CN107950566A - A kind of anilofos emulsifiable granula and preparation method thereof - Google Patents
A kind of anilofos emulsifiable granula and preparation method thereof Download PDFInfo
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- CN107950566A CN107950566A CN201711382453.5A CN201711382453A CN107950566A CN 107950566 A CN107950566 A CN 107950566A CN 201711382453 A CN201711382453 A CN 201711382453A CN 107950566 A CN107950566 A CN 107950566A
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- China
- Prior art keywords
- anilofos
- emulsifiable
- emulsifiable granula
- solvent
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical compound COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000005469 granulation Methods 0.000 title abstract description 5
- 239000003921 oil Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 12
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims abstract description 3
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- -1 alkyl glycosides Chemical class 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 235000012216 bentonite Nutrition 0.000 claims description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 241000978776 Senegalia senegal Species 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 235000010216 calcium carbonate Nutrition 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 238000009472 formulation Methods 0.000 abstract description 6
- 238000012216 screening Methods 0.000 abstract description 6
- 230000000857 drug effect Effects 0.000 abstract description 4
- 239000000428 dust Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000003337 fertilizer Substances 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 239000004927 clay Substances 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 20
- 239000004480 active ingredient Substances 0.000 description 7
- 239000003814 drug Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 235000007164 Oryza sativa Nutrition 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 235000009566 rice Nutrition 0.000 description 6
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 239000004563 wettable powder Substances 0.000 description 5
- 241000192043 Echinochloa Species 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000234653 Cyperus Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 241000400644 Echinochloa oryzicola Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical group 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- 241001290610 Abildgaardia Species 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000234646 Cyperaceae Species 0.000 description 1
- 244000285790 Cyperus iria Species 0.000 description 1
- 241001553700 Euphorbia lathyris Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001582888 Lobus Species 0.000 description 1
- 240000000178 Monochoria vaginalis Species 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of anilofos emulsifiable granula and preparation method thereof, belongs to pesticide technology formulation field.Component forms：The content of anilofos is 1 40%, solvent 1 15%, emulsifying agent 0 15%, dispersant 0 10%, binding agent 0 10%, carrier are supplied.Preparation method：1）Pesticide activity component is dissolved using solvent；2）By ultramicro grinding after binding agent, dispersant, carrier mixing；3）Oil base is adsorbed to 2 with Sprayable）Obtained solid；4）Add water to mediate to be granulated, drying, screening.Anilofos emulsifiable granula provided by the invention have good fluidity, without dust, do not lump, concomitant fertilizer pesticide-clay mixture can be used directly, laborsaving, drug effect is excellent.
Description
Technical field
The invention belongs to pesticide technology formulation field, and in particular to a kind of using anilofos as the emulsifiable of active ingredient
Granula.
Background technology
Anilofos（Anilofos）, belong to less toxic organic phosphates selective inner-adsorption conduction-type herbicide.Pass through the young shoot of plant
Absorbed with subterranean stem, suppress Tom Clancy Splinter Cell stretching, extension, make weeds young leaves be not easy to extract out, growth stops, and finally cries dead.Align sprouting
Weeds effect is best, poor to the weeds effect grown up.Weeds grow stopping after by medicine, blade is dark green, decolourizes sometimes, blade
Shorten and thick, easily fracture, lobus cardiacus is not easy to extract out, and last whole strain is withered.The barnyard grass and Cyperaceae in tri-leaf period can effectively be prevented and kill off
Weeds, to rice safety.
At present, anilofos mainly have two kinds of wettable powder, missible oil formulations, these three formulations are in security, environment-friendly type, province
Work has deficiency.Anilofos wettable powder process dust is big, easy drift, and dust gathers to there is explosion wind to a certain degree
Danger, anilofos missible oil is inflammable and explosive because using a large amount of aromatic hydrocarbon solvents, is not easy pollution degradation environment in the environment, and waste stone
Oily resource.Emulsifiable granula is a kind of novel form for being granulated and being formed on the basis of wettable powder and missible oil, comprehensive missible oil compared with
Good preventive effect and wettable powder characteristic of low cost.
The content of the invention
The object of the present invention is to provide a kind of using anilofos as emulsifiable granula of active ingredient and preparation method thereof.
