CN109652180A - A kind of high-performance magnesium alloy cutting fluid and preparation method thereof - Google Patents
A kind of high-performance magnesium alloy cutting fluid and preparation method thereof Download PDFInfo
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- CN109652180A CN109652180A CN201910027039.5A CN201910027039A CN109652180A CN 109652180 A CN109652180 A CN 109652180A CN 201910027039 A CN201910027039 A CN 201910027039A CN 109652180 A CN109652180 A CN 109652180A
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- magnesium alloy
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- alloy cutting
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 31
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 239000010949 copper Substances 0.000 claims abstract description 14
- 239000004411 aluminium Substances 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 13
- 239000000417 fungicide Substances 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 8
- 239000013556 antirust agent Substances 0.000 claims abstract description 7
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000002738 chelating agent Substances 0.000 claims abstract description 7
- 239000003085 diluting agent Substances 0.000 claims abstract description 7
- 239000008233 hard water Substances 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 239000000080 wetting agent Substances 0.000 claims abstract description 7
- 238000013268 sustained release Methods 0.000 claims abstract description 4
- 239000012730 sustained-release form Substances 0.000 claims abstract description 4
- 230000007797 corrosion Effects 0.000 claims description 22
- 238000005260 corrosion Methods 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 6
- 239000012141 concentrate Substances 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000005555 metalworking Methods 0.000 claims description 6
- 229910001051 Magnalium Inorganic materials 0.000 claims description 4
- -1 alcohol ether carboxylate Chemical class 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000012224 working solution Substances 0.000 claims description 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 3
- AFJJYBRDMZWNNK-UHFFFAOYSA-N C(N)(OCCCC)=O.C#CC.[I] Chemical compound C(N)(OCCCC)=O.C#CC.[I] AFJJYBRDMZWNNK-UHFFFAOYSA-N 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- 239000010696 ester oil Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 125000002270 phosphoric acid ester group Chemical group 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- 235000019441 ethanol Nutrition 0.000 claims 3
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical group CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims 1
- 230000005764 inhibitory process Effects 0.000 claims 1
- 238000010079 rubber tapping Methods 0.000 abstract description 5
- 238000005461 lubrication Methods 0.000 abstract description 4
- 238000002845 discoloration Methods 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract description 2
- 229940125904 compound 1 Drugs 0.000 abstract 1
- 229940125782 compound 2 Drugs 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/41—Chlorine free or low chlorine content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of high-performance magnesium alloy cutting fluids, component including following mass fraction: 3~6 parts of water-based antirust agent, 1~3 part of chelating agent, 4~6 parts of couplant, 8~12 parts of diluent, 2~4 parts of wetting agent, 1~3 part of extraordinary amine, 6~8 parts of emulsifier, hard water resistance dose 1~3 part, compound 2~3 parts of the packet of sustained release agent, compound 1~2 part of the packet of fungicide, 50~60 parts of base oil, 3~5 parts of lubricant, 1~3 part of extreme pressure agent, 1~3 part of stabilizer, 1~3 part of surfactant, compound 0.1~2 part of the packet of defoaming agent.A kind of high-performance magnesium alloy cutting fluid provided by the invention has good boundary and extreme boundary lubrication, makes it in tapping processing, can effectively prevent screw tap fracture；And the discoloration to aluminium, copper and part magnesium alloy, there is certain inhibiting effect.
Description
Technical field
The present invention relates to a kind of machining of metals liquid technical field, especially a kind of high-performance magnesium alloy cutting fluid and
Preparation method.
Background technique
Magnesium alloy all needs in the processing technologys such as turning, drilling, grinding, aperture, fraising, tapping and slight broaching
To realize the functions such as cooling, cleaning, lubrication, antirust, antibacterial using cutting fluid, cutting fluid generally use single machine it is cooling or in
The method of centre cooling system while cooling more cutting apparatus is carried out using it is necessary to have good low bubbles, while also being needed
With certain hard water resistance property.Furthermore in order to meet the requirement of environment protection health, usually also require in cutting fluid without nitrite natrium,
Without chlorine, not sulfur-bearing, it is to be ensured that it is cutting fluid odorlessness, nontoxic, to plant personnel skin not allergy.
