CN108410565A - A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application - Google Patents
A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application Download PDFInfo
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- CN108410565A CN108410565A CN201810134446.1A CN201810134446A CN108410565A CN 108410565 A CN108410565 A CN 108410565A CN 201810134446 A CN201810134446 A CN 201810134446A CN 108410565 A CN108410565 A CN 108410565A
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- China
- Prior art keywords
- agent
- metalworking fluid
- hydramine
- antibacterial
- antibacterial complexing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000012530 fluid Substances 0.000 title claims abstract description 32
- 238000005555 metalworking Methods 0.000 title claims abstract description 32
- 239000008139 complexing agent Substances 0.000 title claims abstract description 31
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000013556 antirust agent Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 claims abstract description 13
- 239000002173 cutting fluid Substances 0.000 claims description 9
- 239000012153 distilled water Substances 0.000 claims description 9
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 24
- 230000000845 anti-microbial effect Effects 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- 238000005119 centrifugation Methods 0.000 abstract description 3
- 238000005520 cutting process Methods 0.000 description 11
- 241000894006 Bacteria Species 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 230000007815 allergy Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of antibacterial complexing agents applied to metalworking fluid comprising following components in percentage by weight：Auxiliary agent 18 22%；Hydramine object 22 28%；Tricarboxylic acid antirust agent 26 32%；Antirust agent 12 18%；Water 8 12%.The present invention also provides a kind of preparation method and application of the antibacterial complexing agent applied to metalworking fluid.Finished product stoste of the present invention stands not stratified in colourless, uniform and smooth and centrifugation；Meanwhile the present invention has dispersibility in extraordinary water, is mixed with a small amount of hydramine and aqueous solution, quickly forms stable stoste, can form stable equilibrium system with the other components of releasing agent, be highly susceptible to allocating.The present invention has the following advantages compared to the prior art：1) alkaline reserve amount is big, is changed over time using liquid PH small, and can efficiently solve PH reduces smelly problem；2) it is improved using liquid system anti-microbial property；3) product is mild, does not stimulate.
Description
Technical field
The present invention relates to a kind of antibacterial complexing agents, in particular to a kind of applied to the antibacterial compound of metalworking fluid
Agent, preparation method and application.
Background technology
Metal cutting process refers to being cut off by forming chip metal layer extra on workpiece by cutter by machining
And obtain the process of all satisfactory part of geometry, dimensional accuracy and surface roughness.However, in this course,
Always there is the contradictions that Tool in Cutting workpiece and workpiece material resist cutting, to generate a series of phenomenons, as cutting deformation,
The abrasion of cutting heat and cutter related with cutter and cutter life, volume bits and chip breaking etc..Reasonable employment cutting fluid is then solution
The certainly main path of problem.So that cutting temperature and cutting force is reduced to greatest extent, improves cutter life and workpiece ruler
Very little precision and surface quality, cutting fluid will have the performances such as cooling, lubrication, cleaning and anticorrosion.
Metal working fluid is not only related with the stability of formula system using the stability of liquid, but also be unable to do without live people
The maintenance of member.Although metal working fluid is universal, also there are many problems in mechanical processing process.It in annual summer, cuts
Cut a series of problems, such as liquid is susceptible to PH reductions, bacteria breed, smelly or even employee's allergy using liquid；Annual winter, meeting
There is the problems such as cutting fluid foam overflow.Therefore, too high using liquid PH, operating personnel are easy to happen allergy；PH is too low, uses liquid
Hold easy bacteria-developing.Currently, when PH reduction phenomenons occurs in onsite application liquid, needs to add PH regulators often, improve using liquid
PH, but in PH regulators include fungicide, it is harmful.
Invention content
In consideration of it, can solve the problems, such as that PH is reduced the present invention provides a kind of and smelly be applied to the antibacterial of metalworking fluid
Complexing agent, preparation method and application.
Thus, on the one hand, the present invention provides a kind of antibacterial complexing agents applied to metalworking fluid comprising following weight
Measure the component of percentage：
Further, a kind of above-mentioned antibacterial complexing agent applied to metalworking fluid includes the group of following weight percent
Point：Auxiliary agent 19-21%；Hydramine object 24-26%；Tricarboxylic acid antirust agent 28-30%；Antirust agent 14-17%；Water 9-11%.
Further, a kind of above-mentioned antibacterial complexing agent applied to metalworking fluid includes the group of following weight percent
Point：Auxiliary agent 20%；Hydramine object 25%；Tricarboxylic acid antirust agent 29%；Antirust agent 16%；Water 10%.
