[go: up one dir, main page]

CN108424795A - Novel environment friendly automobile exhaust detergent - Google Patents

Novel environment friendly automobile exhaust detergent Download PDF

Info

Publication number
CN108424795A
CN108424795A CN201810281319.4A CN201810281319A CN108424795A CN 108424795 A CN108424795 A CN 108424795A CN 201810281319 A CN201810281319 A CN 201810281319A CN 108424795 A CN108424795 A CN 108424795A
Authority
CN
China
Prior art keywords
weight
parts
automobile exhaust
environment friendly
novel environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810281319.4A
Other languages
Chinese (zh)
Inventor
柳溪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Benxi White Petrochemical Co Ltd
Original Assignee
Benxi White Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Benxi White Petrochemical Co Ltd filed Critical Benxi White Petrochemical Co Ltd
Priority to CN201810281319.4A priority Critical patent/CN108424795A/en
Publication of CN108424795A publication Critical patent/CN108424795A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • C10L1/1855Cyclic ethers, e.g. epoxides, lactides, lactones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/023Specifically adapted fuels for internal combustion engines for gasoline engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to novel environment friendly automobile exhaust detergent, which is made of the tetrahydrofuran of the methanol of 100 parts by weight, the ricinoleic acid of 10 80 parts by weight, the methyl acetate of 5 30 parts by weight and 0.1 5 parts by weight.Novel environment friendly automobile exhaust detergent using the present invention, motor vehicle emission major pollutants carbon monoxide, hydrocarbon, nitrogen oxides(NOX), formaldehyde emission substantially reduces, while having good oil-saving effect.

