CN108299908A - A kind of heat resistance modified adhesive and preparation method thereof for coating manufacture - Google Patents
A kind of heat resistance modified adhesive and preparation method thereof for coating manufacture Download PDFInfo
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- CN108299908A CN108299908A CN201710630141.5A CN201710630141A CN108299908A CN 108299908 A CN108299908 A CN 108299908A CN 201710630141 A CN201710630141 A CN 201710630141A CN 108299908 A CN108299908 A CN 108299908A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Wood Science & Technology (AREA)
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of heat resistance modified adhesive for coating manufacture, its raw material includes polyurethane, vinylacetate, polyvinyl alcohol, dibutyl phthalate, allyl methacrylate, toluene di-isocyanate(TDI), bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane, hexamethyldisilazane, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder, aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide, silane coupling agent KH 560, heat resistance modified auxiliary agent, heat resistance modified filler and deionized water.The present invention also proposes a kind of preparation method of above-mentioned heat resistance modified adhesive for coating manufacture.The adhesive applications that the present invention is prepared have excellent heat resistance, good combination property in the manufacture of coating.
Description
Technical field
The present invention relates to the technical field of adhesive more particularly to it is a kind of for coating manufacture heat resistance modified adhesive and
Preparation method.
Background technology
Adhesive have cost of material is low, ample supply and prompt delivery, polymerization under atmospheric pressure, production technology and equipment are simple, environmental pollution is small,
The advantages that adhesive strength is high, nontoxic, be widely used in timber processing, furniture construction, packaging material, architectural decoration and leather paper,
The numerous areas such as the bonding of foamed plastics, fiberboard, porous material, in China, yield is only second to urea-formaldehyde resin adhesive, is most heavy
One of emulsion adhesive wanted, with the development of national economy and widening for its application field, dosage will also significantly increase
It is long.Adhesive in the prior art is when for coating preparation, the requirement that heat resistance can not be in actual production, so there is an urgent need for set
A kind of heat resistance modified adhesive manufactured for coating is counted to solve the problems of the prior art.
Invention content
To solve technical problem present in background technology, the present invention proposes a kind of heat resistance modified glue for coating manufacture
Stick and preparation method thereof, the adhesive applications being prepared have excellent heat resistance in the manufacture of coating, comprehensive
It can be good.
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
60-80 parts of ester, 15-25 parts of vinylacetate, 3-9 parts of polyvinyl alcohol, 4-9 parts of dibutyl phthalate, methacrylic acid alkene
2-6 parts of propyl ester, 3-6 parts of toluene di-isocyanate(TDI), 2-5 parts of bismaleimide, 1-4 parts of polybenzimidazoles, polyimides 3-5
Part, 2-6 parts of diformazan diethoxy silane, 3-5 parts of hexamethyldisilazane, 2-5 parts of white carbon, 1-4 parts of cerium oxide, nano metal
2-5 parts of glass putty, 3-5 parts of multi-walled carbon nanotube, 3-5 parts of nano-ceramic powder, 1-4 parts of aluminium nitride, 3-6 parts of nano imvite, thin,tough silk cloud
1-4 parts of female powder, 2-5 parts of aluminium hydroxide, 2-6 parts of aluminium dihydrogen phosphate, 2-5 parts of calcium stearate, 1-4 parts of zinc oxide, zirconium oxide 3-5
Part, 3-9 parts of iron oxide, KH-5603-6 parts of silane coupling agent, it is auxiliary agent 5-15 parts heat resistance modified, filler 8-16 parts heat resistance modified, go
20-40 parts of ionized water.
Preferably, the raw material of heat resistance modified auxiliary agent includes by weight：5-15 parts of absolute ethyl alcohol, methyltriethoxysilane
3-5 parts, 1-4 parts of phenyl triethoxysilane, 2-6 parts of diphenyl silanediol, 3-5 parts of vinyltriethoxysilane, polyethers two
First alcohol 2-5 parts, 1-4 parts of isophorone diisocyanate, 3-6 parts of hydroxy silicon oil, 2-6 parts of butyl glycidyl ether, four ethylene five
1-5 parts of amine, 4-8 parts of glacial acetic acid.
