose internal and external temperatures have reached a preset temperature to obtain the charge transfer impedance of the battery. 8.一种锂离子电池一致性的评价系统,其特征在于,包括:8. A lithium-ion battery consistency evaluation system, characterized in that, comprising: 存储器,其用于存储多条程序指令;a memory for storing a plurality of program instructions; 处理器,其用于加载存储器中存储的多条程序指令以执行:A processor for loading a plurality of program instructions stored in memory to execute: 对多个具有相同标称容量的锂离子电池进行化成分容处理,得到初步分档后的锂离子电池;Carry out chemical composition treatment on a plurality of lithium-ion batteries with the same nominal capacity, and obtain the lithium-ion batteries after preliminary classification; 对所述初步分档后的锂离子电池进行低温下的交流阻抗谱测试,得到该初步分档后的锂离子电池的电荷转移阻抗,包括:Carry out the AC impedance spectrum test at low temperature on the lithium-ion battery after the preliminary classification, and obtain the charge transfer impedance of the lithium-ion battery after the preliminary classification, including: 将所述初步分档后的锂离子电池充电至同一荷电状态,要求的荷电状态为25-75%,然后搁置于恒温环境仓中静置5h以上,使电池内外部均达到环境仓预先设定的温度,所述环境仓中的低温范围为-20℃~0℃;Charge the lithium-ion battery after the preliminary classification to the same state of charge, the required state of charge is 25-75%, and then place it in a constant temperature environment for more than 5 hours, so that both the inside and outside of the battery reach the pre-condition of the environment. The set temperature, the low temperature range in the environmental chamber is -20 ℃ ~ 0 ℃; 利用电化学工作站对电池进行交流阻抗测试,其中,设置的参数为:频率为10-2~105,振幅为5mV,得到EIS曲线图,并用Zview拟合后求得电化学转移阻抗值;The AC impedance test of the battery was carried out by using an electrochemical workstation. The parameters were set as follows: the frequency was 10 -2 to 10 5 , the amplitude was 5mV, the EIS curve was obtained, and the electrochemical transfer impedance value was obtained after fitting with Zview; 根据所述电荷转移阻抗的大小,对所述初步分档后的锂离子电池进行一致性评价,具体包括:According to the size of the charge transfer impedance, the consistency evaluation of the lithium-ion battery after the preliminary classification is carried out, which specifically includes: 将电荷转移阻抗的差值在差别标准范围内的所有锂离子电池的电荷转移阻抗平均值作为分档标准;The average value of charge transfer impedance of all lithium-ion batteries whose difference in charge transfer impedance is within the range of the difference standard is used as the classification standard; 按照该分档标准,将同一个档位的多个锂离子电池组成电池组。According to this grading standard, multiple lithium-ion batteries in the same notch form a battery pack.
CN201810170001.9A 2018-02-28 2018-02-28 A method and system for evaluating the consistency of lithium-ion batteries Active CN108511815B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810170001.9A CN108511815B (en) 2018-02-28 2018-02-28 A method and system for evaluating the consistency of lithium-ion batteries

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810170001.9A CN108511815B (en) 2018-02-28 2018-02-28 A method and system for evaluating the consistency of lithium-ion batteries

Publications (2)

Publication Number Publication Date
CN108511815A CN108511815A (en) 2018-09-07
CN108511815B true CN108511815B (en) 2021-04-09

Family

ID=63376942

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810170001.9A Active CN108511815B (en) 2018-02-28 2018-02-28 A method and system for evaluating the consistency of lithium-ion batteries

Country Status (1)