There are certain deficiencies for magnesium alloy cutting fluid in the prior art, boundary and extreme boundary lubrication, thus
In tapping processing, it is easy to appear the problem of screw tap is broken；In addition aluminium, copper and part magnesium alloy are processed in conventional Cutting Process
When, workpiece can have certain discoloration problem.
Summary of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of high-performance magnesium alloy cutting fluids, have good
Boundary and extreme boundary lubrication, make its tapping processing in, can effectively prevent screw tap fracture；And aluminium, copper and part magnesium are closed
The discoloration of gold, there is certain inhibiting effect.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of high-performance magnesium alloy cutting fluid, the component including following mass fraction:
As above-mentioned technical proposal specific preferred, the water-based antirust agent is one in boric acid, neodecanoic acid and ternary acid
Kind or a variety of mixing, the ternary acid are the ternary polycarboxylic acids that Hangzhou Lv Pu chemical science and technology limited liability company provides
TAT730；The chelating agent is ETDA-2Na；The couplant is the mixed of one or both of diethanol amine and triethanolamine
It closes；The diluent is deionized water；The wetting agent is glycerol.
As above-mentioned technical proposal specific preferred, the special type amine is that the AMP-95 that Dow Chemical Company provides is more
Function additive, main component are 2-amino-2-methyl-1-propanol, the water containing 5% mass ratio.
As above-mentioned technical proposal specific preferred, the emulsifier is the low bubble that Shang Qing Industrial Co., Ltd. in Shanghai provides
The mixing of one or both of efficient 2815 amide emulsifier of emulsifier Genifol SA6062 and Genimus；It is described anti-hard
Aqua is alcohol ether carboxylate；The base oil is naphthenic mineral oil.
As above-mentioned technical proposal specific preferred, the lubricant is oleic acid；The extreme pressure agent is phosphoric acid ester oil grease.
As above-mentioned technical proposal specific preferred, the compound packet of corrosion inhibiter is that magnesium corrosion inhibiter, aluminium corrosion inhibiter and copper are slow
Erosion agent mixes, and the magnesium corrosion inhibiter is the magnalium corrosion inhibiter OMD that Nanjing Shang Qin new material Science and Technology Ltd. provides, institute
Stating aluminium corrosion inhibiter is the aluminium corrosion inhibiter NEUF815 that safe biotechnology (Hefei) Co. provides, and the copper inhibitor is water
Dissolubility copper inhibitor FUNTAG CU250.
As above-mentioned technical proposal specific preferred, the compound packet of fungicide is metal working fluid fungicide BK, metal
Working fluid fungicide MBM and iodine propyne n-butyl carbamate IPBC antibacterial agent are mixed according to 2/1/2 mass ratio.
As above-mentioned technical proposal specific preferred, the stabilizer is propylene glycol phenylate；The surfactant is department
Disk 80；The compound packet of defoaming agent is Quick-type defoaming agent and long-life type defoaming agent according to the 1/1 mass ratio system of stirring evenly
At the Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, and the long-life type defoaming agent is that Germany is bright
The product type that Ling company provides is the defoaming agent of FoamBan MS-575.