Further, above-mentioned auxiliary agent is AMP-95 auxiliary agents.
Further, above-mentioned hydramine object is Genamin CH 020 (J) hydramine object.
Further, above-mentioned antirust agent is DB-1 antirust agent.
Further, above-mentioned water is distilled water.
On the other hand, the present invention provides a kind of preparation method of the antibacterial complexing agent applied to metalworking fluid, packets
Include following steps：
1) according to above-mentioned proportioning, preparation prepares material；
2) in beaker, water, auxiliary agent and hydramine object is added, is evenly stirred until transparent；
3) it continuously adds tricarboxylic acid antirust agent and antirust agent stirs at least 1 hour, until homogeneous transparent, obtains finished product.
On the other hand, the present invention provides a kind of application of the antibacterial complexing agent applied to metalworking fluid, feature exists
In addition such as a kind of above-mentioned antibacterial complexing agent applied to metalworking fluid, antibacterial complexing agent add in metalworking fluid
Dosage is the 10-20% of total weight.
Further, above-mentioned metalworking fluid is the semi-synthetic cutting fluid of emulsifying.
Finished product stoste of the present invention stands not stratified in colourless, uniform and smooth and centrifugation；Meanwhile the present invention is with very good
Water in dispersibility, mix with a small amount of hydramine and aqueous solution, quickly formed stabilization stoste, can be formed with the other components of releasing agent
Stable equilibrium system is highly susceptible to allocating.
To sum up, provided by the invention a kind of to be compared applied to the antibacterial complexing agent of metalworking fluid, preparation method and application
It is had the following advantages in the prior art：
1) alkaline reserve amount is big, is changed over time using liquid PH small, can efficiently solve PH and reduces and smelly ask
Topic；
2) it is improved using liquid system anti-microbial property；
3) product is mild, does not stimulate.
Specific implementation mode
The exemplary embodiment of the disclosure is described in more detail below.Although showing the exemplary implementation of the disclosure
Example, it being understood, however, that may be realized in various forms the disclosure without should be limited by embodiments set forth here.On the contrary,
These embodiments are provided to facilitate a more thoroughly understanding of the present invention, and can completely be communicated to the scope of the present disclosure
Those skilled in the art.
Embodiment one：
Add AMP-95 auxiliary agents 20%, (J) hydramine of Genamin CH 020 object 25%, tricarboxylic acid antirust agent 29%, DB-
1 antirust agent 16% and distilled water 10%.The proportioning of following weight specifically may be used：MP-95 auxiliary agents 20g, Genamin CH
020 (J) hydramine object 25g, tricarboxylic acid antirust agent 29g, DB-1 antirust agent 16g and distilled water 10g.
Preparation process is as follows：In beaker, 10g distilled water, 20g AMP-95 and 25g Genamin CH 020 is added
(J), it is evenly stirred until transparent.29g tricarboxylic acids antirust agent is added and 16g DB-1 are stirred 1 hour, until homogeneous transparent,
Obtain complexing agent A.
In application, be mainly used in the semi-synthetic cutting fluid of emulsifying, additive amount is 10-20% best results, have compared with
Big alkaline reserve amount, excellent anti-microbial property and biological stability, good emulsifiability etc..
Wherein, Genamin CH 020 (J) special hydramine participates in the allotment of water-based metal working fluid, easily as basic component
Emulsification, anti-microbial property is good, and for it is fully synthetic when, the precipitation of metallic cobalt can be significantly reduced, be commercially available；Ternary carboxylic
Sour antirust agent has good rust-preventing characteristic, extreme low bubble, good hard water stability, in usually used concentration range
Solution to skin and nonirritant mucous membrane the advantages that.It is mainly used for semi-synthetic cutting fluid, fully synthetic lapping liquid, aqueous quenching liquid
And waterborne cleaning agent, automotive antifreeze, the use of corrosion of metal suppressant additive is done in the aqueous products such as aqueous rust preventive, it can be in market
On buy；DB-1 antirust agent borates, can be miscible with water arbitrary proportion, and has good biological stability, has certain
Antibiotic property is commercially available.
Embodiment two：
Other are identical as embodiment one, the difference is that the difference of proportioning：Add AMP-95 auxiliary agents 18%, Genamin
(J) hydramine of CH 020 object 22%, tricarboxylic acid antirust agent 32%, DB-1 antirust agent 18% and distilled water 10%.
