CN108018716A - A kind of preparation method of wear-resisting hydroscopicity non-woven fabrics - Google Patents
A kind of preparation method of wear-resisting hydroscopicity non-woven fabrics Download PDFInfo
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- CN108018716A CN108018716A CN201711468746.5A CN201711468746A CN108018716A CN 108018716 A CN108018716 A CN 108018716A CN 201711468746 A CN201711468746 A CN 201711468746A CN 108018716 A CN108018716 A CN 108018716A
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- woven fabrics
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- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 68
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical class CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 108010010803 Gelatin Proteins 0.000 claims abstract description 24
- 239000008273 gelatin Substances 0.000 claims abstract description 24
- 229920000159 gelatin Polymers 0.000 claims abstract description 24
- 235000019322 gelatine Nutrition 0.000 claims abstract description 24
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 24
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 239000010703 silicon Substances 0.000 claims abstract description 16
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 235000013618 yogurt Nutrition 0.000 claims abstract description 12
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 11
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 11
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 91
- 238000002156 mixing Methods 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 26
- 229910021641 deionized water Inorganic materials 0.000 claims description 26
- -1 polypropylene Polymers 0.000 claims description 26
- 239000004743 Polypropylene Substances 0.000 claims description 25
- 229920001155 polypropylene Polymers 0.000 claims description 25
- 239000003292 glue Substances 0.000 claims description 24
- 238000000855 fermentation Methods 0.000 claims description 23
- 230000004151 fermentation Effects 0.000 claims description 23
- 238000001816 cooling Methods 0.000 claims description 17
- 238000007599 discharging Methods 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 14
- 239000012634 fragment Substances 0.000 claims description 14
- 238000007654 immersion Methods 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 230000035484 reaction time Effects 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 8
- 238000011010 flushing procedure Methods 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 239000003643 water by type Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 6
- 239000000920 calcium hydroxide Substances 0.000 claims description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000010010 raising Methods 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 238000007731 hot pressing Methods 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 3
- 239000012295 chemical reaction liquid Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000661 sodium alginate Substances 0.000 abstract description 10
- 229940005550 sodium alginate Drugs 0.000 abstract description 10
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 abstract description 6
- 238000005213 imbibition Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 239000012744 reinforcing agent Substances 0.000 abstract description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000007259 addition reaction Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101001031591 Mus musculus Heart- and neural crest derivatives-expressed protein 2 Proteins 0.000 description 1
- 206010040914 Skin reaction Diseases 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to non-woven fabrics preparing technical field, and in particular to a kind of preparation method of wear-resisting hydroscopicity non-woven fabrics.The present invention is to make non-woven fabrics base substrate by oneself as base material,Gelatin and modified sodium alginate are made by oneself as reinforcing agent,And it is aided with to be modified from preparing silicon collosol etc. and wear-resisting hydroscopicity non-woven fabrics is prepared,Fish-skin is handled first with aqueous slkali and Yoghourt to obtain self-control gelatin,Sodium metaperiodate is recycled to be modified sodium alginate,Generate oxidized sodium alginate,After calcium chloride solution being added into sodium alginate,Improve the wearability of non-woven fabrics,Hydrophilic radical in self-control gelatin is covered in self-control non-woven fabrics base substrate fiber surface,Make non-woven fabrics that there is preferable water imbibition,In addition sodium alginate, which assigns non-woven fabrics, has tack,Continue with acrylic emulsion and sodium molybdate is modified Ludox,Silica is promoted effectively to be filled in non-woven fabrics,Reduce the porosity of non-woven fabrics,Further improve the wear-resisting property and self-adhesion of non-woven fabrics,It is with a wide range of applications.
Description
Technical field
The present invention relates to non-woven fabrics preparing technical field, and in particular to a kind of preparation method of wear-resisting hydroscopicity non-woven fabrics.
Background technology
Non-woven fabrics is also known as adhesive-bonded fabric, is made of fiber orient or random, because of the appearance with cloth and some property
Can and be called cloth.Non-woven fabrics has moisture-proof, ventilative, flexible, light, not combustion-supporting, easy decomposition, nontoxic nonirritant, color
The features such as abundant, cheap, recyclable.Polypropylene granules are used as raw material, through high-temperature fusion, spinneret, paving guiding principle, heat more
Writing that surpasses all the others takes continuous one-step to produce.It is a kind of fabric that need not be spinned cotton and woven cloth and be formed, simply by textile staple
Or long filament is oriented or randomizing, formed fibre net structure, then using it is mechanical, hot sticky or chemical the methods of reinforce and
Into.
