CN107938327A - A kind of special antibiotic finishing solution of wool cap - Google Patents
A kind of special antibiotic finishing solution of wool cap Download PDFInfo
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- CN107938327A CN107938327A CN201711236359.9A CN201711236359A CN107938327A CN 107938327 A CN107938327 A CN 107938327A CN 201711236359 A CN201711236359 A CN 201711236359A CN 107938327 A CN107938327 A CN 107938327A
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- antibiotic finishing
- finishing solution
- wool cap
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- 210000002268 wool Anatomy 0.000 title claims abstract description 34
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 23
- 229960000892 attapulgite Drugs 0.000 claims abstract description 34
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 34
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 13
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims abstract description 11
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229950005308 oxymethurea Drugs 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 28
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 18
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims description 13
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 12
- 239000001815 (2R)-2-phenylpropan-1-ol Substances 0.000 claims description 11
- RNDNSYIPLPAXAZ-UHFFFAOYSA-N 2-Phenyl-1-propanol Chemical compound OCC(C)C1=CC=CC=C1 RNDNSYIPLPAXAZ-UHFFFAOYSA-N 0.000 claims description 11
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 11
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 108010039918 Polylysine Proteins 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 2
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 4
- 230000000845 anti-microbial effect Effects 0.000 abstract description 2
- 229920000656 polylysine Polymers 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- XGEGHDBEHXKFPX-UHFFFAOYSA-N N-methylthiourea Natural products CNC(N)=O XGEGHDBEHXKFPX-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- XGEGHDBEHXKFPX-NJFSPNSNSA-N methylurea Chemical compound [14CH3]NC(N)=O XGEGHDBEHXKFPX-NJFSPNSNSA-N 0.000 description 3
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- -1 wherein Substances 0.000 description 1
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
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- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
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- D06M13/402—Amides imides, sulfamic acids
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Abstract
The invention discloses a kind of special antibiotic finishing solution of wool cap, its raw material includes by weight：5 20 parts of Nano silica sol, 1 3.8 parts of hexamethylolmelamine, 3 15 parts of zinc oxide colloidal sol, 5 20 parts attapulgite modified, 38 parts of ε polylysines, 12 parts of dimethylol urea, 300 500 parts of water.The special antibiotic finishing solution of wool cap proposed by the present invention, its can effectively eliminating bacteria and mould, assign wool cap excellent anti-microbial property.
Description
Technical field
The present invention relates to wool field of hat, more particularly to a kind of special antibiotic finishing solution of wool cap.
Background technology
Wool cap is prepared by raw material of wool, has the characteristics that cold-proof comfort, is favored by people.Wool is one
Kind protein fibre, is easy to absorption bacterium and mould, but existing wool cap is generally handled without antibacterial and mouldproof,
During wearing, it is easier to be corroded by bacterium and mould, has potential hazard to health.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of special antibiotic finishing solution of wool cap, its
Can effectively eliminating bacteria and mould, assign wool cap excellent anti-microbial property.
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol
5-20 parts, 1-3.8 parts of hexamethylolmelamine, 3-15 parts of zinc oxide colloidal sol, 5-20 parts attapulgite modified, epsilon-polylysine
3-8 parts, 1-2 parts of dimethylol urea, 300-500 parts of water.
Preferably, the solid content of the Nano silica sol is 20-25%.
Preferably, the solid content of the zinc oxide colloidal sol is 10-35%.
Preferably, it is described attapulgite modified to be prepared according to following technique：1,2- phenylpropyl alcohol isothiazoline -3- ketone is added
Enter in water, regulation system pH value is 9-10, then adds attapulgite aqueous solution, 5-9h is stirred at room temperature, is transferred to hydro-thermal
Hydro-thermal reaction 5-9h in kettle, centrifuges, washs, is dried to obtain material A after reaction；Material A, butyl titanate and ethanol are mixed
Close uniformly, 3-5h is stirred after adding water, washed after filtering, is dry, 120-150min is then calcined at 550-650 DEG C obtains thing
Expect B；Material B is added to the water and is stirred evenly, cetyl trimethylammonium bromide stirring 30-50min is then added, adds nitric acid
The ammonia solution of silver, stirs 5-8h, then filters, washs, is dry, and 100-150min is calcined at 550-650 DEG C and obtains described change
Property attapulgite.
Preferably, 1,2- phenylpropyl alcohols isothiazoline -3- ketone, the weight ratio of attapulgite are 1-5：15-30.
Preferably, material A, the weight ratio of butyl titanate are 1：2.5-3.
Preferably, material B, cetyl trimethylammonium bromide, the weight ratio of silver nitrate are 0.5-1.5：3.5-5：0.1-
0.35。
Preferably, its raw material includes by weight：18 parts of Nano silica sol, 2.5 parts of hexamethylolmelamine, zinc oxide
10 parts of colloidal sol, 17 parts attapulgite modified, 6 parts of epsilon-polylysine, 1.5 parts of dimethylol urea, 400 parts of water.
The ammonia solution of the silver nitrate is dissolved in stirring in concentrated ammonia liquor by silver nitrate and obtains.
The special antibiotic finishing solution of wool cap of the present invention, in its raw material, adds Nano silica sol, in wool after processing
The fiber surface of cap forms perforated membrane, has covered the scale structure of wool, and on the one hand imparting wool cap is excellent resists
Pilling tendency, on the other hand, coordinates with the zinc oxide colloidal sol in system, is keeping the situation of wool cap fracture strength and whiteness
Under, assign wool cap excellent antibiotic property and antistatic property, and durability is good；In attapulgite modified preparation process,
First with 1,2- phenylpropyl alcohols isothiazoline -3- ketone and attapulgite for raw material, by controlling the condition of reaction, make the different thiophene of 1,2- phenylpropyl alcohols
Oxazoline -3- ketone is inserted into the piece interlayer of attapulgite, is reacted afterwards with butyl titanate, makes titanium dichloride load in bumps
The surface of rod soil, after being mixed with the ammonia solution of cetyl trimethylammonium bromide and silver nitrate, and bears on the surface of attapulgite
Silver chlorate has been carried, so that 1 has been obtained, the attapulgite that 2- phenylpropyl alcohol isothiazoline -3- ketone, titanium dioxide and silver chlorate are modified, together
When have 1,2- phenylpropyl alcohol isothiazoline -3- ketone, titanium dioxide and silver chlorate property, be added into system, with hexamethylol
Melamine, epsilon-polylysine and dimethylol urea coordinate, and the absorption for enhancing dressing liquid arranges ability, is not damaging fiber
Under the conditions of, make the function adhesion-tight, lasting, the excellent antibiotic property of imparting wool cap.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol
20 parts, 1 part of hexamethylolmelamine, 15 parts of zinc oxide colloidal sol, 5 parts attapulgite modified, 8 parts of epsilon-polylysine, dihydroxy first
1 part of base urea, 500 parts of water.
Embodiment 2
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol 5
Part, 3.8 parts of hexamethylolmelamine, 3 parts of zinc oxide colloidal sol, 20 parts attapulgite modified, 3 parts of epsilon-polylysine, dihydroxy first
2 parts of base urea, 300 parts of water.
Embodiment 3
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol
16 parts, 1.6 parts of hexamethylolmelamine, 13 parts of zinc oxide colloidal sol, 9 parts attapulgite modified, 7 parts of epsilon-polylysine, dihydroxy
1.3 parts of methylurea, 430 parts of water；
Wherein, the solid content of the Nano silica sol is 20%；
The solid content of the zinc oxide colloidal sol is 35%；
It is described attapulgite modified to be prepared according to following technique：1,2- phenylpropyl alcohol isothiazoline -3- ketone is added to the water,
Regulation system pH value is 9, then adds attapulgite aqueous solution, wherein, 1,2- phenylpropyl alcohol isothiazoline -3- ketone, attapulgite
Weight ratio is 5：15,9h is stirred at room temperature, is transferred to hydro-thermal reaction 5h in water heating kettle, centrifuges, wash after reaction, is dry
Obtain material A；Material A, butyl titanate and ethanol are uniformly mixed, wherein, material A, the weight ratio of butyl titanate are 1：
3,3h is stirred after adding water, is washed after filtering, is dry, 120min is then calcined at 650 DEG C obtains material B；Material B is added
Stirred evenly in water, then add cetyl trimethylammonium bromide stirring 50min, add the ammonia solution of silver nitrate, wherein, thing
Expect that B, cetyl trimethylammonium bromide, the weight ratio of silver nitrate are 0.5：5：0.1,8h is stirred, then filters, wash, is dry,
Calcining 150min is obtained described attapulgite modified at 550 DEG C.
