CN109957812A - A kind of electrochemistry producing equipment of ultra-pure hydrogen and ultrapure oxygen - Google Patents
A kind of electrochemistry producing equipment of ultra-pure hydrogen and ultrapure oxygen Download PDFInfo
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- CN109957812A CN109957812A CN201910401657.1A CN201910401657A CN109957812A CN 109957812 A CN109957812 A CN 109957812A CN 201910401657 A CN201910401657 A CN 201910401657A CN 109957812 A CN109957812 A CN 109957812A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
The invention discloses the electrochemistry producing equipments of a kind of ultra-pure hydrogen and ultrapure oxygen, including shell, and it is mounted on the oxygen water tank with strainer in housing cavity, hydrogen filtration water tank, filter device, power supply mould group, the integrated circuit die group being connect with power supply mould group, the hydrogen fuel cell being connect respectively with integrated circuit die group, water pump, indicator light, control panel, speaker and fan.This system carries out filters to the water body for entering hydrogen fuel cell using the filter core of reverse osmosis ultrapure water filtering, it can ensure the purity for participating in the water of electrochemical reaction, combined type water tank increases the contact area of gas and water vapour and cabinet, improve the cooling efficiency of gas and water vapour, the hydrogen and oxygen for reducing the humidity of output gas and the fluctuating range of output gas, and exporting are hyperpure gas.
Description
Technical field
The present invention relates to the electrochemistry producing equipments of a kind of ultra-pure hydrogen and ultrapure oxygen, for passing through electrochemical reaction
Mode manufactures superpurity hydrogen, belongs to electrochemical hydrogen manufacturing.
Background technique
Hydrogen is a kind of natural, since the hydrogen molecule in hydrogen-rich water is very subtle, the quick permeation cell of energy, in
It with " Health Killer " oxygen radical of human body, ultimately produces water and excludes in vitro, and hydrogen has with more than vitamin C, Hu Luo
Polyphenoils known to all mankind such as fore-telling, lecithin, to each caused by the free radicals such as allergic dermatitis, constipation, hypertension, cancer
Class symptom has powerful preventive and therapeutic effect, often inhales Hydrogen Energy and boosts metabolism, makes each cell that can automatically keep health
State, removing body rust, delays senescence, so household suction hydrogen machine is more and more popular with consumers.
Currently, household, which inhales hydrogen machine, generallys use electrochemical method manufacture hydrogen, by metal positive-pole and cathode with as in water,
It is electrolyzed the water by being powered on to metal electrode, to realize producing for hydrogen.But there are following technologies for above equipment
Problem: 1, the hydrogen and oxygen of electrolysis refining can not be kept completely separate, and causing hydrogen with oxygen, there are a certain proportion of mixing phenomenas；
2, positive and negative two electrodes the phenomenon that there are electrode disintegrations during electrolysis water, the metallics being disintegrated is mixed in output
The hydrogen or oxygen and water body containing certain humidity in；3, hydrogen, oxygen and the water body memory being electrolysed of electrolysis refining
In the heavy metal substance for continuing to increase concentration；4, hydrogen and oxygen carry a large amount of steam secretly during exporting, and use for a long time
Easily there is the case where pipeline ponding, the case where ponding enters consumer's nasal cavity by air shooter line then occurs, easily offset
Expense person causes not accommodate or even cause safety accident.
So the equipment for urgently developing a kind of water electrolysis hydrogen making is used with producing ultra-pure hydrogen for consumer.
Summary of the invention
For above-mentioned existing technical problem, the electrochemistry that the present invention provides a kind of ultra-pure hydrogen and ultrapure oxygen, which is produced, to be set
It is standby, the higher hydrogen of purity and oxygen are produced in a manner of through electrochemical reaction.
To achieve the above object, the present invention provides the electrochemistry producing equipment of a kind of ultra-pure hydrogen and ultrapure oxygen, including
Shell, and the oxygen water tank with strainer being mounted in housing cavity, hydrogen filtration water tank, filter device, power supply mould group, with power supply
The integrated circuit die group of mould group connection, the hydrogen fuel cell being connect respectively with integrated circuit die group, water pump, control panel and wind
Fan；
The electrolytic cell inner cavity of the hydrogen fuel cell is divided into anode chamber and cathode chamber, and proton point by proton seperation film
It is successively arranged Catalytic Layer and diffusion layer respectively from film two sides；It is equipped with the anode that can be powered in anode chamber, and is offered on cell wall
Oxygen and moisture outlet；It is equipped with the cathode that can be powered in cathode chamber, and offers water inlet, hydrogen and steam on cell wall and goes out
Mouthful；
The tank upper cover of the oxygen water tank with strainer is equipped with inlet opening and out oxygen outlet, and water tank bottom surface is equipped with into oxygen
With water vapor hole and apopore；The water tank bottom surface of the hydrogen filtration water tank is equipped with into hydrogen and water vapor hole, and tank upper cover is set
There is hydrogen blistering out；
Water injection pipe connects the inlet opening of oxygen water tank with strainer, the apopore of oxygen water tank with strainer by delivery pipe through water pump,
Filter device connects the water inlet of cathode chamber, and the hydrogen of cathode chamber connect hydrogen filtration water tank by delivery pipe with moisture outlet
Into hydrogen and water vapor hole, the hydrogen blistering that goes out of hydrogen filtration water tank connects hydrogen gas outlet by appendix, the oxygen of anode chamber and
By delivery pipe connection oxygen water tank with strainer into oxygen and water vapor hole, the oxygen outlet that goes out of oxygen water tank with strainer passes through moisture outlet
Appendix connects oxygen delivery outlet.
In above-mentioned technical proposal, firstly, carrying out filters, Neng Goubao to the water body for entering hydrogen fuel cell using filter core
Barrier participates in the purity of the water of electrochemical reaction, reduces the impurity accumulating amount in electrochemical reaction process, and final is this system
The cumulative activation service life is long and steady operation provides technical guarantee.
Secondly, hydrogen made from hydrogen fuel cell and oxygen are first back to hydrogen filtration water tank respectively and oxygen crosses drainage
Case, then output outward, on the one hand, using the Physical temperature-lowering ability of two water tank with strainer and system water supply return line, do not increasing
In the case where adding material cost, the temperature of hydrogen and oxygen is quickly reduced；On the other hand, it is with the water in two water tank with strainer
The non-gaseous material for the denier that " hydrogen fuel cell " is discharged in electrochemical reaction process is stranded in water body, makes by medium
It obtains and enters in the gas that reaction generates without the substance being harmful to the human body, while improving the purity of hydrogen and oxygen, hydrogen obtained
Gas and oxygen are superpurity gas (purity >=99.999%).
Furthermore all components are placed in system casing, the miniaturization for producing ultra-pure hydrogen and breathing equipment is realized,
Facilitate the operation and carrying of user.
In addition, being set using voltage sample, current sample, TDS water quality monitoring, the integrated circuit of temperature monitoring and control system
Meter, the performance state of system important component can be grasped in real time, improve the maintenance efficiency of product, reduce after-sales service at
This.
Further, the oxygen, the water tank of hydrogen filtration water tank and tank upper cover are separately connected as Compound Water cabinet
With composite water tank upper cover, combined type water tank is formed；The internal box wall of the Compound Water cabinet is equipped with the anti-wave column protruded to outside wall, should
The inner bottom surface of Compound Water cabinet is equipped with the watertight compartment of connection oxygen water tank with strainer body, hydrogen filtration water tank, and watertight compartment is equipped with
Drainage hole；The composite water tank upper cover bottom surface is equipped with the anti-wave fin of condensate, oxygen outlet and is respectively provided with a protrusion at hydrogen blistering out out
The anti-wave storehouse of top condensate in top surface.
In above-mentioned technical proposal, large area fold and projection design are used inside combined type water tank, improves combined type
Collection of the water tank to contained humidity in gas, the moisture content and the fluctuation during gas submitting for reducing output gas,
Improve user's comforts of use.Combined type water tank warehouse bottom realizes hydrogen mistake using " watertight compartment " design of connection
The peak use rate of water body in two cabinets of water filtering tank and oxygen water tank with strainer, and pass through the intracorporal gas of above-mentioned two case
Absolutely barrier.
Further, the invention also includes collecting box, which includes the box body that catchments, and catchment box cover, is mounted on and catchments
The collecting box Jiao Gai of box cover top surface, and it is respectively communicated with the collecting box air inlet pipe of two sides of box cover of catchmenting and collecting box goes out
Tracheae；The described box cover inner bottom surface that catchments equipped with collecting box condensate grid, the box cover that catchments, the box body that catchments inner cavity in
It is respectively equipped with the upper and lower pressurization air guide storehouse that can be docked, and is pressurized air guide storehouse, lower pressurization air guide storehouse in the connection of collecting box air inlet pipe
Side wall offers the collecting box venthole being connected to box cavity of catchmenting；The hydrogen filtration water tank goes out hydrogen blistering connection collection
Water box air inlet pipe, collecting box escape pipe connect hydrogen gas outlet.
In above-mentioned technical proposal, goes out hydrogen blistering rear end setting " collecting box " in hydrogen filtration water tank, promoted in gas
The collection of contained humidity reduces the moisture content of output gas, improves user's comforts of use.And oxygen do not need into
The filtering of row collecting box, because the volume ratio of hydrogen and oxygen that the water of unit volume generates after electrochemical reaction is about 2:1,
And the volume of oxygen water tank with strainer is much larger than hydrogen filtration water tank, the water content of exported oxygen, which has met, uses needs.
Further, the filter device uses water purification catridge, such as RO reverse osmosis water purification machine filter core.
In above-mentioned technical proposal, in water supply loop use nanofiltration ability filter core, by the substance in system into
Row filters, with the high-purity of the lasting water for guaranteeing to enter in hydrogen fuel cell, to reduce water mineral to electrochemistry
Reaction unit adheres to brought working efficiency and the adverse effect in terms of the service life for a long time, and electrochemical reaction appts are easy to
Maintenance and part replacement.
Further, the invention also includes inclination sensors, connect respectively with integrated circuit die group and power supply mould group, for examining
Surveying body, whether level is put in use, and inclination sensor will be triggered when occurring the inclination of larger angle such as body,
System carries out forcing the emergency processing of lower electricity automatically.
It in above-mentioned technical proposal, is designed using the integrated control of device inclined power-off protection, ensures equipment at big inclination angle
System carries out forcing the emergency processing of lower electricity automatically in the state that degree falls partially, improves the safeguard protection to equipment and user.
Further, it the invention also includes fuel cell leading portion liquid level sensor, is connect with integrated circuit die group, is mounted on hydrogen
In the outer well surface of fuel cell electrolytic cell.
In above-mentioned technical proposal, using trifocal non-contact type water level transducer, to the water entry front end of hydrogen fuel cell
Real-time water level monitoring and prompt are carried out, has prevented hydrogen fuel cell and has worked on power in the case where not obtaining water input, kept away
The generation of dry combustion method phenomenon is exempted from.
Further, the invention also includes high point non-contact type water level transducers, low spot non-contact type water level transducer, with collection
It connects, is mounted on combined type water tank external box wall at circuit module.
In above-mentioned technical proposal, using trifocal non-contact type water level transducer, respectively to the height of combined type cistern water level
Point, low spot carry out real-time water level monitoring and prompt, are warned with the spikes/low- points critical groundwater table to water level in cabinet.
Further, the invention also includes temperature sensors, connect with integrated circuit die group, are mounted on water pump and filter device
In the delivery pipe of connection.
In above-mentioned technical proposal, using temperature sensing digital integration control design case, real-time temperature is tried to system and is protected
Shield monitoring and prompt avoid forced working of the system in the case where crossing low temperature and excessive temperature, have ensured system and the peace of user
Entirely.
Further, it the invention also includes two TDS water quality sensors, connect, is separately mounted to integrated circuit die group
In the delivery pipe that filter device is connected with anode chamber's water inlet and in delivery pipe that water pump is connect with oxygen water tank with strainer.
In above-mentioned technical proposal, digital integration control design case is sensed using water quality monitoring, to the multiterminal water quality of equipment into
Row real-time monitoring and prompt increase the intuitive of system maintenance, reduce because long-term poor water quality brings damage to system
Probability.
Further, the invention also includes baroceptors, connect with integrated circuit die group, are mounted on hydrogen filtration water tank
In the appendix that hydrogen blistering is connect with collecting box out.
In above-mentioned technical proposal, digital integration control design case is sensed using Pressure monitoring, to equipment air shooter line
Real-time gas pressure monitoring is carried out, real-time guard is carried out to system in appendix abnormal air-pressure, to realize to setting
Standby and user safeguard protection.
Compared with prior art, the technical advantages of the present invention are that:
1, filters, Neng Goubao are carried out to the water body for entering hydrogen fuel cell using the filter core of reverse osmosis ultrapure water filtering
Barrier participates in the purity of the water of electrochemical reaction, reduces the impurity accumulating amount in electrochemical reaction process, is the accumulative work of this system
Make service life length and steady operation provides technical guarantee.
2, hydrogen and oxygen obtained, which can be realized, is completely exfoliated, and independent hydrogen filtration water tank and oxygen mistake is respectively adopted
Water filtering tank is collected, and remaining using the metallics that water body strike-through reduces output gas again so that the hydrogen of output and
Oxygen is hyperpure gas, and purity reaches >=99.999%.
3, combined type water tank increases the contact area of gas and water vapour and cabinet, improves the cooling efficiency of gas and water vapour, drop
The low humidity of output gas and the fluctuating range of output gas.
4, using integrated circuit and Control System Design, the performance state of system important component can be grasped in real time, promoted
The maintenance efficiency of product, reduces after-sales service cost.
5, the cumulative activation service life is long, can rated power cumulative activation duration much larger than carbon, titanium, iron be electrode fill
It sets.
Detailed description of the invention
Fig. 1 is structural exploded view one of the invention；
Fig. 2 is structural exploded view two of the invention；
Fig. 3 is the principle of the present invention block diagram；
Fig. 4 is the reaction principle figure of hydrogen fuel cell in the present invention；
Fig. 5 is the structural schematic diagram of hydrogen fuel cell in the present invention；
Fig. 6 is the structural schematic diagram of composite water tank in the present invention；
Fig. 7 is the structural exploded view of composite water tank in the present invention；
Fig. 8 is the structural schematic diagram of Compound Water cabinet in the present invention；
Fig. 9 is the structural schematic diagram of collecting box in the present invention；
Figure 10 is the structural exploded view one of collecting box in the present invention；
Figure 11 is the structural exploded view two of collecting box in the present invention；
In figure: 1, water filling warehouse lid, 2, left side shell, 3, water sink, 4, center, 5, front decoration piece, 6, front panel support, 7,
Sensor integration control circuit board, 8, falling sensor, 9, integration module, 10, baroceptor, 11, digital display tube, 12,
Integrated circuit die group, 13, hydrogen delivery tube one, 14, front panel eyeglass, 15, secondary radiator fan, 16, collecting box, 17, indicator light
Integrated circuit, 18, DC-DC power module, 19, speaker, 20, collecting box door, 21, rear shell, 22, main radiator fan, 23, power supply
Socket, 24, power switch, 25, sump lid Hall switch magnet, 26, sump lid Hall sensor, 27, rear door, 28, rear storehouse
Door Hall switch magnet, 29, rear door Hall sensor, 30, combined type water tank, 31, high point non-contact type water level transducer,
32, water tank is to water filter water-supply-pipe, 33, low spot non-contact type water level transducer, 34, TDS water quality sensor one, and 35, temperature passes
Sensor, 36, water pump, 37, drainpipe, 38, AC-DC power module, 39, right side shell, 40, water injection pipe, 41, hydrogen delivery tube
Two, 42, hydrogen aqueous vapor delivery pipe, 43, the water pipe of filter core to electrolytic cell, 44, fuel cell leading portion liquid level sensor, 45, hydrogen fuel
Battery, 46, filter device, 47, TDS water quality sensor two, 301, go out hydrogen blistering, 302, inlet opening, 303, go out oxygen outlet, 304,
The anti-wave storehouse of top condensate, 305, high water level liquid level sensor position, 306, low water level liquid level sensor position, 307, on composite water tank
Lid, 308, the anti-wave fin of condensate, 309, composite sealing ring, 3010, Compound Water cabinet, 3011 into hydrogen and water vapor hole, and 3012, go out
Water hole, 3013, into oxygen and water vapor hole, 3014, drainage hole, 3015, watertight compartment, 3016, anti-wave column, 161, collecting box Jiao Gai,
162, catchment box cover, and 163, catchment box body, 164, collecting box escape pipe, 165, collecting box condensate grid, 166, collecting box air inlet
Pipe, 1671, upper pressurization air guide storehouse, 1672, lower pressurization air guide storehouse, 168, collecting box venthole.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
As shown in Figs 1-4, the electrochemistry producing equipment of ultra-pure hydrogen of the present invention and ultrapure oxygen, including shell, Yi Jian
Oxygen water tank with strainer in housing cavity, hydrogen filtration water tank, filter device 46, power supply mould group are connect with power supply mould group
Integrated circuit die group 12, the hydrogen fuel cell 45 being connect respectively with integrated circuit die group 12, water pump 36, each sensor, control
Panel, fan, speaker 19 and indicator light processed.The technical requirements of main component are described below.
As shown in figure 5, the electrolytic cell inner cavity of hydrogen fuel cell 45 of the present invention is divided into anode chamber and yin by proton seperation film
Pole room, and proton seperation film two sides are successively arranged Catalytic Layer and diffusion layer respectively；The anode that can be powered is equipped in anode chamber, and
Water inlet, oxygen and moisture outlet are offered on cell wall；It is equipped with the cathode that can be powered in cathode chamber, and offers hydrogen on cell wall
Gas and moisture outlet.The chemical equation of hydrogen fuel cell 45 are as follows:It adopts with inertia such as palladium, platinum, rutheniums
The compound of metal is catalyst, in conjunction with proton exchange membrane and electrode, carries out electrochemistry hydrogen and the oxygen reaction of water.And
And the inert nature of the catalysis material of 45 electrochemical reaction silicol process of this hydrogen fuel cell use is better than ordinary electrode electrolytic hydrogen production
The inertia of the classes electrode materials such as copper, stainless steel, titanium, the carbon that method uses is the cumulative activation service life length and steady operation of this system
Provide technical guarantee.
As shown in Figure 3,4, oxygen water tank with strainer of the invention, hydrogen filtration water tank is using " low spot air inlet, high point exhaust "
" stack effect " be design concept.Specifically, the tank upper cover of oxygen water tank with strainer is equipped with inlet opening 302 and out oxygen outlet
303, water tank bottom surface is equipped with into oxygen and water vapor hole 3013 and apopore 3012；The water tank bottom surface of hydrogen filtration water tank is equipped with
Into hydrogen and water vapor hole 3011, tank upper cover is equipped with hydrogen blistering 301.Also, water inlet of the water injection pipe 40 through oxygen water tank with strainer
Hole 302 and apopore 3012, water pump 36,46 jointed anode room of filter device water inlet；The hydrogen and moisture outlet of anode chamber
By delivery pipe connection hydrogen filtration water tank into hydrogen and water vapor hole 3011, hydrogen blistering 301 is by appendix through collecting box out
16 connection hydrogen gas outlets, improve the collection to contained humidity in hydrogen, reduce the moisture content of output gas；Cathode chamber
Oxygen and moisture outlet by delivery pipe connect oxygen water tank with strainer into oxygen and water vapor hole 3013, oxygen outlet 303 is logical out
Cross appendix connection oxygen delivery outlet.
As shown in figs 6-8, in another embodiment of the present invention, both oxygen water tank with strainer, hydrogen filtration water tank are connected as
One, i.e. the water tank, tank upper cover and sealing ring of the two, which are separately connected, to be integrated, and forms combined type water tank 30.The combined type
Water tank 30 includes Compound Water cabinet 3010, composite water tank upper cover 307 and installation composite sealing ring 309 therebetween, and
3010 inner cavity of Compound Water cabinet is divided into two cavities by an intermediate bulkhead, realizes oxygen water tank with strainer body and hydrogen mistake
The space of drainage cabinet and the independence of function.As shown in fig. 6, the composite water tank upper cover 307 is used as the top surface of oxygen water tank with strainer
Oxygen outlet 303 is taken out of equipped with an inlet opening 302, one and protrudes the anti-wave storehouse 304 of top condensate of top surface, on the composite water tank
The top surface that lid 307 is used as hydrogen filtration water tank is equipped with one and takes hydrogen blistering 301 out of and protrude the anti-wave storehouse of top condensate of top surface
304.As shown in fig. 7,307 bottom surface of composite water tank upper cover has been covered with the anti-wave fin 308 of condensate.As shown in Figure 7,8, the Compound Water
The bottom surface that cabinet 3010 is used as oxygen water tank with strainer body is equipped with into oxygen and water vapor hole 3013 and apopore 3012, the combined-type water
The bottom surface that case 30 is used as hydrogen filtration water tank is equipped with into hydrogen and water vapor hole 3011 and drainage hole 3014.Compound Water cabinet 3010
Inner bottom surface be equipped with connection oxygen water tank with strainer body and hydrogen filtration water tank watertight compartment 3015, and watertight compartment 3015 be equipped with row
Water hole 3014.On the internal box wall of Compound Water cabinet 3010, the inner sidewall in four faces including water tank and intermediate bulkhead two sidewalls
It is equipped with the anti-wave column 3016 of multiple semi-cylindricals protruded to outside wall.As shown in Figure 6,7, the outer container of the Compound Water cabinet 3010
Wall is equipped with low water level liquid level sensor position 306 and high water level liquid level sensor position 305.
As shown in figure 4, filter device 46 of the invention, using RO filter core, direction indicated by arrow is water and gas in figure
The direction of motion of body is pressurized by water pump 36 to after the water filling of oxygen water tank with strainer and promotes liquid from oxygen water tank with strainer through filter core
It is electrochemically reacted into 45 electrolytic cell of hydrogen fuel cell, the gas of generation and the water for reaction are back to oxygen and cross drainage
Case completes filtering of the filter core to water in system using the effect lasts of water pump 36.The present invention is filtered using reverse osmosis ultrapure water
Filter core to enter hydrogen fuel cell 45 water body carry out filters, have the effect that on the one hand, ensured participation electrification
The purity of the water of reaction is learned, so that the water into electrolytic cell is far below national standard 50TDS, degree of purity is much higher than national standard, and is
Water in system remains high purity；On the other hand, since the height of water quality purity directly affects 45 electrification of hydrogen fuel cell
The size for learning impurity deposition in water body in reaction hydrogen manufacturing journey, ensures that the purity for participating in the water of electrochemical reaction just can reduce electricity
Impurity accumulating amount in chemical reaction process, and then ensured the continual and steady work of electrolytic cell, it is final for the accumulative of this system
Long working life and steady operation provide technical guarantee.
As shown in figs. 9-11, collecting box 16 includes the box body 163 that catchments, and catchment box cover 162, is mounted on the box cover that catchments
The collecting box glue lid 161 of 162 top surfaces, and it is respectively communicated with 166 sum aggregate of collecting box air inlet pipe of 162 two sides of box cover of catchmenting
Water box escape pipe 164；Described 162 inner bottom surface of box cover that catchments equipped with collecting box condensate grid 165, the box cover that catchments,
Catchment box body 163 inner cavity in be respectively equipped with the upper and lower pressurization air guide storehouse 1671,1672 that can be docked, and collecting box air inlet pipe
It is pressurized air guide storehouse 1671 in 166 connections, lower pressurization 1672 side wall of air guide storehouse is offered to catchment with what 163 inner cavity of box body of catchmenting was connected to
Box venthole 168；The hydrogen blistering 301 that goes out of the hydrogen filtration water tank connects collecting box air inlet pipe 166, collecting box escape pipe
164 connection hydrogen gas outlets.
As shown in Figs 1-4, sensor of the invention for monitor body put smoothness, water level, water quality, temperature, air pressure,
Warehouse is opening/closing, filter element life state, 45 service life state of hydrogen fuel cell etc., and 1 including being separately connected integrated circuit board 9 is inclined
Oblique sensor, 3 liquid level sensors, 2 TDS sensors, 1 temperature sensor, 35,1 baroceptors, 1 sump lid are suddenly
Door Hall sensor 29 after that sensor 26,1.Wherein: inclination sensor respectively with integrated circuit die group 12 and power supply mould
Group connection ensures the equipment emergency processing electric in the case where the big tilt angle system of falling in the state of partially is forced automatically.Combined type
High point non-contact type water level transducer 31, low spot non-contact type water level transducer 33 are installed, by integrated electricity on 30 external box wall of water tank
Road mould group 12 controls, and carries out real-time water level monitoring and prompt to the high point of 30 water level of combined type water tank, low spot respectively.Hydrogen fuel
Fuel cell leading portion liquid level sensor is installed in the outer well surface of 45 electrolytic cell of battery, is controlled by integrated circuit die group 12, hydrogen is fired
Expect that the water entry front end of battery 45 carries out real-time water level monitoring and prompt.Filter device 46 is connected defeated with anode chamber's water inlet
TDS water quality sensor one, 2 34,47 is installed respectively in water pipe and in water-supply-pipe that water pump 36 is connect with oxygen water tank with strainer,
It is controlled by integrated circuit die group 12, real-time monitoring and prompt is carried out to the multiterminal water quality of equipment.Water pump 36 and filter device 46 connect
Mounting temperature sensor 35 in the water-supply-pipe connect is controlled by integrated circuit die group 12, is tried real-time temperature protection to system and is supervised
It surveys and prompts.Baroceptor is installed in going out for hydrogen filtration water tank in the appendix that hydrogen blistering 301 is connect with collecting box 16, collected
It is controlled at circuit module 12, real-time gas pressure monitoring is carried out to equipment air shooter line.Sump lid is installed suddenly in casing
Your sensor 26, rear door Hall sensor 29, be respectively used to detection casing sump lid and rear door 27 it is opening/closing.
Control panel of the invention includes digital display tube, and uses Capacitance-type built-in non-direct contact button design,
The water proof and dust proof of product is improved, asking for due to using mechanical switch service lifes such as bring mechanical aging is avoided
Topic, sense that the user experience is improved.Indicator light of the invention includes indicator light integrated circuit 17, is located among control panel, is used for
Cooperation control panel indicating equipment is presently in working condition.Control panel is with the following functions: 1, water quality prompts: this equipment pair
The water quality of injected water has quality requirements, and the TDS value for entering water as noted is higher than design standard value, and red number will be presented in control panel
Value display；2, using the time: the accumulative residue using under time and " timing " mode of this booting of display equipment uses the time；
3, timing plus key: equipment is under " timing " mode to the required increase using the time, and every touch-control, which once increases, to be made
Used time a length of 30 minutes；4, timing subtracts key: equipment is under " timing " mode to the required reduction using the time, often
Touch-control once reduces 30 minutes a length of when use；5, beginning/stop key: touch-control primary equipment enters hydrogen and generates mode or equipment
Stop hydrogen-producing mode；6, timing key: touch-control primary equipment enters or exits " timing " mode；7, filter core prompts reset key: equipment
After carrying out abnormal warning to filter filter effect, cancel the reset key warned extremely manually, equipment it is each restart after again
Carry out abnormal prompt.