Embodiment three：
Other are identical as embodiment one, the difference is that the difference of proportioning：Add AMP-95 auxiliary agents 22%, Genamin
(J) hydramine of CH 020 object 28%, tricarboxylic acid antirust agent 26%, DB-1 antirust agent 12% and distilled water 12%.
Example IV：
Other are identical as embodiment one, the difference is that the difference of proportioning：Add AMP-95 auxiliary agents 21%, Genamin
(J) hydramine of CH 020 object 26%, tricarboxylic acid antirust agent 30%, DB-1 antirust agent 14% and distilled water 9%.
Embodiment five：
Other are identical as embodiment one, the difference is that the difference of proportioning：Add AMP-95 auxiliary agents 19%, Genamin
(J) hydramine of CH 020 object 24%, tricarboxylic acid antirust agent 28%, DB-1 antirust agent 17% and distilled water 12%.
The present embodiment 1-5 and the experimental data comparison of comparative example (prior art) are as shown in the table：
Take a common aqueous cutting fluid (prior art)；Sample A adds 10% complexing agent A in aqueous cutting fluid
(the antibacterial complexing agent described in embodiment 1-5), obtains sample A.Product processing is carried out with conventional cutting liquid and sample A, in Liang Tai
Pack alloy is processed on the same CNC boards, liquid bath is 200L, and the experimental data are shown in the following table：
Table one (prior art)：
| Detect the date | Conventional cutting liquid (%) | PH value | Conductance (μ s/cm) | Number of bacteria (cfu/mL) |
| 2017.05.10 | 8 | 8.9 | 850 | ＜ 103 |
| 2017.05.20 | 8.1 | 8.91 | 1110 | ＜ 103 |
| 2017.05.30 | 7.9 | 8.88 | 1450 | ＜ 103 |
| 2017.06.10 | 8.1 | 8.70 | 1750 | ＜ 104 |
| 2017.06.20 | 8 | 8.60 | 2230 | ＜ 104 |
| 2017.06.30 | 7.8 | 8.40 | 2700 | ＜ 104 |
| 2017.07.10 | 8.1 | 8.0 | 3000 | 105 |
| 2017.07.20 | 8 | 8.01 | 3150 | 106 |
| 2017.07.30 | 8.1 | 7.50 | 3400 | 107 |
| 2017.08.10 | 7.9 | 7.42 | 3561 | ＞ 107 |
Table two (present invention)：
| Detect the date | Sample A (%) | PH | Conductance (μ s/cm) | Number of bacteria (cfu/mL) |
| 2017.05.10 | 8 | 8.9 | 850 | ＜ 103 |
| 2017.05.20 | 8.1 | 8.91 | 1110 | ＜ 103 |
| 2017.05.30 | 7.9 | 8.88 | 1450 | ＜ 103 |
| 2017.06.10 | 8.1 | 8.96 | 1750 | ＜ 103 |
| 2017.06.20 | 8 | 9 | 1750 | ＜ 103 |
| 2017.06.30 | 7.8 | 8.89 | 1450 | ＜ 103 |
| 2017.07.10 | 8.1 | 8.9 | 1580 | ＜ 103 |
| 2017.07.20 | 8 | 8.9 | 1750 | ＜ 103 |
| 2017.07.30 | 8.1 | 8.88 | 1850 | ＜ 103 |
| 2017.08.10 | 7.9 | 8.88 | 1880 | ＜ 103 |
| 2017.08.20 | 8.1 | 9.0 | 1780 | ＜ 103 |
| 2017.08.30 | 7.9 | 8.89 | 16800 | ＜ 103 |
| 2017.09.10 | 7.9 | 8.92 | 1790 | ＜ 103 |
| 2017.09.20 | 8.0 | 8.86 | 1830 | ＜ 103 |
| 2017.09.30 | 8.0 | 8.88 | 1850 | ＜ 103 |
Comparing result：The CNC processing grooves of conventional cutting liquid and sample A, 4% that 15-30L is all added per shift (12h) are new
Liquid ensures liquid bath in 180L or so.Conventional cutting liquid is after 2017.08.10, and PH is reduced, and smelly using liquid, number of bacteria is tight
Exceed controlled range again, sample A then uses normal.The result shows that after addition complexing agent A, carried using liquid system anti-microbial property
It is high.
This finished product stoste stands not stratified in colourless, uniform and smooth and centrifugation；Meanwhile the present invention has extraordinary water
Middle dispersibility is mixed with a small amount of hydramine and aqueous solution, quickly forms stable stoste, stabilization can be formed with the other components of releasing agent
Equilibrium system, be highly susceptible to allocating.
