CN108315755A - A kind of hydrogen-rich cup - Google Patents

Abstract

The invention discloses a hydrogen-rich water cup, which comprises a pressure-controlled solubilizing cup cover, a cup body and a hydrogen-oxygen separation electrolysis system. , The lid of the pressure-controlled solubilization cup is provided with air holes, and a water-proof and breathable membrane is arranged in the air holes, and the hydrogen-oxygen separation electrolysis system is arranged at the bottom of the cup body. The hydrogen-rich water cup of the present invention can maintain the cup body under a certain pressure through the pressure-controlled solubilizing cup cover to increase the concentration of hydrogen dissolved in water, and at the same time control the pressure of the cup body so that it will not be too high to cause danger.

Description

A hydrogen-rich water cup

technical field

The invention relates to the technical field of electrolysis, in particular to a hydrogen-rich water cup capable of producing hydrogen-rich water.

Background technique

Scientific research has proved that almost all chronic diseases in the human body are closely related to free radical oxidative damage. Since the authoritative paper published by Professor Shigeo Ota in Japan in 2007, proving that hydrogen can selectively neutralize toxic and harmful free radicals such as hydroxyl radicals and nitrite anions, thereby exerting a selective antioxidant effect, hydrogen medicine has developed rapidly in the health industry. With the provision of quality of life, people pay more attention to their own health.

The main ways for the human body to absorb hydrogen include drinking hydrogen-rich water, injecting hydrogen saline, and inhaling hydrogen directly. Among them, the earliest application of hydrogen is in the field of hydrogen-rich water. The current products on the market are mainly hydrogen-rich water cups, which dissolve hydrogen in water and obtain hydrogen by drinking directly. This method is more convenient, but the solubility of hydrogen in water at normal temperature and pressure is very low, generally 0.5-0.8ppm (mass concentration is 0.5-0.8ppm), and its therapeutic effect must be exerted. , Need to drink a lot of hydrogen water.

The hydrogen-rich water cup provided by the prior art either does not provide pressurization of the water in the water cup, so that the hydrogen dissolved in the water is limited, and at the same time, most of the generated hydrogen is emitted into the air, resulting in waste. Or although a pressurization device is provided, there is no suitable pressure release mechanism, so that the pressure of the cup is increasing, which is prone to danger.

Contents of the invention

Aiming at the problems of the existing hydrogen-rich water cup, the embodiment of the present invention provides a hydrogen-rich water cup, which can increase a certain pressure of the water and greatly increase the concentration of hydrogen in the water. At the same time, when the pressure exceeds a certain value, hydrogen can be discharged from the cup to avoid danger caused by too much pressure in the cup.

A hydrogen-rich water cup provided by an embodiment of the present invention includes a pressure-controlled solubilization cup cover, a cup body and a hydrogen-oxygen separation electrolysis system, the cup mouth is provided with a cup cover interface, and the pressure-controlled solubilization cup cover and the cup body pass through the cup cover The interface can be detachably connected, and the cover of the pressure-controlled solubilization cup is provided with a vent hole, and a water-proof and breathable membrane is arranged in the vent hole, and the hydrogen-oxygen separation electrolysis system is arranged at the bottom of the cup body.

The hydrogen-rich water cup provided by the embodiment of the present invention provides a pressure-controlled solubilization cup cover, and a vent hole is provided in the pressure-controlled solubilization cup cover, and a water-proof and breathable film is provided in the vent hole. The characteristic of the water-proof and breathable membrane is that only when the pressure exceeds 0.1MPa, the gas will be discharged from the water-proof and breathable membrane, and there will be no water leakage. When the pressure is less than 0.1MPa, the gas cannot be discharged, thus ensuring that the working pressure in the cup is always maintained close to 0.1MPa. This can not only fully increase the solubility of hydrogen in water through pressure, increase the concentration of hydrogen-rich water per unit working time, but also maintain the pressure in the cup stably, ensuring the safety of the cup. This avoids the risk of hydrogen-oxygen mixture explosion, water leakage or explosion in the container with too high pressure, and the problem of too low concentration of hydrogen-rich water per unit time when the pressure is too low. The hydrogen-rich water cup provided by the present invention has no complicated electronic or control structure, simple equipment, simple assembly and realization process, and stable and reliable operation.

Preferably, the pressure control solubilization cup cover includes an upper cover and a lower cover, and the corresponding positions of the upper cover and the lower cover are provided with vent holes, and the water-proof and breathable film is arranged between the upper cover and the lower cover, and is connected with the vent holes. Corresponding to the setting, the lower cover is fixed on the bottom surface of the upper cover.

Preferably, the upper cover includes an outer post of the vent hole, the lower cover includes an inner post of the vent hole, the water-proof and breathable membrane is closely attached to the air hole of the inner post of the vent hole, and the inner post of the vent hole is inserted into the outer post of the vent hole.

Preferably, the pressure control solubilization cup cover further includes a fourth sealing silicone ring, a through hole is provided in the middle of the fourth sealing silicone ring, and the fourth sealing silicone ring is nested on the lower cover through the through hole.

Preferably, the hydrogen-oxygen separation electrolysis system includes a hydrogen-oxygen separation electrolysis device and a hydrogen-oxygen separation electrolysis device control system; the hydrogen-oxygen separation electrolysis device control system is arranged at the bottom of the hydrogen-oxygen separation electrolysis device and is sealingly connected with the lower fixing plate.

