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CN107937904B - Method and device for preparing aluminum coating by laser cold spraying - Google Patents

Method and device for preparing aluminum coating by laser cold spraying Download PDF

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CN107937904B
CN107937904B CN201711201894.0A CN201711201894A CN107937904B CN 107937904 B CN107937904 B CN 107937904B CN 201711201894 A CN201711201894 A CN 201711201894A CN 107937904 B CN107937904 B CN 107937904B
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powder
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aluminum
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CN107937904A (en
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孔德军
张静
王文昌
宋仁国
章冬辉
闫保旭
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Beijing Aoweigao Metal Products Technology Development Co ltd
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Changzhou University
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
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  • Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

本发明专利涉及冷喷涂制备涂层技术领域。特指一种激光冷喷涂制备铝涂层的方法与装置。高速气体加速金属粉末进入粉末输送管道,激光束由激光系统发出通过光纤管进入粉末输送管道,调节激光光斑大小与输出粉末束的直径即喷枪口直径相一致,激光束加热铝粉末粒子快速达到喷涂的临界温度。粉末温度的监控由温度检测控制系统监测并反馈回激光系统,激光系统根据温度监测系统反馈的温度并结合粉末粒子的临界温度值和对激光的吸收效率自动调节功率大小,使得喷涂铝粒子温度维持在400℃的临界温度进行喷涂。到达临界温度的铝粉末粒子由气体加速器对其再次进行加速并通过喷枪和超音速喷管被冲击到基体金属S355钢表面形成涂层。

The patent of the present invention relates to the technical field of coating preparation by cold spraying. In particular, it refers to a method and device for preparing an aluminum coating by laser cold spraying. The high-speed gas accelerates the metal powder into the powder conveying pipeline. The laser beam is sent out by the laser system and enters the powder conveying pipeline through the optical fiber tube. The size of the laser spot is adjusted to be consistent with the diameter of the output powder beam, that is, the diameter of the spray gun mouth. The laser beam heats the aluminum powder particles to achieve spraying quickly. critical temperature. The monitoring of the powder temperature is monitored by the temperature detection control system and fed back to the laser system. The laser system automatically adjusts the power according to the temperature fed back by the temperature monitoring system combined with the critical temperature value of the powder particles and the absorption efficiency of the laser, so that the temperature of the sprayed aluminum particles is maintained. Spraying was carried out at a critical temperature of 400°C. The aluminum powder particles that have reached the critical temperature are accelerated again by the gas accelerator and are impacted to the surface of the base metal S355 steel through the spray gun and supersonic nozzle to form a coating.

Description

一种激光冷喷涂制备铝涂层的方法与装置Method and device for preparing aluminum coating by laser cold spraying

技术领域technical field

本发明专利涉及冷喷涂制备涂层技术领域,该技术是将粒子加热到临界温度,由高速气体将金属粒子加速到超音速,和基体发生撞击过程产生塑性变形与基体形成机械镶嵌式结合,是一种新型的铝涂层的制备方法。The patent of the present invention relates to the technical field of coating preparation by cold spraying. This technology is to heat the particles to a critical temperature, accelerate the metal particles to supersonic speed by high-speed gas, and produce plastic deformation during the collision with the substrate to form a mechanical mosaic combination with the substrate. A novel method for preparing an aluminum coating.

背景技术Background technique

冷喷涂设备所采用的加热系统大多为空气加热器,传统的空气加热器是通过加热电阻丝将空气流从初始温度加热到所需要的空气温度,但加热效率低,加热时间长和加热不均匀是其主要弊端。本发明专利采用激光对粉末进行预加热,能够有效地提高加热粉末的效率,减少能量损耗,使得高速冷喷涂粉末快速达到临界温度,冲击基体形成涂层。Most of the heating systems used in cold spraying equipment are air heaters. Traditional air heaters heat the air flow from the initial temperature to the required air temperature through heating resistance wires, but the heating efficiency is low, the heating time is long and the heating is uneven. is its main disadvantage. The patent of the invention uses laser to preheat the powder, which can effectively improve the efficiency of heating the powder and reduce energy loss, so that the high-speed cold spray powder can quickly reach the critical temperature and impact the substrate to form a coating.