Preferably, heat resistance modified auxiliary agent is prepared by following technique：By absolute ethyl alcohol, methyltriethoxysilane, benzene
Ethyl triethoxy silicane alkane, diphenyl silanediol and vinyltriethoxysilane are uniformly mixed, then heating water bath heats up, and are protected
Temperature is cooled to room temperature to obtain material a；Polyether Glycols, isophorone diisocyanate and hydroxy silicon oil are uniformly mixed, risen
Then temperature, heat preservation are added material a, butyl glycidyl ether and tetraethylenepentamine and are uniformly mixed, heat up, heat preservation then cools down,
Glacial acetic acid is added to be uniformly mixed, stirring is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Preferably, heat resistance modified auxiliary agent is prepared by following technique：By absolute ethyl alcohol, methyltriethoxysilane, benzene
Ethyl triethoxy silicane alkane, diphenyl silanediol and vinyltriethoxysilane are uniformly mixed, 45-55 DEG C of heating water bath 1.5-
3.5h then heats to 100-120 DEG C, keeps the temperature 0.5-1.5h, is cooled to room temperature to obtain material a；By polyether Glycols, different Fo Er
Ketone diisocyanate and hydroxy silicon oil are uniformly mixed, and are warming up to 85-95 DEG C, keep the temperature 1.5-3.5h, and material a, butyl is then added
Glycidol ether and tetraethylenepentamine are uniformly mixed, and are warming up to 70-80 DEG C, keep the temperature 2-4h, are then cooled to 50-60 DEG C, are added
Glacial acetic acid is uniformly mixed, and is stirred 0.5-1.5h in 450-650r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Preferably, the raw material of heat resistance modified filler includes by weight：5-15 parts of phenol, 3-9 parts of polyvinyl resin, polysulfones
2-5 parts, 1-4 parts of polyphenylene oxide, 3-6 parts of 2-ethyl-4-methylimidazole, 2-5 parts of cotton fiber, 1-3 parts of carboxymethyl cellulose, nanometer two
2-4 parts of zinc oxide, 3-6 parts of nano silicon dioxide, 2-5 parts of carborundum powder, 1-4 parts of glass powder, Silane coupling reagent KH-570 3-6
Part.
Preferably, heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by phenol and polyethylene tree
Fat is uniformly mixed, and is warming up to 85-95 DEG C, is kept the temperature 1-3h, is cooled to room temperature, and polysulfones is then added and polyphenylene oxide is uniformly mixed, rises
Temperature keeps the temperature 2-4h, is subsequently added into 2-ethyl-4-methylimidazole, cotton fiber, carboxymethyl cellulose, nanometer titanium dioxide to 65-85 DEG C
Zinc, nano silicon dioxide, carborundum powder, glass powder and Silane coupling reagent KH-570 are uniformly mixed, and are warming up to 80-90 DEG C, heat preservation
10-30min is ground after drying, is cooled to room temperature to obtain heat resistance modified filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 80-90 DEG C, 1-2h is kept the temperature, in 650-850r/min
Rotating speed stirs 20-40min, is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
It is warming up to 90-120 DEG C, keeps the temperature 1-3h, then 30-50min is stirred in 450-650r/min rotating speeds, is cooled to room temperature to obtain material
Ⅱ；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 120-140 DEG C, keep the temperature 1-3h,
Then 3-5h is stirred in 2500-3500r/min rotating speeds, is cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
The present invention it is a kind of for coating manufacture heat resistance modified adhesive, raw material include polyurethane, vinylacetate,
Polyvinyl alcohol, dibutyl phthalate, allyl methacrylate, toluene di-isocyanate(TDI), bismaleimide, polyphenyl are simultaneously
Imidazoles, polyimides, diformazan diethoxy silane, hexamethyldisilazane, white carbon, cerium oxide, nano metal glass putty, multi wall
Carbon nanotube, nano-ceramic powder, aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate,
Zinc oxide, zirconium oxide, iron oxide, silane coupling agent KH-560, heat resistance modified auxiliary agent, heat resistance modified filler and deionized water.Its
In, heat resistance modified auxiliary agent is by by absolute ethyl alcohol, methyltriethoxysilane, phenyl triethoxysilane, diphenyl silanediol
It is uniformly mixed with vinyltriethoxysilane, then heating water bath heats up, heat preservation is cooled to room temperature to obtain material a；It will gather
Ether dihydric alcohol, isophorone diisocyanate and hydroxy silicon oil are uniformly mixed, and are heated up, heat preservation, and material a, butyl contracting is then added
Water glycerin ether and tetraethylenepentamine are uniformly mixed, and are heated up, and heat preservation then cools down, and glacial acetic acid is added and is uniformly mixed, stirs, cooling
Heat resistance modified auxiliary agent is obtained to room temperature, applies in the modified adhesive of the present invention, effectively increases the resistance to of invention adhesive
Hot property.Wherein, heat resistance modified filler heats up, protects by the way that under conditions of alkalinity, phenol and polyvinyl resin are uniformly mixed
Temperature is cooled to room temperature, and polysulfones is then added and polyphenylene oxide is uniformly mixed, heats up, heat preservation is subsequently added into 2- ethyl -4- methyl miaows
Azoles, cotton fiber, carboxymethyl cellulose, Nano zinc dioxide impact-resistant, nano silicon dioxide, carborundum powder, glass powder and silane coupling agent
KH-570 is uniformly mixed, and is heated up, and heat preservation grinds after drying, is cooled to room temperature to obtain heat resistance modified filler, applies to the present invention and change
Property adhesive in, coordinate with the heat resistance modified auxiliary agent of addition, further improve the heat resistance of modified adhesive of the present invention.This
The adhesive applications being prepared are invented in the manufacture of coating, there is excellent heat resistance, good combination property.