The hydrogen-oxygen separation electrolysis device includes an electrolytic generator, an upper fixed plate and a lower fixed plate. The electrolytic generator includes a cathode sheet, an anode sheet, and a selective proton permeable membrane. The anode sheet is provided with an anode terminal, the anode terminal is externally connected to the positive pole of the power supply, an electrode hole is arranged on the lower fixed plate, the anode terminal and the cathode terminal pass through the electrode hole, the bottom surface of the upper fixed plate and the top surface of the lower fixed plate are arranged with The cathode sheet, the selective proton permeable membrane, and the anode sheet have matching cavity in shape, the lower fixed plate is detachably connected to the upper fixed plate, and the cathode sheet, the selective proton permeable membrane, and the anode sheet are fixed on the upper fixed plate and the lower fixed plate. In the accommodation cavity between the fixed plates, a hydrogen generation area is formed between the cathode sheet and the selective proton permeable membrane, an oxygen generation area is formed between the anode sheet and the selective proton permeable membrane, and a hydrogen gas discharge port is set in the hydrogen generation area for Hydrogen gas exits the hydrogen generation area and water enters the hydrogen generation area, and an oxygen discharge port is provided in the oxygen generation area for oxygen to exit the oxygen generation area.

Preferably, the hydrogen-oxygen separation electrolysis device further includes an electric plate screw cover, the lower fixing plate is provided with a through hole corresponding to the area of the electrolysis generator, the electric plate screw cover is arranged in the through hole, and the electric plate screw cover can move up and down along the through hole.

Preferably, a plurality of ventilation holes are provided on the cathode sheet and the anode sheet.

Preferably, the cathode sheet, the anode sheet, the selective proton permeable membrane, the upper fixed plate and the lower fixed plate are all arranged in a circular shape with matching sizes, and the cathode sheet, the selective proton permeable membrane, and the anode sheet are arranged in a top-to-bottom order. They are sequentially fixed between the upper fixing plate and the lower fixing plate, the oxygen discharge port is arranged on the lower fixing plate, and the anode sheet, the selective proton permeable membrane and the lower fixing plate are sealed and connected.

Preferably, the selective proton permeable membrane is a self-humidifying proton permeable membrane.

Preferably, it also includes a moisturizing silica gel pad, which is detachably arranged on the hydrogen-oxygen separation electrolysis device.

Preferably, the hydrogen-oxygen separation electrolysis device control system includes a microprocessor, a memory, an automatic voltage regulation module and a switch circuit, the microprocessor is respectively connected to the memory, the automatic voltage regulation module and the switch circuit, and the power supply input end of the automatic voltage regulation module is connected to an external power supply , the positive pole of the power output terminal of the automatic voltage regulation module is externally connected to the anode of the hydrogen-oxygen separation electrolysis device, and the negative pole of the power output terminal of the automatic voltage regulation module is externally connected to the cathode of the hydrogen-oxygen separation electrolysis device;

The memory stores the start-up voltage detection value preset according to the operating voltage of the hydrogen-oxygen separation electrolysis device, the control voltage step value and the computer executable program. The microprocessor reads the computer executable program in the memory and implements the following control methods:

Start-up voltage detection step: detect the power supply voltage of the external power supply, if the power supply voltage is lower than the start-up voltage detection value, stop working and prompt that the voltage is insufficient, otherwise, go to the next step;

Automatic boosting step: control the automatic voltage regulation module to gradually increase the voltage input to the cathode and anode of the hydrogen-oxygen separation electrolysis device with the preset control voltage step value until the actual working voltage of the cathode and anode of the hydrogen-oxygen separation electrolysis device reaches the start-up voltage detection value.

Preferably, the hydrogen-oxygen separation electrolysis device control system also includes a sampling comparison circuit, the input terminal of the sampling comparison circuit is respectively connected to the positive pole and the negative pole of the output terminal of the automatic voltage regulation module power supply, the output terminal of the sampling comparison circuit is connected to the microprocessor, and the sampling comparison circuit obtains hydrogen The actual working voltage of the oxygen separation electrolysis device is input to the microprocessor, and the microprocessor executes the computer executable program to realize the following control method:

Automatic voltage regulation step: compare the actual working voltage with the detected value of the start-up voltage, if the actual working voltage is greater than the detected value of the start-up voltage, control the automatic voltage regulation module to reduce the voltage output to the hydrogen-oxygen separation electrolysis device until The actual working voltage is equal to the detection value of the starting voltage. If the actual working voltage is lower than the detection value of the starting voltage, the automatic voltage regulation module is controlled to increase the voltage output to the hydrogen-oxygen separation electrolysis device until the actual working voltage is equal to the detection value of the starting voltage.

Preferably, the hydrogen-oxygen separation electrolysis device control system also includes a charging and discharging management module and a storage battery. When the module is connected to an external power supply, it is used to adjust the charging voltage and charging current according to the capacitance of the battery; when the charging and discharging management module is powered by the battery, it is used to protect the battery from overcurrent or overload.

Preferably, the hydrogen-oxygen separation electrolysis device control system also includes a light display device, which is connected to the microprocessor, and the light display device is used to receive signals from the microprocessor and display the working status. The working status includes power-on detection, automatic upgrade voltage, automatic voltage regulation, or insufficient power supply voltage.

The hydrogen-rich water cup provided by the embodiment of the present invention can keep the cup body under a certain pressure by controlling the pressure-controlled solubilizing cup cover, increase the concentration of hydrogen dissolved in water, and control the pressure of the cup body so that it will not be too high to cause danger.

Description of drawings

Fig. 1 is a schematic structural diagram of a hydrogen-rich water cup in an embodiment of the present invention;

Fig. 2 is a schematic diagram of the structure of the pressure-controlled solubilizing cup cover in the embodiment of the present invention;

3 is a schematic structural diagram of the control system of the hydrogen-oxygen separation electrolysis device in the embodiment of the present invention;

Fig. 4 is a schematic structural diagram of a preferred embodiment of the control system of the hydrogen-oxygen separation electrolysis device in the embodiment of the present invention;

Fig. 5 is a schematic structural diagram of an exploded view of a hydrogen-oxygen separation electrolysis device in an embodiment of the present invention;

Fig. 6 is a schematic diagram of the assembly structure of the hydrogen-oxygen separation electrolysis device in the embodiment of the present invention.