发明内容Contents of the invention

本发明涉及的冷喷涂系统装置如图1所示,包括:激光输出系统、温度检测控制系统、送粉器、气体加速器、喷枪、超音速喷管和飞溅粒子回收装置。送粉器通过粉末输送管道与喷枪连接,激光输出系统通过光纤管接入粉末输送管道,气体加速器通过管道通过接入粉末输送管道,超音速喷管位于喷枪前方并位于飞溅粒子回收装置的密闭喷涂室内,飞溅粒子回收装置的尾部设有排风扇。温度检测控制系统用于监测激光输出系统发出的激光束加热的铝粉末粒子的温度并反馈给激光输出系统。The cold spraying system device involved in the present invention is shown in Figure 1, including: a laser output system, a temperature detection and control system, a powder feeder, a gas accelerator, a spray gun, a supersonic nozzle and a splash particle recovery device. The powder feeder is connected to the spray gun through the powder conveying pipeline, the laser output system is connected to the powder conveying pipeline through the optical fiber tube, the gas accelerator is connected to the powder conveying pipeline through the pipeline, and the supersonic nozzle is located in front of the spray gun and in the closed spraying of the splash particle recovery device Indoors, an exhaust fan is provided at the tail of the splash particle recovery device. The temperature detection and control system is used to monitor the temperature of the aluminum powder particles heated by the laser beam emitted by the laser output system and feed back to the laser output system.

高速气体加速铝粉末粒子进入粉末输送管道,激光束由激光系统发出通过光纤管进入粉末输送管道,粉末输送管道为耐高温不锈钢管以满足高温铝粉末粒子的输送条件,调节激光光斑大小与输出粉末束的直径即喷枪口直径相一致,激光束加热铝粉末粒子快速达到喷涂的临界温度。粉末温度的监控由温度检测控制系统监测并反馈回激光系统,激光系统根据温度监测系统反馈的温度并结合粉末粒子的临界温度值和对激光的吸收效率自动调节功率大小,使得喷涂铝粒子温度维持在400℃的临界温度进行喷涂。激光功率范围设置在400~800W,能够在喷涂过程中对加热温度进行调整。到达临界温度的铝粉末粒子由气体加速器对其再次进行加速并通过喷枪和超音速喷管被冲击到基体金属S355钢表面形成涂层。喷涂在密闭喷涂室内进行,喷涂过程中未冲击到基体表面而脱落的粒子由飞溅粒子回收装置回收。喷涂结束后,密闭喷涂室内的粉尘粒子由排风扇排出。The high-speed gas accelerates the aluminum powder particles into the powder conveying pipeline. The laser beam is emitted by the laser system and enters the powder conveying pipeline through the optical fiber tube. The powder conveying pipeline is made of high-temperature resistant stainless steel pipe to meet the conveying conditions of high-temperature aluminum powder particles, and the size of the laser spot and the output powder can be adjusted. The diameter of the beam is consistent with the diameter of the nozzle of the spray gun, and the laser beam heats the aluminum powder particles to quickly reach the critical temperature of spraying. The monitoring of the powder temperature is monitored by the temperature detection control system and fed back to the laser system. The laser system automatically adjusts the power according to the temperature fed back by the temperature monitoring system combined with the critical temperature value of the powder particles and the absorption efficiency of the laser, so that the temperature of the sprayed aluminum particles is maintained. Spraying was carried out at a critical temperature of 400°C. The laser power range is set at 400-800W, and the heating temperature can be adjusted during the spraying process. The aluminum powder particles that have reached the critical temperature are accelerated again by the gas accelerator and are impacted to the surface of the base metal S355 steel through the spray gun and supersonic nozzle to form a coating. Spraying is carried out in a closed spraying room, and the particles that fall off without impacting the surface of the substrate during the spraying process are recovered by the splash particle recovery device. After the spraying is finished, the dust particles in the airtight spraying room are exhausted by the exhaust fan.

