CN108240077A - Novel jet-type wall decorating material and preparation method thereof - Google Patents
Novel jet-type wall decorating material and preparation method thereof Download PDFInfo
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- CN108240077A CN108240077A CN201611226997.8A CN201611226997A CN108240077A CN 108240077 A CN108240077 A CN 108240077A CN 201611226997 A CN201611226997 A CN 201611226997A CN 108240077 A CN108240077 A CN 108240077A
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- flame
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- retarding adhesive
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- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
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- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
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- C08K7/12—Asbestos
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09J161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/32—Modified amine-aldehyde condensates
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- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
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- E—FIXED CONSTRUCTIONS
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- E04F13/00—Coverings or linings, e.g. for walls or ceilings
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- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/10—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of wood or with an outer layer of wood
-
- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention provides a kind of novel jet-type wall decorating materials and preparation method thereof.The novel jet-type wall decorating material includes blank assemblies and is at least attached to the flame-retarding adhesive layer formed by the adhesive containing flame-retarding adhesive along at least side surface on the blank assemblies thickness direction, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive contains water soluble amino resin, dehydration catalyst, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is one or more in ammonium polyphosphate, melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is more than 20.The present invention also provides a kind of fire proofings.The glue performance of novel jet-type wall decorating material that method using the present invention is prepared meets requirements of the national standard, and assigns base material flame retardant property；Moreover, do not interfere with the mechanical property of base material, burst size of methanal is also at E1 grades or more, safety and environmental protection；Meanwhile maintain the native texture of timber, good decorating effect.
Description
Technical field
The present invention relates to a kind of novel jet-type wall decorating material and preparation method thereof and including the novel jet-type wall
The fire proofing of face ornament materials.
Background technology
It is many to the research of timber and wood materials flame retardant treatment at present but existing to wood materials progress flame retardant treatment
Method there are various defects.If CN1911613A discloses a kind of Wood fire retardant treatment process, which is by timber
It is put into the container of sealing, the container vacuum including timber is handled, then fire resistant fluid by high-pressure pump is input to and is in
In the container of vacuum state, after fire resistant fluid reaches saturation state in wood, take out timber and be dried；The fire resistant fluid contains
There are ammonium sulfate, diammonium hydrogen phosphate, boric acid and borax.This method is the method for pressure impregnating fire retardant, this to treating of wood side
Method there are it is certain the problem of：(1) fire retardant allows for being dissolved in the water, and impregnates in timber in liquid form, therefore, tree
The permeability of kind has a significant impact to its amount of impregnating and the uniformity impregnated；(2) the inorganic based flame retardant majority can not be with timber
Chemical bonding is formed, surface precipitation phenomenon is easily generated, influences subsequent secondary operation；(3) above-mentioned fire retardant is to the object of timber
Managing mechanical property, there are harmful effects, and e.g., MOR (static bending strength), MOE (elasticity modulus) are reduced, and brittleness increases；(4)
Want to reach higher fire-retardant rank, it is necessary to increase the amount of impregnating of fire retardant matter；(5) the necessary redrying of treated timber,
Timber is easily made to generate secondary cracking, deformation, loss increases.
If when carrying out flame retardant treatment to finished product glued board, the adhesive for being generally employed to produce glued board is phenolic resin
Or cyanurotriamide modified urea resin, and gluing oxidant layer has larger impact to the scattering and permeating of fire retardant.If face ply
When remaining more fire retardant, product easily generates moisture absorption and returns white phenomenon, and subsequent secondary operation can and paint poor performance, if
Only to plywood skin veneer flame retardant treatment, expected flame retardant effect is often not achieved, needs to increase aid in treatment or increase to answer
Qualifications.
In conclusion at present in the production of fire retarding wood and wood materials, it is necessary to whole to plank component units or plank
It carries out fire retardant matter impregnation and can be only achieved ideal flame retardant effect.This flame retardant treatment mode brings many unfavorable shadows
It rings, such as complex treatment process reduces the physical and mechanical property of material, there is harmful effect phenomenon to adhesive curing performance, influences
Follow-up suitability for secondary processing repeats dry and increases energy consumption etc..