In the drawings: 100, hydrogen and oxygen separation electrolysis device; 111, cathode piece; 1112, cathode terminal; 1113, cathode piece boss; 112, anode piece; 1122, anode terminal; 1123, anode piece boss; 113, Selective proton permeable membrane; 121, lower fixing plate; 122, electrode hole; 131, upper fixing plate; 132, fixing screw cap; 133, electrode slot; 134, accommodating cavity; Electrical plate screw cap; 142, oxygen discharge port; 151, first sealing silicone ring; 152, second sealing silicone ring; 153, third sealing silicone ring; 154, fourth sealing silicone ring; 161, hydrogen generation area; 162 . Oxygen generation area; 170. Moisturizing silica gel pad; 200. Hydrogen and oxygen separation electrolysis device control system; 210. Microprocessor; 220. Automatic voltage regulation module; 230. Memory; 240. Switching circuit; 250. Sampling comparison circuit; , charging and discharging management module; 270, storage battery; 280, light display device; 290, tilt sensing device; 300, cup body; 310, control base; 400, external power supply; ; 511, the outer column of the ventilation hole; 520, the lower cover; 521, the inner column of the ventilation hole; 530, the water-proof and breathable membrane.

Detailed ways

Below, the present invention will be further described in conjunction with the accompanying drawings and specific implementation methods. It should be noted that, under the premise of not conflicting, the various embodiments described below or the technical features can be combined arbitrarily to form new embodiments. .

A hydrogen-rich water cup provided by an embodiment of the present invention. The hydrogen-oxygen separation electrolysis system includes a hydrogen-oxygen separation electrolysis device, which is used to produce hydrogen-rich water in daily life, so as to meet the problem of people using hydrogen-rich water for disease prevention and body conditioning, and to avoid free radical oxidative damage in the body.

Example 1:

As shown in Figure 1 and Figure 2, the hydrogen-rich water cup provided by the embodiment of the present invention includes a pressure-controlled solubilization cup cover 500, a cup body 300 and a hydrogen-oxygen separation electrolysis system, the cup body 300 is equipped with a cup lid interface, and the pressure control The solubilizing cup cover 500 is detachably connected to the cup body 300 through the cup cover interface. The pressure-controlled solubilizing cup cover 500 is provided with a vent hole, and a water-proof and breathable membrane 530 is arranged in the vent hole. The hydrogen-oxygen separation electrolysis system is set on the cup body. 300 bottom. The connection between the pressure control solubilization cup cover 500 and the cup body 300 through the cup cover interface includes threaded connection, buckle connection or other common fitting installation methods, such as extrusion connection using elastic components. In the technical solution of the present invention, threaded connection is preferably adopted. An external thread is provided on the mouth of the cup body 300 , and an internal thread is provided on the inner side of the pressure-controlling solubilization cup cover 500 , and the cup body 300 and the pressure-controlling solubilization cup cover 500 are connected together through thread matching. The cup body 300 adopts a special hydrogen-rich water cup cup body, that is, an installation mechanism is provided at the bottom of the cup body 300 so as to install the hydrogen-oxygen separation electrolysis system on the bottom of the cup body 300 . At the same time, a waterproof control interface is provided to connect to the outer wall of the cup body 300, such as a control switch, a power interface, and the like.

The hydrogen-rich water cup provided in the embodiment of the present invention provides a pressure-controlled solubilization cup cover 500, and a vent hole is provided in the pressure-controlled solubilization cup cover 500, and a water-proof and breathable film 530 is provided in the vent hole. The characteristic of the water-proof and gas-permeable membrane 530 is that only when the pressure exceeds 0.1 MPa, the gas will be discharged from the water-proof and gas-permeable membrane 530 without water leakage. When the pressure is less than 0.1 MPa, the gas cannot be discharged, thus ensuring that the working pressure in the cup body 300 is always maintained close to 0.1 MPa. This can not only fully increase the solubility of hydrogen in water through pressure, increase the concentration of hydrogen-rich water per unit working time, but also stably maintain the pressure in the cup body 300, ensuring the safety of the cup. This avoids the risk of hydrogen-oxygen mixture explosion, water leakage or explosion in the container with too high pressure, and the problem of too low concentration of hydrogen-rich water per unit time when the pressure is too low. The hydrogen-rich water cup provided by the present invention has no complicated electronic or control structure, simple equipment, simple assembly and realization process, and stable and reliable operation.

Wherein, the pressure control solubilization cup cover 500 includes an upper cover 510 and a lower cover 520, and the corresponding positions of the upper cover 510 and the lower cover 520 are all provided with air holes, and the water-proof and breathable membrane 530 is arranged on the upper cover 510 and the lower cover 520. Between, and corresponding to the ventilation holes, the lower cover 520 is fixed on the bottom surface of the upper cover 510 . The upper cover 510 includes an outer column 511 of the air hole, the lower cover 520 includes an inner column 521 of the air hole, the water-proof and breathable membrane 530 is closely attached to the air hole of the inner column 521 of the air hole, and the inner column 521 of the air hole is inserted into the outer column 511 of the air hole.

The pressure control solubilization cup cover 500 also includes a fourth sealing silicone ring 154 , and a through hole is arranged in the middle of the fourth sealing silicone ring 154 , and the fourth sealing silicone ring 154 is nested on the lower cover 520 through the through hole. By arranging the fourth sealing silicone ring 154, the waterproof performance and thermal insulation performance of the pressure control solubilization cup cover 500 can be increased.