Non-woven fabrics is widely portable to agricultural film, shoemaking, process hides, chemical industry, printing, vapour as environment-friendly materials of new generation
Car, building materials, home decoration, mattress bedding, dress and personal adornment, health care disposable utensil, hotel's disposable product and gift
The numerous areas such as bag, shopping bag, packaging bag.
Non-woven fabrics was being used in, it is existing obvious the defects of be exactly that wear-resisting property is poor, after a period of time,
Its surface can be fluffed by mill, directly affect the performance and appearance of non-woven fabrics.The wear-resisting method of modifying of existing non-woven fabrics, usually
It is that abrasionproof glue, even hard anti-wear glue-line are attached on two surfaces of non-woven fabrics, although playing the effect of abrasionproof,
Non-woven fabrics soft specific in itself is lost, cannot get the accreditation of consumer.In addition, also there are water imbibition for current non-woven fabrics
Difference, antibacterial ability is poor, anti-skidding and self-adhesion is not so good, and the non-woven fabrics being laid on furniture and floor is easy to slide from surface
The defects of opening, making non-woven fabrics lose defencive function.
Therefore, developing a kind of non-woven fabrics that can solve above-mentioned performance issue is highly desirable.
The content of the invention
The technical problems to be solved by the invention：For current common non-woven fabric in use for some time, its surface meeting
Fluffed by mill, directly affect the performance and appearance of non-woven fabrics, in addition also there are water imbibition difference and tack for common non-woven fabric
Can be poor the problem of, the non-woven fabrics being laid on furniture and floor is easy to slip off from surface, non-woven fabrics is lost defencive function
A kind of defect, there is provided preparation method of wear-resisting hydroscopicity non-woven fabrics.
In order to solve the above technical problems, the present invention is using technical solution as described below：
A kind of preparation method of wear-resisting hydroscopicity non-woven fabrics, it is characterised in that specifically preparation process is：
（1）Weigh 35~45g fish-skins and be put into pulper and blend, obtain fish-skin fragment, by fish-skin fragment, calcium hydroxide and go from
The mixing of sub- water, which is placed in beaker, soaks, and obtains immersion fish-skin, with deionized water cleaning and dipping fish-skin, then by the fish-skin after cleaning and
Yoghourt mixing is placed in fermentation tank, is sealed by fermentation, and after fermentation, takes out tunning, with deionized water rinsing tunning,
Tunning after flushing and distilled water are mixed to be placed in water-bath and carry glue, filtering removes filter residue, takes out glue, glue is put
Rotated in rotary evaporator, remove moisture removal, obtain self-control gelatin；
（2）Weigh 12~16g sodium alginates and pour into the beaker with 20~30mL absolute ethyl alcohols and be mixed, it is outstanding to obtain self-control
Supernatant liquid, then weigh 3~5g sodium metaperiodates and pour into the beaker with 24~30mL deionized waters and be mixed, obtain making by oneself molten
Liquid, self-control solution is added in above-mentioned self-control suspension, and reaction is mixed at room temperature unglazed, obtains reaction solution, continues
The polyethylene glycol that reaction solution volume 3% is added into reaction solution is mixed, and obtains mixed liquor, mixed liquor and absolute ethyl alcohol are mixed
Stirring is closed, filters and removes filtrate, wash filter residue with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then by table
Face ware is placed in drying in baking oven, obtains modified sodium alginate；
（3）Absolute ethyl alcohol, ammonium hydroxide and deionized water are mixed to be placed in beaker and stir reaction, obtains reaction solution, then into beaker
The ethyl orthosilicate of reaction solution volume 11% and the absolute ethyl alcohol hybrid reaction of mixeding liquid volume 0.2% are added, obtains self-control reaction
Liquid, then reaction solution, the acrylic emulsion that solid content is 49% and sodium molybdate will be made by oneself and mix and be placed in beaker, continue stirring instead
Should, cooling discharging, obtains modified from preparing silicon collosol；
（4）Weighing 100~120g polypropylene heat temperature raisings makes its softening, and the polypropylene after softening is put into spinneret in spinneret,
Self-control polypropylene fibre is obtained, self-control polypropylene fibre is placed in hot-forming in hot press, cooling discharging, obtains self-control nonwoven
Cloth base substrate；
（5）Modified sodium alginate, self-control gelatin and calcium chloride solution are mixed to be placed in beaker and stir reaction, obtains reaction solution,
It is mixed again by reaction solution and from preparing silicon collosol, obtains mixed liquor, continues self-control non-woven fabrics base substrate being put into mixed liquor
Beaker in soak, be put into baking oven and dry after immersion, cooling discharging, up to wear-resisting hydroscopicity non-woven fabrics.