Specific implementation mode
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent replacement etc. are in this hair
In bright protection domain.
In specific implementation mode, the parts by weight of polyurethane can be 60 parts, 65 parts, 70 parts, 75 parts, 80 parts；Vinyl acetate
The parts by weight of ester can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts；Polyethylene
The parts by weight of alcohol can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of dibutyl phthalate can be 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The parts by weight of allyl methacrylate
It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of toluene di-isocyanate(TDI) can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts；The parts by weight of bismaleimide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Polyphenyl
And the parts by weight of imidazoles can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of polyimides can be 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of diformazan diethoxy silane can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Pregnancy
The parts by weight of base disilazane can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of white carbon can be 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of cerium oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts；The parts by weight of nano metal glass putty can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Multi-walled carbon nanotube
Parts by weight can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of nano-ceramic powder can be 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts；The parts by weight of aluminium nitride can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Nano imvite
Parts by weight can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sericite in powder can be 1 part, 1.5
Part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of aluminium hydroxide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts；The parts by weight of aluminium dihydrogen phosphate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of calcium stearate can be 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of zinc oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts；The parts by weight of zirconium oxide can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of iron oxide can be 3 parts, 4
Part, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of silane coupling agent KH-560 can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts,
5.5 parts, 6 parts；The parts by weight of heat resistance modified auxiliary agent can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts,
14 parts, 15 parts；The parts by weight of heat resistance modified filler can be 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16
Part；The parts by weight of deionized water can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts.
Embodiment 1
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
70 parts of ester, 20 parts of vinylacetate, 6 parts of polyvinyl alcohol, 6.5 parts of dibutyl phthalate, 4 parts of allyl methacrylate,
4.5 parts of toluene di-isocyanate(TDI), 3.5 parts of bismaleimide, 2.5 parts of polybenzimidazoles, 4 parts of polyimides, diformazan diethoxy
4 parts of base silane, 4 parts of hexamethyldisilazane, 3.5 parts of white carbon, 2.5 parts of cerium oxide, 3.5 parts of nano metal glass putty, multi wall carbon
4 parts of nanotube, 4 parts of nano-ceramic powder, 2.5 parts of aluminium nitride, 4.5 parts of nano imvite, 2.5 parts of sericite in powder, aluminium hydroxide 3.5
Part, 4 parts of aluminium dihydrogen phosphate, 3.5 parts of calcium stearate, 2.5 parts of zinc oxide, 4 parts of zirconium oxide, 6 parts of iron oxide, silane coupling agent KH-
5604.5 parts, 10 parts of heat resistance modified auxiliary agent, 12 parts of heat resistance modified filler, 30 parts of deionized water.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 10 parts of absolute ethyl alcohols, 4 parts of methyl triethoxies
Silane, 2.5 parts of phenyl triethoxysilanes, 4 parts of diphenyl silanediols and 4 parts of vinyltriethoxysilane are uniformly mixed, and 50
DEG C heating water bath 2.5h then heats to 110 DEG C, keeps the temperature 1h, is cooled to room temperature to obtain material a；By 3.5 parts of polyether Glycols,
2.5 parts of isophorone diisocyanate and 4.5 parts of hydroxy silicon oils are uniformly mixed, and are warming up to 90 DEG C, are kept the temperature 2.5h, then admixture