Description

Novel environment friendly automobile exhaust detergent
Technical field
The present invention relates to novel environment friendly automobile exhaust detergents.
Background technology
With the continuous development of auto industry, car ownership increases year by year, and the emission pollution problem of automobile more and more draws Play the great attention of people.National governments and each car manufacturer put into the side of a large amount of manpower and materials control motor vehicle emission Method, development and the exploitation of eco-friendly car even zero-emission vehicle are the focus and development trend of various countries' auto industry competition. Currently, Domestic Automotive Industry is in Rapid development stage, China's vehicle in use is taken a sample test according to authoritative department the result shows that, 90% vehicle in use discharge exceeds national standard, some severe overweights.Therefore, energetically vehicle emission control technology, development are low The discharge even automobile of zero-emission are environment protections, realize the needs of China's strategy of sustainable development.
The compositions of automotive emissions and rule gasoline is generated and diesel oil is made of carbon and protium, into starting After machine, if fuel completely burned will generate carbon dioxide, water, if air capacity deficiency or fuel oil in engine combustion process With air undercompounding, then carbon and hydrogen can't burn completely, a portion will be formed carbon monoxide, hydrocarbon or Hydrocarbon oxidizing aromatic hydrocarbons and carbon particle.Some fuel is due to added with leaded additive, then also will produce Organic leadP compound, together When, under the high temperature and pressure of burning, oxygen and nitrogen in air can be combined to NO and NO2, and also ozone generates, and motor vehicle emission is given up In gas, in addition to the carbon dioxide of generation, water, ozone are nontoxic to people, remaining is toxic to human body, is generated to air quality serious It influences.Although carbon dioxide is nontoxic to human body, it is one of the principal element for generating greenhouse effects.
Since motor vehicle emission major pollutants are carbon monoxide, hydrocarbon, nitrogen oxides(NOX), so, it is general to arrange The object for putting rules and regulations pollutant catabolic gene and detection is carbon monoxide, hydrocarbon, nitrogen oxides(NOX), flue dust(For For diesel engine), carbon monoxide, hydrocarbon, flue dust are when oxygen content deficiency or temperature are relatively low, fuel mixing is uneven Generate more, and nitrogen oxides(NOX)It generates at high temperature very fast.The strategy of the automobile gas emission pollution of various countries' control at present is to formulate Severeer automobile emission regulation forces automobile manufacturing company using various advanced emission control technique control vehicles in use Discharge is sought to clean alternative fuel, improves energy source of car structure, develops various on-fuel power plants(Such as:Electric vehicle, Solar telephone etc.).
Main problem is existing for the part of gasoline quality in China:Olefin(e) centent height, arene content are relatively low in gasoline, Vapour pressure is higher, and oxygenatedchemicals is low, and octane Distribution value is poor, and the content of sulphur is higher.Since alkene contains more easily in China's gasoline Carbon deposit is formed, atomizing effect and discharge are influenced, it is unfavorable to electric―controlled direct jet gasoline engine.
Invention content
In order to solve the above technical problem, the present invention provides novel environment friendly automobile exhaust detergent, the tail gas cleaning Agent is by the methanol of 100 parts by weight, the ricinoleic acid of 10-80 parts by weight, the methyl acetate of 5-30 parts by weight and 0.1-5 parts by weight Tetrahydrofuran forms.
Technology technical solution as one preferred, methanol of the tail gas detergent by 100 parts by weight, 40-70 weight The tetrahydrofuran composition of the ricinoleic acid of part, the methyl acetate of 15-30 parts by weight and 1-3 parts by weight.
Technology technical solution as one preferred, the tail gas detergent further include the cosolvent of 1-3 parts by weight, 0.1- The fire retardant of 2 parts by weight, the anti-knock agent of 0.01-1 parts by weight, the corrosion inhibitor of 0.01-1 parts by weight, 0.01-1 parts by weight The gas-tight resist of detergent-dispersant additive, the antioxidant of 0.01-1 parts by weight, 0.01-1 parts by weight.
Technology technical solution as one preferred, the cosolvent are selected from sec-octyl alcohol, isobutanol, butyl glycol ether, second One or more of glycol ether, acetic acid isoamyl fat, dimethyl ether;
Technology technical solution as one preferred, the combustion adjuvant are selected from butyl acetate, methyl ethyl ketone, tert-butyl alcohol nitro One or more of benzene, nitrotoleune, isoamyl nitrate.
Technology technical solution as one preferred, the anti-knock agent is in isobutanol, methyl tertiary butyl ether(MTBE), isooctane One or more.
Technology technical solution as one preferred, the metal corrosion inhibitor are selected from pyrazolone, three nitrogen of methyl benzo Azoles, butyl stearate, 2, one or more of 4 diisopropyl phenols, isopropyl palmitate.
Technology technical solution as one preferred, the detergent-dispersant additive are selected from two Polyoxyethylene fatty acid amides fatty acid esters, Sanya One or more of tetramine, isopropanol.
Technology technical solution as one preferred, the antioxidant are selected from 2,6-di-tert-butyl-4-methylphenol, Meng's oxygen One or more of base -2 (5H) furanone.
Technology technical solution as one preferred, the gas-tight resist are tert-butyl alcohol vinyl pyrrolidone.
Novel environment friendly automobile exhaust detergent using the present invention, motor vehicle emission major pollutants carbon monoxide, hydrocarbonization Close object, nitrogen oxides(NOX), formaldehyde emission substantially reduces, while having good oil-saving effect.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
Specific implementation mode
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of fields of the present invention The normally understood identical meaning of art personnel.When there is a conflict, the definition in this specification shall prevail.
The present invention relates to novel environment friendly automobile exhaust detergent, methanol, 10- of the tail gas detergent by 100 parts by weight The tetrahydrofuran of the ricinoleic acid of 80 parts by weight, the methyl acetate of 5-30 parts by weight and 0.1-5 parts by weight forms.
As a preferred embodiment, the tail gas detergent is by the methanol of 100 parts by weight, 40-70 parts by weight The tetrahydrofuran of two ricinoleic acids, the methyl acetate of 15-30 parts by weight and 1-3 parts by weight forms.
As a preferred embodiment, the tail gas detergent further includes the cosolvent of 1-3 parts by weight, 0.1-2 weights Measure part fire retardant, the anti-knock agent of 0.01-1 parts by weight, the corrosion inhibitor of 0.01-1 parts by weight, 0.01-1 parts by weight it is peace and quiet The gas-tight resist of dispersant, the antioxidant of 0.01-1 parts by weight, 0.01-1 parts by weight.
As a preferred embodiment, the cosolvent is selected from sec-octyl alcohol, isobutanol, butyl glycol ether, ethylene glycol One or more of ether, acetic acid isoamyl fat, dimethyl ether;
As a preferred embodiment, the combustion adjuvant is selected from butyl acetate, methyl ethyl ketone, tert-butyl alcohol nitrobenzene, nitre One or more of base toluene, isoamyl nitrate.
As a preferred embodiment, the anti-knock agent in isobutanol, methyl tertiary butyl ether(MTBE), isooctane one Kind is several.
As a preferred embodiment, the metal corrosion inhibitor is selected from pyrazolone, methyl benzotriazazole, hard Resin acid butyl ester, 2, one or more of 4 diisopropyl phenols, isopropyl palmitate.
As a preferred embodiment, the detergent-dispersant additive is selected from two Polyoxyethylene fatty acid amides fatty acid esters, triethylene One or more of tetramine, isopropanol.
As a preferred embodiment, the antioxidant is selected from 2,6-di-tert-butyl-4-methylphenol, Meng's oxygroup -2 One or more of (5H) furanone.
As a preferred embodiment, the gas-tight resist is tert-butyl alcohol vinyl pyrrolidone.