Step（1）The time that blends is 8~10min, and the mass ratio of fish-skin fragment, calcium hydroxide and deionized water is
1：2：5, soaking time is 3~5h, and wash number is 3~5 times, and the mass ratio of fish-skin and Yoghourt after cleaning is 1：5, fermentation temperature
Spend for 35~45 DEG C, fermentation time is 1~2 day, and washing time is 2~4 times, the quality of tunning and distilled water after flushing
Than for 1：4, glue temperature is put forward as 65~80 DEG C, and it is 1~3h to carry the glue time, and the revolving time is 8~12min.
Step（2）The mixing time is 24~32min, and mixing time is 6~8min, the stirring reaction time for 4~
6h, mixing time are 45~60min, and the volume ratio of mixed liquor and absolute ethyl alcohol is 1；4, continue to be mixed the time as 9
~11min, washing times are 1~3 time, and drying temperature is 65~75 DEG C, and drying time is 2~4h.
Step（3）The volume ratio of the absolute ethyl alcohol, the ammonium hydroxide that mass fraction is 16% and deionized water is 5：1：2, stir
Reaction temperature is mixed as 32~45 DEG C, the stirring reaction time be 10~12min, and reaction temperature is 55~65 DEG C, the reaction time is 1~
2h, the mass ratio of self-control reaction solution, the acrylic emulsion that solid content is 49% and sodium molybdate is 3：1：1, continue to stir reaction temperature
For 85~95 DEG C, it is 45~60min to continue the stirring reaction time.
Step（4）The heat temperature raising temperature is 165~175 DEG C, and spinneret pressure is 0.4~0.6MPa, hot pressing temperature
For 100~120 DEG C, hot pressing pressure is 1~3MPa.
Step（5）The mass ratio of the modified sodium alginate, self-control gelatin and calcium chloride solution that mass fraction is 7%
For 5：3：1, stirring reaction temperature is 75~85 DEG C, and the stirring reaction time is 24~32min, reaction solution and the matter from preparing silicon collosol
Amount is than being 3：1, the mixing time is 10~12min, and soaking temperature is 45~65 DEG C, and soaking time is 1~2h, drying temperature
For 75~85 DEG C, drying time is 1~3h.
Compared with other methods, advantageous effects are the present invention：
（1）The present invention makes gelatin and modified sodium alginate by oneself as reinforcing agent, and be aided with and change to make non-woven fabrics base substrate by oneself as base material
Property from preparing silicon collosol etc. wear-resisting hydroscopicity non-woven fabrics is prepared, reaction treatment is carried out to fish-skin first with aqueous slkali and Yoghourt
Self-control gelatin is obtained, recycles sodium metaperiodate to be modified sodium alginate, due to containing in a monomeric unit of sodium alginate
There are two adjacent hydroxyls, hydroxyl can be by sodium periodate oxidation into two aldehyde radicals, and generates oxidized sodium alginate, is preparing
Cheng Zhong, itself and self-control gelatin are occurred physically or chemically to react, form the inierpeneirating network structure of densification, which is conducive to nothing
The wear-resisting property of woven fabric is improved, while containing substantial amounts of-OH and-COO- in sodium alginate, and make by oneself in gelatin containing big
- the NH of amount2With-COOH, Maillard reaction can occur between sodium alginate and self-control gelatin, and pass through intermolecular force, hydrogen
The effect such as key and ionic bond is combined, so as to form interpenetrating cross-linked network structure, improve interaction force therebetween and
Compatibility, after in addition adding calcium chloride solution into sodium alginate, two in sodium ion and calcium chloride solution in sodium alginate
Chelation occurs for valency calcium ion, forms cross-linked network structure, improves the wearability of non-woven fabrics again；
（2）The present invention carries out fish-skin reaction treatment using aqueous slkali and Yoghourt and obtains self-control gelatin, makes by oneself in gelatin containing big
- the NH of amount2With-COOH, these hydrophilic radicals are covered in the fiber surface of self-control non-woven fabrics base substrate, have non-woven fabrics preferable
Water imbibition, in addition sodium alginate is a kind of high-molecular compound of high viscosity so that non-woven fabrics has tack, continues with third
Olefin(e) acid lotion and sodium molybdate are modified to having sticking Ludox, since the silica in Ludox can be with acrylic acid
Hydroxyl in resin crosslinks reaction, forms fine and close net structure, while colloidal silica particles pass through-OH keys or-O-
With the anion ligand in sodium molybdate coordination cross-linked reaction occurs for key, forms colloidal sol formula structure, silica can be promoted to have
It is filled in non-woven fabrics to effect, reduces the porosity of non-woven fabrics, make the structure of non-woven fabrics interbed finer and close, further improve nothing
The wear-resisting property and self-adhesion of woven fabric, are with a wide range of applications.