Expect that a, 4 parts of butyl glycidyl ethers and 3 parts of tetraethylenepentamine are uniformly mixed, is warming up to 75 DEG C, keeps the temperature 3h, be then cooled to 55
DEG C, 6 parts of glacial acetic acid are added and are uniformly mixed, stirs 1h in 550r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by weight by 10 parts of phenol and 6 parts
Polyvinyl resin is uniformly mixed, and is warming up to 90 DEG C, is kept the temperature 2h, is cooled to room temperature, and 3.5 parts of polysulfones and 2.5 parts of polyphenyl are then added
Ether is uniformly mixed, and is warming up to 75 DEG C, is kept the temperature 3h, is subsequently added into 4.5 parts of 2-ethyl-4-methylimidazoles, 3.5 parts of cotton fibers, 2 parts of carboxylics
Methylcellulose, 3 parts of Nano zinc dioxide impact-resistants, 4.5 parts of nano silicon dioxides, 3.5 parts of carborundum powders, 2.5 parts of glass powders and 4.5 parts
Silane coupling reagent KH-570 is uniformly mixed, and is warming up to 85 DEG C, is kept the temperature 20min, is ground after drying, be cooled to room temperature to obtain heat-resisting change
Property filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 85 DEG C, kept the temperature 1.5h, stirred in 750r/min rotating speeds
30min is mixed, is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
105 DEG C are warming up to, 2h is kept the temperature, then 40min is stirred in 550r/min rotating speeds, is cooled to room temperature to obtain material II；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 130 DEG C, keep the temperature 2h, then in
3000r/min rotating speeds stir 4h, are cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
Embodiment 2
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
60 parts of ester, 25 parts of vinylacetate, 3 parts of polyvinyl alcohol, 9 parts of dibutyl phthalate, 2 parts of allyl methacrylate, first
6 parts of phenylene diisocyanate, 2 parts of bismaleimide, 4 parts of polybenzimidazoles, 3 parts of polyimides, diformazan diethoxy silane 6
Part, 3 parts of hexamethyldisilazane, 5 parts of white carbon, 1 part of cerium oxide, 5 parts of nano metal glass putty, multi-walled carbon nanotube 3 part, nanometer
5 parts of ceramic powder, 1 part of aluminium nitride, 6 parts of nano imvite, 1 part of sericite in powder, 5 parts of aluminium hydroxide, 2 parts of aluminium dihydrogen phosphate, tristearin
It is 5 parts of sour calcium, 1 part of zinc oxide, 5 parts of zirconium oxide, 3 parts of iron oxide, KH-5606 parts of silane coupling agent, 5 parts of heat resistance modified auxiliary agent, resistance to
16 parts of heat modification filler, 20 parts of deionized water.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 5 parts of absolute ethyl alcohols, 5 parts of methyl triethoxies
Silane, 1 part of phenyl triethoxysilane, 6 parts of diphenyl silanediols and 3 parts of vinyltriethoxysilane are uniformly mixed, 55 DEG C
Heating water bath 1.5h then heats to 120 DEG C, keeps the temperature 0.5h, is cooled to room temperature to obtain material a；By 5 parts of polyether Glycols, 1 part
Isophorone diisocyanate and 6 parts of hydroxy silicon oils are uniformly mixed, and are warming up to 85 DEG C, keep the temperature 3.5h, be then added material a, 2 parts
Butyl glycidyl ether and 5 parts of tetraethylenepentamine are uniformly mixed, and are warming up to 70 DEG C, are kept the temperature 4h, be then cooled to 50 DEG C, are added 8
Part glacial acetic acid is uniformly mixed, and is stirred 1.5h in 450r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by weight by 5 parts of phenol and 9 parts
Polyvinyl resin is uniformly mixed, and is warming up to 85 DEG C, is kept the temperature 3h, is cooled to room temperature, and 2 parts of polysulfones are then added and 4 parts of polyphenylene oxide are mixed
It closes uniformly, is warming up to 65 DEG C, keep the temperature 4h, be subsequently added into 3 parts of 2-ethyl-4-methylimidazoles, 5 parts of cotton fibers, 1 part of carboxymethyl cellulose
Element, 4 parts of Nano zinc dioxide impact-resistants, 3 parts of nano silicon dioxides, 5 parts of carborundum powders, 1 part of glass powder and 6 parts of Silane coupling reagent KH-570s
It is uniformly mixed, is warming up to 80 DEG C, keep the temperature 30min, ground after drying, be cooled to room temperature to obtain heat resistance modified filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 80 DEG C, keep the temperature 2h, stirred in 650r/min rotating speeds
40min is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
90 DEG C are warming up to, 3h is kept the temperature, then 50min is stirred in 450r/min rotating speeds, is cooled to room temperature to obtain material II；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 120 DEG C, keep the temperature 3h, then in
2500r/min rotating speeds stir 5h, are cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
Embodiment 3
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
80 parts of ester, 15 parts of vinylacetate, 9 parts of polyvinyl alcohol, 4 parts of dibutyl phthalate, 6 parts of allyl methacrylate, first
3 parts of phenylene diisocyanate, 5 parts of bismaleimide, 1 part of polybenzimidazoles, 5 parts of polyimides, diformazan diethoxy silane 2
Part, 5 parts of hexamethyldisilazane, 2 parts of white carbon, 4 parts of cerium oxide, 2 parts of nano metal glass putty, multi-walled carbon nanotube 5 part, nanometer
3 parts of ceramic powder, 4 parts of aluminium nitride, 3 parts of nano imvite, 4 parts of sericite in powder, 2 parts of aluminium hydroxide, 6 parts of aluminium dihydrogen phosphate, tristearin
It is 2 parts of sour calcium, 4 parts of zinc oxide, 3 parts of zirconium oxide, 9 parts of iron oxide, KH-5603 parts of silane coupling agent, 15 parts of heat resistance modified auxiliary agent, resistance to
8 parts of heat modification filler, 40 parts of deionized water.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 15 parts of absolute ethyl alcohols, 3 parts of methyl triethoxies
Silane, 4 parts of phenyl triethoxysilanes, 2 parts of diphenyl silanediols and 5 parts of vinyltriethoxysilane are uniformly mixed, 45 DEG C
Heating water bath 3.5h then heats to 100 DEG C, keeps the temperature 1.5h, is cooled to room temperature to obtain material a；By 2 parts of polyether Glycols, 4 parts
Isophorone diisocyanate and 3 parts of hydroxy silicon oils are uniformly mixed, and are warming up to 95 DEG C, keep the temperature 1.5h, be then added material a, 6 parts
Butyl glycidyl ether and 1 part of tetraethylenepentamine are uniformly mixed, and are warming up to 80 DEG C, are kept the temperature 2h, be then cooled to 60 DEG C, are added 4
Part glacial acetic acid is uniformly mixed, and is stirred 0.5h in 650r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by weight by 15 parts of phenol and 3 parts
Polyvinyl resin is uniformly mixed, and is warming up to 95 DEG C, is kept the temperature 1h, is cooled to room temperature, and 5 parts of polysulfones are then added and 1 part of polyphenylene oxide is mixed
It closes uniformly, is warming up to 85 DEG C, keep the temperature 2h, be subsequently added into 6 parts of 2-ethyl-4-methylimidazoles, 2 parts of cotton fibers, 3 parts of carboxymethyl celluloses
Element, 2 parts of Nano zinc dioxide impact-resistants, 6 parts of nano silicon dioxides, 2 parts of carborundum powders, 4 parts of glass powders and 3 parts of Silane coupling reagent KH-570s
It is uniformly mixed, is warming up to 90 DEG C, keep the temperature 10min, ground after drying, be cooled to room temperature to obtain heat resistance modified filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 90 DEG C, keep the temperature 1h, stirred in 850r/min rotating speeds
20min is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
120 DEG C are warming up to, 1h is kept the temperature, then 30min is stirred in 650r/min rotating speeds, is cooled to room temperature to obtain material II；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 140 DEG C, keep the temperature 1h, then in
3500r/min rotating speeds stir 3h, are cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
Embodiment 4
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
65 parts of ester, 22 parts of vinylacetate, 4 parts of polyvinyl alcohol, 8 parts of dibutyl phthalate, 3 parts of allyl methacrylate, first
5 parts of phenylene diisocyanate, 3 parts of bismaleimide, 3 parts of polybenzimidazoles, 3.5 parts of polyimides, diformazan diethoxy silane 5
Part, 3.5 parts of hexamethyldisilazane, 4 parts of white carbon, 2 parts of cerium oxide, 4 parts of nano metal glass putty, 3.5 parts of multi-walled carbon nanotube,
4.5 parts of nano-ceramic powder, 2 parts of aluminium nitride, 5 parts of nano imvite, 2 parts of sericite in powder, 4 parts of aluminium hydroxide, aluminium dihydrogen phosphate 3
Part, heat resistance modified is helped 4 parts of calcium stearate, 2 parts of zinc oxide, 4.5 parts of zirconium oxide, 4 parts of iron oxide, KH-5605 parts of silane coupling agent
8 parts of agent, 15 parts of heat resistance modified filler, 25 parts of deionized water.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 8 parts of absolute ethyl alcohols, 4.5 parts of three ethoxies of methyl
Base silane, 2 parts of phenyl triethoxysilanes, 5 parts of diphenyl silanediols and 3.5 parts of vinyltriethoxysilane are uniformly mixed,
52 DEG C of heating water bath 1.8h then heat to 115 DEG C, keep the temperature 0.8h, are cooled to room temperature to obtain material a；By 4 parts of polyethers binary
Alcohol, 2 parts of isophorone diisocyanate and 5 parts of hydroxy silicon oils are uniformly mixed, and are warming up to 88 DEG C, are kept the temperature 3.2h, then admixture
Expect that a, 3 parts of butyl glycidyl ethers and 4 parts of tetraethylenepentamine are uniformly mixed, is warming up to 72 DEG C, keeps the temperature 3.5h, be then cooled to 52
DEG C, 7 parts of glacial acetic acid are added and are uniformly mixed, stirs 1.2h in 455r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by weight by 8 parts of phenol and 8 parts
Polyvinyl resin is uniformly mixed, and is warming up to 88 DEG C, is kept the temperature 2.5h, is cooled to room temperature, and 3 parts of polysulfones and 3 parts of polyphenylene oxide are then added
It is uniformly mixed, is warming up to 68 DEG C, keep the temperature 3.5h, be subsequently added into 4 parts of 2-ethyl-4-methylimidazoles, 4 parts of cotton fibers, 1.5 parts of carboxylic first
Base cellulose, 3.5 parts of Nano zinc dioxide impact-resistants, 4 parts of nano silicon dioxides, 4 parts of carborundum powders, 2 parts of glass powders and 5 parts are silane coupled
Agent KH-570 is uniformly mixed, and is warming up to 82 DEG C, is kept the temperature 25min, is ground after drying, be cooled to room temperature to obtain heat resistance modified filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 82 DEG C, kept the temperature 1.8h, stirred in 680r/min rotating speeds
35min is mixed, is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
95 DEG C are warming up to, 2.5h is kept the temperature, then 45min is stirred in 455r/min rotating speeds, is cooled to room temperature to obtain material II；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 125 DEG C, keep the temperature 2.5h, then
4.5h is stirred in 2800r/min rotating speeds, is cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
Embodiment 5
A kind of heat resistance modified adhesive for coating manufacture proposed by the present invention, raw material include by weight：Poly- ammonia
75 parts of ester, 18 parts of vinylacetate, 8 parts of polyvinyl alcohol, 5 parts of dibutyl phthalate, 5 parts of allyl methacrylate, first
4 parts of phenylene diisocyanate, 4 parts of bismaleimide, 2 parts of polybenzimidazoles, 4.5 parts of polyimides, diformazan diethoxy silane 3
Part, 4.5 parts of hexamethyldisilazane, 3 parts of white carbon, 3 parts of cerium oxide, 3 parts of nano metal glass putty, 4.5 parts of multi-walled carbon nanotube,
3.5 parts of nano-ceramic powder, 3 parts of aluminium nitride, 4 parts of nano imvite, 3 parts of sericite in powder, 3 parts of aluminium hydroxide, aluminium dihydrogen phosphate 5
Part, heat resistance modified is helped 3 parts of calcium stearate, 3 parts of zinc oxide, 3.5 parts of zirconium oxide, 8 parts of iron oxide, KH-5604 parts of silane coupling agent
12 parts of agent, 9 parts of heat resistance modified filler, 35 parts of deionized water.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 12 parts of absolute ethyl alcohols, 3.5 parts of three ethoxies of methyl
Base silane, 3 parts of phenyl triethoxysilanes, 3 parts of diphenyl silanediols and 4.5 parts of vinyltriethoxysilane are uniformly mixed,
48 DEG C of heating water bath 3.2h then heat to 105 DEG C, keep the temperature 1.2h, are cooled to room temperature to obtain material a；By 3 parts of polyethers binary
Alcohol, 3 parts of isophorone diisocyanate and 4 parts of hydroxy silicon oils are uniformly mixed, and are warming up to 92 DEG C, are kept the temperature 1.8h, then admixture
Expect that a, 5 parts of butyl glycidyl ethers and 2 parts of tetraethylenepentamine are uniformly mixed, is warming up to 78 DEG C, keeps the temperature 2.5h, be then cooled to 58
DEG C, 5 parts of glacial acetic acid are added and are uniformly mixed, stirs 0.8h in 645r/min rotating speeds, is cooled to room temperature to obtain heat resistance modified auxiliary agent.