The hydrogen-oxygen separation electrolysis system includes a hydrogen-oxygen separation electrolysis device 100 and a hydrogen-oxygen separation electrolysis device control system 200; the hydrogen-oxygen separation electrolysis device control system 200 is fixed on the bottom of the hydrogen-oxygen separation electrolysis device 100 by a fixture and is sealed with the lower fixing plate 121 connect. The hydrogen-oxygen separation electrolysis system is set on the control base 310 . An installation structure is provided at the bottom of the cup body 300 , and the hydrogen-oxygen separation electrolysis system is fixed on the cup bottom of the cup body 300 by fixing the control base 310 . For the specific structures of the hydrogen-oxygen separation electrolysis device control system 200 and the hydrogen-oxygen separation electrolysis device 100 of the hydrogen-oxygen separation electrolysis system, please refer to Embodiment 2 and Embodiment 3.

Example 2:

As shown in Fig. 3 and Fig. 4, a hydrogen-oxygen separation electrolysis device control system 200 provided by the embodiment of the present invention includes a microprocessor 210, a memory 230, an automatic voltage regulation module 220 and a switch circuit 240, and the microprocessor 210 is respectively Connect the memory 230, the automatic voltage regulation module 220 and the switch circuit 240, the power input terminal of the automatic voltage regulation module 220 is connected to an external power supply 400, the positive pole of the power output terminal of the automatic voltage regulation module 220 is externally connected to the anode of the hydrogen-oxygen separation electrolysis device 100, and the automatic voltage regulation module 220 The negative pole of the output terminal of the power supply is externally connected to the cathode of the hydrogen-oxygen separation electrolysis device 100;

The memory 230 stores the start-up voltage detection value preset according to the working voltage of the hydrogen-oxygen separation electrolysis device 100, the control voltage step value and the computer executable program, and the microprocessor 210 reads the computer executable program in the memory 230 and realizes the following control method:

Start-up voltage detection step: detect the power supply voltage of the external power supply 400, if the power supply voltage is lower than the start-up voltage detection value, stop working and prompt that the voltage is insufficient, otherwise, go to the next step;

Automatic boosting step: control the automatic voltage regulation module 220 to gradually increase the voltage input to the cathode and anode of the hydrogen-oxygen separation electrolysis device 100 with the preset control voltage step value until the actual working voltage of the cathode and anode of the hydrogen-oxygen separation electrolysis device 100 Reach the power-on voltage detection value.

In one preferred implementation manner, the preset start-up voltage detection value in the memory 230 is set as the rated working voltage of the hydrogen-oxygen separation electrolysis device. The automatic voltage regulation module 220 gradually increases the voltage input to the cathode and anode of the hydrogen-oxygen separation electrolysis device 100 with a preset control voltage step value. For example, the control voltage step value can be set to increase by 0.5V per second to output a reasonable voltage and current To hydrogen and oxygen separation electrolysis device 100. Reasonable voltage means that the electrode loading voltage requires a slow boost.

The switch circuit 240 controls the power on and off of the hydrogen-oxygen separation electrolysis system. When shutting down, the switch circuit 240 sends different signals to the microprocessor 210 at the same time, and the microprocessor 210 processes different signals to calculate the timing. Send the shutdown signal to the automatic voltage regulation module 220 to complete the shutdown.

The control system 200 of the hydrogen-oxygen separation electrolysis device provided by the embodiment of the present invention detects the power supply voltage when starting up, and gradually increases the voltage to the working voltage when starting the hydrogen-oxygen separation electrolysis device 100, avoiding the problem of the hydrogen-oxygen separation electrolysis device 100. Input a momentary high-change voltage at the start of electrolysis to avoid ozone generation.

The hydrogen-oxygen separation electrolysis device control system 200 provided in this embodiment can be directly connected to household power distribution through an adapter. But this limits the use of the device. Since the hydrogen-oxygen separation electrolysis device 100 does not require high voltage and current during operation, in a preferred embodiment, the hydrogen-oxygen separation electrolysis device control system 200 provided in the embodiment of the present invention also includes a charging and discharging management module 260 and a storage battery 270 , the automatic voltage regulation module 220 is simultaneously connected to the power source 400 and the storage battery 270 through the charging and discharging management module 260 . When the external power supply 400 is used to supply power, the charger provides a regulated 5V voltage output, and the charging and discharging management module 260 can adjust the charging voltage and charging current according to the capacitance of the storage battery 270; , the charging and discharging management module 260 provides overcurrent or overload protection for the storage battery 270 . The charging and discharging management module 260 protects the charging and discharging of the storage battery 270 , so that the battery can be charged quickly without damaging the battery and prolonging the service life of the battery.

In a preferred implementation of this embodiment, it also includes a sampling comparison circuit 250, the input terminals of the sampling comparison circuit 250 are respectively connected to the positive pole and the negative pole of the output terminal of the automatic voltage regulation module 220, and the output terminal of the sampling comparison circuit 250 is connected to the microprocessor 210, The sampling comparison circuit 250 obtains the actual working voltage of the hydrogen-oxygen separation electrolysis device 100, and inputs it to the microprocessor 210, and the microprocessor 210 executes a computer executable program to realize the following control method:

Automatic voltage regulation step: compare the actual working power supply with the detected value of the starting voltage, if the actual working voltage is greater than the detected value of the starting voltage, control the automatic voltage regulating module 220 to reduce the voltage output to the hydrogen-oxygen separation electrolysis device 100 until the actual working voltage is equal to Start-up voltage detection value, if the actual working voltage is lower than the start-up voltage detection value, control the automatic voltage regulation module 220 to increase the voltage output to the hydrogen-oxygen separation electrolysis device 100 until the actual working voltage is equal to the start-up voltage detection value.