Invention content
There can be the novel of fine flame retarding function it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of
Sprayed wall decorating material and the fire proofing with good flame retardant effect and mechanical property.The novel jet-type wall decorative
The fire retardant treatment process of material and fire proofing is simple, need to will be only coated with containing the liquid mixture of flame-retarding adhesive and curing agent
In blank assemblies at least novel injection is can obtain along the side surface on the blank assemblies thickness direction and hot-press solidifying
Formula wall decorating material, the surface that novel jet-type wall decorating material is covered on to processed material (base material) are i.e. available
The fire proofing of flame retardant effect and good mechanical performance, and base material need not do any flame retardant treatment.This processing mode can make
Base material is not easy to be damaged, and the performance of base material will not be had an impact, and appearance looks elegant, be easy to industrialized production.
To the purpose of the present invention can be achieved through the following technical solutions：
The present invention provides a kind of novel jet-type wall decorating material, wherein, which includes
It blank assemblies and is at least attached to along the side surface on the blank assemblies thickness direction by the glue containing flame-retarding adhesive
The flame-retarding adhesive layer that stick is formed, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive contains water
Dissolubility amino resins, dehydration catalyst, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is selected from poly phosphorus
It is one or more in sour ammonium, melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate
It is more than 20.
The present invention also provides a kind of preparation method of novel jet-type wall decorating material, wherein, this method includes will
Containing flame-retarding adhesive and curing agent liquid mixture be coated on blank assemblies at least along the blank assemblies thickness direction
A side surface and hot-press solidifying, the blank assemblies include at least one layer of Wooden veneer, the flame-retarding adhesive contains water-soluble
Property amino resins, dehydration catalyst, carbon forming agent and adjuvant and the water selectively contained；The dehydration catalyst is selected from poly
It is one or more in ammonium phosphate, melamine orthophosphates and melamine pyrophosphate；The polymerization of the ammonium polyphosphate
Spend is more than 20.
In addition, the present invention also provides a kind of fire proofing, which includes base material and is attached at substrate surface
Novel jet-type wall decorating material, the novel jet-type wall decorating material are novel jet-type wall surface provided by the invention
Ornament materials.
Compared with prior art, the present invention has the following advantages：
1. insulation and decoration is two-in-one to integrate the high-efficiency insulated performance of mineral wool and the decoration functions of decorative panel, one block of plank
Two kinds of functions；
2. heat preservation, heat-proof quality are good
Heat insulating decorative board of the present invention is stablized using industrialization Automatic Production Line, product quality, the high density of intermediate insulating layer
Mineral wool has fabulous heat-insulating property, thermal conductivity factor λ≤0.035W/mK, the polyphenyl second generally used with the current country
Alkene (thermal conductivity factor λ≤0.042W/mK), rock wool (thermal conductivity factor λ≤0.050W/mK) are compared, and heat insulation effect carries
After high 20% -25% by keel and wall connecting, the air layer between plank and wall can play double-layer heat insulation, be separated with
Beneficial effect
The hollow pipe and accessory of uniform shapes improve acoustic decoration board standardization in itself and aesthetics；Quickly connection and
Connector system improves acoustic decoration board producing efficiency and technological level；Strong adsorption magnet arrangement and self-priming bayonet unit
Application, the installation speed of acoustic decoration board can be significantly improved, project installation expense and time is saved, dragon can be directly installed on
On bone, the application of the levelling base's plank of building interior is saved, the synthesis cost and building for significantly reducing engineering are born a heavy burden, and are expanded and are inhaled
Cavity after soundboard significantly improves the sound absorption function of abatvoix；Flatness regulatory function device and all directions translational adjustment function dress
The application put can significantly improve the flatness and aesthetics on acoustic decoration board surface, improve the decorative effect of sound-absorbing engineering；It is living
The application of dynamic plug-in card, can radical change acoustic decoration board can not it is easy to disassemble, cannot replace and can not be used repeatedly
Drawback improves the utilization ratio of product itself and resource reutilization ability；Product does not have to gypsum, without resin adhesive curing, no
With timber, make product that there is the features such as intensity height, good environmental protection, fire-proof and water-proof, non-deformability is strong.
