CN107796858A - A kind of preparation method of metal electrode - Google Patents
A kind of preparation method of metal electrode Download PDFInfo
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- CN107796858A CN107796858A CN201710757955.5A CN201710757955A CN107796858A CN 107796858 A CN107796858 A CN 107796858A CN 201710757955 A CN201710757955 A CN 201710757955A CN 107796858 A CN107796858 A CN 107796858A
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 58
- 239000002184 metal Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 239000012266 salt solution Substances 0.000 claims abstract description 28
- 238000007747 plating Methods 0.000 claims abstract description 20
- 238000010147 laser engraving Methods 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000008236 heating water Substances 0.000 claims abstract description 6
- 238000002386 leaching Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 238000009938 salting Methods 0.000 claims abstract description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
- 239000010931 gold Substances 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 239000008139 complexing agent Substances 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 229910052737 gold Inorganic materials 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 150000001879 copper Chemical class 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 238000003475 lamination Methods 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 230000037361 pathway Effects 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 abstract description 38
- 239000008280 blood Substances 0.000 abstract description 20
- 210000004369 blood Anatomy 0.000 abstract description 20
- 235000012000 cholesterol Nutrition 0.000 abstract description 18
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 17
- 239000008103 glucose Substances 0.000 abstract description 17
- 238000012360 testing method Methods 0.000 abstract description 16
- 238000000034 method Methods 0.000 abstract description 13
- 238000001514 detection method Methods 0.000 abstract description 8
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 abstract description 4
- 230000003862 health status Effects 0.000 abstract description 4
- 230000035484 reaction time Effects 0.000 abstract description 4
- 230000032798 delamination Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910021645 metal ion Inorganic materials 0.000 description 6
- 206010012601 diabetes mellitus Diseases 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 206010008190 Cerebrovascular accident Diseases 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 208000006011 Stroke Diseases 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 208000017667 Chronic Disease Diseases 0.000 description 1
- 108010093096 Immobilized Enzymes Proteins 0.000 description 1
- 208000001132 Osteoporosis Diseases 0.000 description 1
- 206010060862 Prostate cancer Diseases 0.000 description 1
- 208000000236 Prostatic Neoplasms Diseases 0.000 description 1
- 208000001647 Renal Insufficiency Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004204 blood vessel Anatomy 0.000 description 1
- 230000002490 cerebral effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000001952 enzyme assay Methods 0.000 description 1
- 230000004153 glucose metabolism Effects 0.000 description 1
- 208000019622 heart disease Diseases 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 201000006370 kidney failure Diseases 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 208000010125 myocardial infarction Diseases 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 230000003239 periodontal effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/327—Biochemical electrodes, e.g. electrical or mechanical details for in vitro measurements
- G01N27/3271—Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hematology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
Abstract
The invention discloses a kind of preparation method of metal electrode, step includes：The first laser engraving electrode lines on substrate；Then in substrate plating surface last layer pre-plating layer；Preparing metal salting liquid, then the substrate for being coated with pre-plating layer leaching is put and reacted in metal salt solution；Substrate is put into heating water bath in chemical plating bath afterwards, taken out after being heated to 60 DEG C；40 ~ 120min of last laser irradiation substrate.By the above-mentioned means, the present invention can effectively reduce cost of manufacture, it is simple, easy to make, and is adapted to promote the use of；The metal electrode made using this method can be as the conductive electrode of the test paper such as detection blood glucose, cholesterol, and will not be by external environment influence, there is electrode delamination and the phenomenon being corroded, and current signal can be quickly produced in detection process, reaction time is short, test result is accurate, is easy to patient accurately to grasp the health status of oneself.
Description
Technical field
The present invention relates to metal electrode field, more particularly to a kind of preparation method of metal electrode.
Background technology
Diabetes are a kind of very universal in the world and endanger very big chronic disease, ID（International
Diabetes Federation, IDF）Newest report shows, about 60 years old of half in 2013
The cause of the death of following dead adult is diabetes；And the morbidity crowd of diabetes is still increasing year by year.Current medical science skill
For art also without the effective ways that can cure diabetes, main countermeasure is that the blood of patient is continually detected with blood glucose meter
Glucose（That is blood glucose）Content, the glucose metabolism in patient is regulated and controled accordingly.
Blood glucose meter major part operation principle is all electrochemical method at present, and enzyme and glucose in blood produce instantaneous when reacting
Electronics is captured by electron mediator, and electric current is electronically formed under voltage effect, and blood glucose meter detection electric current simultaneously converts the current into
The concentration of Blood Glucose shows that therefore, the degree of accuracy of blood glucose meter test result is heavily dependent on blood sugar test paper
Electrode material above.