本发明专利主要特征:Main features of the invention patent:

(1)在冷喷涂设备中,采用激光为加热源能够扩大冷喷涂技术的应用范围,如可以应用于陶瓷涂层的喷涂。(1) In cold spraying equipment, using laser as a heating source can expand the application range of cold spraying technology, for example, it can be applied to the spraying of ceramic coatings.

(2)采用激光和温度监控系统可以精准的控制和调节粉末粒子的加热温度。(2) The laser and temperature monitoring system can accurately control and adjust the heating temperature of powder particles.

(3)采用激光作为加热源能够提高加热的速度,并且能够有效地使粉末粒子受热更加均匀。(3) The use of laser as a heating source can increase the heating speed, and can effectively make the powder particles heated more uniformly.

附图说明Description of drawings

图1激光冷喷涂系统。Figure 1 Laser cold spray system.

1.激光输出系统;2.送粉器;3.气体加速器;4.温度检测控制系统;5.喷枪;6.超音速喷管;7.涂层;8.基体;9.飞溅粒子回收装置;10.密闭喷涂室;11.排风扇。1. Laser output system; 2. Powder feeder; 3. Gas accelerator; 4. Temperature detection and control system; 5. Spray gun; 6. Supersonic nozzle; 7. Coating; 8. Substrate; 9. Splash particle recovery device ; 10. Airtight spray booth; 11. Exhaust fan.

图2激光冷喷涂铝涂层的表面与界面形貌。Fig. 2 Surface and interface morphology of laser cold sprayed aluminum coating.

具体实施方式Detailed ways

(1)使用180#-1000#砂纸对基材S355钢表面进行打磨,用无水乙醇清洗,丙酮脱脂,以去掉试样表面油脂和杂物,确保基材表面清洁度达到Sa3级;(1) Use 180#-1000# sandpaper to polish the surface of the substrate S355 steel, clean it with absolute ethanol, and degrease with acetone to remove the grease and sundries on the surface of the sample to ensure that the surface cleanliness of the substrate reaches Sa3 level;

(2)使用粒径为1mm铸铁砂为磨粒,压缩空气压力>0.8MPa,喷砂距离为200mm,喷砂角度为20°,使精糙度到达Rz 60μm;(2) Use cast iron sand with a particle size of 1mm as abrasive grains, compressed air pressure > 0.8MPa, sandblasting distance of 200mm, and sandblasting angle of 20°, so that the roughness can reach Rz 60μm;

(3)如图1所示,高速气体将送粉器内纯铝粉颗粒输送喷涂管道,铝粉末为WFT1532型纯铝粉,直径为20-45μm。送粉器内参数:压力3.5MPa,送分量1L/min。设置喷枪枪速200mm/s,喷枪与试样距离40mm。(3) As shown in Figure 1, the high-speed gas transports the pure aluminum powder particles in the powder feeder to the spraying pipeline. The aluminum powder is WFT1532 pure aluminum powder with a diameter of 20-45 μm. Internal parameters of the powder feeder: pressure 3.5MPa, delivery volume 1L/min. Set the speed of the spray gun to 200mm/s, and the distance between the spray gun and the sample to 40mm.

