CN107793966B - A kind of preparation method of mould proof closestool positioning glue - Google Patents
A kind of preparation method of mould proof closestool positioning glue Download PDFInfo
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- CN107793966B CN107793966B CN201711099932.6A CN201711099932A CN107793966B CN 107793966 B CN107793966 B CN 107793966B CN 201711099932 A CN201711099932 A CN 201711099932A CN 107793966 B CN107793966 B CN 107793966B
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- mould proof
- silicon
- modified resin
- proof organic
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- 239000003292 glue Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- JTWZVKMWOCBJEV-KLLFFGQPSA-N ethane-1,2-diol (2S,3R,4R,5S,6R)-2-(hydroxymethyl)-6-[(2S,3R,4S,5S,6S)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-3,4,5-triol (2S,3S,4R,5S,6S)-2,3,4-trimethoxy-6-(methoxymethyl)-5-[(2R,3S,4R,5S,6S)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane Chemical compound OCCO.OC[C@@H]1O[C@H](O[C@@H]2[C@@H](O)[C@H](O)[C@@H](O)O[C@H]2CO)[C@@H](O)[C@H](O)[C@H]1O.COC[C@@H]1O[C@H](O[C@H]2[C@H](COC)O[C@H](OC)[C@@H](OC)[C@@H]2OC)[C@@H](OC)[C@H](OC)[C@H]1OC JTWZVKMWOCBJEV-KLLFFGQPSA-N 0.000 claims abstract description 8
- AMMPRZCMKXDUNE-UHFFFAOYSA-N trihexyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(O)(C(=O)OCCCCCC)CC(=O)OCCCCCC AMMPRZCMKXDUNE-UHFFFAOYSA-N 0.000 claims abstract description 8
- BUBVLQDEIIUIQG-UHFFFAOYSA-N 3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-one Chemical compound C=1C=CC=CC=1COC1C(OCC=2C=CC=CC=2)C(OCC=2C=CC=CC=2)C(=O)OC1COCC1=CC=CC=C1 BUBVLQDEIIUIQG-UHFFFAOYSA-N 0.000 claims abstract description 5
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 10
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 9
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003729 cation exchange resin Substances 0.000 claims description 8
- BVTLTBONLZSBJC-UHFFFAOYSA-N 2,4,6-tris(ethenyl)-2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O1 BVTLTBONLZSBJC-UHFFFAOYSA-N 0.000 claims description 7
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- -1 4,5- bis- chloro- 2- n-octyl Chemical group 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- YHKCOJIIHLGDFJ-UHFFFAOYSA-N 3-chloro-2-octyl-1,2-thiazol-5-one Chemical compound ClC=1N(SC(C=1)=O)CCCCCCCC YHKCOJIIHLGDFJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 244000248349 Citrus limon Species 0.000 claims 2
- 235000005979 Citrus limon Nutrition 0.000 claims 2
- 239000000047 product Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 13
- 239000013065 commercial product Substances 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000004965 Silica aerogel Substances 0.000 description 3
- PHOQVHQSTUBQQK-UHFFFAOYSA-N aldono-1,5-lactone Chemical compound OCC1OC(=O)C(O)C(O)C1O PHOQVHQSTUBQQK-UHFFFAOYSA-N 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JWYUFVNJZUSCSM-UHFFFAOYSA-N 2-aminobenzimidazole Chemical compound C1=CC=C2NC(N)=NC2=C1 JWYUFVNJZUSCSM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of preparation methods of mould proof closestool positioning glue.By weight, mould proof organic-silicon-modified resin obtained by step 1, silica solution, aerosil, methyl -2- hydroxyethyl cellulose are added in a stirring kettle, citric acid tri-n-hexyl ester, 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactone stirs evenly to get positioning glue product is arrived.
Description
Technical field
The present invention relates to a kind of production method of closestool positioning glue, especially a kind of preparation side of mould proof closestool positioning glue
Method.