Crowd's cholesterol levels generally raise, because
This will pay attention to the preventing and treating of high cholesterol.Recently the Asia-Pacific angiocarpy cohort study announced shows, Asia cardiovascular disease incidence rate
Rapid development, and will focus on from now in teenager and urban population.It is expected that the probability that Chinese a middle-aged person suffers from a heart complaint will
Maintain an equal level with the U.S., China will welcome that cerebral apoplexy is high, zooming second of angiocardiopathy peak of myocardial infarction.Courage
The normal value of sterol is 0-5.2mmo/L (0-200mg/dl), is exactly to show as cholesterol height more than this value, cholesterol is high
Harm mainly has：The speed of growth of prostate cancer can be accelerated, the kidney trouble of kidney failure lipid can be triggered；The longevity of people can be reduced
Life, the especially life-span of male apoplexy probability simultaneously relevant with blood vessel can be with increases；Understand clogged heart arteries and make its change
It is narrow, it is easier to trigger heart disease；It can uprise the possibility of osteoporosis, while excessive intake cholesterol can cause periodontal
Ditch gap between disease, tooth and tooth gap can expand.As can be seen here, the high patient of cholesterol will arrive hospital in time and be treated, in order to avoid
Delay treatment, causes that sb.'s illness took a turn for the worse.
The assay method of T-CHOL can be divided into chemical reagent colorimetric method, enzyme assay, fluorescence at present more than 200 kinds
The major class of method, gas phase and high performance liquid chromatography etc. five.The current most widely used method for most easily detecting internal cholesterol concentration
It is domestic portable vitro detection cholesterol instrument, mixes matching test paper, operation principle is similar to blood glucose meter, in test paper
Upper immobilized enzyme and electron transfer mediator, the cholesterol concentration in blood sample is detected by electron transmission.
, it is necessary to provide certain voltage to test paper, induced enzyme and glucose and cholesterol are anti-when measuring blood glucose or cholesterol
The free electric current that electronically forms, blood glucose meter and cholesterol instrument should be produced to be converted according to blood glucose value and the complicated of cholesterol and current value
Relation shows corresponding concentration.
What nowadays market occurred mainly has two class electrodes, carbon electrode and metal electrode.Carbon electrode is mainly using printing
Mode is made, and the method is that graphite and a kind of elargol mixture are mixed, and is coated to surface of plastic matrix, forms electrode.
Current most blood sugar test paper and cholesterol test paper is all to use graphite electrode as working electrode, but graphite electrode makes
During, it can easily be come off and be corroded by external environment influence, and when detecting blood glucose or cholesterol, carbon electricity
Pole transmission speed is low, and caused current signal is slow, reaction time length so that and there is error in test result, test result is inaccurate,
Influence patient and accurately grasp the health status of oneself, so as to easily delay golden hour.Therefore, increasing researcher opens
Begin electrode of the research using metal as conductive media, and metal electrode is mainly with gold, palladium, silver for material.What application was most at present is to adopt
The method of electricity consumption chemical vacuum sputtering prepares metal electrode；Because metal material itself is expensive, and use the method easy
Cause the waste of material so that making material cost is higher, and the equipment price of chemical sputtering is expensive, and operating the equipment also needs
Certain technical foundation is wanted, therefore this method also is difficult to obtain promoting the use of for large area.
Therefore, in order to solve the above problems, there is provided a kind of preparation method of metal electrode.
The content of the invention
The present invention solves the technical problem of a kind of preparation method of metal electrode is provided, system can be effectively reduced
Make cost, it is simple, easy to make, and is adapted to promote the use of；The metal electrode made using this method can be as detection blood
The conductive electrode of the test paper such as sugar, cholesterol.
In order to solve the above technical problems, one aspect of the present invention is：A kind of making of metal electrode is provided
Method, step include：The first laser engraving electrode lines on substrate；Then in substrate plating surface last layer pre-plating layer；Prepare gold
Belong to salting liquid, then the substrate for being coated with pre-plating layer leaching is put and reacted in metal salt solution；Substrate is put into chemical plating bath afterwards
Middle heating water bath, taken out after being heated to 60 DEG C；40 ~ 120min of last laser irradiation substrate.
Preferably, the metal salt solution is to contain gold（Au）, palladium（Pb）, silver（Ag）, copper（Cu）Saturated salt solution.
Preferably, activator and complexing agent are added in the metal salt solution, activator and complexing agent are with ion shape
State is present in metal salt solution.
Preferably, the material of the substrate is polyvinylchloride or polypropylene PP.
Preferably, the pre-plating layer is nickel dam or layers of copper or aluminium lamination.
Preferably, the pulse frequency of the laser engraving electrode lines is 90 ~ 110KHZ, the speed of laser engraving electrode lines
Spend for 2 ~ 3m/s.
Preferably, the laser exposure pathways are the image of the electrode lines.