The preparation method of above-mentioned high-performance magnesium alloy cutting fluid, comprising the following steps:
S1, water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, be put into agitated kettle stirring half an hour；
S2, wetting agent and extraordinary amine are weighed according to the ratio, be added in agitated kettle, stir evenly；
S3, emulsifier and hard water resistance dose are weighed according to the ratio, be added in agitated kettle, stir evenly；
S4, the compound packet of sustained release agent and the compound packet of fungicide are weighed according to the ratio, be added in agitated kettle, stir evenly；
S5, base oil, lubricant, extreme pressure agent and stabilizer are weighed according to the ratio, be added in agitated kettle, stir evenly；
S6, surfactant being weighed according to the ratio, being added in agitated kettle, stirred evenly, solution will gradually become yellow at this time
Color transparency liquid；
S7, the compound packet of defoaming agent is weighed according to the ratio, be added slowly in agitated kettle, stir evenly finished product concentrate.
Further, further comprising the steps of:
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
A kind of high-performance magnesium alloy cutting fluid provided by the present invention has with below compared with prior art
Beneficial effect:
1, properties can meet or exceed chinese national standard GB/T7453-2013 and China Petroleum Ministry of Chemical Industry
Related index in ministerial standard SY1374-77, can completely outside surrogate famous brand name similar product；
2, there is preferably lubricity, can be applied in the plurality of devices such as CNC, lathe for machining, milling machine, sawing machine, can cope with
Tapping processing, and effective protection screw tap is not broken, can also effectively reduce tool wear, improves cutting-tool's used life；
3, there is good antirust cleaning function, effective refractive power 70 ± 1%, workpieces processing surface brightness is high, and has
Preferably cleaning effect；
Though 4, cutting fluid provided by the invention is high containing oil product, its working solution is in translucent and more clear state,
It is more convenient for observing operating condition appearance of the workpiece in processing；
5, by using a variety of special magnalium copper functional slow-release agent, it is suitable for the non-ferrous metals material workpiece such as magnesium, aluminium, copper
Processing, the especially processing of aluminum bronze part and part magnesium alloy member；
6, the compound packet of functional form formed by using various sterilization agent can effectively inhibit fungi, mould etc. to generate, constant
It is matter, not smelly, can single machine use, can also centralizedly supply use；
7, the achievable long-life uses and is recycled, and can be changed without new liquid for a long time, need to only carry out monitoring dimension family, in time
New liquid is supplemented, possessing certain concentration can be used for a long time；
8, there is preferable board rustless property, do not destroy paint, it is compatible with usually used lathe sealing element；
9, formula be free of, chlorine, phenols and nitrite, also not poisonous and harmful substances such as sulfur-bearing, to no damage to human body, to ring
Border belongs to environmentally friendly machine without influence.
Specific embodiment
The present invention is further described combined with specific embodiments below.
Specific embodiment 1
A kind of high-performance magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
Specifically, the water-based antirust agent is one of boric acid, neodecanoic acid and ternary acid or a variety of mixing, described three
First acid is the ternary polycarboxylic acids TAT730 that Hangzhou Lv Pu chemical science and technology limited liability company provides；The chelating agent is ETDA-
2Na；The couplant is the mixing of one or both of diethanol amine and triethanolamine；The diluent is deionized water；
The wetting agent is glycerol.The special type amine is the AMP-95 multifunctional assistant that Dow Chemical Company provides, main component
For 2-amino-2-methyl-1-propanol, the water containing 5% mass ratio.The emulsifier is what Shang Qing Industrial Co., Ltd. in Shanghai provided
The mixing of one or both of the low efficient 2815 amide emulsifier of emulsifier Genifol SA6062 and Genimus of bubble；It is described
Hard water resistance dose is alcohol ether carboxylate；The base oil is naphthenic mineral oil.The lubricant is oleic acid；The extreme pressure agent is phosphoric acid
Ester oil grease.The compound packet of corrosion inhibiter mixes for magnesium corrosion inhibiter, aluminium corrosion inhibiter and copper inhibitor, and the magnesium corrosion inhibiter
For the magnalium corrosion inhibiter OMD that Nanjing Shang Qin new material Science and Technology Ltd. provides, the aluminium corrosion inhibiter is that promise Thailand biotechnology (closes
Fertilizer) Co., Ltd provide aluminium corrosion inhibiter NEUF815, the copper inhibitor be water soluble copper corrosion inhibitor FUNTAG CU250.Institute
Stating the compound packet of fungicide is metal working fluid fungicide BK, metal working fluid fungicide MBM and iodine propyne n-butyl carbamate
IPBC antibacterial agent is mixed according to 2/1/2 mass ratio.The stabilizer is propylene glycol phenylate；The surfactant is department
Disk 80；The compound packet of defoaming agent is Quick-type defoaming agent and long-life type defoaming agent according to the 1/1 mass ratio system of stirring evenly
At the Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, and the long-life type defoaming agent is that Germany is bright
The product type that Ling company provides is the defoaming agent of Foam Ban MS-575.