By setting the sampling comparison circuit 250 to detect the working voltage of the hydrogen-oxygen separation electrolysis device in real time, and adjust the working voltage to the rated working voltage in time, the hydrogen-oxygen separation electrolysis device can maintain a stable working voltage and working current. Especially when the storage battery 270 is used for power supply, the working voltage output to the hydrogen-oxygen separation electrolysis device is easily changed due to the change of the battery power. By providing a stable working voltage and working current, the stability of hydrogen generation can be guaranteed, and at the same time, the amount of hydrogen dissolved in water can be guaranteed, and the concentration of hydrogen water can be guaranteed. At the same time, the stable working voltage and working current are also conducive to prolonging the service life of the equipment.

The sampling comparison circuit 250 can be implemented by the microprocessor 210 executing a computer program, or can be implemented by a circuit. The rated operating voltage of the hydrogen-oxygen separation electrolysis device 100 is preset in the sampling comparison circuit 250 . The sampling comparison circuit 250 is provided with a sampling circuit and a comparison circuit. The sampling circuit obtains the actual working voltage of the hydrogen-oxygen separation electrolysis device 100 and inputs it into the comparison circuit. The comparison result is sent to the microprocessor 210 .

In a preferred implementation of this embodiment, a light display device 280 is also included, and the light display device 280 is connected with the microprocessor 210. The switch circuit 240 sends different signals to the microprocessor 210, the microprocessor 210 processes different signals, and outputs the light signal to the light display device 280, the light display device 280 is used to receive the signal from the microprocessor 210, and lights up different lights according to different signals. light. Such as power-on detection, automatic voltage boosting, automatic voltage regulation or insufficient power supply voltage, hydrogen production time at different timings can also be displayed through the light display device 280 . The light display device 280 can display different working states through different lights, so as to remind the operator to take appropriate measures.

Example 3:

Embodiment 2 of the present invention provides a hydrogen-oxygen separation electrolysis system. Including the hydrogen-oxygen separation electrolysis device 100 and the hydrogen-oxygen separation electrolysis device control system 200 as in Embodiment 1, the hydrogen-oxygen separation electrolysis device control system 200 is arranged at the lower end of the hydrogen-oxygen separation electrolysis device 100 and is sealed and connected.

As shown in Figure 5 and Figure 6, the hydrogen-oxygen separation electrolysis device 100 includes an electrolytic generator, an upper fixed plate 131 and a lower fixed plate 121, and the electrolytic generator includes a cathode sheet 111, an anode sheet 112, a selective proton permeable 113 membrane, The upper fixing plate 131 and the lower fixing plate 121, the cathode piece 111 is provided with a cathode terminal 1112, the cathode terminal 1112 is connected to the negative pole of the external power supply 400, specifically, the cathode terminal 1112 is connected to the negative pole of the output terminal of the automatic voltage regulating module 220; the anode piece 112 is set Anode terminal 1122, the anode terminal 1122 is connected to the positive pole of the external power supply 400, specifically, the anode terminal 1122 is connected to the positive pole of the power output terminal of the automatic voltage regulation module 220; the lower fixed plate 121 is provided with an electrode hole 122, the anode terminal 1122 and the cathode connection The end 1112 passes through the electrode hole 122, and an accommodating cavity 134 matching the shape of the cathode sheet 111, the selective proton permeable membrane 113, and the anode sheet 112 can be provided on the bottom surface of the upper fixing plate 131 or the top surface of the lower fixing plate 121, The accommodating cavity 134 matching the shape of the cathode sheet 111, the selective proton permeable membrane 113, and the anode sheet 112 can also be set on the bottom surface of the upper fixing plate 131 and the top surface of the lower fixing plate 121 at the same time, and the lower fixing plate 121 and the upper The fixed plate 131 is detachably connected, the cathode sheet 111, the selective proton permeable membrane 113, and the anode sheet 112 are fixed in the accommodation cavity 134 between the upper fixed plate 131 and the lower fixed plate 121, and the cathode sheet 111 and the selective proton A hydrogen generation region 161 is formed between the permeable membranes 113, an oxygen generation region 162 is formed between the anode sheet 112 and the selective proton permeable membrane 113, and a hydrogen discharge port is set in the hydrogen generation region 161 for hydrogen to exit the hydrogen generation region 161 and water enters the hydrogen generation region Zone 161 , oxygen generating zone 162 is provided with an oxygen discharge port 142 for oxygen to exit the oxygen generating zone 162 .

A through hole is provided in the middle of the upper fixing plate 131 , and the through hole extends to the cathode sheet 111 and the hydrogen generation region 161 between the cathode sheet and the selective proton permeable membrane 113 . The through hole in the middle part of the upper fixing plate 131 forms a hydrogen discharge port. The water required for electrolysis directly enters the cathode sheet 111 and the selective proton permeable membrane 113 from the through hole, and fills the accommodating cavity above the entire selective proton permeable membrane. After the hydrogen is generated in the hydrogen generating area 161, it can be directly dissolved into the water located in the hydrogen generating area 161, or it can be discharged into the cup through the through hole in the middle of the upper fixing plate 131 and dissolved in other water. Excess hydrogen will exit the cup from the water through the mouth of the cup.

The edge of the bottom surface of the upper fixing plate 131 is provided with an electrode slot 133 communicating with the accommodating cavity 134 and the outer wall of the side of the upper fixing plate, and the cathode plate 111 and the anode plate 112 are provided with a cathode plate boss 1113 and an anode plate boss respectively. 1123 , the cathode tab 1113 and the anode tab 1123 are clamped in the electrode slot 133 , so as to fix the cathode tab 111 and the anode tab 112 .