Country Link
CN (1) CN108511815B (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109365325B (en) * 2018-09-17 2021-04-09 深圳市华格安瑞技术咨询有限公司 Manufacturing method and system of battery
CN109675837B (en) * 2019-02-19 2021-02-02 惠州亿纬锂能股份有限公司 Battery screening method, device, equipment and storage medium
CN109884532A (en) * 2019-03-06 2019-06-14 郑州大学 Grid energy storage battery detection device and detection method
CN111580003A (en) * 2020-04-08 2020-08-25 国电南瑞科技股份有限公司 Impedance spectrum-based secondary battery inconsistency identification method and apparatus
CN111965555B (en) * 2020-09-18 2022-05-03 重庆长安新能源汽车科技有限公司 Parallel connection group screening method for single batteries
CN112415416A (en) * 2020-11-12 2021-02-26 河北零点新能源科技有限公司 Method for rapidly detecting consistency of lithium batteries
CN113189507A (en) * 2021-03-23 2021-07-30 天津力神电池股份有限公司 Method for rapidly representing stability of SEI (solid electrolyte interface) film of lithium battery
CN113093010B (en) * 2021-04-28 2024-12-13 惠州市湘誉新能源有限公司 A lithium-ion battery consistency evaluation method
CN113406504A (en) * 2021-06-17 2021-09-17 上海空间电源研究所 Consistency screening method for high-power lithium ion storage battery
CN114035066A (en) * 2021-10-21 2022-02-11 合肥国轩高科动力能源有限公司 A Lithium Battery Consistency Evaluation Method
CN113884923B (en) * 2021-11-03 2023-07-11 合肥国轩高科动力能源有限公司 A kind of lithium-ion battery internal resistance screening method
CN115291107B (en) * 2022-06-24 2024-06-21 广东新型储能国家研究院有限公司 Testing and evaluating method for state change degree of single structure of lithium ion battery system
CN118072891B (en) * 2024-04-22 2024-08-02 远景睿泰动力技术(上海)有限公司 Method and device for designing material scheme of battery cell and related equipment

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002260634A (en) * 2001-02-28 2002-09-13 Toyota Central Res & Dev Lab Inc Lithium secondary battery

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101907688B (en) * 2010-08-02 2012-08-22 天津力神电池股份有限公司 Method for detecting electrical property consistency of lithium ion battery
CN104730463A (en) * 2013-12-20 2015-06-24 北汽福田汽车股份有限公司 Method for detecting consistency of single batteries
CN103909068B (en) * 2014-02-28 2016-04-20 清华大学 The method for separating of battery
CN105006597B (en) * 2015-05-18 2017-06-27 北京波士顿动力电池有限公司 With the method for symmetry electrode Fast Evaluation lithium ion cell electrode conformity of production

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002260634A (en) * 2001-02-28 2002-09-13 Toyota Central Res & Dev Lab Inc Lithium secondary battery

Also Published As

Publication number Publication date
CN108511815A (en) 2018-09-07

Similar Documents

Publication Publication Date Title
CN108511815B (en) A method and system for evaluating the consistency of lithium-ion batteries
CN102553838B (en) Battery sorting method based on alternating-current impedance spectrum
CN106680726B (en) Method for testing cycle performance of lithium ion battery
CN109731808B (en) A detection and sorting method for cascade utilization of lithium batteries
CN111036575B (en) A Lithium-ion Battery Sorting Method Based on Temperature Change Analysis
CN104438138B (en) Lithium ion battery screening method
JP2004053598A (en) Method for selecting capacity of secondary battery using specific resistance factor calculation of equivalent circuit model replicated from impedance spectrum
CN105680108B (en) Screening method of lithium ion battery
CN103785629A (en) Screening grouping method of echelon utilization type lithium batteries
CN104237802A (en) Detection method for low-temperature performance uniformity of lithium ion batteries
CN107607874A (en) The bikini screening technique of quick charge/discharge lithium ion battery
CN105866700A (en) Lithium ion battery quick screening method
CN108152752B (en) Battery measuring method
CN106371022A (en) Inspection method for all-solid secondary battery and manufacturing method of the all-solid secondary battery
CN112526352A (en) SOH estimation method for retired lithium ion battery
CN105510836A (en) Lithium ion battery self-discharge test method and battery assembling method
CN107597621A (en) Screening method and matching method for improving consistency of ternary lithium ion battery pack
Zheng et al. A comparative study of battery balancing strategies for different battery operation processes
CN113093010B (en) A lithium-ion battery consistency evaluation method
CN105911477B (en) Screening method for self-discharge of power lithium ion battery
CN113238158A (en) Method for detecting consistency of battery cores in power battery pack
CN110187291B (en) Lithium ion battery self-discharge rapid screening device and screening method based on direct-current impedance
JP2018067498A (en) Method of manufacturing battery
CN117471324A (en) Method and device for evaluating consistency of single capacity in battery module
CN107589375B (en) Method and system for group performance optimization of ternary cells based on voltage secondary sorting

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant