CN106637909A - Warm collagen and cashmere composite fabric with high thermal stability and production method thereof - Google Patents
Warm collagen and cashmere composite fabric with high thermal stability and production method thereof Download PDFInfo
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- CN106637909A CN106637909A CN201611144284.7A CN201611144284A CN106637909A CN 106637909 A CN106637909 A CN 106637909A CN 201611144284 A CN201611144284 A CN 201611144284A CN 106637909 A CN106637909 A CN 106637909A
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- 210000000085 cashmere Anatomy 0.000 title claims abstract description 47
- 102000008186 Collagen Human genes 0.000 title claims abstract description 35
- 108010035532 Collagen Proteins 0.000 title claims abstract description 35
- 229920001436 collagen Polymers 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 239000004744 fabric Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 239000000835 fiber Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 14
- 240000002853 Nelumbo nucifera Species 0.000 claims abstract description 11
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims abstract description 11
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims abstract description 11
- 229920001491 Lentinan Polymers 0.000 claims abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940115286 lentinan Drugs 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000004417 polycarbonate Substances 0.000 claims abstract description 5
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 5
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 241000219071 Malvaceae Species 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 4
- -1 Thiazolinyl trimethoxy silane Chemical compound 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000036541 health Effects 0.000 abstract description 5
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003431 cross linking reagent Substances 0.000 abstract description 4
- 238000009987 spinning Methods 0.000 abstract description 3
- 210000002268 wool Anatomy 0.000 abstract description 2
- PBIDWHVVZCGMAR-UHFFFAOYSA-N 1-methyl-3-prop-2-enyl-2h-imidazole Chemical compound CN1CN(CC=C)C=C1 PBIDWHVVZCGMAR-UHFFFAOYSA-N 0.000 abstract 1
- 244000146553 Ceiba pentandra Species 0.000 abstract 1
- 235000003301 Ceiba pentandra Nutrition 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 238000007781 pre-processing Methods 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 208000012886 Vertigo Diseases 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- HSDVRWZKEDRBAG-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COC(CCCCC)OCC1CO1 HSDVRWZKEDRBAG-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003519 biomedical and dental material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses warm collagen and cashmere composite fabric with high thermal stability. The fabric is formed by the following materials in parts by weight: 40-43 parts of cashmere fibers, 16-18 parts of kapok fibers, 13-16 parts of polycarbonate fibers, 8.6-8.9 parts of pure collagen powder, 2.6-2.9 parts of ethylene glycol diglycidyl ether, 6-7 parts of lotus leaves, 1-2 parts of volcanic mud, 2-3 parts of polyving akohol, 0.7-0.9 part of lentinan, 2.6-2.9 parts of nanometer ferroferric oxide, 1.1-1.3 parts of vinyl trimethoxy silane, 188-192 parts of 1-allyl-3-methylimidazole chloride and a proper amount of water. According to a production method of the fabric provided by the invention, oxygen low-temperature plasma is used for pre-processing, and then the ethylene glycol diglycidyl ether is used as a cross-linking agent for grafting the modified collagen onto the surfaces of cashmere composite fibers. The produced cashmere composite fabric has the characteristics, such as being stiff, smooth and elegant, of original wool spinning products, and also has the performance of keeping warm and protecting health.
Description
Technical field
The present invention relates to textile material technical field, more particularly to a kind of warming collagen cashmere composite surface of heat endurance
Material and preparation method thereof.
Background technology
Cashmere fiber is a kind of natural precious textile material, and in recent years, cashmere apparel product is competing in fierce garment market
In striving with its comfortable feel, color and luster is unique, quality is frivolous, heat-insulation breathable is good the features such as be increasingly subject to consumers.But
As ecological environment opposite applies flexibly the friendly requirement of light green color, health, comfortable, environmental protection, the safe consumption master for having become people
Topic.Therefore, using environmental pollution is little or free of contamination process technology, exploitation with skin-friendly and the features such as emollient, can
The high-grade cashmere fabric for lifting its added value of product is the direction for being worth research.
Collagen has low antigenicity, superior biocompatibility and biological degradability, in biomedical material, medicine
Many fields such as delivery vehicles, organizational project, cosmetics, food have critically important status.Especially in recent years, with collagen egg
White bioaffinity is at the aspect such as textile material is modified, compound gradually into focus.Collagen can be given necessary to skin layer
Nutrient, strengthens the collagen activity in skin, keeps the integrality of cuticula moisture and fibre structure, improves skin thin
The physiology circulation of born of the same parents' living environment and enhancing skin histology.Once collagen is securable to cashmere fiber, then may produce
The various health care functions such as skin care, anti-aging and whitening,《Using plasma-crosslinking agent complex technique in cashmere fiber
Collagen is fixed on surface》One literary grace pre-processes cashmere fiber with oxygen low temperature plasma, using ethylene glycol diglycidyl
Collagen is grafted onto cashmere surface by ether as crosslinking agent, as a result shows absorb-discharge humid and the dyeing of collagen modification cashmere fiber
Property is superior to untreatment fiber.In addition, the fixation of collagen has certain changing to the ultimate strength and extension at break of fiber
Kind effect.
The absorb-discharge humid and dyeability of cashmere are only improved in text, but cashmere yield is few expensive, pure cashmere is such as
Fruit stores the improper even raw mite that goes mouldy that can make moist because of the humidity of environment, due to the intensity of cashmere itself it is poor, it is washed how easy
Crushing, conglomeration, balling-up, the especially cold north are dried, and cashmere product is also also easy to produce electrostatic etc..So that develop having
Multifunctional novel collagen Cashmere composite shell fabric.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of warming collagen cashmere of heat endurance
Composite material and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of warming collagen Cashmere composite shell fabric of heat endurance, is prepared by the raw materials in：Cashmere fiber 40-
43rd, common bombax flower fiber 16-18, polycarbonate 13-16, pure collagen protein powder 8.6-8.9, ethylene glycol diglycidylether
2.6-2.9, lotus leaf 6-7, volcanic mud 1-2, polyvinyl alcohol 2-3, lentinan 0.7-0.9, nano ferriferrous oxide 2.6-2.9,
Vinyltrimethoxy silane 1.1-1.3,1- pi-allyl -3- methylimidazole villaumites 188-192, suitable quantity of water.
A kind of preparation method of the warming collagen Cashmere composite shell fabric of described heat endurance, comprises the following steps：
（1）By nano ferriferrous oxide in 465-485 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds second
Thiazolinyl trimethoxy silane is stirred 10-15 minutes, dry modified Nano ferroso-ferric oxide；
（2）Lotus leaf is dried into ground 100 mesh sieve, the hydrochloric acid solution for spraying mass concentration for 4-8% is stirred and evenly mixed, in 60-80 DEG C
Magnetic agitation 2-3 hour in water bath with thermostatic control, washs to neutral vacuum drying, adds polyvinyl alcohol ultrasonic grinding 1-3 hours, drying
Must be modified lotus leaf superfines；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, common bombax flower fiber, Merlon
Fiber grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material, volcanic mud stirring reaction 50-70 minute, spin
Silk, drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtains
Gas ions pre-process cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add
Lentinan, step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
It is an advantage of the invention that：Optimization of C/C composites of the present invention improves production technology, by common bombax flower fiber, polycarbonate and
Cashmere fiber is combined, and cashmere composite fibre is obtained by binding agent Jing wet spinnings of modified lotus leaf superfines, not only alleviate by
The problem that the cashmere fiber brought in environmental degradation is reduced year by year also overcomes pure cashmere product balling-up, low intensity and easily goes mouldy raw mite
Etc. defect, finally obtained cashmere composite fibre is pre-processed using oxygen low temperature plasma, the damage to fibrous inside
The less environmentally safe of wound, plasma can etch the scale on cashmere surface, make scale layer thinning, weaken surface scale
" barrier " is acted on, and so as to strengthen its humidity absorption and release, improves hydrophily of the cashmere during follow-up dyeing and finishing etc., is then used by second
Modified collagen is grafted onto cashmere surface by Hexanediol diglycidyl ether as crosslinking agent, because collagen also belongs to protect
The good protein of wet performance, improves the skin-friendly and beauty and health care performance of fabric, obtained Cashmere composite shell fabric after crosslinking
With high thermal stability, spinning property is strong, both maintained original wool spinning product it is well-pressed, graceful the features such as, have again it is highly warming,
The wearability of health care.
Specific embodiment
A kind of warming collagen Cashmere composite shell fabric of heat endurance, is prepared by the raw materials in：Cashmere fiber
40th, common bombax flower fiber 16, polycarbonate 13, pure collagen protein powder 8.6, ethylene glycol diglycidylether 2.6, lotus leaf 6, fire
Minishanny 1, polyvinyl alcohol 2, lentinan 0.7, nano ferriferrous oxide 2.6, vinyltrimethoxy silane 1.1,1- pi-allyls-
3- methylimidazole villaumites 188, suitable quantity of water.
A kind of preparation method of the warming collagen Cashmere composite shell fabric of described heat endurance, comprises the following steps：
（1）By nano ferriferrous oxide in 465-485 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds second
Thiazolinyl trimethoxy silane is stirred 10-15 minutes, dry modified Nano ferroso-ferric oxide；
（2）Lotus leaf is dried into ground 100 mesh sieve, the hydrochloric acid solution for spraying mass concentration for 4-8% is stirred and evenly mixed, in 60-80 DEG C
Magnetic agitation 2-3 hour in water bath with thermostatic control, washs to neutral vacuum drying, adds polyvinyl alcohol ultrasonic grinding 1-3 hours, drying
Must be modified lotus leaf superfines；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, common bombax flower fiber, Merlon
Fiber grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material, volcanic mud stirring reaction 50-70 minute, spin
Silk, drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtains
Gas ions pre-process cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add
Lentinan, step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
The bacteriostasis rate of staphylococcus aureus can reach using collagen Cashmere composite shell fabric obtained in the present invention
96.741%；Average ultimate strength is 8.86cN；Dyeing dye uptake can reach 98%.
Claims (2)
1. the warming collagen Cashmere composite shell fabric of a kind of heat endurance, it is characterised in that be prepared by the raw materials in：
Cashmere fiber 40-43, common bombax flower fiber 16-18, polycarbonate 13-16, pure collagen protein powder 8.6-8.9, ethylene glycol two
Glycidol ether 2.6-2.9, lotus leaf 6-7, volcanic mud 1-2, polyvinyl alcohol 2-3, lentinan 0.7-0.9, the oxidation of nanometer four three
Iron 2.6-2.9, vinyltrimethoxy silane 1.1-1.3,1- pi-allyl -3- methylimidazole villaumites 188-192, suitable quantity of water.
2. the preparation method of the warming collagen Cashmere composite shell fabric of a kind of heat endurance according to claim 1, it is special
Levy is to comprise the following steps：
（1）By nano ferriferrous oxide in 465-485 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds second
Thiazolinyl trimethoxy silane is stirred 10-15 minutes, dry modified Nano ferroso-ferric oxide；
（2）Lotus leaf is dried into ground 100 mesh sieve, the hydrochloric acid solution for spraying mass concentration for 4-8% is stirred and evenly mixed, in 60-80 DEG C
Magnetic agitation 2-3 hour in water bath with thermostatic control, washs to neutral vacuum drying, adds polyvinyl alcohol ultrasonic grinding 1-3 hours, drying
Must be modified lotus leaf superfines；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, common bombax flower fiber, Merlon
Fiber grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material, volcanic mud stirring reaction 50-70 minute, spin
Silk, drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtains
Gas ions pre-process cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add
Lentinan, step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611144284.7A CN106637909A (en) | 2016-12-13 | 2016-12-13 | Warm collagen and cashmere composite fabric with high thermal stability and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611144284.7A CN106637909A (en) | 2016-12-13 | 2016-12-13 | Warm collagen and cashmere composite fabric with high thermal stability and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106637909A true CN106637909A (en) | 2017-05-10 |
Family
ID=58824826
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611144284.7A Pending CN106637909A (en) | 2016-12-13 | 2016-12-13 | Warm collagen and cashmere composite fabric with high thermal stability and production method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN106637909A (en) |
Cited By (2)
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| CN111584862A (en) * | 2020-05-25 | 2020-08-25 | 曾尚一 | Lithium ion battery anode slurry and preparation process thereof |
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