A kind of preparation method of high-performance magnesium alloy cutting fluid provided by the present embodiment, comprising the following steps:
S1, water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, be put into agitated kettle stirring half an hour.
S2, wetting agent and extraordinary amine are weighed according to the ratio, be added in agitated kettle, stir evenly.
S3, emulsifier and hard water resistance dose are weighed according to the ratio, be added in agitated kettle, stir evenly.
S4, the compound packet of sustained release agent and the compound packet of fungicide are weighed according to the ratio, be added in agitated kettle, stir evenly.
S5, base oil, lubricant, extreme pressure agent and stabilizer are weighed according to the ratio, be added in agitated kettle, stir evenly.
S6, surfactant being weighed according to the ratio, being added in agitated kettle, stirred evenly, solution will gradually become yellow at this time
Color transparency liquid.
S7, the compound packet of defoaming agent is weighed according to the ratio, be added slowly in agitated kettle, stir evenly finished product concentrate.
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
Specific embodiment 2
A kind of high-performance magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
The specific raw material type of above-mentioned each component is identical as specific embodiment 1.
A kind of preparation method of high-performance magnesium alloy cutting fluid, identical as specific embodiment 1 provided by the present embodiment.
Specific embodiment 3
A kind of high-performance magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
The specific raw material type of above-mentioned each component is identical as specific embodiment 1.
A kind of preparation method of high-performance magnesium alloy cutting fluid, identical as specific embodiment 1 provided by the present embodiment.
Better embodiment of the invention is specifically described above, certainly, the present invention can also using with it is upper
The different form of embodiment is stated, those skilled in the art are made equivalent on the premise of without prejudice to spirit of the invention
Transformation or corresponding change, all should belong in protection scope of the present invention.
Claims (10)
1. a kind of high-performance magnesium alloy cutting fluid, which is characterized in that the component including following mass fraction:
2. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the water-based antirust agent is
One of boric acid, neodecanoic acid and ternary acid or a variety of mixing, the ternary acid are that the green general chemical science and technology share in Hangzhou is limited
The ternary polycarboxylic acids TAT730 that company provides；The chelating agent is ETDA-2Na；The couplant is diethanol amine and three ethyl alcohol
The mixing of one or both of amine；The diluent is deionized water；The wetting agent is glycerol.
3. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the special type amine is the U.S.
The AMP-95 multifunctional assistant that Dow Chemical provides, main component is 2-amino-2-methyl-1-propanol, contains 5% mass ratio
Water.
4. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the emulsifier is Shanghai
In the efficient 2815 amide emulsifier of emulsifier Genifol SA6062 and Genimus of low bubble that Shang Qing Industrial Co., Ltd. provides
One or two kinds of mixing；Described hard water resistance dose is alcohol ether carboxylate；The base oil is naphthenic mineral oil.
5. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the lubricant is oil
Acid；The extreme pressure agent is phosphoric acid ester oil grease.
6. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the compound packet of corrosion inhibiter
It is mixed for magnesium corrosion inhibiter, aluminium corrosion inhibiter and copper inhibitor, and the magnesium corrosion inhibiter is that the still diligent new material science and technology in Nanjing is limited
The magnalium corrosion inhibiter OMD that company provides, the aluminium corrosion inhibiter are the aluminium inhibition that safe biotechnology (Hefei) Co. provides
Agent NEUF815, the copper inhibitor are water soluble copper corrosion inhibitor FUNTAG CU250.
7. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the compound packet of fungicide
For metal working fluid fungicide BK, metal working fluid fungicide MBM and iodine propyne n-butyl carbamate IPBC antibacterial agent according to
2/1/2 mass ratio mixes.
8. a kind of high-performance magnesium alloy cutting fluid according to claim 1, it is characterised in that: the stabilizer is the third two
Alcohol phenylate；The surfactant is sorbester p17；The compound packet of defoaming agent is Quick-type defoaming agent and long-life type defoaming agent
It stirs evenly and is made according to 1/1 mass ratio, the Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, institute
Stating long-life type defoaming agent is the defoaming agent that the product type that German Ming Ling company provides is Foam Ban MS-575.
9. according to claim 1 in -8 a kind of any high-performance magnesium alloy cutting fluid preparation method, feature exists
In, comprising the following steps:
S1, water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, be put into agitated kettle stirring half an hour；
S2, wetting agent and extraordinary amine are weighed according to the ratio, be added in agitated kettle, stir evenly；
S3, emulsifier and hard water resistance dose are weighed according to the ratio, be added in agitated kettle, stir evenly；
S4, the compound packet of sustained release agent and the compound packet of fungicide are weighed according to the ratio, be added in agitated kettle, stir evenly；
S5, base oil, lubricant, extreme pressure agent and stabilizer are weighed according to the ratio, be added in agitated kettle, stir evenly；
S6, surfactant being weighed according to the ratio, being added in agitated kettle, stirred evenly, solution will be turned yellow gradually at this time
Prescribed liquid；
S7, the compound packet of defoaming agent is weighed according to the ratio, be added slowly in agitated kettle, stir evenly finished product concentrate.
10. a kind of preparation method of high-performance magnesium alloy cutting fluid according to claim 9, which is characterized in that also wrap
Include following steps:
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
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| CN110577824A (en) * | 2019-08-01 | 2019-12-17 | 安庆帝伯格茨活塞环有限公司 | Water-based grinding agent and preparation method thereof |
| CN110819429A (en) * | 2019-11-25 | 2020-02-21 | 上海森帝润滑技术有限公司 | An emulsified cutting fluid |
| CN111849601A (en) * | 2020-08-11 | 2020-10-30 | 广州洛德化工科贸有限公司 | Low-temperature antirust agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN111909767A (en) * | 2020-09-16 | 2020-11-10 | 江苏赢新润滑科技有限公司 | High-performance water-based magnesium alloy processing fluid |
| CN113817534A (en) * | 2021-10-29 | 2021-12-21 | 南京科润工业介质股份有限公司 | Corrosion inhibition additive for aluminum alloy cutting fluid |
| CN114854480A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Semisynthetic cutting fluid |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110577824A (en) * | 2019-08-01 | 2019-12-17 | 安庆帝伯格茨活塞环有限公司 | Water-based grinding agent and preparation method thereof |
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| CN110819429A (en) * | 2019-11-25 | 2020-02-21 | 上海森帝润滑技术有限公司 | An emulsified cutting fluid |
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| CN111849601A (en) * | 2020-08-11 | 2020-10-30 | 广州洛德化工科贸有限公司 | Low-temperature antirust agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN111909767A (en) * | 2020-09-16 | 2020-11-10 | 江苏赢新润滑科技有限公司 | High-performance water-based magnesium alloy processing fluid |
| CN114854480A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Semisynthetic cutting fluid |
| CN113817534A (en) * | 2021-10-29 | 2021-12-21 | 南京科润工业介质股份有限公司 | Corrosion inhibition additive for aluminum alloy cutting fluid |
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