Fan of the invention includes main radiator fan 22, secondary radiator fan 15, and forms an active forced-ventilated heat heat dissipation
Air duct, the temperature for being conducive to equipment are adjusted.Wherein: the Major Function of main radiator fan 22 is to arrange all heats of internal system
Out, the Major Function of secondary radiator fan 15 is to the biggish hydrogen fuel cell of internal system calorific value 45, DC-DC power module
18, AC-DC power supply and the more combined type water tank 30 of heat accumulation carry out auxiliary fan heat.Also, major and minor radiator fan 22,15
Inlet end uses built-in dust filtering device, is conducive to that the cleannes of internal body and user is kept voluntarily quickly to clean.
The generating unit that speaker 19 of the invention is prompted using individual cavity as system audio, the audio content played
It is distorted that small, boosting is big, high sensitivity, sense of hearing are more preferable, the user experience is improved and product technology sense.
When this equipment is assembled, as shown in Figs. 1-2, left side shell 2, center 4, right side shell 39 and rear shell 21 assemble forming apparatus
Shell.The top surface of center 4 opens up water sink 3, and 3 upper cover of water sink is equipped with openable and closable water filling warehouse lid 1, fills the water 1 medial surface of warehouse lid
Sump lid Hall switch magnet 25 is installed, 4 medial surface of center corresponding with water filling 1 position of warehouse lid is equipped with sump lid Hall and passes
Sensor 26 carries out water filling storehouse by sensing digital integration control design case using " Hall sensor " to movable water filling warehouse lid 1
Lid 1 is opened and the monitoring of closed state, to carry out the automatic control of function to system, realizes that the safety to equipment and user is protected
Shield.4 front upper of center is equipped with front decoration piece 5, and collecting box door 20 is installed in lower part, and front panel support 6 is installed at middle part, and preceding
Digital display tube 11, the indicator light integrated circuit 17 that installation is connect with integrated control circuit board 7 in panel rack 6, upper cover dress
Front panel eyeglass 14.
4 inner cavity of center be equipped with combined type water tank 30, water pump 36, filter device 46, hydrogen fuel cell 45, collecting box 16,
Speaker 19, main radiator fan 22, secondary radiator fan 15, DC-DC power module 18, AC-DC power module 38, integrated circuit die group
12, sensor integration control circuit board 7, integration module 9 and each sensor.Water sink 3 is connected compound by water injection pipe 40
The apopore 3012 of the top surface inlet opening 302 of formula water tank 30, combined type water tank 30 successively connects through water tank to water filter water-supply-pipe 32
Water pump 36 and filter device 46, filter device 46 connect hydrogen fuel cell 45, hydrogen fuel through the water pipe 43 of filter core to electrolytic cell
For battery 45 through the connection combined type water tank 30 of hydrogen aqueous vapor delivery pipe 42 into hydrogen and water vapor hole 3011, combined type water tank 30 goes out hydrogen
Stomata 301 connects collecting box 16 through hydrogen delivery tube one, 2 13,41, and collecting box 16 connects hydrogen gas outlet, combined type water tank 30
Drainage hole 3014 connect drainpipe 37, drainage stopper, and collecting box 16 and 20 position of collecting box door are installed on drainpipe 37
Corresponding, drainpipe 37 is corresponding with rear 27 position of door, facilitates loading or unloading operation.
Falling sensor 8 is mounted in sensor integration control circuit board 7, and sensor integration control circuit board 7 is mounted on
The corresponding of integration module 9 is formulated on region.High point non-contact type water level transducer 31, low spot non-contact type water level transducer 33
On sensor integration control panel 7, collection terminal is located at the height on the external box wall of combined type water tank 30 for control circuit and software
Water level liquid level sensor position, low water level liquid level sensor position 305,306.The control terminal electricity of fuel cell leading portion liquid level sensor 44
On sensor integration control panel 7, collection terminal is mounted in the outer well surface of 45 electrolytic cell of hydrogen fuel cell for road and software, is fired to hydrogen
Expect that the water entry front end of battery 45 carries out real-time water level monitoring and prompt.The control terminal of TDS water quality sensor one, 2 34,47
Circuit and software are on sensor integration control panel 7, and collection terminal is located at the water inlet front end and water outlet rear end of filter core, for supervising
Survey the matter situation and the water quality situation after filter element filtering of water in combined type water tank 30.35 collection terminal of temperature sensor is mounted on water
In case to water filter water-supply-pipe 32, real-time temperature protection is tried to system and monitors and prompts.The control terminal of baroceptor 10
On sensor integration control panel 7, collection terminal is located between hydrogen delivery tube one, 2 13,41 for circuit and software.
21 top of rear shell offers the heat dissipation wind channel of corresponding main radiator fan 22, is equipped with power outlet 23 and power switch
24, AC-DC power module 38 connects power outlet 23 through power switch 24.21 lower part of rear shell is equipped with openable and closable rear door
27, rear door Hall switch magnet 28 is installed on the medial surface of rear door 27, rear shell 21 corresponding with rear 27 position of door
Medial surface is equipped with rear door Hall sensor 29, with the unlatching of door 27 after monitoring and closed state, realizes to equipment and use
The safeguard protection at family.