Methanol is the very strong substance of polarity, can completely be dissolved each other with water.For unleaded gas, the suction of methanol gasoline It is aqueous to significantly increase.Moisture should not be underestimated to the intermiscibility destruction of methanol and gasoline.To enable methanol gasoline to dissolve each other and can Storage-stable and use need to find out the maximum of cosolvent at different temperatures, in the case of different gasoline and different methanol ratios Water repelling property.In fact, it is the relative stability for evaluating methanol gasoline in storage to meet water resisting phase separation performance.
Methanol and gasoline cannot be mutually mixed under appropriate environment temperature with arbitrary proportion, generally be less than 20 in temperature Cosolvent will be added when mixing 10% or more methanol under conditions of DEG C, due to the corrosivity and swellability of methanol, for service life Longer vehicle, initial stage of burning methanol gasoline may there is a phenomenon where fuel filters to block, contain in methanol gasoline discharge There are carcinogen formaldehyde, the discharge capacity of engine formaldehyde higher.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only Illustrate and not restrictive.If raw materials used to be all commercially available without other explanations.
The present invention is described in detail referring to several examples.
Related experiment:Engine performance test, experimental rig:Jiangsu translocation electromechanics Science and Technology Co., Ltd. starts Machine tests system(This research is using Toyota's 8A-FE engines, in-line 4 cylinders, 4 stroke of water-cooled, per 4 gas of cylinder Door cross-flow type, Dual Over Head Camshaft, fuel supply use closed loop multiple spot electronic fuel injection), current vortex hydraulic dynamometer, exhaust Analyzer.In experiment to engine speed, torque, cooling water temperature, oil temperature and pressure and other parameters carry out in real time monitoring and Control, to ensure the stabilization of operating condition of test.NOX, HC's, CO, formaldehyde in engine speed 3000r/min analysis exhaust contains Amount.The novel environment friendly automobile exhaust detergent of 20% present invention is added using common No. 93 gasoline as fuel.
Actual road test
Vehicle road test refers to same model vehicle in same road conditions, with the road performance test under equidistant, same weather condition, (The Novel ring of 20% present invention is added using common No. 93 gasoline using Toyota's 8A-FE engines for this research Automobile exhaust detergent is protected as fuel)Experiment during take annular running section, while ensure each sections of road speed, Transport condition and running time are identical, simulate outskirts of a town driving cycle.The fuel tank of test vehicle uses circumscribed.Examination every time When testing, when starting point and vehicle return to this, external experiment oil tank fuel weight is weighed respectively, then show that it is often followed Ring actual consumption amount.When using the fuel oil that additive is added, engine does not make any adjustment, directly upper road traveling, in order to ensure Stringent comparison condition, experiment by stages has recorded the driving condition of different sections of highway, when in the hope of with adding agent oil, running car with It is consistent using traveling state of vehicle when regular gasoline.When using regular gasoline and plus agent oil not An the same terms travelled it is same After Duan Lu, it is respectively G0, G1 to record the amount of gasoline that traveling is consumed twice, according to the two test datas according to following Formula calculate rate of economizing gasoline:
Embodiment 1
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 40 parts by weight, the methyl acetate of 20 parts by weight, 1.5 parts by weight Tetrahydrofuran, the sec-octyl alcohol of 2 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.05 parts by weight, 0.1 parts by weight first Base benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.3 parts by weight, the 2,6- di-t-butyl -4- cresols of 0.1 parts by weight, 0.1 The tert-butyl alcohol vinyl pyrrolidone of parts by weight forms.
Embodiment 2
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 50 parts by weight, the methyl acetates of 15 parts by weight, 2 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 2 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.05 parts by weight, 0.2 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 3
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 60 parts by weight, the methyl acetates of 25 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 4
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 10 parts by weight, the methyl acetates of 25 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 5
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 60 parts by weight, the methyl acetates of 5 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 6
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 60 parts by weight, the methyl acetate of 5 parts by weight, 0.2 parts by weight Tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight first Base benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, the 2,6- di-t-butyl -4- cresols of 0.2 parts by weight, 0.2 The tert-butyl alcohol vinyl pyrrolidone of parts by weight forms.
Embodiment 7
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 80 parts by weight, the methyl acetates of 5 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 8
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 80 parts by weight, the methyl acetates of 30 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Embodiment 9
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 80 parts by weight, the methyl acetates of 30 parts by weight, 5 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Comparative example 1
Tail gas detergent is by the methanol of 100 parts by weight, the methyl acetate of 25 parts by weight, the tetrahydrofuran of 3 parts by weight, 1 parts by weight Sec-octyl alcohol, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight methyl benzotriazazole, 0.1 weight The tert-butyl alcohol ethylene of amount two Polyoxyethylene fatty acid amides fatty acid esters of part, the 2,6- di-t-butyl -4- cresols of 0.2 parts by weight, 0.2 parts by weight Base pyrrolidones forms.
Comparative example 2
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 60 parts by weight, the tetrahydrofurans of 3 parts by weight, 1 parts by weight Sec-octyl alcohol, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, the methyl benzotriazazole of 0.1 parts by weight, 0.1 weight The tert-butyl alcohol vinyl of two Polyoxyethylene fatty acid amides fatty acid esters of part, the 2,6- di-t-butyl -4- cresols of 0.2 parts by weight, 0.2 parts by weight Pyrrolidones forms.
Comparative example 3
Tail gas detergent is by the methanol of 100 parts by weight, the ricinoleic acid of 60 parts by weight, the methyl acetates of 25 parts by weight, 1 parts by weight Sec-octyl alcohol, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, the methyl benzotriazazole of 0.1 parts by weight, 0.1 weight The tert-butyl alcohol vinyl of two Polyoxyethylene fatty acid amides fatty acid esters of part, the 2,6- di-t-butyl -4- cresols of 0.2 parts by weight, 0.2 parts by weight Pyrrolidones forms.
Comparative example 4
Tail gas detergent is by the methanol of 100 parts by weight, the palmitic acid of 60 parts by weight, the methyl acetates of 25 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
Comparative example 5
Tail gas detergent is by the methanol of 100 parts by weight, the stearic acid of 60 parts by weight, the methyl acetates of 25 parts by weight, 3 parts by weight The methyl of tetrahydrofuran, the sec-octyl alcohol of 1 parts by weight, the butyl acetate of 1 parts by weight, the isobutanol of 0.08 parts by weight, 0.1 parts by weight 2,6- di-t-butyl -4- cresols, 0.2 weight of benzotriazole, two Polyoxyethylene fatty acid amides fatty acid esters of 0.1 parts by weight, 0.2 parts by weight Measure the tert-butyl alcohol vinyl pyrrolidone composition of part.
As can be seen that the novel environment friendly automobile exhaust detergent of the present invention has good technique effect.It is using the present invention new Type ring protects automobile exhaust detergent, contains special ricinoleic acid so that motor vehicle emission major pollutants carbon monoxide, nytron Object, nitrogen oxides(NOX), formaldehyde emission substantially reduces, while having good oil-saving effect.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is every The equivalent changes and modifications done according to the content of present invention are encompassed by the scope of the claims of the present invention.