(4)根据喷涂的铝涂层厚度要求,设置激光参数,光斑直径3.5mm,即与喷枪口直径相一致。参考铝粉对激光的吸收率和铝粉的临界温度,设置激光功率为500W,将铝粉温度控制在400℃,喷涂过程中激光功率可根据温度检测器的反馈做出调整。(4) According to the thickness requirements of the sprayed aluminum coating, set the laser parameters, and the diameter of the spot is 3.5mm, which is consistent with the diameter of the nozzle of the spray gun. Referring to the absorptivity of the aluminum powder to the laser and the critical temperature of the aluminum powder, set the laser power to 500W and control the temperature of the aluminum powder to 400°C. During the spraying process, the laser power can be adjusted according to the feedback from the temperature detector.

(5)激光加热后的铝颗粒通过喷枪冲击到基体S355钢表面形成致密的铝涂层,铝粉末粒子未发生熔融现象,形成的铝涂层的孔隙率低,如图2(a)所示。铝涂层厚度为250μm,与基体结合性能好,无孔隙,如图2(b)所示。(5) After the laser heating, the aluminum particles are impacted by the spray gun to the surface of the substrate S355 steel to form a dense aluminum coating. The aluminum powder particles do not melt, and the formed aluminum coating has a low porosity, as shown in Figure 2(a) . The thickness of the aluminum coating is 250 μm, which has good bonding performance with the substrate and no porosity, as shown in Figure 2(b).

Claims (5)

1. A method for preparing an aluminum coating by cold spraying with a device for preparing an aluminum coating by laser cold spraying, the device comprising: the device comprises a laser output system, a temperature detection control system, a powder feeder, a gas accelerator, a spray gun, a supersonic speed spray pipe and a splash particle recovery device; the powder feeder is connected with the spray gun through a powder conveying pipeline, the laser output system is connected into the powder conveying pipeline through an optical fiber pipe, the gas accelerator is connected into the powder conveying pipeline through a pipeline, the supersonic speed spray pipe is positioned in front of the spray gun and in a closed spray coating chamber of the splashing particle recovery device, and an exhaust fan is arranged at the tail part of the splashing particle recovery device; the temperature detection control system is used for monitoring the temperature of the aluminum powder particles heated by the laser beam emitted by the laser output system and feeding the temperature back to the laser output system, and is characterized in that high-speed gas accelerates the aluminum powder particles to enter a powder conveying pipeline, the laser beam is emitted by the laser output system and enters the powder conveying pipeline through an optical fiber pipe, and the aluminum powder particles are heated by the laser beam to quickly reach the critical temperature of spraying; the aluminum powder particles having reached the critical temperature are accelerated again by the gas accelerator and are collided with the surface of the base metal S355 steel through the spray gun and the supersonic nozzle to form a coating layer.
2. The method of claim 1, wherein the powder delivery duct is a high temperature stainless steel pipe to satisfy delivery conditions of the high temperature aluminum powder particles.
3. The method of claim 1 wherein the laser spot size is adjusted to correspond to the diameter of the output powder beam, i.e., the diameter of the spray gun nozzle.
4. The method of claim 1, wherein the monitoring of the powder temperature is monitored by a temperature detection control system and fed back to a laser output system, the laser output system automatically adjusts the power according to the temperature fed back by the temperature detection control system and by combining the critical temperature value of the powder particles and the absorption efficiency of the laser, so that the temperature of the sprayed aluminum particles is maintained at the critical temperature of 400 ℃ for spraying, and the laser power range is set at 400 ~ 800W, so that the heating temperature can be adjusted during the spraying process.
5. The method according to claim 1, wherein the spraying is performed in a closed spraying chamber, particles falling off without hitting the surface of the substrate during the spraying are recovered by a spatter particle recovery means, and dust particles in the closed spraying chamber are discharged by a discharge fan after the spraying is completed.
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CN110872712A (en) * 2019-11-11 2020-03-10 北京科技大学 Preparation and testing method of zinc-aluminum corrosion-resistant coating on inner wall of SA106B pipe
CN111005018B (en) * 2019-12-27 2021-12-24 深圳市欣天科技股份有限公司 Preparation method for spraying metal powder to form metal coating on surface of ceramic substrate

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