When the invention works, as shown in figure 4, inlet opening 302 and apopore 3012, water pump of the water through oxygen water tank with strainer
36, filter device 46, anode chamber water inlet enter the anode chamber of hydrogen fuel cell 45, carry out the electrochemistry hydrogen and oxygen of water
Solid/liquid/gas reactions.React the obtained hydrogen of hydrogen and steam through cathode chamber and moisture outlet, hydrogen filtration water tank into hydrogen and water
Steam vent 3011 is filtered water removal into hydrogen filtration water tank, filters resulting hydrogen from hydrogen filtration water tank and goes out hydrogen blistering
301 remove water again into collecting box 16, finally export high-purity hydrogen from hydrogen gas outlet.Oxygen and steam obtained is reacted to pass through
The oxygen of anode chamber and moisture outlet, oxygen water tank with strainer were carried out into oxygen and the entrance oxygen water tank with strainer of water vapor hole 3013
Water is filtered out, finally exports high-purity oxygen from oxygen delivery outlet, while the water in oxygen water tank with strainer continuously passes through water pump 36, mistake
The anode chamber that device 46 enters hydrogen fuel cell 45 is filtered, electrochemistry hydrogen and the reaction of oxygen of water are continued.Also, this
Each water-supply-pipe is invented using fast connection interface design is drained, is conducive to easy to be quickly clear to system inner storing water and waterline progress
It is clean.
As shown in figure 3, the present invention is using " voltage sample ", the integrated circuit of " current sample " and Control System Design, collection
It is built-in with AD sampling algorithm at circuit board 9, and with DC-DC power module 18 there are signal communication, integrated circuit board 9 is being obtained
After the operating current and voltage status of DC-DC power module 18, the current shape for learning hydrogen fuel cell 45 is calculated through internal algorithm
State realizes the control to hydrogen fuel cell 45 to control DC-DC power module 18.Specifically, pass through adjusting
The mode of front end source current power output realizes that " hydrogen fuel cell 45 " electrochemical hydrogen and oxygen production quantity are stably and controllable.By
Be in material in hydrogen fuel cell 45 it is default, i.e. material resistance characteristic has been preset, in use, electrode due to catalysis
Agent effect can continue aging, physical behavior be internal resistance increase, and the water for participating in electrochemical reaction be through filter core into
The stable ultra-pure water of the impedance value of row contaminant filter, in such circumstances, every consumption 1A electric current can produce about 7.5ml hydrogen peace treaty
The oxygen of 3.75ml, the how much source current amount sizes provided by system for generating hydrogen and oxygen are proportional.This hydrogen fuel
The power supply of battery 45 uses adjustable constant voltage supply, and when hydrogen fuel internal resistance increases, electric current is in steady state,
The stabilization of system hydrogen and oxygen yield is ensured.
Suitable environment requirement of the invention: place: indoor；Power supply: AC220V 50Hz 300W max；Temperature: 5 DEG C -45
℃；Humidity :≤90%；Height above sea level: < 1000m；Injection water quality: pure water or distilled water, user's practical operation step and attention
Item is as follows:
1, it connects power supply: connecting external power supply by plugging ac power cable, pull up rocker type switch to " 1 ", equipment starts work
Make, control panel is shown, fan rotates and 16 blue lamp of collecting box is always on, and simultaneously with booting voice prompting.
2, it adds pure water: pushing the crest water flooding warehouse lid 1 of equipment open, the suitable pure water of filling or steaming in water sink 3
Distilled water.Note: the total capacity of combined type water tank 30 built in this equipment is 1500ml, it is noted that the full water prompt in the injecting process
Sound, and stop continuing to add water after prompt tone sounds, in case extra water overflows.
3, check collecting box 16: collecting box 16 is the device for collecting the steam in use process rich in hydrogen, must be arrived in water level
The water in box is removed before up to 16 maximum value of collecting box.
4, start hydrogen manufacturing: shutting water filling warehouse lid 1 and rear door 27, press red " starting/stopping " key on control panel,
Red colored lamp switchs to blue breath light, below collecting box 16 lamp be also always on by blue switch to breath light, the water after 10S in collecting box 16
Start to generate bubble, equipment hydrogen manufacturing starts work and completes.
5, timing setting: pressing the control panel lower left corner " timing " key, light white lamp, and " starting/stopping " key sends out a warning temporarily
Stop state；Control panel is " 0,002 00 " shown above, i.e., 2 hours (initial value 2H), passes through "+", "-" key 30 minutes every time
Plus-minus setting, then presses " starting/stopping " key starting device, and the time can be with using the time to gradually decrease；It presses " timing ", it is white
Colored lights goes out, and indicates to cancel time setting.
6, it inhales hydrogen operation: plugging nasal tube on the hydrogen gas outlet of collecting box 16, the air entry of nasal tube is inserted into nose
Hole can inhale hydrogen.It please ensure to avoid fire far from open fire when use.
7, drain operation: when needing the water body inside device for transferring, then door 27 after opening is extracted on drainpipe 37
Drainage stopper, wait drain after please turn back to drainage stopper again, in order to avoid influence normal use.
8, filter core is replaced:
8.1, when replacing filter core, door 27 after opening holds filter core lower end and upward 15 ° of lift.Filter core when used for a long time
Surface Contact Temperature be 40 DEG C -50 DEG C, replacement filter core and draining when pay attention to high temperature, prevent from scalding.