Heat resistance modified filler is prepared by following technique：Under conditions of alkalinity, by weight by 12 parts of phenol and 4 parts
Polyvinyl resin is uniformly mixed, and is warming up to 92 DEG C, is kept the temperature 1.5h, is cooled to room temperature, and 4 parts of polysulfones and 2 parts of polyphenylene oxide are then added
It is uniformly mixed, is warming up to 82 DEG C, keep the temperature 2.5h, be subsequently added into 5 parts of 2-ethyl-4-methylimidazoles, 3 parts of cotton fibers, 2.5 parts of carboxylic first
Base cellulose, 2.5 parts of Nano zinc dioxide impact-resistants, 5 parts of nano silicon dioxides, 3 parts of carborundum powders, 3 parts of glass powders and 4 parts are silane coupled
Agent KH-570 is uniformly mixed, and is warming up to 88 DEG C, is kept the temperature 15min, is ground after drying, be cooled to room temperature to obtain heat resistance modified filler.
A kind of preparation method of heat resistance modified adhesive for coating manufacture of the present invention, includes the following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 88 DEG C, kept the temperature 1.2h, stirred in 820r/min rotating speeds
25min is mixed, is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene diisocynate
Ester, bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed,
115 DEG C are warming up to, 1.5h is kept the temperature, then 35min is stirred in 645r/min rotating speeds, is cooled to room temperature to obtain material II；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder,
Aluminium nitride, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide,
Heat resistance modified auxiliary agent, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 135 DEG C, keep the temperature 1.5h, then
3.5h is stirred in 3200r/min rotating speeds, is cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
By GB11178-89 venamul adhesive standards to being used in 1- of embodiment of the present invention embodiments 5
The heat resistance modified adhesive and commercially available common adhesives of coating manufacture are detected, and performance compares such as table 1.
Table 1：
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of heat resistance modified adhesive for coating manufacture, which is characterized in that its raw material includes by weight：Polyurethane
60-80 parts, 15-25 parts of vinylacetate, 3-9 parts of polyvinyl alcohol, 4-9 parts of dibutyl phthalate, methacrylic acid allyl
2-6 parts of ester, 3-6 parts of toluene di-isocyanate(TDI), 2-5 parts of bismaleimide, 1-4 parts of polybenzimidazoles, 3-5 parts of polyimides,
2-6 parts of diformazan diethoxy silane, 3-5 parts of hexamethyldisilazane, 2-5 parts of white carbon, 1-4 parts of cerium oxide, nano metal tin
2-5 parts of powder, 3-5 parts of multi-walled carbon nanotube, 3-5 parts of nano-ceramic powder, 1-4 parts of aluminium nitride, 3-6 parts of nano imvite, sericite
1-4 parts of powder, 2-5 parts of aluminium hydroxide, 2-6 parts of aluminium dihydrogen phosphate, 2-5 parts of calcium stearate, 1-4 parts of zinc oxide, 3-5 parts of zirconium oxide,
3-9 parts of iron oxide, KH-5603-6 parts of silane coupling agent, it is auxiliary agent 5-15 parts heat resistance modified, filler 8-16 parts heat resistance modified, go from
Sub- water 20-40 parts.
2. the heat resistance modified adhesive according to claim 1 for coating manufacture, which is characterized in that heat resistance modified auxiliary agent
Raw material include by weight：5-15 parts of absolute ethyl alcohol, 3-5 parts of methyltriethoxysilane, phenyl triethoxysilane 1-4
Part, 2-6 parts of diphenyl silanediol, 3-5 parts of vinyltriethoxysilane, 2-5 parts of polyether Glycols, isophorone diisocyanate
1-4 parts of ester, 3-6 parts of hydroxy silicon oil, 2-6 parts of butyl glycidyl ether, 1-5 parts of tetraethylenepentamine, 4-8 parts of glacial acetic acid.
3. the heat resistance modified adhesive according to claim 1 or 2 for coating manufacture, which is characterized in that heat resistance modified
Auxiliary agent is prepared by following technique：By absolute ethyl alcohol, methyltriethoxysilane, phenyl triethoxysilane, diphenyl silicon
Glycol and vinyltriethoxysilane are uniformly mixed, then heating water bath heats up, and heat preservation is cooled to room temperature to obtain material a；
Polyether Glycols, isophorone diisocyanate and hydroxy silicon oil are uniformly mixed, heated up, then material a, fourth is added in heat preservation
Base glycidol ether and tetraethylenepentamine are uniformly mixed, and are heated up, and heat preservation then cools down, and glacial acetic acid is added and is uniformly mixed, stirring,
It is cooled to room temperature to obtain heat resistance modified auxiliary agent.