Thermal effect, heat-insulating property are far above the standard of national energy-saving 65%.
3. decorative effect is more
Appearance is rich and varied, imitates a variety of decorative forms such as stone material, imitative ceramic tile, imitation wood line and aluminum facade, can meet different clients
Individual demand.
4. security performance is high
Heat insulating decorative board, using dry construction, avoids aging obscission caused by traditional chemistry is pasted, in addition from heavy and light
Mineral wool is A grades of incombustible materials, eliminates security risk.
5. construction efficiency is high
Traditional exterior-wall heat insulation Finish System construction, general on-site layering are gradually constructed, and the construction time is long, complex procedures, by day
Gas factor influences big.The complete dry construction of heat insulating decorative board of the present invention is installed not by weather, seasonal effect, and mounting means is simple and direct,
Construction efficiency is 2 times of traditional method or more.
It is 6. applied widely
Building that is newly-built and repairing, public building, civil buildings can be used, and be not required to carry out building wall cumbersome
Pretreatment, especially in the reducing energy consumption to existing building, on the basis of not needing to handle original building exterior wall,
It can construct.
It is 7. durable
With preferable weatherability, service life can be with building the same service life.External surface coating is handled through special process, is not only adhered to
Performance is strong, and plate surface has excellent performance in terms of wear-resisting, acidproof, alkaline-resisting, salt spray resistance erosion.
8. comprehensive cost low
Heat preservation and decoration of outer wall system of the present invention keeps the temperature, is decoration integrated, simplifies construction procedure in installation, and reduction is constructed into
This, 20 years practical architectural appearances are still relatively new, and with the building same service life, primary input is lifelong to be benefited.
Specific embodiment
Novel jet-type wall decorating material provided by the invention includes blank assemblies and is at least attached to along the plank
The flame-retarding adhesive layer formed by the adhesive containing flame-retarding adhesive of a side surface on component thickness direction, the plank
Component include at least one layer of Wooden veneer, the flame-retarding adhesive contain water soluble amino resin, dehydration catalyst, carbon forming agent and
Adjuvant and with or without water；The dehydration catalyst is selected from ammonium polyphosphate, melamine orthophosphates and melamine
It is one or more in pyrophosphate；The degree of polymerization of the ammonium polyphosphate is more than 20, preferably 1000-1500.
In flame-retarding adhesive provided by the invention, the content of above-mentioned various components can change within a large range,
Under preferable case, on the basis of the total weight of flame-retarding adhesive, the content of water soluble amino resin is 30-70 weight %, is dehydrated
The content of catalyst is 8-35 weight %, and the content of carbon forming agent is 2-20 weight %, and the content of adjuvant is 2-30 weights
% is measured, the content of water is 0-40 weight %.It is water-soluble on the basis of the total weight of flame-retarding adhesive in the case of further preferably
Property amino resins content for 40-60 weight %, the content of dehydration catalyst is 10-25 weight %, and the content of carbon forming agent is
5-15 weight %, the content of adjuvant is 3-20 weight %, and the content of water is 0-30 weight %.The present inventor also sends out
Existing, when each component is in above-mentioned preferred content range, the flame retardant property of obtained flame-retarding adhesive is good, and glue performance is equal
Meet requirements of the national standard.
According to the present invention, the main function of the dehydration catalyst is the dehydration carbonization for promoting carbon forming agent, while under high temperature
The non-flammable gases generated due to resin decomposition make carbide foaming and intumescing so that form one layer uniformly in combustible surface
Expanding layer, completely cuts off external heat and oxygen internally transmits, so as to achieve the purpose that base material is protected to prevent it from burning.