Thus, a kind of antibacterial complexing agent applied to metalworking fluid provided in this embodiment, preparation method and application phase
It is had the following advantages compared with the prior art：
1) alkaline reserve amount is big, is changed over time using liquid PH small, can efficiently solve PH and reduces and smelly ask
Topic；
2) it is improved using liquid system anti-microbial property；
3) product is mild, does not stimulate.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
God and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to include these modifications and variations.
Claims (10)
1. a kind of antibacterial complexing agent applied to metalworking fluid, which is characterized in that including following components in percentage by weight：
2. a kind of antibacterial complexing agent applied to metalworking fluid according to claim 1, which is characterized in that including following
The component of weight percent：Auxiliary agent 19-21%；Hydramine object 24-26%；Tricarboxylic acid antirust agent 28-30%；Antirust agent 14-
17%；Water 9-11%.
3. a kind of antibacterial complexing agent applied to metalworking fluid according to claim 1, which is characterized in that including following
The component of weight percent：Auxiliary agent 20%；Hydramine object 25%；Tricarboxylic acid antirust agent 29%；Antirust agent 16%；Water 10%.
4. according to a kind of any antibacterial complexing agents applied to metalworking fluid of claim 1-3, which is characterized in that institute
It is AMP-95 auxiliary agents to state auxiliary agent.
5. according to a kind of any antibacterial complexing agents applied to metalworking fluid of claim 1-3, which is characterized in that institute
It is Genamin CH 020 (J) hydramine object to state hydramine object.
6. according to a kind of any antibacterial complexing agents applied to metalworking fluid of claim 1-3, which is characterized in that institute
It is DB-1 antirust agent to state antirust agent.
7. according to a kind of any antibacterial complexing agents applied to metalworking fluid of claim 1-3, which is characterized in that institute
It is distilled water to state water.
8. a kind of preparation method of antibacterial complexing agent applied to metalworking fluid, which is characterized in that include the following steps：
1) according to any proportionings of claim 1-7, preparation prepares material；
2) in beaker, water, auxiliary agent and hydramine object is added, is evenly stirred until transparent；
3) it continuously adds tricarboxylic acid antirust agent and antirust agent stirs at least 1 hour, until homogeneous transparent, obtains finished product.
9. a kind of application of antibacterial complexing agent applied to metalworking fluid, which is characterized in that added such as in metalworking fluid
A kind of any antibacterial complexing agents applied to metalworking fluid of claim 1-7, the additive amount of the antibacterial complexing agent
For the 10-20% of total weight.
10. a kind of application of antibacterial complexing agent applied to metalworking fluid according to claim 9, which is characterized in that
The metalworking fluid is the semi-synthetic cutting fluid of emulsifying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810134446.1A CN108410565A (en) | 2018-02-09 | 2018-02-09 | A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810134446.1A CN108410565A (en) | 2018-02-09 | 2018-02-09 | A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application |
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|---|---|
| CN108410565A true CN108410565A (en) | 2018-08-17 |
Family
ID=63127069
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|---|---|---|---|
| CN201810134446.1A Pending CN108410565A (en) | 2018-02-09 | 2018-02-09 | A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application |
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| CN105733791A (en) * | 2016-03-28 | 2016-07-06 | 启东尤希路化学工业有限公司 | Water-based cutting fluid for molybdenum alloy processing |
| CN106318586A (en) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | Multifunctional semi-synthetic metal processing liquid and preparation method thereof |
-
2018
- 2018-02-09 CN CN201810134446.1A patent/CN108410565A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011256376A (en) * | 2010-05-11 | 2011-12-22 | Kyodo Yushi Co Ltd | Water-soluble working oil agent composition for fixed-abrasive wire saw |
| JP2013107937A (en) * | 2011-11-17 | 2013-06-06 | Idemitsu Kosan Co Ltd | Water-soluble metalworking oil, metalworking fluid, and metalworking method |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN104479833A (en) * | 2014-12-17 | 2015-04-01 | 江苏鑫露新材料股份有限公司 | High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof |
| CN105176656A (en) * | 2015-09-29 | 2015-12-23 | 广州机械科学研究院有限公司 | Environment-friendly semisynthetic cutting fluid for titanium alloys as well as preparation method and application of cutting fluid |
| CN105733791A (en) * | 2016-03-28 | 2016-07-06 | 启东尤希路化学工业有限公司 | Water-based cutting fluid for molybdenum alloy processing |
| CN106318586A (en) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | Multifunctional semi-synthetic metal processing liquid and preparation method thereof |
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