The beneficial effects of the invention are as follows：The present invention can effectively reduce cost of manufacture, and it is simple, easy to make, and is adapted to push away
It is wide to use；The metal electrode made using this method can as detection blood glucose, the conductive electrode of the test paper such as cholesterol, and
Will not be by external environment influence, the phenomenon that electrode delamination occurs and be corroded, and can quickly be produced in detection process
Current signal, the reaction time is short, and test result is accurate, is easy to patient accurately to grasp the health status of oneself.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that apparent clearly defined so as to be made to protection scope of the present invention.
The embodiment of the present invention includes：
Embodiment 1：A kind of preparation method of metal electrode, step include：First laser engraving electrode lines, the substrate on substrate
Material is polyvinylchloride；The pulse frequency of laser engraving electrode lines is 100KHZ, and the speed of laser engraving electrode lines is
2.5m/s.Then in substrate plating surface last layer nickel dam；Preparing metal salting liquid, metal salt solution are to contain gold（Au）, palladium
（Pb）, silver（Ag）, copper（Cu）Saturated salt solution, and activator and complexing agent, activator are also added into the metal salt solution
It is present in complexing agent with ionic formses in metal salt solution；The substrate for being coated with nickel dam leaching is put again anti-in metal salt solution
Should, nickel dam can be obtained with reacting metal salt solution containing gold（Au）, palladium（Pb）, silver（Ag）, copper（Cu）Coating；Afterwards base
Plate is put into heating water bath in chemical plating bath, is taken out after being heated to 60 DEG C；Last laser irradiation substrate 40min, laser irradiation road
Footpath be the electrode lines image, can inducing metal ion deposited on electrode lines, one fixed width and thickness can be formed
The metal electrode of degree, prevent metal ion in the other surfaces deposition in addition to electrode lines.
Embodiment 2：A kind of preparation method of metal electrode, step include：The first laser engraving electrode lines on substrate, should
Baseplate material is polyvinylchloride；The pulse frequency of laser engraving electrode lines is 100KHZ, the speed of laser engraving electrode lines
Spend for 2.5m/s.Then in substrate plating surface last layer layers of copper；Preparing metal salting liquid, metal salt solution are to contain gold（Au）、
Palladium（Pb）, silver（Ag）, copper（Cu）Saturated salt solution, and be also added into activator and complexing agent in the metal salt solution, activate
Agent and complexing agent are present in metal salt solution with ionic formses；The substrate for being coated with nickel dam leaching is put in metal salt solution again
Reaction, layers of copper can be obtained with reacting metal salt solution containing gold（Au）, palladium（Pb）, silver（Ag）, copper（Cu）Coating；Handle afterwards
Substrate is put into heating water bath in chemical plating bath, is taken out after being heated to 60 DEG C；Last laser irradiation substrate 50min, laser irradiation
Path be the electrode lines image, can inducing metal ion deposited on electrode lines, can be formed one fixed width and
The metal electrode of thickness, prevent metal ion in the other surfaces deposition in addition to electrode lines.
Embodiment 3：A kind of preparation method of metal electrode, step include：The first laser engraving electrode lines on substrate, should
Baseplate material is polypropylene PP；The pulse frequency of laser engraving electrode lines is 100KHZ, the speed of laser engraving electrode lines
For 2.5m/s.Then in substrate plating surface last layer aluminium lamination；Preparing metal salting liquid, metal salt solution are to contain gold（Au）, palladium
（Pb）, silver（Ag）, copper（Cu）Saturated salt solution, and activator and complexing agent, activator are also added into the metal salt solution
It is present in complexing agent with ionic formses in metal salt solution；The substrate for being coated with nickel dam leaching is put again anti-in metal salt solution
Should, aluminium lamination can be obtained with reacting metal salt solution containing gold（Au）, palladium（Pb）, silver（Ag）, copper（Cu）Coating；Afterwards base
Plate is put into heating water bath in chemical plating bath, is taken out after being heated to 60 DEG C；Last laser irradiation substrate 60min, laser irradiation road
Footpath be the electrode lines image, can inducing metal ion deposited on electrode lines, one fixed width and thickness can be formed
The metal electrode of degree, prevent metal ion in the other surfaces deposition in addition to electrode lines.
The present invention can effectively reduce cost of manufacture, and it is simple, easy to make, and is adapted to promote the use of；Use party's legal system
Make metal electrode out and can be used as to detect blood glucose, the conductive electrode of the test paper such as cholesterol, and will not by external environment influence,
There is electrode delamination and the phenomenon being corroded, and current signal can be quickly produced in detection process, the reaction time is short,
Test result is accurate, is easy to patient accurately to grasp the health status of oneself.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
The equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, it is included within the scope of the present invention.