Embodiment 4
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol 7
Part, 3.2 parts of hexamethylolmelamine, 6 parts of zinc oxide colloidal sol, 16 parts attapulgite modified, 4.3 parts of epsilon-polylysine, dihydroxy
1.8 parts of methylurea, 350 parts of water；
Wherein, the solid content of the Nano silica sol is 25%；
The solid content of the zinc oxide colloidal sol is 10%；
It is described attapulgite modified to be prepared according to following technique：1,2- phenylpropyl alcohol isothiazoline -3- ketone is added to the water,
Regulation system pH value is 10, then adds attapulgite aqueous solution, wherein, 1,2- phenylpropyl alcohol isothiazoline -3- ketone, attapulgite
Weight ratio is 1：30,5h is stirred at room temperature, is transferred to hydro-thermal reaction 9h in water heating kettle, centrifuges, wash after reaction, is dry
Obtain material A；Material A, butyl titanate and ethanol are uniformly mixed, wherein, material A, the weight ratio of butyl titanate are 1：
2.5,5h is stirred after adding water, is washed after filtering, is dry, 150min is then calcined at 550 DEG C obtains material B；Material B is added
Enter in water and stir evenly, then add cetyl trimethylammonium bromide stirring 30min, add the ammonia solution of silver nitrate, wherein,
Material B, cetyl trimethylammonium bromide, the weight ratio of silver nitrate are 1.5：3.5：0.35,5h is stirred, then filter, wash,
Dry, calcining 100min is obtained described attapulgite modified at 650 DEG C.
Embodiment 5
A kind of special antibiotic finishing solution of wool cap proposed by the present invention, its raw material include by weight：Nano silica sol
18 parts, 2.5 parts of hexamethylolmelamine, 10 parts of zinc oxide colloidal sol, 17 parts attapulgite modified, 6 parts of epsilon-polylysine, dihydroxy
1.5 parts of methylurea, 400 parts of water；
Wherein, the solid content of the Nano silica sol is 22%；
The solid content of the zinc oxide colloidal sol is 31%；
It is described attapulgite modified to be prepared according to following technique：1,2- phenylpropyl alcohol isothiazoline -3- ketone is added to the water,
Regulation system pH value is 9.5, then adds attapulgite aqueous solution, wherein, 1,2- phenylpropyl alcohol isothiazoline -3- ketone, attapulgite
Weight ratio be 3：22,7h is stirred at room temperature, is transferred to hydro-thermal reaction 6h in water heating kettle, centrifuges, wash after reaction, is dry
It is dry to obtain material A；Material A, butyl titanate and ethanol are uniformly mixed, wherein, material A, the weight ratio of butyl titanate are
1：2.7,4h is stirred after adding water, is washed after filtering, is dry, 130min is then calcined at 600 DEG C obtains material B；By material B
It is added to the water and stirs evenly, then add cetyl trimethylammonium bromide stirring 40min, adds the ammonia solution of silver nitrate, its
In, material B, cetyl trimethylammonium bromide, the weight ratio of silver nitrate are 1：4：0.3,6h is stirred, then filters, wash, is dry
Dry, calcining 130min is obtained described attapulgite modified at 600 DEG C.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of special antibiotic finishing solution of wool cap, it is characterised in that its raw material includes by weight：Nano silica sol 5-20
Part, 1-3.8 parts of hexamethylolmelamine, 3-15 parts of zinc oxide colloidal sol, 5-20 parts attapulgite modified, epsilon-polylysine 3-8
Part, 1-2 parts of dimethylol urea, 300-500 parts of water.
2. the special antibiotic finishing solution of wool cap according to claim 1, it is characterised in that consolidating for the Nano silica sol contains
Measure as 20-25%.
3. the special antibiotic finishing solution of wool cap according to claim 1 or claim 2, it is characterised in that the zinc oxide colloidal sol
Solid content is 10-35%.