Embodiment
Weigh 35~45g fish-skins and be put into pulper and blend 8~10min, obtain fish-skin fragment, be in mass ratio 1：2：5
Fish-skin fragment, calcium hydroxide and deionized water are mixed and are placed in 3~5h of immersion in beaker, immersion fish-skin is obtained, uses deionized water
Cleaning and dipping fish-skin 3~5 times, then be 1 in mass ratio：5 are placed in the fish-skin after cleaning and Yoghourt mixing in fermentation tank, in temperature
To be sealed by fermentation under conditions of 35~45 DEG C 1~2 day, after fermentation, tunning is taken out, fermented and produced with deionized water rinsing
Thing 2~4 times, is 1 in mass ratio by the tunning after flushing and distilled water：4 mixing are placed in water-bath, temperature for 65~
1~3h of glue is carried at 80 DEG C, filtering removes filter residue, takes out glue, and glue is placed in 8~12min of revolving in rotary evaporator, is removed
Moisture, obtains self-control gelatin；Weigh 12~16g sodium alginates and pour into the beaker with 20~30mL absolute ethyl alcohols and be mixed
24~32min, obtains self-control suspension, then weighs 3~5g sodium metaperiodates and pour into the beaker with 24~30mL deionized waters
6~8min is mixed, obtains self-control solution, self-control solution is added in above-mentioned self-control suspension, is mixed at room temperature unglazed
Stirring 4~6h of reaction is closed, obtains reaction solution, the polyethylene glycol for continuing to add reaction solution volume 3% into reaction solution is mixed 45
~60min, obtains mixed liquor, is by volume 1；9~11min is mixed in mixed liquor and absolute ethyl alcohol by 4, is filtered and is removed filter
Liquid, washs filter residue 1~3 time with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then surface plate is placed in baking oven
In, dry 2~4h at being 65~75 DEG C in temperature, obtains modified sodium alginate；It is 5 by volume：1：2 by absolute ethyl alcohol, matter
Amount fraction be 16% ammonium hydroxide and deionized water mixing is placed in beaker, temperature be 32~45 DEG C at stirring reaction 10~
12min, obtains reaction solution, then the nothing of the ethyl orthosilicate of addition reaction solution volume 11% and mixeding liquid volume 0.2% into beaker
Water-ethanol, 1~2h of hybrid reaction at being 55~65 DEG C in temperature, obtains self-control reaction solution, then is 3 in mass ratio：1：1 will self-control
Reaction solution, the acrylic emulsion that solid content is 49% and sodium molybdate mixing are placed in beaker, under conditions of temperature is 85~95 DEG C
Continue stirring 45~60min of reaction, cooling discharging, obtains modified from preparing silicon collosol；Weigh 100~120g polypropylene heat temperature raisings
Make its softening to 165~175 DEG C, the polypropylene after softening is put into spinneret, under conditions of pressure is 0.4~0.6MPa
Spinneret, obtains self-control polypropylene fibre, and self-control polypropylene fibre is placed in hot press, is 100~120 DEG C, pressure in temperature
For hot-forming, cooling discharging under conditions of 1~3MPa, self-control non-woven fabrics base substrate is obtained；By modified sodium alginate, self-control gelatin
The calcium chloride solution for being 7% with mass fraction is 5 in mass ratio：3：1 mixing is placed in beaker, is stirred at being 75~85 DEG C in temperature
24~32min of reaction is mixed, obtains reaction solution, then is 3 in mass ratio：1 by reaction solution and from preparing silicon collosol be mixed 10~
12min, obtains mixed liquor, continues self-control non-woven fabrics base substrate being put into the beaker with mixed liquor, is 45~65 DEG C in temperature
1~2h of lower immersion, is put into baking oven after immersion, and 1~3h, cooling discharging, up to wear-resisting suction are dried at being 75~85 DEG C in temperature
Water type non-woven fabrics.