Wherein, the selective proton permeable membrane 113 is a self-humidifying proton permeable membrane. Specifically, the self-humidifying proton permeable membrane is a perfluorosulfonic acid ion membrane. Adopt self-humidification type proton permeable membrane, oxygen generation region 162 does not need to inject water in advance, the water in hydrogen generation region 161 can permeate self-humidification type proton membrane to oxygen generation region 162 to infiltrate a small amount of water to satisfy electrolysis demand, then A small amount of water in the oxygen generation area 162 is transferred to the hydrogen generation area 161 in the form of hydrated protons (H3O+), thereby preventing the water in the oxygen generation area 162 from flowing out with the generated oxygen and avoiding the generation of waste liquid.

Wherein, a plurality of ventilation holes are provided on the cathode sheet 111 and the anode sheet 112 . By setting a plurality of air holes, the generated hydrogen enters the water in the form of small bubbles, which can make the diameter of the hydrogen small, the specific surface area large, the gas rise and escape slowly, and the dissolution rate is higher.

Both the cathode sheet 111 and the anode sheet 112 are made of titanium electrodes, which are prepared from titanium particles of three different particle sizes by transfer printing, molding, electrochemical deposition, impregnation reduction or vacuum sputtering, arranged in a honeycomb shape .

Wherein, the connection between the upper fixing plate 131 and the lower fixing plate 121 may adopt buckle connection, screw connection or other possible connection methods. This embodiment adopts screw connection as described in FIG. 1 , threaded blind holes are set on the upper fixing plate 131 , threaded through holes are set at corresponding positions of the lower fixing plate 121 , and the upper fixing plate 131 and the lower fixing plate 121 are tightly connected together by screws. A detent 135 can be set on the bottom surface of the upper fixed plate 131, and a corresponding position of the lower fixed plate 121 is provided with a clamping hole, and the upper fixed plate 131 and the lower fixed plate 121 are positioned by the detent 135 and the clamped hole.

In the hydrogen-oxygen separation electrolysis device 100 provided by the present invention, the cathode sheet 111 and the anode sheet 112 are separated by a selective proton permeable membrane 113 to form a hydrogen generation region 161 and an oxygen generation region 162 . The selective proton permeable membrane 113 is a membrane that allows the passage of hydrated protons (H3O+), and the hydrated protons are combined with groups in the selective proton permeable membrane 113, and then passed from one group to another, and finally reach the other side . After first electrifying, water just loses electron e- at anode sheet 112 immediately and generates hydrogen ion and oxygen (2H2O-4e-=4H++O2 ↑), and oxygen is discharged from oxygen discharge port 142. Hydrogen ions are transferred to the cathode sheet 111 through the selective proton permeable membrane 113 in the form of hydrated protons (H3O+), and electrons are obtained to generate hydrogen gas (4H3O++4e-=4H2O+ H2↑), and the hydrogen gas is dissolved in the water in the hydrogen gas generation area 161, There is also a part of hydrogen discharged from the hydrogen discharge port into the cup, so as to achieve safe and stable separation of hydrogen and oxygen, while preventing oxygen or ozone from dissolving into the water.

In a preferred embodiment of a hydrogen-oxygen separation electrolysis device 100 provided by the present invention, the cathode sheet 111, the anode sheet 112, the selective proton permeable membrane 113, the upper fixing plate 131 and the lower fixing plate 121 are all set to match in size The round shape is better used to make hydrogen-rich water cups or hydrogen-rich water dispensers. The cathode sheet 111, the selective proton permeable membrane 113, and the anode sheet 112 may be arranged in order from top to bottom, or may be arranged in order from bottom to top. In the embodiment of the present invention, the cathode sheet 111, the selective proton permeable membrane 113, and the anode sheet 112 are preferably fixed in the cavity 134 between the upper fixing plate 131 and the lower fixing plate 121 in order from top to bottom, and the anode sheet 112 . A sealed connection between the selective proton permeable membrane 113 and the lower fixing plate 121 . This setting can facilitate the arrangement of the oxygen discharge port 142 on the lower fixing plate 121, which is beneficial to remove oxygen from the device through the bottom, so that when making a hydrogen-rich water cup, the oxygen can be directly discharged out of the cup through the bottom of the cup. At the same time, the sealing arrangement can prevent water from directly entering the oxygen generating region 162 without passing through the selective proton permeable membrane 113 to form waste water. Wherein, a first sealing silicone ring 151 is arranged between the cathode sheet 111 and the upper fixing plate 131 , and a second sealing silicone ring 152 is arranged between the anode sheet 112 and the lower fixing plate 121 . By setting the sealing silicone ring, the airtightness and waterproofness of the connection between the various components are increased.

The embodiment of the present invention provides a further improved hydrogen-oxygen separation electrolysis device 100, which also includes an electric plate screw cover 141. The top of the electric plate screw cover 141 is set as a flat plane, and the lower fixing plate 121 is provided with a through hole corresponding to the area of the electrolytic generator. The electric board screw cover 141 is arranged in the through hole, and the electric board screw cover 141 can move up and down along the through hole. In one embodiment, an external thread is provided on the electric board screw cap 141, and an internal thread matching with the thread of the electric board screw cap 141 is provided on the side wall of the through hole, and the electric board screw cover 141 and the lower fixing plate 121 pass through threaded connection. In the electrolytic generator, the cathode sheet 111, the selective proton permeable membrane 113 and the anode sheet 112 are fixed between the upper fixing plate 131 and the lower fixing plate 121 from top to bottom, passing through the flat plane on the top of the electric plate screw cover 141, The distance between the anode piece 112 and the cathode piece 111 can be adjusted to make the distance between the anode piece 112 and the cathode piece 111 more balanced, and the current passing between the anode piece 112 and the cathode piece 111 is also more balanced, so that the electrolytic reaction Occurs equally across the entire anode sheet 112 and cathode sheet 111, increasing the efficiency of hydrogen generation. At the same time, the distance between the anode sheet 112 and the cathode sheet 111 is compressed by adjusting the electric plate screw cover 141, so that the anode sheet 112 and the cathode sheet 111 are bonded closer through the selective proton permeable membrane, thereby making the resistance between them more compact. Smaller, higher current, faster decomposition power and speed.

In a further preferred implementation of the control system 2100 of the hydrogen-oxygen separation electrolysis device provided in the embodiment of the present invention, it also includes a tilt sensing device 290, which is connected to the microprocessor 210 for detecting the tilt angle of the device, and when tilting When the angle exceeds a preset value, an alarm is issued or the voltage input to the cathode piece 111 and the anode piece 112 is cut off. The inclination of the hydrogen-oxygen separation electrolysis device is detected by setting the tilt sensing device 290. When the hydrogen-oxygen separation electrolysis device is tilted and the anode piece 112 and the cathode piece 111 are not in contact with water, the circuit is closed to prevent damage to the electrolysis system of the device.

In a further preferred embodiment of the hydrogen-oxygen separation electrolysis device 100 provided in the embodiment of the present invention, it also includes an electrolysis system card slot and a fixed screw cover 132, and the fixed screw cover 132 is detachably connected to the top of the upper fixed plate 131. In the technical scheme, an external thread is arranged on the top surface of the upper fixing plate 131, an inner hole is arranged on the bottom surface of the fixing screw cap 132, and an inner thread matching with the thread of the upper fixing plate 131 is arranged on the side wall of the inner hole, and the fixing screw cap 132 and the upper fixing plate 131 are connected by thread. The slot of the electrolysis system is provided with bayonet, and the bayonet is snapped between the upper fixing plate 131 and the fixed screw cover 132, the electrolytic generator is fixed in the slot of the electrolysis system through the fixed screw cover 132, and the A third sealing silicone ring 153 is arranged between the fixing plates 131 to increase waterproofness. A through hole is provided in the middle of the fixed screw cap 132 corresponding to the through hole in the middle of the upper fixed plate 131, so that the upper fixed plate 131 and the fixed screw cap 132 communicate to form a hydrogen discharge port. In one preferred embodiment, a moisturizing silicone pad 170 can also be provided on the fixed screw cap 132, and the moisturizing silicone pad 170 can be connected with the fixed screw cap 132 by adsorption, buckle or other connection methods. When the hydrogen-oxygen separation electrolysis device 100 needs to be out of work for a relatively long time, a certain amount of water can be poured into the hydrogen generation area 161 between the selective proton permeable membrane 113 and the cathode sheet 111, and then the moisturizing silica gel pad is fixed on a fixed surface. Screw cap 132 on. The moisture-retaining silica gel pad can keep the moisture on the hydrogen generating area 161 from evaporating easily, and maintain the wettability of the selective proton permeable membrane 113, thereby ensuring the good function and service life of the hydrogen-oxygen separation electrolysis device 100.

The above-mentioned embodiment is only a preferred embodiment of the present invention, and cannot be used to limit the protection scope of the present invention. Any insubstantial changes and substitutions made by those skilled in the art on the basis of the present invention belong to the scope of the present invention. Scope of protection claimed.

Claims (14)

1. a kind of hydrogen-rich cup, which is characterized in that including pressure control solubilising cup lid, cup body and hydrogen-oxygen detach electrolysis system, the cup Cup lid interface is arranged in body rim of a cup, and the pressure control solubilising cup lid is detachably connected with cup body by the cup lid interface, the pressure control Solubilized cup lid is equipped with air hole, and water proof ventilated membrane is provided in the air hole, and the hydrogen-oxygen separation electrolysis system setting exists The bottom of cup.

2. hydrogen-rich cup as described in claim 1, which is characterized in that the pressure control solubilising cup lid includes upper cover and lower cover, institute It states upper cover and lower cover opposite position is both provided with air hole, the water proof ventilated membrane is arranged between the upper cover, lower cover, and It is correspondingly arranged with the air hole, the lower cover is fixed on the upper cover bottom surface.

3. hydrogen-rich cup as claimed in claim 2, which is characterized in that the upper cover includes air hole column jacket, the lower cover packet Air hole inner prop is included, the water proof ventilated membrane is fitted tightly on the stomata of the air hole inner prop, and the air hole inner prop is inserted Enter the air hole column jacket.

4. hydrogen-rich cup as claimed in claim 3, which is characterized in that the pressure control solubilising cup lid further includes the 4th sealed silicone It encloses, is provided with through-hole among the 4th sealed silicon cushion rubber, the 4th sealed silicon cushion rubber is nested in lower cover by the through-hole On.