The method have the characteristics that form uniform emulsion after the particles with water dilution prepared.
The present invention is achieved by the following technical programs, it is characterised in that：
Anilofos 1-40%
Solvent 1-15%
Emulsifying agent 1-15%
Dispersant 0-10%
Binding agent 0-10%
Carrier is mended to 100%
Solvent mixing one or more of in C9 solvent naphthas, sec-butyl acetate, isophorone.
The emulsifying agent is selected from fatty alcohol polyoxyethylene ether, alkyl glycosides, castor oil polyoxyethylene ether, detergent alkylate
One or more of mixtures in sulfoacid calcium, styryl phenol polyethenoxy ether, polyol fatty acid ester.
The dispersant is selected from lauryl sodium sulfate, sodium lignin sulfonate, calcium lignosulfonate, pull open powder, poly- carboxylic
One or more of mixtures in hydrochlorate salt.
The binding agent is selected from sodium carboxymethylcellulose, polyvinyl alcohol, xanthans, gum arabic, carboxymethyl starch
One or more of mixtures in sodium.
The carrier is selected from white carbon, diatomite, attapulgite, kaolin, bentonite, sodium sulphate, sodium benzoate, carbon
One or more of mixtures in sour calcium, white sugar, urea, ammonium sulfate, ammonium hydrogen carbonate.
The present invention also provides a kind of preparation method of anilofos emulsifiable granula, comprise the steps of：
（1）Pesticide activity component anilofos are dissolved in suitable solvent, and add emulsifying agent and form oil base；
（2）Dispersant, binding agent and carrier are uniformly mixed, ultramicro grinding is carried out by airslide disintegrating mill, obtains a 400 mesh left side
Right fine powder；
（3）Oil base even spraying is complete to absorption on the dispersant and carrier by air-flow crushing；
（4）Water is added into step 2 obtained solid, and is transferred to mediate in Squeezinggranulator and is granulated；
（5）To the drying of made particle, screening, the anilofos emulsifiable granula finished product of qualification can obtain.
Beneficial effects of the present invention：The present invention is a kind of emulsifiable granula, and when use adds water to form uniform emulsion,
Drug effect is better than the wettable powder with active ingredient；The present invention adds a large amount of carriers, substitutes organic solvent, and safety is stored in transport,
Better than the missible oil of same active ingredient；The present invention uses particle form, available for companion's soil, and enters water rear bearing physical efficiency and is disintegrated completely, makes
Medicament can be adsorbed more preferably on soil, increase the lasting period, and save labor using process；Emulsifying agent of the present invention has relatively strong infiltration
Property, medicament can be faster penetrated into plant after plant is contacted, and strengthen the conduction of active ingredient.
Embodiment
First, example of formulations
1st, embodiment 1:2% anilofos emulsifiable granula
Anilofos 2%
Sec-butyl acetate 2%
Octyl phenol polyoxyethylene ether phosphate 2%
Sodium carboxymethyl starch 5%
Calcium carbonate is mended to 100%
By technical scheme, pesticide activity component anilofos are dissolved in sec-butyl acetate, add emulsifier for mixing
Uniformly, oil base is obtained；Binding agent and carrier are transferred to kneader after mixing after air-flow crushing, into kneader with Sprayable
Oil base is added, after abundant absorption completely, adds suitable quantity of water to mediate, is granulated by rotary squeezing comminutor, it is dry after the completion of granulation
Screening, you can 2% anilofos emulsifiable granula of the present invention is made.
2nd, embodiment 2:5% anilofos emulsifiable granula
Anilofos 5%
Sec-butyl acetate 4%
Sodium lignin sulfonate 2%
White carbon 3%
Sodium carboxymethyl starch 5%
Calcium carbonate is mended to 100%
By technical scheme, pesticide activity component anilofos are dissolved in sec-butyl acetate, add emulsifier for mixing
Uniformly, oil base is obtained；Binding agent, dispersant and carrier are transferred to kneader after mixing after air-flow crushing, into kneader with
Sprayable adds oil base, after abundant absorption completely, adds suitable quantity of water to mediate, is granulated, has been granulated by rotary squeezing comminutor
Into rear dry screening, you can 5% anilofos emulsifiable granula of the present invention is made.