8.2, it holds filter core lower end and rotates counterclockwise half-turn, filter core is taken out.Note: filter core has big when taking out
The water of amount is discharged, and must clean out the water of spilling after replacing filter core, to guarantee that equipment works under normal dry environment.It is long
Phase, replacement filter core paid attention to high temperature with when draining, and prevents from scalding in use, the surface Contact Temperature of filter core is 40 DEG C -50 DEG C；
8.3, door 27 after closing: drainpipe 37 and filter core are withdrawn, rear door 27 is gently back closed, is heard
" click " it is light loud when for door bolt fasten sound.
To sum up, the present invention can grasp the performance state of system important component in real time, promote the maintenance efficiency of product, reduce
After-sales service cost, and show using digital content, light prompt, audio prompt comprehensively control prompt design, raising user
Intuitive acquisition and user experience to equipment and equipment working state information.
Claims (10)
1. the electrochemistry producing equipment of a kind of ultra-pure hydrogen and ultrapure oxygen, which is characterized in that including shell, and be mounted on shell
Oxygen water tank with strainer in intracoelomic cavity, hydrogen filtration water tank, filter device, power supply mould group, the integrated electricity being connect with power supply mould group
Road mould group, the hydrogen fuel cell being connect respectively with integrated circuit die group, water pump, control panel and fan；
The electrolytic cell inner cavity of the hydrogen fuel cell is divided into anode chamber and cathode chamber, and proton seperation film by proton seperation film
Two sides are successively arranged Catalytic Layer and diffusion layer respectively；It is equipped with the anode that can be powered in anode chamber, and offers oxygen on cell wall
With moisture outlet；It is equipped with the cathode that can be powered in cathode chamber, and offers water inlet, hydrogen and moisture outlet on cell wall；
The tank upper cover of the oxygen water tank with strainer is equipped with inlet opening and out oxygen outlet, and water tank bottom surface is equipped with into oxygen and water
Steam vent and apopore；The water tank bottom surface of the hydrogen filtration water tank is equipped with into hydrogen and water vapor hole, and tank upper cover is equipped with
Hydrogen blistering；
Water injection pipe connects the inlet opening of oxygen water tank with strainer, and the apopore of oxygen water tank with strainer is by delivery pipe through water pump, filtering
Device connects the water inlet of cathode chamber, the hydrogen of cathode chamber and moisture outlet by delivery pipe connect hydrogen filtration water tank into hydrogen
The hydrogen blistering that goes out of gas and water vapor hole, hydrogen filtration water tank connects hydrogen gas outlet, the oxygen and steam of anode chamber by appendix
By delivery pipe connection oxygen water tank with strainer into oxygen and water vapor hole, the oxygen outlet that goes out of oxygen water tank with strainer passes through gas transmission for outlet
Pipe connects oxygen delivery outlet.
2. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that institute
The water tank and tank upper cover of the oxygen, hydrogen filtration water tank stated are separately connected as Compound Water cabinet and composite water tank upper cover, group
At combined type water tank；The internal box wall of the Compound Water cabinet is equipped with the anti-wave column protruded to outside wall, the interior bottom of the Compound Water cabinet
Face is equipped with the watertight compartment of connection oxygen water tank with strainer body, hydrogen filtration water tank, and watertight compartment is equipped with drainage hole；The composite water tank
Upper cover bottom surface is equipped with the anti-wave fin of condensate, oxygen outlet and is respectively provided with the top condensate that one protrudes from top surface at hydrogen blistering out out and prevents
Wave storehouse.
3. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
Including collecting box, which includes the box body that catchments, and catchment box cover, is mounted on the collecting box Jiao Gai of collecting box upper cover top surface,
And it is respectively communicated with the collecting box air inlet pipe and collecting box escape pipe of two sides of box cover of catchmenting；Described catchments in box cover
Bottom surface be equipped with collecting box condensate grid, the box cover that catchments, the box body that catchments inner cavity in be respectively equipped with can dock it is upper and lower
Be pressurized air guide storehouse, and collecting box air inlet pipe connection on be pressurized air guide storehouse, lower pressurization air guide storehouse side wall offer in collecting box body
The collecting box venthole of chamber connection；The hydrogen blistering that goes out of the hydrogen filtration water tank connects collecting box air inlet pipe, collecting box outlet
Pipe connects hydrogen gas outlet.
4. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that institute
The filter device stated uses water purification catridge.
5. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
Including inclination sensor, it is connect respectively with integrated circuit die group and power supply mould group.
6. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
It including fuel cell leading portion liquid level sensor, is connect with integrated circuit die group, is mounted on the outer well surface of hydrogen fuel cell electrolytic cell
On.
7. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
It including high point non-contact type water level transducer, low spot non-contact type water level transducer, connect, is mounted on multiple with integrated circuit die group
On the external box wall of box-like water tank.
8. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
It including temperature sensor, connect, is mounted in the delivery pipe that water pump is connect with filter device with integrated circuit die group.
9. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that also
It including two TDS water quality sensors, is connect with integrated circuit die group, is separately mounted to filter device and cathode chamber water inlet connects
In the delivery pipe connect and in delivery pipe that water pump is connect with oxygen water tank with strainer.
10. the electrochemistry producing equipment of a kind of ultra-pure hydrogen according to claim 1 and ultrapure oxygen, which is characterized in that
Further include baroceptor, connect with integrated circuit die group, the hydrogen blistering that goes out for being mounted on hydrogen filtration water tank is connect with collecting box
Appendix in.
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