According to the present invention, the adjuvant can known in those skilled in the art various improve the fire retardant glue
The flame retardant property of stick, smoke suppressing and the substance for reducing free formaldehyde, under preferable case, the adjuvant is aluminium hydroxide
And/or magnesium hydroxide or for selected from alumina silicate fibre, glass fibre, asbestos fibre, hollow glass microbead, modified silicic acid
Boron, expansible graphite, have layer silicate, silica, alundum (Al2O3) and urea in one or more and hydrogen
The mixture of aluminium oxide and/or magnesium hydroxide.
Wherein, the aluminium hydroxide and magnesium hydroxide decompose caloric receptivity greatly, and the H2O generated after pyrolytic can play suction
Heat effect, the oxide isolation heat and the translocation of oxygen internally of molten condition, and the oxide after decomposition is resistance to
High temperature substance, the progress of burning can further be prevented again by being attached to combustible surface.Aluminium hydroxide and magnesium hydroxide are entire
It is not only generated during fire-retardant without any harmful substance, and the product decomposed also is able to play elimination cigarette fire-retardant while
Mist and the effect for absorbing heat.
According to the present invention, the water soluble amino resin can be selected from the various water soluble amino resins of this field routine,
Under preferable case, the water soluble amino resin in melamine resin and cyanurotriamide modified urea resin one
Kind is a variety of.The various methods that cyanurotriamide modified urea resin used in the present invention is known in the art obtain, the trimerization
Cyanamide modified urea-formaldehyde resin can be by commercially available or be prepared, for example, can be according to method disclosed in CN100572445C
Cyanurotriamide modified urea resin is prepared.The water soluble amino resin using have good glue performance and water resistance as
It is main, while one of composition for also doubling as fire retardant matter, heat, which can decompose, releases the non-flammable compressive gases such as ammonia, vapor, reduces
The heat of combustible surface dilutes the concentration of combustible surface fuel gas, therefore water soluble amino resin is this item hair
One of bright crucial component.The water soluble amino resin can be commercially available, can also be according to known in this field
Various preparation methods obtain, for example, can be according to CN1527853A, CN 1105694A, CN 1834186A, CN
101134835A and document [J Wood Sci (2001) 47：451-457] etc. disclosed in method be prepared.
According to the present invention, the carbon forming agent can be selected from the various carbon forming agents of this field routine, under preferable case, it is described into
One or more of charcoal agent in sucrose, sorbose, starch, pentaerythrite, dipentaerythritol and tripentaerythritol.With water solubility
The non-flammable compressive gases such as ammonia, vapor that amino resins heat releases are air source, and the carbon forming agent is in the effect of dehydration catalyst
Lower dehydration carbonization forms the expanded charred layer of foam-like in combustible surface, has been coated in the expanded charred layer of the foam-like big
The non-flammable compressive gas of amount has not only effectively obstructed radiation effects of the external heat source to internal timber, but also has separated oxygen and inside
The contact of timber, so as to reach fire-retardant, fire prevention purpose.
The preparation method of the flame-retarding adhesive is not particularly limited in the present invention, for example, by water soluble amino resin, taking off
Water catalyst, carbon forming agent and fire-retardant adjuvant and the water selectively contained are uniformly mixed；The dehydration catalyst is selected from
It is one or more in ammonium polyphosphate, melamine orthophosphates and melamine pyrophosphate；The ammonium polyphosphate
The degree of polymerization is more than 20, preferably 1000-1500.
Wherein, the dosage of each substance is preferably so that on the basis of the total weight of flame-retarding adhesive, water soluble amino resin
Content is 30-70 weight %, and the content of dehydration catalyst is 8-35 weight %, and the content of carbon forming agent is 2-20 weight %, auxiliary
The content of auxiliary agent is 2-30 weight %, and the content of water is 0-40 weight %.In the case of further preferably, the dosage of each substance makes
It is able on the basis of the total weight of flame-retarding adhesive, the content of water soluble amino resin is 40-60 weight %, dehydration catalyst
Content is 10-25 weight %, and the content of carbon forming agent is 5-15 weight %, and the content of adjuvant is 3-20 weight %, and water contains
It measures as 0-30 weight %.