3rd, embodiment 3:10% anilofos emulsifiable granula
Anilofos 10%
C9 solvent naphthas 6%
Fatty alcohol polyoxyethylene ether 4%
Sodium lignin sulfonate 2%
White carbon 5%
Bentonite is mended to 100%
By technical scheme, pesticide activity component anilofos are dissolved in C9 solvent naphthas, it is equal to add emulsifier for mixing
It is even, obtain oil base；Binding agent, dispersant and carrier are transferred to kneader after mixing after air-flow crushing, into kneader with spray
Mist form adds oil base, after abundant absorption completely, adds suitable quantity of water to mediate, is granulated by rotary squeezing comminutor, is granulated and completes
Dry screening afterwards, you can 10% anilofos emulsifiable granula of the present invention is made.
4th, embodiment 4:30% anilofos emulsifiable granula
Anilofos 30%
C9 solvent naphthas 10%
Castor oil polyoxyethylene ether 2%
Pull open powder 5%
Polyvinyl alcohol 1%
Bentonite is mended to 100%
By technical scheme, pesticide activity component anilofos are dissolved in sec-butyl acetate, add emulsifier for mixing
Uniformly, oil base is obtained；Binding agent, dispersant and carrier are transferred to kneader after mixing after air-flow crushing, into kneader with
Sprayable adds oil base, after abundant absorption completely, adds suitable quantity of water to mediate, is granulated, has been granulated by rotary squeezing comminutor
Into rear dry screening, you can 20% anilofos emulsifiable granula of the present invention is made.
5th, embodiment 5:40% anilofos emulsifiable granula
Anilofos 40%
Isophorone 10%
Castor oil polyoxyethylene ether 5%
Calcium dodecyl benzene sulfonate 2%
Polycarboxylate 1%
Diatomite is mended to 100%
By technical scheme, pesticide activity component anilofos are dissolved in isophorone, it is equal to add emulsifier for mixing
It is even, obtain oil base；Dispersant and carrier are transferred to kneader after mixing after air-flow crushing, are added into kneader with Sprayable
Enter oil base, after abundant absorption completely, add suitable quantity of water to mediate, be granulated by rotary squeezing comminutor, dry sieve after the completion of granulation
Point, you can 40% anilofos emulsifiable granula of the present invention is made.
2nd, it is raw to survey embodiment
1st, toxicity measures
Test method：By quantitative weed seed（Barnyard grass, rice barnyard grass, cyperus iria, the rhizome of nutgrass flatsedge）The modeling of diameter 9cm is seeded in respectively
Expect in alms bowl, per 20, basin seed, after planting 0.5~1cm of earthing or so, each processing is repeated 5 times, then distinguishes different agents
Carry out soil treatment.Placed after processing in greenhouse, periodical visual inspection observes the weeds emergence situation of each processing, and the 7th day, 21
My god, carry out within 35 days investigation weeds coverage, record the actual survival rate of weeds of each processing, calculate strain preventive effect.（It the results are shown in Table 1）
It is 21 grams of active ingredient per acre to test each processing dosage.
Strain preventive effect E（%）=(C（Compare weeds coverage rate）-T（Handle weeds coverage rate）)/(C（Compare weeds coverage rate）)×100
2nd, field control effectiveness test
Reagent agent：Embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5.
Comparison medicament：30% anilofos granule, 30% anilofos missible oil.
For studying thing：Rice terrace, imperial round-grained rice 31
Controlling object：The main weeds that the first three years field occurs have barnyard grass, rice barnyard grass, moleplant seed, Monochoria vaginalis, rhizoma alismatis, angustifolia arrowhead herb, rain
Long flower, the rhizome of nutgrass flatsedge, different in nature nutgrass flatsedge etc..Only investigate grassy weed and sedge weed in field.
Application method：
1st, 3 days before rice transplanting, medicament is administered to field using the method for soil treatment.
2nd, after rice transplanting slow seedling, there are unearthed weeds in water layer, barnyard grass is uniformly spread in 1.5 leaf phases, medicament
Processing is applied, comparison medicament is mixed soil and spread fertilizer over the fields.
It is 21 grams of active ingredient per acre to test each processing dosage.