Claims (7)
1. a kind of preparation method of metal electrode, it is characterised in that step includes：The first laser engraving electrode lines on substrate；
Then in substrate plating surface last layer pre-plating layer；Preparing metal salting liquid, then the substrate for being coated with pre-plating layer leaching is put in metal salt
Reacted in solution；Substrate is put into heating water bath in chemical plating bath afterwards, taken out after being heated to 60 DEG C；Last laser irradiation base
40 ~ 120min of plate.
A kind of 2. preparation method of metal electrode according to claim 1, it is characterised in that：The metal salt solution be containing
There is gold（Au）, palladium（Pb）, silver（Ag）, copper（Cu）Saturated salt solution.
A kind of 3. preparation method of metal electrode according to claim 2, it is characterised in that：Add in the metal salt solution
Activator and complexing agent are entered, activator and complexing agent are present in metal salt solution with ionic formses.
A kind of 4. preparation method of metal electrode according to claim 1, it is characterised in that：The material of the substrate is poly-
Vinyl chloride PVC or polypropylene PP.
A kind of 5. preparation method of metal electrode according to claim 1, it is characterised in that：The pre-plating layer be nickel dam or
Layers of copper or aluminium lamination.
A kind of 6. preparation method of metal electrode according to claim 1, it is characterised in that：The laser engraving electrode line
The pulse frequency on road is 90 ~ 110KHZ, and the speed of laser engraving electrode lines is 2 ~ 3m/s.
A kind of 7. preparation method of metal electrode according to claim 1, it is characterised in that：The laser exposure pathways are
The image of the electrode lines.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710757955.5A CN107796858A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of metal electrode |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710757955.5A CN107796858A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of metal electrode |
Publications (1)
| Publication Number | Publication Date |
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| CN107796858A true CN107796858A (en) | 2018-03-13 |
Family
ID=61532193
Family Applications (1)
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| CN201710757955.5A Pending CN107796858A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of metal electrode |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108213719A (en) * | 2018-01-06 | 2018-06-29 | 武汉吉事达科技股份有限公司 | A kind of laser production method of multi-electrode blood sugar test paper |
| CN112251739A (en) * | 2020-10-23 | 2021-01-22 | 哈尔滨工业大学 | Aluminum-induced chemical plating method for pre-plating copper film |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1192485A (en) * | 1997-12-08 | 1998-09-09 | 中国科学院感光化学研究所 | Photoinduction method for surface metallation of insulator |
| CN101245480A (en) * | 2008-03-19 | 2008-08-20 | 厦门大学 | A kind of method for preparing nickel coating on metal surface |
| CN101634018A (en) * | 2008-07-27 | 2010-01-27 | 比亚迪股份有限公司 | Selective chemical plating method for plastic base material |
| CN103476199A (en) * | 2013-09-27 | 2013-12-25 | 电子科技大学 | Printed circuit addition manufacturing method based on copper autocatalysis and chemical copper plating |
| CN104073845A (en) * | 2014-06-11 | 2014-10-01 | 安徽长青电子机械（集团）有限公司 | Gold plating method for PCB |
| CN105829576A (en) * | 2013-08-06 | 2016-08-03 | 全球第电路技术公司 | Forming a conductive image using high speed electroless plating |
-
2017
- 2017-08-29 CN CN201710757955.5A patent/CN107796858A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1192485A (en) * | 1997-12-08 | 1998-09-09 | 中国科学院感光化学研究所 | Photoinduction method for surface metallation of insulator |
| CN101245480A (en) * | 2008-03-19 | 2008-08-20 | 厦门大学 | A kind of method for preparing nickel coating on metal surface |
| CN101634018A (en) * | 2008-07-27 | 2010-01-27 | 比亚迪股份有限公司 | Selective chemical plating method for plastic base material |
| CN105829576A (en) * | 2013-08-06 | 2016-08-03 | 全球第电路技术公司 | Forming a conductive image using high speed electroless plating |
| CN103476199A (en) * | 2013-09-27 | 2013-12-25 | 电子科技大学 | Printed circuit addition manufacturing method based on copper autocatalysis and chemical copper plating |
| CN104073845A (en) * | 2014-06-11 | 2014-10-01 | 安徽长青电子机械（集团）有限公司 | Gold plating method for PCB |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108213719A (en) * | 2018-01-06 | 2018-06-29 | 武汉吉事达科技股份有限公司 | A kind of laser production method of multi-electrode blood sugar test paper |
| CN112251739A (en) * | 2020-10-23 | 2021-01-22 | 哈尔滨工业大学 | Aluminum-induced chemical plating method for pre-plating copper film |
| CN112251739B (en) * | 2020-10-23 | 2021-09-03 | 哈尔滨工业大学 | Aluminum-induced chemical plating method for pre-plating copper film |
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