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CN107895806A - fuel cell humidifying system, method and fuel cell system - Google Patents

fuel cell humidifying system, method and fuel cell system Download PDF

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Publication number
CN107895806A
CN107895806A CN201711385811.8A CN201711385811A CN107895806A CN 107895806 A CN107895806 A CN 107895806A CN 201711385811 A CN201711385811 A CN 201711385811A CN 107895806 A CN107895806 A CN 107895806A
Authority
CN
China
Prior art keywords
fuel cell
air
circulating valve
tail row
internal resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711385811.8A
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Chinese (zh)
Inventor
何凡
何一凡
林琦
胡哲
林岑雯
孙北
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Chongsu Energy Technology Co Ltd
Original Assignee
Shanghai Chongsu Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Chongsu Energy Technology Co Ltd filed Critical Shanghai Chongsu Energy Technology Co Ltd
Priority to CN201711385811.8A priority Critical patent/CN107895806A/en
Publication of CN107895806A publication Critical patent/CN107895806A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • H01M8/04141Humidifying by water containing exhaust gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The present invention relates to a kind of fuel cell humidifying system, method and fuel cell system, wherein humidification system, including:Voltage-current sensor, it is connected with the electric energy output end of fuel cell pack, for gathering the output current and output voltage of fuel cell pack;Mass air flow sensor, on the air inlet pipeline of the air supply system of fuel cell stack system, for gathering the air flow rate signal of incoming fuel battery pile;The outlet of the air supply system of tail row's circulating valve, its one end and fuel cell system connects, and the other end is connected to the air compressor air intake mouth of air inlet pipeline;Humidity controller, it is connected respectively with voltage-current sensor, mass air flow sensor and tail row's circulating valve, output current and output voltage for fuel cell heap estimate the internal resistance of fuel cell pack, and the aperture of circulating valve is arranged with reference to the internal resistance of battery pile and the both air flow modulation tail of incoming fuel battery pile.Compared with prior art, the present invention has the advantages that integrated level is high, cost is low and small volume.