Example 1
Weigh 35g fish-skins and be put into pulper and blend 8min, obtain fish-skin fragment, be in mass ratio 1：2：5 by fish-skin fragment, hydrogen
Calcium oxide and deionized water mixing are placed in beaker and soak 3h, obtain immersion fish-skin, with deionized water cleaning and dipping fish-skin 3 times,
It is 1 in mass ratio again：5 are placed in the fish-skin after cleaning and Yoghourt mixing in fermentation tank, are sealed under conditions of being 35 DEG C in temperature
Fermentation 1 day, after fermentation, takes out tunning, with deionized water rinsing tunning 2 times, by the tunning after flushing
It is 1 in mass ratio with distilled water：4 mixing are placed in water-bath, carry glue 1h at being 65 DEG C in temperature, filtering removes filter residue, takes out
Glue, glue is placed in rotary evaporator and rotates 8min, removes moisture removal, obtains self-control gelatin；12g sodium alginates are weighed to pour into
24min is mixed in beaker with 20mL absolute ethyl alcohols, obtains self-control suspension, then weigh 3g sodium metaperiodates and pour into and carry
6min is mixed in the beaker of 24mL deionized waters, obtains self-control solution, self-control solution is added to above-mentioned self-control suspension
In, reaction 4h is mixed at room temperature unglazed, obtains reaction solution, continues to add the poly- second of reaction solution volume 3% into reaction solution
45min is mixed in glycol, obtains mixed liquor, is by volume 1；9min is mixed in mixed liquor and absolute ethyl alcohol by 4, is filtered
Filtrate is removed, filter residue is washed 1 time with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then surface plate is placed in
In baking oven, dry 2h at being 65 DEG C in temperature, obtains modified sodium alginate；It is 5 by volume：1：2 divide absolute ethyl alcohol, quality
Number is placed in beaker for 16% ammonium hydroxide and deionized water mixing, and stirring reaction 10min, obtains reaction solution at being 32 DEG C in temperature,
The ethyl orthosilicate of reaction solution volume 11% and the absolute ethyl alcohol of mixeding liquid volume 0.2% are added into beaker again, is 55 in temperature
Hybrid reaction 1h at DEG C, obtains self-control reaction solution, then is 3 in mass ratio：1：1 propylene that will make reaction solution by oneself, solid content is 49%
Yogurt liquid and sodium molybdate mixing is placed in beaker, temperature be 85 DEG C under conditions of continue stirring reaction 45min, cooling discharging,
Obtain modified from preparing silicon collosol；Weighing 100g polypropylene and being heated to 165 DEG C makes its softening, and the polypropylene after softening is put into
In spinneret, the spinneret under conditions of pressure is 0.4MPa obtains self-control polypropylene fibre, and self-control polypropylene fibre is placed in heat
In press, hot-forming, the cooling discharging under conditions of temperature is 100 DEG C, pressure is 1MPa, obtains self-control non-woven fabrics base substrate；
It is 5 in mass ratio by the calcium chloride solution that modified sodium alginate, self-control gelatin and mass fraction are 7%：3：1 mixing is placed in beaker
In, stirring reaction 24min, obtains reaction solution at being 75 DEG C in temperature, then is 3 in mass ratio：1 by reaction solution and from preparing silicon collosol
10min is mixed, obtains mixed liquor, continues self-control non-woven fabrics base substrate being put into the beaker with mixed liquor, is in temperature
1h is soaked at 45 DEG C, is put into after immersion in baking oven, 1h is dried at being 75 DEG C in temperature, cooling discharging, up to wear-resisting hydroscopicity without
Woven fabric.
Example 2
Weigh 40g fish-skins and be put into pulper and blend 9min, obtain fish-skin fragment, be in mass ratio 1：2：5 by fish-skin fragment, hydrogen
Calcium oxide and deionized water mixing are placed in beaker and soak 4h, obtain immersion fish-skin, with deionized water cleaning and dipping fish-skin 4 times,
It is 1 in mass ratio again：5 are placed in the fish-skin after cleaning and Yoghourt mixing in fermentation tank, are sealed under conditions of being 40 DEG C in temperature
Fermentation 1.5 days, after fermentation, takes out tunning, and with deionized water rinsing tunning 3 times, the fermentation after flushing is produced
Thing and distilled water are 1 in mass ratio：4 mixing are placed in water-bath, carry glue 2h at being 93 DEG C in temperature, filtering removes filter residue, takes
Go out glue, glue is placed in rotary evaporator and rotates 10min, remove moisture removal, obtain self-control gelatin；Weigh 14g sodium alginates
Pour into the beaker with 25mL absolute ethyl alcohols and 28min is mixed, obtain self-control suspension, then weigh 4g sodium metaperiodates and pour into
7min is mixed in beaker with 26mL deionized waters, obtains self-control solution, self-control solution is added to above-mentioned self-control hangs
In supernatant liquid, reaction 5h is mixed at room temperature unglazed, obtains reaction solution, continues to add reaction solution volume 3% into reaction solution
53min is mixed in polyethylene glycol, obtains mixed liquor, is by volume 1；4 mixed liquor and absolute ethyl alcohol are mixed
10min, filters and removes filtrate, wash filter residue 2 times with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then will
Surface plate is placed in baking oven, and dry 3h at being 70 DEG C in temperature, obtains modified sodium alginate；It is 5 by volume：1：2 will be anhydrous