Claims (10)

1. novel environment friendly automobile exhaust detergent, which is characterized in that methanol, 10-80 of the tail gas detergent by 100 parts by weight The tetrahydrofuran of the ricinoleic acid of parts by weight, the methyl acetate of 5-30 parts by weight and 0.1-5 parts by weight forms.
2. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the tail gas detergent by The tetrahydrochysene of the methanol of 100 parts by weight, the ricinoleic acid of 40-70 parts by weight, the methyl acetate of 15-30 parts by weight and 1-3 parts by weight Furans forms.
3. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the tail gas detergent also wraps Include the cosolvent of 1-3 parts by weight, the fire retardant of 0.1-2 parts by weight, the corruption of the anti-knock agent, 0.01-1 parts by weight of 0.01-1 parts by weight The anti-vapour lock of corrosion inhibitor, the detergent-dispersant additive of 0.01-1 parts by weight, the antioxidant of 0.01-1 parts by weight, 0.01-1 parts by weight Agent.
4. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the cosolvent is selected from Zhong Xin One or more of alcohol, isobutanol, butyl glycol ether, ethylene glycol ethyl ether, acetic acid isoamyl fat, dimethyl ether.
5. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the combustion adjuvant is selected from acetic acid One or more of butyl ester, methyl ethyl ketone, tert-butyl alcohol nitrobenzene, nitrotoleune, isoamyl nitrate.
6. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the anti-knock agent is selected from isobutyl One or more of alcohol, methyl tertiary butyl ether(MTBE), isooctane.
7. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the metal corrosion inhibitor Selected from pyrazolone, methyl benzotriazazole, butyl stearate, 2, one kind or several in 4 diisopropyl phenols, isopropyl palmitate Kind.
8. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the detergent-dispersant additive is selected from One or more of two Polyoxyethylene fatty acid amides fatty acid esters, trien, isopropanol.
9. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the antioxidant is selected from 2, One or more of 6- di-t-butyl -4- cresols, Meng's oxygroup -2 (5H) furanone.
10. novel environment friendly automobile exhaust detergent according to claim 1, which is characterized in that the gas-tight resist is uncle Butanol vinyl pyrrolidone.
CN201810281319.4A 2018-04-02 2018-04-02 Novel environment friendly automobile exhaust detergent Pending CN108424795A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810281319.4A CN108424795A (en) 2018-04-02 2018-04-02 Novel environment friendly automobile exhaust detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810281319.4A CN108424795A (en) 2018-04-02 2018-04-02 Novel environment friendly automobile exhaust detergent