Description

Fuel cell humidifying system, method and fuel cell system
Technical field
The present invention relates to a kind of fuel cell humidifying system, more particularly, to a kind of fuel cell humidifying system, method and Fuel cell system.
Background technology
Fuel cell water management is of crucial importance to the performance of fuel cell, efficiency, cold start-up and life-span etc..In fuel electricity PEM needs that the conductibility of proton could be kept with reference to water in the running of pond, and water content very little, can cause fuel electric Pond internal resistance increase;If hypervolia, negative electrode water logging can be caused again.When the ohmic internal resistance of fuel cell is fuel cell operation One important parameter, it reflects the running status of fuel battery inside.From the point of view of short time span, the change of ohmic internal resistance , can be to the humidity of film by the estimation to ohmic internal resistance there is relation very greatly between the humidity change of PEM Estimated indirectly, be the offer input of the humidification control strategy of film.Existing fuel cell humidifying method is noted including aqueous water Humidification, heating humidification, aqueous water injection humidification and permeable membrane humidification etc. are penetrated, although these outer humidification schemes are to fuel cell Performance has been lifted, but is added the volume of fuel cell whole system or added extra energy consumption, and can not regulate and control humidification The shortcomings that spending.
The content of the invention
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide a kind of fuel cell humidifying System, method and fuel cell system.
The purpose of the present invention can be achieved through the following technical solutions:
One kind arranges circulating valve fuel cell humidifying system based on tail, including:
Voltage-current sensor, it is connected with the electric energy output end of fuel cell pack, for gathering the output of fuel cell pack Electric current and output voltage;
Mass air flow sensor, on the air inlet pipeline of the air supply system of fuel cell stack system, enter combustion for gathering Expect the air flow rate signal of battery pile;
The outlet of the air supply system of tail row's circulating valve, its one end and fuel cell system connects, and the other end is connected to described The air compressor air intake mouth of air inlet pipeline;
Humidity controller, it is connected respectively with voltage-current sensor, mass air flow sensor and tail row's circulating valve, for according to combustion Expect the output current of battery pile and the internal resistance of output voltage estimation fuel cell pack, internal resistance and incoming fuel electricity with reference to battery pile The aperture of Chi Dui both air flow modulation tail row's circulating valve.
The tie point of tail row's circulating valve and the air inlet pipeline is located at after the mass air flow sensor.
Air throttle is additionally provided with the outlet pipe, the air throttle is located at the connection of tail row's circulating valve and the outlet pipe After point.
It is a kind of containing the fuel cell system based on tail row's circulating valve fuel cell humidifying system, including fuel cell pack, And the air supply system and reducing agent system being connected with fuel cell pack, the fuel cell system also include voltage x current and passed Sensor, mass air flow sensor, tail row's circulating valve, and connect respectively with voltage-current sensor, mass air flow sensor and tail row's circulating valve Humidity controller, the electric energy output end connection of the voltage-current sensor and fuel cell pack are connect, the mass air flow sensor is set In on the air inlet pipeline of air supply system, one end of the tail row circulating valve and the outlet of air supply system are connected, and the other end is connected to The air compressor air intake mouth of air inlet pipeline.
Air filter is additionally provided with the air inlet pipeline of the air supply system, the air filter is located at before mass air flow sensor.
Charge air cooler is additionally provided with the air inlet pipeline of the air supply system, the charge air cooler is located at after air compressor machine.
A kind of humidification processing method based on tail row's circulating valve fuel cell humidifying system, including:
The internal resistance of output current and output voltage the estimation fuel cell pack of fuel cell heap;
The internal resistance of fuel cell heap, and the air mass flow of incoming fuel battery pile, regulation tail row's circulating valve are opened Degree.
The internal resistance of output current and output voltage the estimation fuel cell pack of the fuel cell heap, it is specially:Root Estimate to obtain the internal resistance of fuel cell pack using double Kalman filtering algorithms according to the output current and output voltage of fuel cell pack.
The internal resistance of the fuel cell pack, and the air mass flow of incoming fuel battery pile, regulation tail row's circulating valve are opened Degree, including:
The internal resistance of the fuel cell pack obtained according to estimation determines the humidity of PEM;
If humidity is too low, the aperture of increase tail row's circulating valve, on the contrary reduce the aperture of tail row's circulating valve.
While the aperture of tail row's circulating valve is reduced, increase the aperture of air throttle.
Compared with prior art, the invention has the advantages that:
1) exhaust that circulating valve control moistening is arranged by tail keeps the skin wet to be humidified to PEM to air inlet, it is only necessary to The valve of one electronics adjustable opening, infiltration membrane humidifier scheme is matched compared to outside, the system architecture integrated level is high, cost It is low, design it is simple the advantages that.
2) due to eliminating humidifier, the flow resistance on fuel battery air road is reduced, reduces the power consumption of air compressor machine indirectly, Improve the efficiency of fuel cell whole system.
3) target internal resistance control is carried out to fuel cell, water management effectively can be carried out to fuel cell, improve combustion Expect battery efficiency, performance, and powerful measure is provided for the water content control of cold start-up film.