Ethanol, the ammonium hydroxide that mass fraction is 16% and deionized water mixing are placed in beaker, stirring reaction 11min at being 38 DEG C in temperature,
Reaction solution, then the absolute ethyl alcohol of the ethyl orthosilicate of addition reaction solution volume 11% and mixeding liquid volume 0.2% into beaker are obtained,
Hybrid reaction 1.5h at being 60 DEG C in temperature, obtains self-control reaction solution, then is 3 in mass ratio：1：1 will make reaction solution by oneself, contain admittedly
Measure and be placed in for 49% acrylic emulsion and sodium molybdate mixing in beaker, continue stirring reaction under the conditions of at a temperature of 90 °C
53min, cooling discharging, obtains modified from preparing silicon collosol；Weighing 110g polypropylene and being heated to 170 DEG C makes its softening, will be soft
Polypropylene after change is put into spinneret, and the spinneret under conditions of pressure is 0.5MPa, obtains self-control polypropylene fibre, will make by oneself
Polypropylene fibre is placed in hot press, and hot-forming under conditions of temperature is 110 DEG C, pressure is 2MPa, cooling discharging, obtains
Make non-woven fabrics base substrate by oneself；It is 5 in mass ratio by the calcium chloride solution that modified sodium alginate, self-control gelatin and mass fraction are 7%：
3：1 mixing is placed in beaker, and stirring reaction 28min, obtains reaction solution at being 80 DEG C in temperature, then is 3 in mass ratio：1 will be anti-
Answer liquid and 11min is mixed from preparing silicon collosol, obtain mixed liquor, continue self-control non-woven fabrics base substrate being put into mixed liquor
In beaker, 1.5h is soaked at being 55 DEG C in temperature, is put into after immersion in baking oven, 2h is dried at being 80 DEG C in temperature, cooling discharging,
Up to wear-resisting hydroscopicity non-woven fabrics.
Example 3
Weigh 45g fish-skins and be put into pulper and blend 10min, obtain fish-skin fragment, be in mass ratio 1：2：5 by fish-skin fragment,
Calcium hydroxide and deionized water mixing are placed in beaker and soak h, obtain immersion fish-skin, with deionized water cleaning and dipping fish-skin 5 times,
It is 1 in mass ratio again：5 are placed in the fish-skin after cleaning and Yoghourt mixing in fermentation tank, are sealed under conditions of being 45 DEG C in temperature
Fermentation 2 days, after fermentation, takes out tunning, with deionized water rinsing tunning 4 times, by the tunning after flushing
It is 1 in mass ratio with distilled water：4 mixing are placed in water-bath, carry glue 3h at being 80 DEG C in temperature, filtering removes filter residue, takes out
Glue, glue is placed in rotary evaporator and rotates 12min, removes moisture removal, obtains self-control gelatin；16g sodium alginates are weighed to fall
Enter in the beaker with 30mL absolute ethyl alcohols and 32min is mixed, obtain self-control suspension, then weigh 5g sodium metaperiodates and pour into band
Have in the beaker of 30mL deionized waters and 8min is mixed, obtain self-control solution, self-control solution is added to above-mentioned self-control suspends
In liquid, reaction 6h is mixed at room temperature unglazed, obtains reaction solution, continues to add the poly- of reaction solution volume 3% into reaction solution
60min is mixed in ethylene glycol, obtains mixed liquor, is by volume 1；11min is mixed in mixed liquor and absolute ethyl alcohol by 4,
Filter and remove filtrate, wash filter residue 3 times with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then by surface plate
It is placed in baking oven, dry 4h at being 75 DEG C in temperature, obtains modified sodium alginate；It is 5 by volume：1：2 by absolute ethyl alcohol, matter
The ammonium hydroxide and deionized water mixing that amount fraction is 16% are placed in beaker, and stirring reaction 12min, obtains anti-at being 45 DEG C in temperature
Liquid, then the absolute ethyl alcohol of the ethyl orthosilicate of addition reaction solution volume 11% and mixeding liquid volume 0.2% into beaker are answered, in temperature
For hybrid reaction 2h at 65 DEG C, self-control reaction solution is obtained, then is 3 in mass ratio：1：1 will make reaction solution by oneself, solid content is 49%
Acrylic emulsion and sodium molybdate mixing are placed in beaker, are continued stirring reaction 60min under conditions of being 95 DEG C in temperature, are cooled down out
Material, obtains modified from preparing silicon collosol；Weighing 120g polypropylene and being heated to 175 DEG C makes its softening, by the polypropylene after softening
It is put into spinneret, the spinneret under conditions of pressure is 0.6MPa, obtains self-control polypropylene fibre, self-control polypropylene fibre is put
In hot press, hot-forming, the cooling discharging under conditions of temperature is 120 DEG C, pressure is 3MPa, obtains self-control non-woven fabrics base
Body；It is 5 in mass ratio by the calcium chloride solution that modified sodium alginate, self-control gelatin and mass fraction are 7%：3：1 mixing is placed in burning
In cup, stirring reaction 32min, obtains reaction solution at being 85 DEG C in temperature, then is 3 in mass ratio：1 is molten by reaction solution and self-control silicon
12min is mixed in glue, obtains mixed liquor, continues self-control non-woven fabrics base substrate being put into the beaker with mixed liquor, in temperature
To soak 2h at 65 DEG C, it is put into after immersion in baking oven, 3h, cooling discharging, up to wear-resisting hydroscopicity is dried at being 85 DEG C in temperature
Non-woven fabrics.