According to the present invention, the selection of the type of above-mentioned each component has been described above, and repeats no more herein.
The application method of flame-retarding adhesive of the present invention is to be mixed to get aqueous flame-retarding adhesive with curing agent
The mixture is coated on the surface of the material of pending flame retardant treatment by mixture, then will be coated with the flame-retarding adhesive
Wood materials assembly and hot-press solidifying.The painting of the mixture of aqueous flame-retarding adhesive and curing agent containing the present invention
Cloth amount can be depending on the fire-retardant demand to various different materials, and there is no particular limitation.It in other words, can when unused
Directly flame-retarding adhesive provided by the invention will be can obtain after the mixing of each solid component.
According to the present invention, the mixing of various components can be carried out at the same time and can also carry out step by step, and the sequence of mixing can't
The performance of flame-retarding adhesive to obtaining has an impact, for example, can water and water soluble amino resin first be mixed to get liquid
Water soluble amino resin, then remaining component is uniformly mixed with the water soluble amino resin of the liquid again or
A certain amount of water can also be filled into as needed to meet the needs of coating；After can also each component directly be mixed with water
It arrives；When in use, the content of water is preferably the 20-30 weight % of the total weight of aqueous flame-retarding adhesive.
Time of the present invention to the temperature of mixing and mixing, there is no particular limitation, as long as various components is made to be uniformly mixed i.e.
Can, under preferable case, the temperature of mixing can be 10-40 DEG C, and the time of mixing can be 10-60 minutes.
Flame-retarding adhesive provided by the invention can carry out flame retardant treatment to a variety of materials, especially suitable for wooden material
Material, is more applicable for being coated directly onto the surface of single-board materials to carry out flame retardant treatment.
According to the present invention, the blank assemblies include at least one layer of Wooden veneer, and in other words, the blank assemblies can be
One layer of Wooden veneer, or multilayer laminated, gluing mutually multilayered wood veneer.
Wherein, the number of plies of the multilayered wood veneer can reach according to the thickness and actual needs of individual layer Wooden veneer
Flame retardant effect depending on.The thickness of the individual layer Wooden veneer is by depending on the wood quality that selects, under normal circumstances, the individual layer
The thickness of Wooden veneer can be 0.1-5mm, further preferably preferably 0.1-1.5mm, 0.15-1mm.Multilayered wood veneer
The number of plies usually can be by 1-30 layers, the preferably 2-20 layers of individual layer Wooden veneer is laminated, is bonded to obtain including delta wood
The blank assemblies of matter veneer.The Wooden veneer of required thickness can be used that well known to a person skilled in the art various methods to obtain, example
Such as, the method for rotary-cut or slicing.The material of the Wooden veneer can be various wood materials, described wooden under preferable case
Veneer is coniferous wood or broad-leaved wood, the coniferous wood or broad-leaved wood can and preferably poplar, Eucalyptus, Korean pine, China fir
Wood, birch, paulownia, larch.
It is above disclosed to be merely a preferred embodiment of the present invention, the right of the present invention cannot be limited with this certainly
Range, therefore the equivalent variations made according to scope of the present invention patent, are still within the scope of the present invention.
Claims (8)
1. a kind of novel jet-type wall decorating material, which is characterized in that the novel jet-type wall decorating material includes plank
It component and is at least attached to along at least side surface on the blank assemblies thickness direction by the glue containing flame-retarding adhesive
The flame-retarding adhesive layer that stick is formed, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive is water-soluble
Property amino resins, dehydration catalyst, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is selected from polyphosphoric acids
It is one or more in ammonium, melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is
1000-1500 ；The adjuvant be aluminium hydroxide and/or magnesium hydroxide or for selected from alumina silicate fibre, glass fibre,
Asbestos fibre, hollow glass microbead, modified borosilicate, expansible graphite, the silicate with layer structure, silica, three
The mixture of one or more and aluminium hydroxide and/or magnesium hydroxide in Al 2 O and urea.