4) tie point of tail row's circulating valve and air inlet pipeline is located at after the mass air flow sensor, enters from gas exhaust piping The fluid of air pipe avoids repeated sampling, the design of simplify control algorithm not within the acquisition target of mass air flow sensor.
5) air throttle is additionally provided with outlet pipe, the effect of tail row's circulating valve can be improved.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention;
Wherein:1st, voltage-current sensor, 2, mass air flow sensor, 3, tail row's circulating valve, 4, humidity controller, 5, fuel electricity Chi Dui, 6, air compressor machine, 7, air throttle, 8, air filter, 9, charge air cooler, 10, DC transfer circuit, 11, high voltage power battery.
Embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.The present embodiment is with technical solution of the present invention Premised on implemented, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to Following embodiments.
The application proposes a kind of new fuel cell humidification scheme, has that humidification degree is controllable, simple in construction, and it is excellent that cost is low etc. Point.The reaction product of the minus plate led to due to the air supply system of fuel cell system has water, therefore present applicant proposes will be for The tail gas of gas system discharge is directed into air inlet side, the humidity of air inlet side is improved, so as to realize the purpose of humidification.
Specifically, providing a kind of tail that is based on arranges the fuel cell humidifying system of circulating valve 3, as shown in figure 1, including:
Voltage-current sensor 1, it is connected with the output end of fuel cell pack 5, for gathering the output electricity of fuel cell pack 5 Stream and output voltage;
Mass air flow sensor 2, on the air inlet pipeline of the air supply system of the system of fuel cell pack 5, enter for gathering The air mass flow of fuel cell pack 5;
The outlet of the air supply system of tail row's circulating valve 3, its one end and fuel cell system connects, and the other end is connected to air inlet The air inlet of air compressor machine 6 of pipeline;
Humidity controller 4, it is connected respectively with voltage-current sensor 1, mass air flow sensor 2 and tail row's circulating valve 3, for root The internal resistance of fuel cell pack 5 is estimated according to the output current and output voltage of fuel cell pack 5, with reference to the internal resistance and entrance of battery pile The aperture of both air flow modulation tail row's circulating valve 3 of fuel cell pack 5.
In addition, the tie point of tail row's circulating valve 3 and air inlet pipeline is located at after mass air flow sensor 2, enter from gas exhaust piping The fluid of air inlet pipeline avoids repeated sampling, the design of simplify control algorithm not within the acquisition target of mass air flow sensor 2. In addition, being additionally provided with air throttle 7 on outlet pipe, the air throttle 7 is located at after the tie point of tail row's circulating valve 3 and outlet pipe, Adjusted by the aperture of air throttle, the effect of tail row's circulating valve 3 can be improved.
Likewise, based on above-mentioned humidification system, a kind of improved fuel cell system, including fuel electricity can also be provided Pond heap 5, and the air supply system and reducing agent system being connected with fuel cell pack 5, fuel cell system also include voltage electricity Flow sensor 1, mass air flow sensor 2, tail row's circulating valve 3, and arranged respectively with voltage-current sensor 1, mass air flow sensor 2 and tail Circulating valve 3 connects humidity controller 4, and voltage-current sensor 1 is connected with the output end of fuel cell pack 5, and mass air flow sensor 2 is set In on the air inlet pipeline of air supply system, one end of tail row's circulating valve 3 is connected with the outlet with air supply system, the other end be connected into The air inlet of air compressor machine 6 of air pipe.
Air filter 8 is additionally provided with the air inlet pipeline of air supply system, the air filter 8 is located at before mass air flow sensor 2, air supply system Charge air cooler 9 is additionally provided with air inlet pipeline, the charge air cooler 9 is located at after air compressor machine 6.The output end of fuel cell pack 5 can pass through DC transfer circuit 11 connects high voltage power battery 11.
For humidity controller 4, its input is the internal resistance of air mass flow and fuel cell pack 5, and tail row's circulating valve 3 is one Can electrical adjustment aperture valve.
Therefore humidification processing method disclosed in the present application, including:
The output current and output voltage of fuel cell heap 5 estimate fuel cell pack using double Kalman filtering algorithms 5 internal resistance;
The internal resistance of fuel cell heap 5, and the air mass flow of incoming fuel battery pile 5, regulation tail row's circulating valve 3 Aperture, specifically, the internal resistance of the fuel cell pack 5 obtained first according to estimation determines the humidity of PEM, then, if wet Spend it is low then, increase tail row circulating valve 3 aperture, otherwise reduce tail row circulating valve 3 aperture.In addition, reducing tail row's circulation While the aperture of valve 3, increase the aperture of air throttle 7.
And then when film is done, tail row's aperture of circulating valve 3 is increased and reduces the aperture of air throttle 7, by more negative electrodes Circulation of tail gas backflow air compressor machine 6 front end for the high humidity higher temperatures discharged after reaction, is sent into fuel cell pack 5 by air compressor machine 6 and enters Mouthful, to reach humidification purpose.When water logging, the rotating speed by improving air compressor machine 6 increases metering ratio, increases the aperture of air throttle 7, fits When reducing circulation of tail gas valve, the water of negative electrode is discharged, and then prevent water logging.
It should be noted that the application is by controlling the humidity of film, it is possible to achieve the control to the internal resistance of fuel cell pack 5.