Comparative example
With the non-woven fabrics of company of Changshu City production as a comparison case
Non-woven fabrics in wear-resisting hydroscopicity non-woven fabrics produced by the present invention and comparative example is detected, the testing result such as institute of table 1
Show：
Tensile strength：It is measured using the standard of GB/T3917.3.
Tearing strength：It is measured using the standard of GB/T3923.1.
Wear-resisting property is tested：
Example 1~3 and comparative example product prepared by the present invention, the sample that size is 5cm × 5cm is cut into cut-off knife,
It is divided into 4 groups, every group of 5 parts of parallel samples.20 samples are put into folder cloth annulus and screwed respectively, place it in disc type fabric
On resistance to grinding machine.Start button is pressed, and observes the degree that sample is damaged, treats that sample ruptures, presses stop button, and record
Data, are averaged.
Pilling is tested：
Martindale's fluffing instrument is selected, reference standard GB/T4802.2 is tested.
1 grade：It is qualified（The point that tangles is 0）It is phozy；
2 grades：It is qualified（Entanglement Dian≤5）Slight fluffing；
3 grades：It is unqualified（Entanglement Dian≤10）Fluff more serious；
4 grades：It is unqualified（Entanglement point>10）Fluffing is serious.
Water imbibition is tested：
Each one piece of the sample of two kinds of 30 × 60mm of sample is taken, its dry weight is weighed respectively, sample is put into the beaker of 250mL, add
Enter 100mL deionized waters, place 10,30 and 60min, each period takes out and weighs once.Should gently it be trembled before weighing to not having
Under water droplet.
Water content=sample weight in wet base-sample dry weight
1 performance measurement result of table
From the data in table 1, it can be seen that wear-resisting hydroscopicity non-woven fabrics produced by the present invention, have mechanical property it is strong, it is wear-resisting and be not easy balling-up,
The advantages that good water absorption, hence it is evident that better than comparative example product.Therefore, there is wide prospect of the application.
Claims (6)
1. a kind of preparation method of wear-resisting hydroscopicity non-woven fabrics, it is characterised in that specifically preparation process is：
（1）Weigh 35~45g fish-skins and be put into pulper and blend, obtain fish-skin fragment, by fish-skin fragment, calcium hydroxide and go from
The mixing of sub- water, which is placed in beaker, soaks, and obtains immersion fish-skin, with deionized water cleaning and dipping fish-skin, then by the fish-skin after cleaning and
Yoghourt mixing is placed in fermentation tank, is sealed by fermentation, and after fermentation, takes out tunning, with deionized water rinsing tunning,
Tunning after flushing and distilled water are mixed to be placed in water-bath and carry glue, filtering removes filter residue, takes out glue, glue is put
Rotated in rotary evaporator, remove moisture removal, obtain self-control gelatin；
（2）Weigh 12~16g sodium alginates and pour into the beaker with 20~30mL absolute ethyl alcohols and be mixed, it is outstanding to obtain self-control
Supernatant liquid, then weigh 3~5g sodium metaperiodates and pour into the beaker with 24~30mL deionized waters and be mixed, obtain making by oneself molten
Liquid, self-control solution is added in above-mentioned self-control suspension, and reaction is mixed at room temperature unglazed, obtains reaction solution, continues
The polyethylene glycol that reaction solution volume 3% is added into reaction solution is mixed, and obtains mixed liquor, mixed liquor and absolute ethyl alcohol are mixed
Stirring is closed, filters and removes filtrate, wash filter residue with absolute ethyl alcohol, finally the filter residue after washing is put into surface plate, then by table
Face ware is placed in drying in baking oven, obtains modified sodium alginate；
（3）Absolute ethyl alcohol, ammonium hydroxide and deionized water are mixed to be placed in beaker and stir reaction, obtains reaction solution, then into beaker
The ethyl orthosilicate of reaction solution volume 11% and the absolute ethyl alcohol hybrid reaction of mixeding liquid volume 0.2% are added, obtains self-control reaction
Liquid, then reaction solution, the acrylic emulsion that solid content is 49% and sodium molybdate will be made by oneself and mix and be placed in beaker, continue stirring and react,
Cooling discharging, obtains modified from preparing silicon collosol；
（4）Weighing 100~120g polypropylene heat temperature raisings makes its softening, and the polypropylene after softening is put into spinneret in spinneret,
Self-control polypropylene fibre is obtained, self-control polypropylene fibre is placed in hot-forming in hot press, cooling discharging, obtains self-control nonwoven
Cloth base substrate；
（5）Modified sodium alginate, self-control gelatin and calcium chloride solution are mixed to be placed in beaker and stir reaction, obtains reaction solution,
It is mixed again by reaction solution and from preparing silicon collosol, obtains mixed liquor, continues self-control non-woven fabrics base substrate being put into mixed liquor
Beaker in soak, be put into baking oven and dry after immersion, cooling discharging, up to wear-resisting hydroscopicity non-woven fabrics.