4. being used for the heat resistance modified adhesive of coating manufacture according to claim 1-3 any one of them, which is characterized in that heat-resisting
Modified additive is prepared by following technique：By absolute ethyl alcohol, methyltriethoxysilane, phenyl triethoxysilane, hexichol
Base silicon diol and vinyltriethoxysilane are uniformly mixed, and 45-55 DEG C of heating water bath 1.5-3.5h then heats to 100-
120 DEG C, 0.5-1.5h is kept the temperature, is cooled to room temperature to obtain material a；By polyether Glycols, isophorone diisocyanate and hydroxyl
Silicone oil is uniformly mixed, and is warming up to 85-95 DEG C, keeps the temperature 1.5-3.5h, and material a, butyl glycidyl ether and four ethylene are then added
Five amine are uniformly mixed, and are warming up to 70-80 DEG C, keep the temperature 2-4h, are then cooled to 50-60 DEG C, and glacial acetic acid is added and is uniformly mixed, in
450-650r/min rotating speeds stir 0.5-1.5h, are cooled to room temperature to obtain heat resistance modified auxiliary agent.
5. being used for the heat resistance modified adhesive of coating manufacture according to claim 1-4 any one of them, which is characterized in that heat-resisting
The raw material of modified filler includes by weight：5-15 parts of phenol, 3-9 parts of polyvinyl resin, 2-5 parts of polysulfones, 1-4 parts of polyphenylene oxide,
3-6 parts of 2-ethyl-4-methylimidazole, 2-5 parts of cotton fiber, 1-3 parts of carboxymethyl cellulose, 2-4 parts of Nano zinc dioxide impact-resistant, nanometer two
3-6 parts of silica, 2-5 parts of carborundum powder, 1-4 parts of glass powder, 3-6 parts of Silane coupling reagent KH-570.
6. being used for the heat resistance modified adhesive of coating manufacture according to claim 1-5 any one of them, which is characterized in that heat-resisting
Modified filler is prepared by following technique：Under conditions of alkalinity, phenol and polyvinyl resin are uniformly mixed, are warming up to
85-95 DEG C, 1-3h is kept the temperature, is cooled to room temperature, polysulfones is then added and polyphenylene oxide is uniformly mixed, is warming up to 65-85 DEG C, keeps the temperature 2-
4h is subsequently added into 2-ethyl-4-methylimidazole, cotton fiber, carboxymethyl cellulose, Nano zinc dioxide impact-resistant, nano silicon dioxide, carbon
SiClx powder, glass powder and Silane coupling reagent KH-570 are uniformly mixed, and are warming up to 80-90 DEG C, are kept the temperature 10-30min, are ground after drying
Mill, is cooled to room temperature to obtain heat resistance modified filler.
7. a kind of preparation method of heat resistance modified adhesive according to claim 1-6 any one of them for coating manufacture,
It is characterised in that it includes following steps：
S1, polyethylene glycol and deionized water are uniformly mixed, are warming up to 80-90 DEG C, 1-2h is kept the temperature, in 650-850r/min rotating speeds
20-40min is stirred, is cooled to room temperature to obtain material I；
S2, by polyurethane, vinylacetate, dibutyl phthalate, allyl methacrylate, toluene di-isocyanate(TDI),
Bismaleimide, polybenzimidazoles, polyimides, diformazan diethoxy silane and hexamethyldisilazane are uniformly mixed, and are risen
Temperature keeps the temperature 1-3h to 90-120 DEG C, then stirs 30-50min in 450-650r/min rotating speeds, is cooled to room temperature to obtain material
Ⅱ；
S3, by material I, material II, white carbon, cerium oxide, nano metal glass putty, multi-walled carbon nanotube, nano-ceramic powder, nitridation
It is aluminium, nano imvite, sericite in powder, aluminium hydroxide, aluminium dihydrogen phosphate, calcium stearate, zinc oxide, zirconium oxide, iron oxide, heat-resisting
Modified additive, heat resistance modified filler and silane coupling agent KH-560 are uniformly mixed, and are warming up to 120-140 DEG C, keep the temperature 1-3h, then
3-5h is stirred in 2500-3500r/min rotating speeds, is cooled to room temperature to obtain the heat resistance modified adhesive manufactured for coating.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112315661A (en) * | 2020-10-26 | 2021-02-05 | 广东泰宝医疗科技股份有限公司 | Ion induction paste with long lasting period |
| CN114316761A (en) * | 2022-01-07 | 2022-04-12 | 振恒(天津)科技发展有限公司 | Nanocomposite coating for high-speed rail brake friction gasket |
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| CN1886479A (en) * | 2003-12-01 | 2006-12-27 | 德古萨股份公司 | Adhesive and sealant systems |
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