Publications (1)

Publication Number Publication Date
CN108424795A true CN108424795A (en) 2018-08-21

Family

ID=63159773

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810281319.4A Pending CN108424795A (en) 2018-04-02 2018-04-02 Novel environment friendly automobile exhaust detergent

Country Status (1)

Country Link
CN (1) CN108424795A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135851A (en) * 2018-10-08 2019-01-04 张文涛 A kind of additive for automobile exhaust detergent
CN109762610A (en) * 2019-02-21 2019-05-17 赵彤 A kind of eco-friendly car tail gas detergent and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102559297A (en) * 2012-02-07 2012-07-11 容启团 Composite gasoline and diesel oil with high energy-saving environmental protection used for vehicles
CN107011953A (en) * 2017-04-14 2017-08-04 北京天下通衢技术股份有限公司 Multi-function gasoline additives and preparation method thereof and the fuel combination containing the multi-function gasoline additives

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102559297A (en) * 2012-02-07 2012-07-11 容启团 Composite gasoline and diesel oil with high energy-saving environmental protection used for vehicles
CN107011953A (en) * 2017-04-14 2017-08-04 北京天下通衢技术股份有限公司 Multi-function gasoline additives and preparation method thereof and the fuel combination containing the multi-function gasoline additives

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135851A (en) * 2018-10-08 2019-01-04 张文涛 A kind of additive for automobile exhaust detergent
CN109762610A (en) * 2019-02-21 2019-05-17 赵彤 A kind of eco-friendly car tail gas detergent and preparation method thereof

Similar Documents

Publication Publication Date Title
ES2300103T3 (en) FUEL COMPOUND WITHOUT LEAD.
CN109207212A (en) Environment-friendly combustion-supporting diesel additive and preparation method thereof
CN109207214A (en) A kind of environment-friendly gasoline additive and preparation method thereof
CN105419890A (en) Fuel oil additive and preparation method therefor
US6579330B2 (en) Alternative fuel to gasoline
Prabu et al. Inhibition of NO emission by adding antioxidant mixture in Jatropha biodiesel on the performance and emission characteristics of a CI engine
CN104745252B (en) The high activity composite modified additive of automotive methanol gasoline and preparation technology thereof
CN108424795A (en) Novel environment friendly automobile exhaust detergent
CN105733710A (en) Efficient vehicle-protecting and environment-friendly fuel additive
Al‐Farayedhi Effects of octane number on exhaust emissions of a spark ignition engine
CN105400554B (en) Methanol gasoline efficient composite additive and preparation method thereof
CN106701219A (en) Navigation alcohol fuel combustion-supporting additive for automobile and manufacturing method thereof
EP1505143A1 (en) Fuel for internal combustion engine
Senthil et al. Effect of fuel additives on performance improvement and emission control in diesel engines
CN109161412A (en) A kind of vehicle environment protection alcohol-based fuel
TWI824230B (en) Methanol additives, preparation method thereof, and modified methanol and use
CN102634386A (en) Chemically combined diesel oil
JP5283950B2 (en) Low temperature, premixed compression ignition engine fuel oil composition
CN105694997A (en) Efficient engine-protective environment-friendly fuel gas
CN106995730B (en) Mixed diesel fuel
JP2004285346A (en) Low-pollution fuel composition
TWI808502B (en) Carbon neutral gasoline and diesel enhanced formula
CN109022065A (en) A kind of gasoline compounding agent
KR102812708B1 (en) Fuel additives composition and use of the same
WO2014046982A1 (en) Fuels and fuel additives comprising ester derivatives of 5-methyl-2-furoic acid

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180821

RJ01 Rejection of invention patent application after publication