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CN108384212A - A kind of novel heat-conducting plastics and its application - Google Patents

A kind of novel heat-conducting plastics and its application Download PDF

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Publication number
CN108384212A
CN108384212A CN201810122174.3A CN201810122174A CN108384212A CN 108384212 A CN108384212 A CN 108384212A CN 201810122174 A CN201810122174 A CN 201810122174A CN 108384212 A CN108384212 A CN 108384212A
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CN
China
Prior art keywords
cement
heat
conducting
resin
plastics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810122174.3A
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Chinese (zh)
Inventor
阮伟
于会珠
郑烨亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruan Wei
Original Assignee
Hangzhou Wan Pestle Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Wan Pestle Mstar Technology Ltd filed Critical Hangzhou Wan Pestle Mstar Technology Ltd
Priority to CN201810122174.3A priority Critical patent/CN108384212A/en
Publication of CN108384212A publication Critical patent/CN108384212A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of novel heat-conducting plastics and its application, the heat-conducting plastic is by resin and cement composition, and their mass percentage content is respectively:Resin 8~80%, cement 20~92%.High heat conduction plastics disclosed in this invention, production cost is low, and heat conduction and good insulation preformance can be used for the fields such as LED illumination, automobile, electronic apparatus.

Description

A kind of novel heat-conducting plastics and its application
Technical field
The invention belongs to new material technology fields, and in particular to a kind of novel heat-conducting plastics and its application.
Background technology
LED has that energy conservation and environmental protection, small, light emission color temperature is friendly, long lifespan etc. as a kind of novel energy-conserving light source product Advantage is widely applied in the every field for producing and living.The work temperature in the light extraction efficiency of LED and service life and chip There is degree direct relationship, the electric light transformation efficiency of white LED light source to be generally 30% or so, and 70% energy is converted into thermal energy, These thermal energy generate huge side effect to LED, if cannot effectively radiate, LED internal temperatures can be made to increase, lead to LED's Luminous efficiency reduces, and directly affects the service life of LED chip, therefore heat dissipation is great power LED key application place.No matter LED cores Piece encapsulation or Design of Luminaires application, generally require to discharge heat caused by LED by Heat Conduction Material, for heat dissipation Cost alsies occupy the proportion of system cost about 20%~30%, seeks the heat dissipation solution of high performance-price ratio and also become always to chase after The target asked.Due to plastics design freedom is high, easily molded processing, light weight and it is at low cost etc. the advantages of, people will In plastic applications to the lamps and lanterns manufacture of LED industry, however the thermal coefficient very little of most of plastics, influence their application.It carries The approach of high plastics thermal conductivity:First, the synthetic material inherently resin matrix with high thermal conductivity, such as has and well leads Polyaniline, polypyrrole of hot property etc., but such material there is a problem of it is expensive;Second is that using having high heat conduction filler to fill out Plastics are filled to realize, the filler of generally use has metal powder filler such as aluminium powder, copper powder and silver powder etc., and metal oxide filler is such as Aluminium oxide, bismuth oxide, beryllium oxide, magnesia and zinc oxide etc., inorganic non-metallic filler for example graphite, silicon carbide, glass fibre and Ceramics etc., such as with the carbon fiber of high length-diameter ratio and boron nitride cooperation using metal, metal oxide as filler, product obtained Thermal coefficient is 20W/mK (ZL99815810.0);Or using insulating packings such as metal oxide, silicon carbide as filler, it is made The thermal coefficient of product (ZL200510101700.0) between 2~4 W/mK.
Currently, most of heat-conducting plastic heat conductivility is not high enough, mechanical performance is unstable or heat conductivility is still but steady It is qualitative bad, it is on the high side the problems such as still annoying LED illumination manufacturing enterprise.It is grown rapidly as LED illuminates application, and Move towards consuming public, the requirements such as the automation size production of lamps and lanterns product, cost control, safety, lightweight also increasingly carry The market demand of height, heat-conducting plastic also increases year by year.Therefore, seek what a kind of low production cost, heat conduction and insulation performance were done Novel heat-conducting plastics have prodigious commercial value.
