CN108208002A - A kind of disinsection method using charged nanosize material - Google Patents
A kind of disinsection method using charged nanosize material Download PDFInfo
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- CN108208002A CN108208002A CN201711335375.3A CN201711335375A CN108208002A CN 108208002 A CN108208002 A CN 108208002A CN 201711335375 A CN201711335375 A CN 201711335375A CN 108208002 A CN108208002 A CN 108208002A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protection of plants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/22—Killing insects by electric means
- A01M1/223—Killing insects by electric means by using electrocution
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Pest Control & Pesticides (AREA)
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- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Insects & Arthropods (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of disinsection method using charged nanosize material, specific method is：Charged nanosize insecticide is sprayed to crops, the charge itself carried using the insecticide cuts the phospholipid bilayer of pest polypide, and then kills pest.The disinsection method of the present invention belongs to physical desinsection, negative electrical charge titanium dioxide nanoparticle is made to load on the surface of positive charge nano zine oxide by electrostatic interaction, it can avoid the reunion of nano particle, after being further introduced into the hydrophilic radical with positive charge, so that insecticide integrally carries positive charge, the charge itself carried using charged nanosize insecticide cuts the phospholipid bilayer of pest polypide, and then kill pest, it is nontoxic, compared with traditional insecticide, it does not develop immunity to drugs, environment will not be polluted.
Description
Technical field
The present invention relates to technical field of pesticide, more particularly to a kind of disinsection method using charged nanosize material.
Background technology
With the rapid development of agricultural and the growth of the size of population, the throughput requirements of crops are higher and higher, thereupon
Insecticide dosage it is increasing.But most of insecticide is all harmful to human body, and the use of insecticide can be tight
Ghost image rings ecological environment, and remaining insecticide can also constantly be concentrated in biological chain, very harmful.Therefore, agricultural development with
Balance is obtained between ecological environment to be particularly important.
The use for a long time repeatedly of insecticide also results in drug resistance, and a kind of insecticide often must not after a period of use
Without replacing, huge fund of scientific research waste is caused.
It is mostly not soluble in water or be slightly soluble in water in addition, preparing protodrug is mostly oily liquids, and this can directly affect medicine
Effect release, therefore how to improve its water solubility is also a current important R＆D direction.
Invention content
Present invention aim to provide a kind of disinsection method using charged nanosize material.
To achieve the above object, the present invention is achieved by the following scheme：
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge itself carried using the insecticide cuts the phospholipid bilayer of pest polypide, and then kills pest.
Preferably, the charged nanosize insecticide contains hydrophilic radical.
It is further preferred that the hydrophilic radical is hydroxyl.
Preferably, the charged nanosize insecticide is powder, with the water dissolution of 600~700 times of weight during use, is then sprayed
It spills in crop surface.
It is further preferred that the charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 50~60 DEG C of water,
Continue stirring after addition 20~30 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 5~6 minutes, taken
Be dehydrated after going out, it is dry to get.
Still more preferably, the mass ratio of polyvinyl alcohol and water is 1: 30~32 in step (1).
Still more preferably, the specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 3~4g/L in Nanometer Titanium Dioxide Hydrosol,
Ultrasonic disperse 15~20 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged completely in the hydrosol
The surface of nano zine oxide；
(22) adsorbed product is centrifugally separating to obtain, is then washed 2~3 times with absolute ethyl alcohol, it is dry, obtain nano combined material
Material.
Still more preferably, in step (22), dry process conditions are：Vacuum drying 8~12 hours.
Still more preferably, the preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：By butyl titanate and chelating agent
It is mixed 20~30 minutes, is then slowly added dropwise into the mixed solution of catalyst and water, stand 1 hour, obtain nanometer two
The titanium oxide hydrosol；Wherein, the molar ratio of butyl titanate, chelating agent and water is 1: 6: 93, and catalyst accounts for whole system gross weight
The 3.2% of amount.
Still more preferably, the chelating agent and catalyst are acetic acid.
Still more preferably, in step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 7~8.
Still more preferably, it in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
The beneficial effects of the invention are as follows：
1st, disinsection method of the invention belongs to physical desinsection, makes negative electrical charge titanium dioxide nanoparticle by electrostatic interaction
It loads on the surface of positive charge nano zine oxide, the reunion of nano particle can be avoided, be further introduced into the parent with positive charge
After water base group so that for insecticide integrally with positive charge, the charge itself carried using charged nanosize insecticide cuts pest worm
The phospholipid bilayer of body, and then pest is killed, it is nontoxic, compared with traditional insecticide, do not develop immunity to drugs, it will not
Pollute environment.