4. according to the special antibiotic finishing solution of wool cap any one of claim 1-3, it is characterised in that the modification is recessed
Convex rod soil is prepared according to following technique：1,2- phenylpropyl alcohol isothiazoline -3- ketone is added to the water, regulation system pH value is 9-
10, attapulgite aqueous solution is then added, 5-9h is stirred at room temperature, is transferred to hydro-thermal reaction 5-9h in water heating kettle, reaction knot
Centrifuged after beam, wash, be dried to obtain material A；Material A, butyl titanate and ethanol are uniformly mixed, 3- is stirred after adding water
5h, washs after filtering, is dry, and 120-150min is then calcined at 550-650 DEG C obtains material B；Material B is added to the water and is stirred
Mix uniformly, then add cetyl trimethylammonium bromide stirring 30-50min, add the ammonia solution of silver nitrate, stir 5-8h,
Then filter, wash, is dry, calcining 100-150min is obtained described attapulgite modified at 550-650 DEG C.
5. the special antibiotic finishing solution of wool cap according to claim 4, it is characterised in that 1,2- phenylpropyl alcohol isothiazoline -3-
Ketone, the weight ratio of attapulgite are 1-5：15-30.
6. according to the special antibiotic finishing solution of wool cap of claim 4 or 5, it is characterised in that material A, butyl titanate
Weight ratio be 1：2.5-3.
7. according to the special antibiotic finishing solution of wool cap any one of claim 4-6, it is characterised in that material B, 16
Alkyl trimethyl ammonium bromide, the weight ratio of silver nitrate are 0.5-1.5：3.5-5：0.1-0.35.
8. according to the special antibiotic finishing solution of wool cap any one of claim 1-7, it is characterised in that its raw material is by weight
Amount part includes：18 parts of Nano silica sol, 2.5 parts of hexamethylolmelamine, 10 parts of zinc oxide colloidal sol, attapulgite modified 17
Part, 6 parts of epsilon-polylysine, 1.5 parts of dimethylol urea, 400 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711236359.9A CN107938327A (en) | 2017-11-30 | 2017-11-30 | A kind of special antibiotic finishing solution of wool cap |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711236359.9A CN107938327A (en) | 2017-11-30 | 2017-11-30 | A kind of special antibiotic finishing solution of wool cap |
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| CN107938327A true CN107938327A (en) | 2018-04-20 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851854A (en) * | 2009-03-31 | 2010-10-06 | 北京华美精创纳米相材料科技有限责任公司 | Nano finishing method for preparing super hydrophilic wool fabric with washing fastness |
| CN103437146A (en) * | 2013-09-12 | 2013-12-11 | 上海纳纺科技有限公司 | Nanometer fabric finishing agent as well as preparation method and application thereof |
| CN103485163A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Finishing method of antibacterial anti-felting wool |
| CN104894876A (en) * | 2015-06-15 | 2015-09-09 | 湖州市菱湖重兆金辉丝织厂 | Novel light, thin, breathable and uvioresistant fabric |
| CN107393630A (en) * | 2017-07-19 | 2017-11-24 | 安徽国电电缆股份有限公司 | A kind of preparation method with conductive and antibacterial cable attapulgite composite material |
-
2017
- 2017-11-30 CN CN201711236359.9A patent/CN107938327A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851854A (en) * | 2009-03-31 | 2010-10-06 | 北京华美精创纳米相材料科技有限责任公司 | Nano finishing method for preparing super hydrophilic wool fabric with washing fastness |
| CN103485163A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Finishing method of antibacterial anti-felting wool |
| CN103437146A (en) * | 2013-09-12 | 2013-12-11 | 上海纳纺科技有限公司 | Nanometer fabric finishing agent as well as preparation method and application thereof |
| CN104894876A (en) * | 2015-06-15 | 2015-09-09 | 湖州市菱湖重兆金辉丝织厂 | Novel light, thin, breathable and uvioresistant fabric |
| CN107393630A (en) * | 2017-07-19 | 2017-11-24 | 安徽国电电缆股份有限公司 | A kind of preparation method with conductive and antibacterial cable attapulgite composite material |
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Application publication date: 20180420 |