5. the hydrogen-rich cup as described in Claims 1-4 is any, which is characterized in that the hydrogen-oxygen separation electrolysis system includes hydrogen Oxygen separating electrolysis unit and hydrogen-oxygen detach electrolysis unit control system；

The hydrogen-oxygen detaches electrolysis unit, including electrolysis generator, upper mounted plate and bottom plate, the electrolysis generator include Cathode sheets, anode strip, selective proton penetrate film, cathode sheets setting cathode connection end, the external electricity in cathode connection end Source cathode, anode strip setting anode connection end, anode connection end external power supply is positive, is arranged on the bottom plate Electrode hole, the anode connection end and cathode connection end pass through the electrode hole, the bottom surface of fixed plate and/or it is described under The top surface setting of fixed plate is with cathode sheets, selective proton through film, the matched accommodating cavity of anode plate shape, the lower fixation Plate is detachably connected with upper mounted plate, and the cathode sheets, selective proton penetrates film, anode strip is fixed on upper mounted plate and lower solid In accommodating cavity between fixed board, the cathode sheets and selective proton are through formation hydrogen generation area, the anode between film Piece and selective proton are discharged through oxygen generation area, the hydrogen generation area setting hydrogen discharge confession hydrogen is formed between film Hydrogen generation area and water enter hydrogen generation area, and the oxygen generation area setting oxygen floss hole oxygen is discharged oxygen and generates Area；

The hydrogen-oxygen separation electrolysis unit set-up of control system detaches the bottom of electrolysis unit and and bottom plate in the hydrogen-oxygen It is tightly connected.

6. the hydrogen-rich cup as described in claim 5 is any, which is characterized in that the hydrogen-oxygen separation electrolysis unit further includes battery plate Spiral cover, the bottom plate correspond to electrolysis generator region setting through-hole, and the battery plate spiral cover is arranged in through-hole, the battery plate Spiral cover can be moved up and down along the through-hole.

7. the hydrogen-rich cup as described in claim 5 is any, which is characterized in that be arranged in the cathode sheets and anode strip multiple Stomata.

8. hydrogen-rich cup as claimed in claim 5, which is characterized in that the cathode sheets, anode strip, selective proton penetrate Film, upper mounted plate and bottom plate are disposed as the matched circle of size, and the cathode sheets, selective proton are through film, anode Piece is fixed on by sequence from top to bottom between upper mounted plate and bottom plate, and the oxygen floss hole is arranged in bottom plate On, the anode strip, selective proton are penetrated and are tightly connected between film and bottom plate.

9. hydrogen-rich cup as claimed in claim 8, which is characterized in that the selectivity proton is from humidification type proton through film Through film.

10. hydrogen-rich cup as claimed in claim 8, which is characterized in that further include moisturizing silicagel pad, the moisturizing silicagel pad can Releasably it is arranged on hydrogen-oxygen separation electrolysis unit.

11. the hydrogen-rich cup as described in Claims 1-4 is any, which is characterized in that the hydrogen-oxygen separation electrolysis system includes hydrogen Oxygen separating electrolysis unit and hydrogen-oxygen detach electrolysis unit control system；The hydrogen-oxygen detaches electrolysis unit control system sealed set In hydrogen-oxygen separation electrolysis unit bottom；

The hydrogen-oxygen detaches electrolysis unit control system, including microprocessor, memory, automatic Regulation module and switching circuit, The microprocessor is separately connected memory, automatic Regulation module and switching circuit, the automatic Regulation modular power source input terminal External power supply, the anode of the external hydrogen-oxygen separation electrolysis unit of automatic Regulation modular power source output head anode, the automatic tune The cathode of the external hydrogen-oxygen separation electrolysis unit of die block power output end cathode；

The memory is stored with detaches the preset booting voltage detecting value of electrolysis unit operating voltage according to hydrogen-oxygen, controls voltage Step value and computer executable program, computer executable program in the microcomputer reads memory are simultaneously realized following Control method：

Be switched on voltage detecting step：The supply voltage of external power supply is detected, if the supply voltage is less than booting voltage detecting value, It is stopped and prompts undertension, otherwise, execute next step；

Automatic boosting step：Control automatic Regulation module is stepped up with preset control voltage steps value is input to hydrogen-oxygen separation The voltage of electrolysis unit cathode and anode, until the real work voltage that hydrogen-oxygen detaches electrolysis unit cathode and anode reaches booting Voltage detecting value.

12. hydrogen-rich cup as claimed in claim 11, which is characterized in that the hydrogen-oxygen detaches electrolysis unit control system, also Including sampling comparison circuit, the sampling compares circuit input end and is separately connected automatic Regulation modular power source output head anode and bears Circuit output end connection microprocessor is compared in pole, the sampling, and the sampling comparison circuit obtains hydrogen-oxygen separation electrolysis unit Real work voltage, and it is input to microprocessor, the microprocessor executes computer executable program and realizes following controlling party Method：

Automatic Regulation step：The size for comparing the real work voltage and the booting voltage detecting value, if real work Voltage is more than the booting voltage detecting value, and controlling the automatic Regulation module reduces the electricity that output detaches electrolysis unit to hydrogen-oxygen Pressure, until the real work voltage is equal to the booting voltage detecting value, if real work voltage is less than booting electricity Detected value is pressed, the automatic Regulation module is controlled and increases the voltage that output detaches electrolysis unit to hydrogen-oxygen, until the practical work Make voltage and is equal to the booting voltage detecting value.

13. hydrogen-rich cup as claimed in claim 12, which is characterized in that the hydrogen-oxygen separation electrolysis unit control system is also wrapped Management of charging and discharging module and accumulator are included, the automatic Regulation module is described by the management of charging and discharging module external power supply Accumulator is separately connected external power supply and automatic Regulation module, the management of charging and discharging module by the management of charging and discharging module In external power supply, for the capacitance adjustment charging voltage and charging current according to accumulator；The management of charging and discharging module exists When storage battery power supply, for carrying out overcurrent or overload protection to accumulator.

14. hydrogen-rich cup as claimed in claim 13, which is characterized in that the hydrogen-oxygen separation electrolysis unit control system is also wrapped Light display apparatus is included, the light display apparatus is connect with microprocessor, and the light display apparatus is for receiving microprocessor The signal of device, and display working condition, the working condition include booting detection, automatic boosting, automatic Regulation or power supply electricity Pressure is insufficient.