Claims (10)

1. one kind is based on tail row's circulating valve fuel cell humidifying system, it is characterised in that including:
Voltage-current sensor, it is connected with the electric energy output end of fuel cell pack, for gathering the output current of fuel cell pack And output voltage;
Mass air flow sensor, on the air inlet pipeline of the air supply system of fuel cell stack system, for gathering incoming fuel electricity Chi Dui air flow rate signal signal;
The outlet of the air supply system of tail row's circulating valve, its one end and fuel cell system connects, and the other end is connected to the air inlet The air compressor air intake mouth of pipeline;
Humidity controller, it is connected respectively with voltage-current sensor, mass air flow sensor and tail row's circulating valve, for according to fuel electricity The internal resistance of Chi Dui output current and output voltage estimation fuel cell pack, internal resistance and incoming fuel battery pile with reference to battery pile Both air flow modulation tail row circulating valve aperture.
It is 2. according to claim 1 a kind of based on tail row's circulating valve fuel cell humidifying system, it is characterised in that the tail The tie point of row's circulating valve and the air inlet pipeline is located at after the mass air flow sensor.
It is 3. according to claim 1 a kind of based on tail row's circulating valve fuel cell humidifying system, it is characterised in that it is described go out Air throttle is additionally provided with air pipe, the air throttle is located at after the tie point of tail row's circulating valve and the outlet pipe.
4. a kind of fuel cell system based on tail row's circulating valve fuel cell humidifying system containing described in claims 1 to 3, Characterized in that, the fuel cell system also includes voltage-current sensor, mass air flow sensor, tail row's circulating valve, Yi Jifen Be connected humidity controller with voltage-current sensor, mass air flow sensor and tail row's circulating valve, the voltage-current sensor and The electric energy output end connection of fuel cell pack, on the air inlet pipeline of air supply system, the tail row follows the mass air flow sensor One end of ring valve and the outlet of air supply system connect, and the other end is connected to the air compressor air intake mouth of air inlet pipeline.
5. fuel cell system according to claim 4, it is characterised in that also set on the air inlet pipeline of the air supply system There is air filter, the air filter is located at before mass air flow sensor.
6. fuel cell system according to claim 4, it is characterised in that also set on the air inlet pipeline of the air supply system There is charge air cooler, the charge air cooler is located at after air compressor machine.
7. a kind of humidification processing method based on tail row's circulating valve fuel cell humidifying system as described in claims 1 to 3, its It is characterised by, including:
The internal resistance of output current and output voltage the estimation fuel cell pack of fuel cell heap;
The internal resistance of fuel cell heap, and the air mass flow of incoming fuel battery pile, the aperture of regulation tail row's circulating valve.
8. according to the method for claim 7, it is characterised in that the output current and output electricity of the fuel cell heap The internal resistance of pressure estimation fuel cell pack, it is specially:The output current and output voltage of fuel cell heap use double card Germania Filtering algorithm is estimated to obtain the internal resistance of fuel cell pack.
9. according to the method for claim 7, it is characterised in that the internal resistance of the fuel cell pack, and incoming fuel electricity Chi Dui air mass flow, the aperture of regulation tail row's circulating valve, including:
The internal resistance of the fuel cell pack obtained according to estimation determines the humidity of PEM;
If humidity is too low, the aperture of increase tail row's circulating valve, on the contrary reduce the aperture of tail row's circulating valve.
10. according to the method for claim 7, it is characterised in that while the aperture of tail row's circulating valve is reduced, increase section The aperture of valve.
CN201711385811.8A 2017-12-20 2017-12-20 fuel cell humidifying system, method and fuel cell system Pending CN107895806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711385811.8A CN107895806A (en) 2017-12-20 2017-12-20 fuel cell humidifying system, method and fuel cell system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711385811.8A CN107895806A (en) 2017-12-20 2017-12-20 fuel cell humidifying system, method and fuel cell system

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Publication Number Publication Date
CN107895806A true CN107895806A (en) 2018-04-10

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109830714A (en) * 2019-02-01 2019-05-31 清华大学 Fuel cell diagnostic method, device and storage medium
CN109888335A (en) * 2019-02-20 2019-06-14 华北电力大学 a fuel cell system
CN110531270A (en) * 2019-09-18 2019-12-03 上海重塑能源科技有限公司 A kind of diagnostic method and its diagnostic system of fuel cell air supply system
CN111029621A (en) * 2019-11-08 2020-04-17 珠海格力电器股份有限公司 Hydrogen fuel cell self-humidifying structure and system
CN112018411A (en) * 2020-08-25 2020-12-01 一汽解放汽车有限公司 Humidification system of fuel cell and control method thereof
CN112397745A (en) * 2020-11-09 2021-02-23 一汽解放汽车有限公司 Air system and control method thereof, fuel cell engine and vehicle
CN112652792A (en) * 2021-02-05 2021-04-13 北京亿华通科技股份有限公司 Fuel cell, control method thereof, vehicle, and computer-readable storage medium
CN112928307A (en) * 2021-03-24 2021-06-08 苏州弗尔赛能源科技股份有限公司 Air supply system of fuel cell engine and control method
CN113363540A (en) * 2021-06-03 2021-09-07 上海重塑能源科技有限公司 Humidifier leak diagnosis method and fuel cell system
CN113707916A (en) * 2021-07-23 2021-11-26 上海重塑能源科技有限公司 Fuel cell humidity estimation method and estimation system
US20230092461A1 (en) * 2020-02-17 2023-03-23 Japan Aerospace Exploration Agency Method for controlling fuel cell device
US12278407B2 (en) * 2020-02-17 2025-04-15 Japan Aerospace Exploration Agency Method for controlling fuel cell device