2nd, insecticide of the invention is powder, soluble easily in water, it may be convenient to be diluted with water dissolution with hydrophilic radical
After spray, give full play to desinsection drug effect.
3rd, insecticide of the invention is nanoscale, low-residual, it is ensured that food and ecological safety.
4th, for soaking time with 5~6 minutes, soaking time was too short, can not ensure in nanocomposite addition hydrophilic solution
Hydrophilic radical is sufficiently introduced into, and influences the negative charge amount and hydrophily of pesticide product；Long soaking time, itself is positively charged
Hydrophilic radical squeeze positively charged nano zine oxide, influence the stability of nanocomposite, and then insecticide is caused to produce
The insecticidal effect of product is deteriorated.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiments obtained without making creative work belong to the model that the present invention protects
It encloses.
Embodiment 1
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge carried using insecticide itself cuts the phospholipid bilayer of pest polypide, and then kills pest.
Wherein, charged nanosize insecticide contains hydrophilic radical (hydroxyl).
Charged nanosize insecticide is powder, with the water dissolution of 600 times of weight during use, is then sprayed on crop surface.
Charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 50 DEG C of water, added in
After continue stirring 20 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 5 minutes, after taking-up
Dehydration, it is dry to get.
The mass ratio of polyvinyl alcohol and water is 1: 30 in step (1).
The specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 3g/L in Nanometer Titanium Dioxide Hydrosol, ultrasound
Dispersion 15 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nano oxidized completely in the hydrosol
The surface of zinc；
(22) adsorbed product is centrifugally separating to obtain, is then washed 2 times with absolute ethyl alcohol, is dried in vacuo 8 hours, obtains nanometer
Composite material.
The preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：Butyl titanate and chelating agent are mixed 20 minutes,
Then it is slowly added dropwise into the mixed solution of catalyst and water, stands 1 hour, obtain Nanometer Titanium Dioxide Hydrosol；Wherein, titanium
The molar ratio of sour four butyl esters, chelating agent and water is 1: 6: 93, and catalyst accounts for the 3.2% of whole system total weight.It chelating agent and urges
Agent is acetic acid.
In step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 7.
It in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
Embodiment 2
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge carried using insecticide itself cuts the phospholipid bilayer of pest polypide, and then kills pest.
Wherein, charged nanosize insecticide contains hydrophilic radical (hydroxyl).
Charged nanosize insecticide is powder, with the water dissolution of 700 times of weight during use, is then sprayed on crop surface.
Charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 60 DEG C of water, added in
After continue stirring 30 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 6 minutes, after taking-up
Dehydration, it is dry to get.
The mass ratio of polyvinyl alcohol and water is 1: 32 in step (1).
The specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 4g/L in Nanometer Titanium Dioxide Hydrosol, ultrasound
Dispersion 20 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nano oxidized completely in the hydrosol
The surface of zinc；
(22) adsorbed product is centrifugally separating to obtain, is then washed 3 times with absolute ethyl alcohol, is dried in vacuo 12 hours, is received
Nano composite material.
The preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：Butyl titanate and chelating agent are mixed 30 minutes,
Then it is slowly added dropwise into the mixed solution of catalyst and water, stands 1 hour, obtain Nanometer Titanium Dioxide Hydrosol；Wherein, titanium
The molar ratio of sour four butyl esters, chelating agent and water is 1: 6: 93, and catalyst accounts for the 3.2% of whole system total weight.It chelating agent and urges
Agent is acetic acid.
In step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 8.
It in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
Embodiment 3
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge carried using insecticide itself cuts the phospholipid bilayer of pest polypide, and then kills pest.
Wherein, charged nanosize insecticide contains hydrophilic radical (hydroxyl).
Charged nanosize insecticide is powder, with the water dissolution of 600 times of weight during use, is then sprayed on crop surface.
Charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 60 DEG C of water, added in
After continue stirring 20 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 6 minutes, after taking-up
Dehydration, it is dry to get.
The mass ratio of polyvinyl alcohol and water is 1: 30 in step (1).
The specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 4g/L in Nanometer Titanium Dioxide Hydrosol, ultrasound
Dispersion 15 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nano oxidized completely in the hydrosol
The surface of zinc；
(22) adsorbed product is centrifugally separating to obtain, is then washed 3 times with absolute ethyl alcohol, is dried in vacuo 8 hours, obtains nanometer
Composite material.
The preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：Butyl titanate and chelating agent are mixed 30 minutes,
Then it is slowly added dropwise into the mixed solution of catalyst and water, stands 1 hour, obtain Nanometer Titanium Dioxide Hydrosol；Wherein, titanium
The molar ratio of sour four butyl esters, chelating agent and water is 1: 6: 93, and catalyst accounts for the 3.2% of whole system total weight.It chelating agent and urges
Agent is acetic acid.
In step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 7.
It in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
Embodiment 4
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge carried using insecticide itself cuts the phospholipid bilayer of pest polypide, and then kills pest.
Wherein, charged nanosize insecticide contains hydrophilic radical (hydroxyl).
Charged nanosize insecticide is powder, with the water dissolution of 700 times of weight during use, is then sprayed on crop surface.
Charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 50 DEG C of water, added in
After continue stirring 30 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 5 minutes, after taking-up
Dehydration, it is dry to get.
The mass ratio of polyvinyl alcohol and water is 1: 32 in step (1).
The specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 3g/L in Nanometer Titanium Dioxide Hydrosol, ultrasound
Dispersion 20 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nano oxidized completely in the hydrosol
The surface of zinc；
(22) adsorbed product is centrifugally separating to obtain, is then washed 2 times with absolute ethyl alcohol, is dried in vacuo 12 hours, is received
Nano composite material.
The preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：Butyl titanate and chelating agent are mixed 20 minutes,
Then it is slowly added dropwise into the mixed solution of catalyst and water, stands 1 hour, obtain Nanometer Titanium Dioxide Hydrosol；Wherein, titanium
The molar ratio of sour four butyl esters, chelating agent and water is 1: 6: 93, and catalyst accounts for the 3.2% of whole system total weight.It chelating agent and urges
Agent is acetic acid.
In step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 8.
It in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
Embodiment 5
A kind of disinsection method using charged nanosize material, specific method are：Charged nanosize insecticide is sprayed to crops,
The charge carried using insecticide itself cuts the phospholipid bilayer of pest polypide, and then kills pest.
Wherein, charged nanosize insecticide contains hydrophilic radical (hydroxyl).
Charged nanosize insecticide is powder, with the water dissolution of 650 times of weight during use, is then sprayed on crop surface.
Charged nanosize insecticide is prepared by the following method to obtain：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 55 DEG C of water, added in
After continue stirring 25 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse
The two is sufficiently mixed, titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, is received
Nano composite material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 5 minutes, after taking-up
Dehydration, it is dry to get.
The mass ratio of polyvinyl alcohol and water is 1: 31 in step (1).
The specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 3.5g/L in Nanometer Titanium Dioxide Hydrosol, surpassed
Sound disperses 18 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nano oxygen completely in the hydrosol
Change the surface of zinc；
(22) adsorbed product is centrifugally separating to obtain, is then washed 3 times with absolute ethyl alcohol, is dried in vacuo 10 hours, is received
Nano composite material.
The preparation method of Nanometer Titanium Dioxide Hydrosol is as follows：Butyl titanate and chelating agent are mixed 25 minutes,
Then it is slowly added dropwise into the mixed solution of catalyst and water, stands 1 hour, obtain Nanometer Titanium Dioxide Hydrosol；Wherein, titanium
The molar ratio of sour four butyl esters, chelating agent and water is 1: 6: 93, and catalyst accounts for the 3.2% of whole system total weight.It chelating agent and urges
Agent is acetic acid.
In step (3), the mass ratio of nanocomposite and hydrophilic solution is 1: 7.5.
It in step (3), is dehydrated using centrifugal process, drying means is natural air drying.
Test example
Examples 1 to 5 is investigated to the insecticidal effect of diamondback moth larvae and penthaleus major duges adult, the results are shown in Table 1.Wherein, band
Susceptance rice insecticide is powder, and with the water dissolution of 650 times of weight during use, dosage is 60L per acre, investigates the death rate after medicine：
Refer to using after a certain period of time, death toll accounts for the percentage of total test number after drug.
1. insect killing effect test result of table
As shown in Table 1, after charged nanosize insecticide application of the invention 1 day can to diamondback moth larvae and penthaleus major duges into
Worm can reach higher killing rate, realize within 2 days after and all kill substantially, illustrate the charged nanosize desinsection of the present invention
Agent has fabulous insecticidal effect.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of disinsection method using charged nanosize material, which is characterized in that specific method is：It is received to crops sprinkling electrification
Rice insecticide, the charge itself carried using the insecticide cuts the phospholipid bilayer of pest polypide, and then kills pest.
2. disinsection method according to claim 1, which is characterized in that the charged nanosize insecticide is powder, during use
With the water dissolution of 600~700 times of weight, it is then sprayed on crop surface.