Pilot survey：The security of 7 days investigation crops estimates Weed-control effect at the same time after dispenser, 21 days after dispenser, adjusts within 35 days
Weeds coverage rate is looked into, and calculates weeds strain preventive effect.
Result of the test：By 1 indoor biometrics of table, the result shows that, anilofos emulsifiable granula shows higher removing activity,
Better than anilofos granule and missible oil.Found additionally by field trial, in dispenser, emulsifiable granula meets water can be quickly newborn
Uniform liquid is melted into, so that general performance goes out higher preventive effect, pesticide supplying effect is better than granule, and customer service granule disperses inequality,
The shortcomings that drug effect release is slow, while the shortcomings that solve missible oil formulation dispenser is arduously taken a lot of work after rice transplanting, emulsifiable grain
Agent can directly be spread fertilizer over the fields.Emulsifiable granula drug effect is uniform and the lasting period is grown, and difference between different content, and general performance is most
Excellent is 10% anilofos emulsifiable granula and 20% anilofos emulsifiable granula.
Claims (7)
1. a kind of anilofos emulsifiable granula, it is characterized in that, the component and each component content of the preparation are as follows:
Anilofos 1-40%
Solvent 1-15%
Emulsifying agent 1-15%
Dispersant 0-10%
Binding agent 0-10%
Carrier is mended to 100%.
2. emulsifiable granula according to claim 1, it is characterised in that the solvent is selected from C9 solvent naphthas, acetic acid Zhong Ding
One or more of mixing in ester, isophorone.
3. emulsifiable granula according to claim 1, it is characterised in that the emulsifying agent is selected from aliphatic alcohol polyethenoxy
Ether, alkyl glycosides, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate, styryl phenol polyethenoxy ether, polyol fat
One or more of mixtures in acid esters.
4. emulsifiable granula according to claim 1, it is characterised in that the dispersant be selected from lauryl sodium sulfate,
One or more of mixtures in sodium lignin sulfonate, calcium lignosulfonate, pull open powder, polycarboxylate salt.
5. emulsifiable granula according to claim 1, it is characterised in that the binding agent be selected from sodium carboxymethylcellulose,
One or more of mixtures in polyvinyl alcohol, xanthans, gum arabic, sodium carboxymethyl starch.
6. emulsifiable granula according to claim 1, it is characterised in that the carrier is selected from white carbon, diatomite, recessed
One kind in convex rod soil, kaolin, bentonite, sodium sulphate, sodium benzoate, calcium carbonate, white sugar, urea, ammonium sulfate, ammonium hydrogen carbonate
Or several mixture.
A kind of 7. preparation method of anilofos emulsifiable granula according to claim 1, it is characterised in that specifically include with
Lower step：
（1）Pesticide activity component is dissolved using suitable solvent and to add emulsifier for mixing uniform, it is spare as oil phase；
（2）Dispersant, binding agent and carrier are uniformly mixed, ultramicro grinding is carried out by airslide disintegrating mill, obtains a 400 mesh left side
Right fine powder；
（3）Fine powder in step 2 is sent into top the kneader of spraying device, while stirring material, by oil phase in step 1
Material is adsorbed in the form of spraying, suitable quantity of water is added with Sprayable after having adsorbed, fully mediates and obtains wet stock；
（4）Step 3 gained wet stock is transferred to rotary squeezing comminutor and carries out extruder grain, obtains solid particle；
（5）Step 4 obtained solid particle is dried, is sieved, obtains qualified emulsifiable granula finished product.
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| WO2023077262A1 (en) * | 2021-11-02 | 2023-05-11 | 中国农业科学院植物保护研究所 | Pesticide microgranule for aerial foliar spraying, preparation method therefor, and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102187858A (en) * | 2010-11-19 | 2011-09-21 | 南通联农农药制剂研究开发有限公司 | Pesticide emulsifiable granules and method for preparing same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102187858A (en) * | 2010-11-19 | 2011-09-21 | 南通联农农药制剂研究开发有限公司 | Pesticide emulsifiable granules and method for preparing same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023077262A1 (en) * | 2021-11-02 | 2023-05-11 | 中国农业科学院植物保护研究所 | Pesticide microgranule for aerial foliar spraying, preparation method therefor, and application thereof |
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