2. the novel jet-type wall decorating material according to claim 1, wherein, using the total weight of flame-retarding adhesive as
Benchmark, the content of water soluble amino resin is 30-70 weight %；The content of dehydration catalyst is 8-35 weight %；Carbon forming agent
Content be 2-20 weight %；The content of adjuvant is 2-30 weight %；The content of water is 0-40 weight %.
3. the novel jet-type wall decorating material according to claim 2, wherein, using the total weight of flame-retarding adhesive as
Benchmark, the content of water soluble amino resin is 40-60 weight %；The content of dehydration catalyst is 10-25 weight %；Into charcoal
The content of agent is 5-15 weight %；The content of adjuvant is 3-20 weight %；The content of water is 0-30 weight %.
4. the novel jet-type wall decorating material according to any one in claim 1-3, wherein, the water solubility
Amino resins is one or more in melamine resin and cyanurotriamide modified urea resin.
5. the novel jet-type wall decorating material according to any one in claim 1-3, wherein, the carbon forming agent
It is one or more in sucrose, sorbose, starch, pentaerythrite, dipentaerythritol and tripentaerythritol.
6. the novel jet-type wall decorating material according to claim 1, wherein, the blank assemblies include multilayer layer
Folded, glued Wooden veneer mutually is further included by the adhesive containing flame-retarding adhesive between two layers adjacent of Wooden veneer
The flame-retarding adhesive layer of formation；The dosage of the flame-retarding adhesive is 50-500g/m2；The thickness of the Wooden veneer is 0.1-
5mm, the Wooden veneer are coniferous wood or broad-leaved wood.
7. a kind of preparation method of novel jet-type wall decorating material, which is characterized in that this method includes that fire retardant glue will be contained
The liquid of stick and curing agent mixing after be coated on blank assemblies at least along at least one on the blank assemblies thickness direction
Side surface and hot-press solidifying, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive is water soluble amino
Resin, dehydration catalyst, carbon forming agent and adjuvant and the water selectively contained；The dehydration catalyst is selected from polyphosphoric acids
It is one or more in ammonium, melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is
1000-1500 ；The adjuvant be aluminium hydroxide and/or magnesium hydroxide or for selected from alumina silicate fibre, glass fibre,
Asbestos fibre, hollow glass microbead, modified borosilicate, expansible graphite, the silicate with layer structure, silica, three
The mixture of one or more and aluminium hydroxide and/or magnesium hydroxide in Al 2 O and urea.
8. the method according to claim 7, wherein, the blank assemblies include it is multilayer laminated, mutually fit it is wooden
Veneer, coating is containing the mixing of the liquid of flame-retarding adhesive and curing agent between this method is additionally included in two layers adjacent of Wooden veneer
Object and hot pressing, curing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611226997.8A CN108240077A (en) | 2016-12-27 | 2016-12-27 | Novel jet-type wall decorating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611226997.8A CN108240077A (en) | 2016-12-27 | 2016-12-27 | Novel jet-type wall decorating material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108240077A true CN108240077A (en) | 2018-07-03 |
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ID=62701588
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611226997.8A Withdrawn CN108240077A (en) | 2016-12-27 | 2016-12-27 | Novel jet-type wall decorating material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109291198A (en) * | 2018-11-27 | 2019-02-01 | 浙江世友木业有限公司 | A kind of low TVOC flame retardant solid composite floor and processing technology |
-
2016
- 2016-12-27 CN CN201611226997.8A patent/CN108240077A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109291198A (en) * | 2018-11-27 | 2019-02-01 | 浙江世友木业有限公司 | A kind of low TVOC flame retardant solid composite floor and processing technology |
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Application publication date: 20180703 |