Invention content
In view of the problems of the existing technology, low it is an object of the invention to design a kind of production cost of offer, while energy Take into account heat conduction and the novel heat-conducting plastics of insulation performance and its technical solution of application.
A kind of novel heat-conducting plastics, it is characterised in that the heat-conducting plastic is by resin and cement composition, the tree The mass percentage content of fat and cement is:Resin 8~80%, cement 20~92%.
The resin is polyamide(PA), makrolon(PC), polybutylene terephthalate (PBT)(PBT), it is poly- to benzene Naphthalate(PET), polyformaldehyde(POM), polyphenylene oxide(PPO), acrylonitrile-butadiene-styrene (ABS)(ABS), polypropylene (PP), polyphenylene sulfide(PPS), polysulfones(PSF), polyethylene(PE), polymethyl methacrylate(PMMA), polytetrafluoroethylene (PTFE) (PTFE)In one kind or arbitrary several mixture.
A kind of novel heat-conducting plastics, it is characterised in that the cement is portland cement, slag silicate brine One kind in mud, Portland pozzolana cement, Portland fly ash cement, composite Portland cement or arbitrary several mixing Object.
A kind of novel heat-conducting plastics, it is characterised in that the heat-conducting plastic moulding process is injection moulding, squeezes Go out molding, compression moulding, blow molding or cast molding.
A kind of novel heat-conducting plastics, it is characterised in that the thermal conductivity of the heat-conducting plastic is 1~3 W/mK.
A kind of application of the novel heat-conducting plastics as Heat Conduction Material.
It is compared with existing technology, the invention has the advantages that:High heat conduction plastics disclosed in this invention, production It is at low cost, while preferable heat conduction and insulation performance can be taken into account, it can be used for the fields such as LED illumination, automobile, electronic apparatus.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
Content calculation by mass percentage takes resin [makrolon(PC)20% and polyamide(PA66)18%] totally 38% and cement (Portland cement 45% and portland slag cement 17%)It totally 62% is placed in mixing and blending machine after mixing, is squeezed by twin-screw Go out machine extruding pelletization to get to the present invention a kind of high heat conduction plastic product.After gained heat-conducting plastic is melted and molded, heat conduction is used The thermal coefficient of coefficient tester determination sample is 1.3 W/mK.
Embodiment 2
Content calculation by mass percentage takes resin [polyamide(PA6)16% and polybutylene terephthalate (PBT)(PBT)11%] Totally 27% and cement(Portland pozzolana cement 52%, Portland fly ash cement 21%)Totally 73% be placed in high-speed mixer mix Close uniformly after, by double screw extruder extruding pelletization to get to the present invention a kind of high heat conduction plastic product.Gained heat conduction is moulded It is 1.1 W/mK with the thermal coefficient of heat conduction coefficient tester determination sample after material is melted and molded.
Embodiment 3
Content calculation by mass percentage takes acrylonitrile-butadiene-styrene (ABS)(ABS)19% and cement(Portland cement)81% It is placed in high-speed mixer after mixing, is moulded to get to a kind of high heat conduction of the present invention by double screw extruder extruding pelletization Expect product.It is 1.6 W/m with the thermal coefficient of heat conduction coefficient tester determination sample after gained heat-conducting plastic is melted and molded K。
Embodiment 4
Content calculation by mass percentage takes resin [polypropylene(PP)20% and polyamide(PA6)10%] totally 30% and cement(Powder Coal ash portland cement 55%, composite Portland cement 15%)It totally 70% is placed in high-speed mixer after mixing, by twin-screw Extruder extruding pelletization to get to the present invention a kind of high heat conduction plastic product.After gained heat-conducting plastic is melted and molded, with leading The thermal coefficient of hot coefficient tester determination sample is 1.3 W/mK.
Embodiment 5
Content calculation by mass percentage takes polyamide(PA6)35% and cement(Portland cement 43%, fly ash silicate water Mud 22%)Totally 65% be placed in high-speed mixer after mixing, by double screw extruder extruding pelletization to get to the present invention one Kind high heat conduction plastic product.After gained heat-conducting plastic is melted and molded, with the thermal coefficient of heat conduction coefficient tester determination sample For 1.1 W/mK.
Embodiment 6
Content calculation by mass percentage takes resin [polypropylene(PP)20% and polybutylene terephthalate (PBT)(PBT)7%] altogether 27% and cement(Portland cement 42%, composite Portland cement 21%)Totally 73% be placed in high-speed mixer after mixing, by Double screw extruder extruding pelletization to get to the present invention a kind of high heat conduction plastic product.Gained heat-conducting plastic is melted and molded Afterwards, it is 1.6 W/mK with the thermal coefficient of heat conduction coefficient tester determination sample.