3. disinsection method according to claim 2, which is characterized in that the charged nanosize insecticide is by the following method
It is prepared：
(1) preparation of hydrophilic solution：The polyvinyl alcohol containing hydrophilic radical is added in while stirring in 50~60 DEG C of water, added in
After continue stirring 20~30 minutes, obtain hydrophilic solution, it is spare；
(2) positively charged nano zine oxide is added in negatively charged Nanometer Titanium Dioxide Hydrosol, ultrasonic disperse makes two
Person is sufficiently mixed, and titanium dioxide nanoparticle is made to load on the surface of nano zine oxide by electrostatic interaction, obtains nanometer and answers
Condensation material；
(3) nanocomposite obtained by step (2) is added in hydrophilic solution obtained by step (1) and impregnated 5~6 minutes, after taking-up
Dehydration, it is dry to get.
4. disinsection method according to claim 3, which is characterized in that the mass ratio of polyvinyl alcohol and water is 1 in step (1)
: 30~32.
5. according to claim 3-4 any one of them disinsection methods, which is characterized in that the specific method of step (2) is：
(21) positively charged nano zine oxide is added according to the ratio of 3~4g/L in Nanometer Titanium Dioxide Hydrosol, ultrasound
Dispersion 15~20 minutes so that negatively charged nano-titania particle is adsorbed onto positively charged nanometer completely in the hydrosol
The surface of zinc oxide；
(22) adsorbed product is centrifugally separating to obtain, is then washed 2~3 times with absolute ethyl alcohol, it is dry, obtain nanocomposite.
6. according to claim 4-5 any one of them disinsection methods, which is characterized in that in step (22), dry technique item
Part is：Vacuum drying 8~12 hours.
7. the disinsection method according to claim 3 or 5, which is characterized in that the preparation method of Nanometer Titanium Dioxide Hydrosol
It is as follows：Butyl titanate and chelating agent are mixed 20~30 minutes, the mixing being then slowly added dropwise to catalyst and water is molten
In liquid, 1 hour is stood, obtains Nanometer Titanium Dioxide Hydrosol；Wherein, the molar ratio of butyl titanate, chelating agent and water is 1: 6
: 93, catalyst accounts for the 3.2% of whole system total weight.
8. according to claim 6-7 any one of them disinsection methods, which is characterized in that the chelating agent and catalyst are second
Acid.
9. disinsection method according to claim 3, which is characterized in that in step (3), nanocomposite and hydrophilic solution
Mass ratio be 1: 7~8.
10. disinsection method according to claim 3, which is characterized in that in step (3), be dehydrated, done using centrifugal process
Drying method is natural air drying.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1261824A (en) * | 1997-07-04 | 2000-08-02 | 南安普敦大学 | Improved targeting of flying insects with insecticides and apparatus for charging liquids |
| CN1805684A (en) * | 2003-06-18 | 2006-07-19 | 布鲁克·钱德勒·墨菲 | Pesticides with physical mode of action |
| CN101511193A (en) * | 2006-02-16 | 2009-08-19 | 萨克特本化学有限责任公司 | Biocidal composition |
| CN102413691A (en) * | 2009-04-30 | 2012-04-11 | 美国陶氏益农公司 | Insecticide composition comprising a spinosyn and a metal oxide |
| CN107896752A (en) * | 2017-11-27 | 2018-04-13 | 浙江夏远信息技术有限公司 | A kind of disinsection method using charged nanosize material |
| CN109794231A (en) * | 2017-11-17 | 2019-05-24 | 沙冰娟 | A kind of preparation method of titanium dioxide-zinc oxide nano catalytic material |
-
2017
- 2017-12-10 CN CN201711335375.3A patent/CN108208002A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1261824A (en) * | 1997-07-04 | 2000-08-02 | 南安普敦大学 | Improved targeting of flying insects with insecticides and apparatus for charging liquids |
| CN1805684A (en) * | 2003-06-18 | 2006-07-19 | 布鲁克·钱德勒·墨菲 | Pesticides with physical mode of action |
| CN101511193A (en) * | 2006-02-16 | 2009-08-19 | 萨克特本化学有限责任公司 | Biocidal composition |
| CN102413691A (en) * | 2009-04-30 | 2012-04-11 | 美国陶氏益农公司 | Insecticide composition comprising a spinosyn and a metal oxide |
| CN109794231A (en) * | 2017-11-17 | 2019-05-24 | 沙冰娟 | A kind of preparation method of titanium dioxide-zinc oxide nano catalytic material |
| CN107896752A (en) * | 2017-11-27 | 2018-04-13 | 浙江夏远信息技术有限公司 | A kind of disinsection method using charged nanosize material |
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