A kind of 2. preparation method of wear-resisting hydroscopicity non-woven fabrics according to claim 1, it is characterised in that：Step（1）Institute
The time that blends stated is 8~10min, and the mass ratio of fish-skin fragment, calcium hydroxide and deionized water is 1：2：5, soaking time 3
~5h, wash number are 3~5 times, and the mass ratio of fish-skin and Yoghourt after cleaning is 1：5, fermentation temperature is 35~45 DEG C, fermentation
Time is 1~2 day, and washing time is 2~4 times, and the mass ratio of tunning and distilled water after flushing is 1：4, put forward glue temperature
For 65~80 DEG C, it is 1~3h to carry the glue time, and the revolving time is 8~12min.
A kind of 3. preparation method of wear-resisting hydroscopicity non-woven fabrics according to claim 1, it is characterised in that：Step（2）Institute
The mixing time stated is 24~32min, and mixing time is 6~8min, and the stirring reaction time is 4~6h, be mixed the time be
The volume ratio of 45~60min, mixed liquor and absolute ethyl alcohol is 1；4, it is 9~11min to continue the mixing time, and washing times are
1~3 time, drying temperature is 65~75 DEG C, and drying time is 2~4h.
A kind of 4. preparation method of wear-resisting hydroscopicity non-woven fabrics according to claim 1, it is characterised in that：Step（3）Institute
The ammonium hydroxide and the volume ratio of deionized water that absolute ethyl alcohol, the mass fraction stated are 16% are 5：1：2, stirring reaction temperature for 32~
45 DEG C, the stirring reaction time is 10~12min, and reaction temperature is 55~65 DEG C, and the reaction time is 1~2h, and self-control reaction solution, consolidate
The acrylic emulsion and the mass ratio of sodium molybdate that content is 49% are 3：1：1, it is 85~95 DEG C to continue to stir reaction temperature, is continued
The stirring reaction time is 45~60min.
A kind of 5. preparation method of wear-resisting hydroscopicity non-woven fabrics according to claim 1, it is characterised in that：Step（4）Institute
The heat temperature raising temperature stated is 165~175 DEG C, and spinneret pressure is 0.4~0.6MPa, and hot pressing temperature is 100~120 DEG C, hot pressing
Pressure is 1~3MPa.
A kind of 6. preparation method of wear-resisting hydroscopicity non-woven fabrics according to claim 1, it is characterised in that：Step（5）Institute
The mass ratio for the calcium chloride solution that modified sodium alginate, self-control gelatin and the mass fraction stated are 7% is 5：3：1, stirring reaction temperature
Spend for 75~85 DEG C, the stirring reaction time is 24~32min, and reaction solution and the mass ratio from preparing silicon collosol are 3：1, it is mixed
Time is 10~12min, and soaking temperature is 45~65 DEG C, and soaking time be 1~2h, and drying temperature is 75~85 DEG C, during drying
Between be 1~3h.
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| CN110093810A (en) * | 2019-05-08 | 2019-08-06 | 吉林大学 | A kind of paper base for detecting water-injected meat/silica solution/polyvinyl alcohol (PVA) changes colour composite membrane, preparation method and applications |
| CN111485427A (en) * | 2020-05-08 | 2020-08-04 | 安徽省农业科学院棉花研究所 | Method capable of enhancing hydrophilic property of cotton fiber |
| CN111485427B (en) * | 2020-05-08 | 2022-06-07 | 安徽省农业科学院棉花研究所 | Method capable of enhancing hydrophilic property of cotton fiber |
| CN111979760A (en) * | 2020-09-03 | 2020-11-24 | 王言 | Waterproof non-woven fabric and preparation method thereof |
| WO2024214334A1 (en) * | 2023-04-11 | 2024-10-17 | 株式会社日本製鋼所 | Method for producing nonwoven fabric sheet, device for producing nonwoven fabric sheet, and nonwoven fabric sheet |
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