Claims (5)

1. a kind of novel heat-conducting plastics, it is characterised in that the heat-conducting plastic is by resin and cement composition, the resin and cement Mass percentage content be:Resin 8~80%, cement 20~92%;
The resin is polyamide, makrolon, polybutylene terephthalate (PBT), polyethylene terephthalate, gathers Formaldehyde, polyphenylene oxide, acrylonitrile-butadiene-styrene (ABS), polypropylene, polyphenylene sulfide, polysulfones, polyethylene, poly-methyl methacrylate One kind in ester, polytetrafluoroethylene (PTFE) or arbitrary several mixture.
2. a kind of novel heat-conducting plastics as described in claim 1, it is characterised in that the cement is portland cement, slag One kind or arbitrary several in portland cement, Portland pozzolana cement, Portland fly ash cement, composite Portland cement The mixture of kind.
3. a kind of novel heat-conducting plastics as described in claim 1, it is characterised in that the heat-conducting plastic moulding process is note Penetrate molding, extrusion molding, compression moulding, blow molding or cast molding.
4. a kind of novel heat-conducting plastics as described in claim 1, it is characterised in that the thermal conductivity of the heat-conducting plastic is 1~ 3 W/m·K。
5. a kind of application of the novel heat-conducting plastics as described in claim 1 as Heat Conduction Material.
CN201810122174.3A 2018-02-07 2018-02-07 A kind of novel heat-conducting plastics and its application Pending CN108384212A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810122174.3A CN108384212A (en) 2018-02-07 2018-02-07 A kind of novel heat-conducting plastics and its application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810122174.3A CN108384212A (en) 2018-02-07 2018-02-07 A kind of novel heat-conducting plastics and its application

Publications (1)

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CN108384212A true CN108384212A (en) 2018-08-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111286184A (en) * 2020-03-24 2020-06-16 上海锦湖日丽塑料有限公司 PC/ABS alloy resistant to damp-heat aging and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101186748A (en) * 2006-11-15 2008-05-28 东丽纤维研究所(中国)有限公司 Nano composite material of polyester and inorganic silicate, and preparation method thereof
CN101405236A (en) * 2006-03-22 2009-04-08 诺瓦化学公司 Lightweight concrete compositions
CN104403311A (en) * 2014-12-24 2015-03-11 江阴济化新材料有限公司 Heat conducting nylon material and preparation method thereof
CN107011646A (en) * 2017-04-25 2017-08-04 柳州市够旺贸易有限公司 Polycarbonate engineering plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101405236A (en) * 2006-03-22 2009-04-08 诺瓦化学公司 Lightweight concrete compositions
CN101186748A (en) * 2006-11-15 2008-05-28 东丽纤维研究所(中国)有限公司 Nano composite material of polyester and inorganic silicate, and preparation method thereof
CN104403311A (en) * 2014-12-24 2015-03-11 江阴济化新材料有限公司 Heat conducting nylon material and preparation method thereof
CN107011646A (en) * 2017-04-25 2017-08-04 柳州市够旺贸易有限公司 Polycarbonate engineering plastic

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘学来,等: "《热工学理论基础》", 31 December 2004, 中国电力出版社 *
宋波: "《塑料改性技术》", 31 October 2016, 中国纺织出版社 *
梁基照: "《高分子复合材料传热学导论》", 31 March 2013, 华南理工大学出版社 *
王沛: "《中药制药工程原理与设备》", 31 August 2016, 中国中医药出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111286184A (en) * 2020-03-24 2020-06-16 上海锦湖日丽塑料有限公司 PC/ABS alloy resistant to damp-heat aging and preparation method thereof

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Effective date of registration: 20191128

Address after: 200050 No. 390, Anhua Road, Shanghai, Changning District

Applicant after: Ruan Wei

Address before: Room 19, No. 101-44, No. 1399, good road, front street, Cang Qian street, Yuhang District, Hangzhou, Zhejiang

Applicant before: Hangzhou Wan pestle Mstar Technology Ltd