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CN102751521A (en) * 2012-07-03 2012-10-24 新源动力股份有限公司 Air recirculation heating system and method for starting fuel cell at low temperature
CN104409750A (en) * 2014-10-28 2015-03-11 航天新长征电动汽车技术有限公司 Fuel-cell tail gas circulation system
CN105960728A (en) * 2014-01-30 2016-09-21 日产自动车株式会社 Fuel cell system
CN207818786U (en) * 2017-12-20 2018-09-04 上海重塑能源科技有限公司 Fuel cell humidifying system and fuel cell system

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Publication number Priority date Publication date Assignee Title
CN1943067A (en) * 2004-04-08 2007-04-04 丰田自动车株式会社 Fuel cell system
CN102751521A (en) * 2012-07-03 2012-10-24 新源动力股份有限公司 Air recirculation heating system and method for starting fuel cell at low temperature
CN105960728A (en) * 2014-01-30 2016-09-21 日产自动车株式会社 Fuel cell system
CN104409750A (en) * 2014-10-28 2015-03-11 航天新长征电动汽车技术有限公司 Fuel-cell tail gas circulation system
CN207818786U (en) * 2017-12-20 2018-09-04 上海重塑能源科技有限公司 Fuel cell humidifying system and fuel cell system

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109830714A (en) * 2019-02-01 2019-05-31 清华大学 Fuel cell diagnostic method, device and storage medium
CN109888335A (en) * 2019-02-20 2019-06-14 华北电力大学 a fuel cell system
CN110531270A (en) * 2019-09-18 2019-12-03 上海重塑能源科技有限公司 A kind of diagnostic method and its diagnostic system of fuel cell air supply system
CN111029621A (en) * 2019-11-08 2020-04-17 珠海格力电器股份有限公司 Hydrogen fuel cell self-humidifying structure and system
US20230092461A1 (en) * 2020-02-17 2023-03-23 Japan Aerospace Exploration Agency Method for controlling fuel cell device
US12278407B2 (en) * 2020-02-17 2025-04-15 Japan Aerospace Exploration Agency Method for controlling fuel cell device
CN112018411A (en) * 2020-08-25 2020-12-01 一汽解放汽车有限公司 Humidification system of fuel cell and control method thereof
CN112018411B (en) * 2020-08-25 2022-04-01 一汽解放汽车有限公司 Humidification system of fuel cell and control method thereof
CN112397745A (en) * 2020-11-09 2021-02-23 一汽解放汽车有限公司 Air system and control method thereof, fuel cell engine and vehicle
CN112652792A (en) * 2021-02-05 2021-04-13 北京亿华通科技股份有限公司 Fuel cell, control method thereof, vehicle, and computer-readable storage medium
CN112928307A (en) * 2021-03-24 2021-06-08 苏州弗尔赛能源科技股份有限公司 Air supply system of fuel cell engine and control method
CN112928307B (en) * 2021-03-24 2022-08-02 苏州弗尔赛能源科技股份有限公司 Air supply system of fuel cell engine and control method
CN113363540A (en) * 2021-06-03 2021-09-07 上海重塑能源科技有限公司 Humidifier leak diagnosis method and fuel cell system
CN113363540B (en) * 2021-06-03 2022-12-20 上海重塑能源科技有限公司 Humidifier leak diagnosis method and fuel cell system
CN113707916B (en) * 2021-07-23 2023-08-04 上海重塑能源科技有限公司 Method and system for estimating humidity of fuel cell
CN113707916A (en) * 2021-07-23 2021-11-26 上海重塑能源科技有限公司 Fuel cell humidity estimation method and estimation system

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