Background technique
In the closestool of house ornamentation, usually only hanging closestool just will use high-intensitive bolt, and to install, (such as C-shaped frame is pacified
Fill closestool/or L shape frame installation closestool/or wall-hung type closestool), such closestool only uses bolt that could install fixation；
It the use of glue is that fixed can not be installed in general, the price of this seed type closestool is higher, the people of selection is less.
For the upper toilet product installation situation of market, the closestool of most of console mode mounting means does not all have usually
There is the anchor (bolt) hole for setting installation, fixed using glass cement or glue for tile to prevent from being displaced, prevent leak, reinforces closestool.
CN103642399A discloses a kind of glass cement, belongs to chemical technology field, which wraps by weight percentage
It includes: phenolic resin 15%, waterglass 50%, silicic acid 20%, acrylic resin 10%, fragrance 5%.Advantages of the present invention: it uses
It is convenient, it is environmentally protective.
CN106085350A discloses a kind of weather-proof glass cement, is made of the raw material of following mass fraction: inclined five water silicons acid
10-15 parts of sodium, 7-9 parts of acetone, 7-10 parts of dioctyl phthalate, 6-10 parts of cumyl peroxide, 4-6 parts of zinc oxide,
9-11 parts of Cocoamidopropyl betaine, 7-8 parts of polyester fiber, 8-10 parts of olive oil, 17-19 parts of waterglass.
Existing closestool positioning glue, mostly uses greatly simple glass glue that waterproof is fixed, in this environmental wet in toilet
Spend larger, in the environment of mould easy to breed, most positioning are easy to produce mould with glue, it is difficult to clean.
Summary of the invention
The object of the present invention is to provide a kind of manufacturing methods of closestool positioning glue, it is characterised in that following steps:
Step 1: the preparation of mould proof organic-silicon-modified resin
By weight, tripropylene glycol diacrylate, acrylic trimethoxy silane, 4- are added in a kettle
Simultaneously [1,2-A] benzimidazolyl-2 radicals-amine, 4,5- bis- chloro- 2- are just pungent for [(E) -2- phenyl vinyl]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Base -3- isothiazolinone, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane, in polystyrene cation exchange tree
Under the catalysis of rouge, be warming up to 60-70 DEG C, react 4-8h, after remove styrene type cation exchange resin, obtain mould proof having
Machine Si modification resin.
Step 2: the preparation of positioning glue mixture
By weight, mould proof organic-silicon-modified resin obtained by step 1, silica solution, dioxy are added in a stirring kettle
SiClx aeroge, methyl -2- hydroxyethyl cellulose, citric acid tri-n-hexyl ester, 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acids -
1,5- lactone, is warming up to 60-70 DEG C, stirs 0.5-2.5h with the revolving speed of 150-350rpm to get positioning glue product is arrived.
The mould proof organic-silicon-modified resin, material quality amount ratio are tripropylene glycol diacrylate: acrylic
Trimethoxy silane: 4- [(E) -2- phenyl vinyl] -1,4- dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine:
The chloro- 2- n-octyl -3- isothiazolinone of 4,5- bis-: 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane=100:35-
50:0.2-1:0.5-1.5:0.5-2.
The silica solution, quality dosage are the 35-50% of mould proof organic-silicon-modified resin.
The aerosil, quality dosage are the 4-10% of mould proof organic-silicon-modified resin.
Methyl -2- the hydroxyethyl cellulose, quality dosage are the 2-5% of mould proof organic-silicon-modified resin.
The citric acid tri-n-hexyl ester, quality dosage are the 0.5-1.5% of mould proof organic-silicon-modified resin.
Described 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactones, quality dosage are that mould proof organosilicon changes
The 0.05-0.2% of property resin.
The tripropylene glycol diacrylate is commercial product, as Beijing Orient subfamily power Chemical Co., Ltd. produces
Product；Acrylic trimethoxy silane is commercial product, the product produced such as Henan Kang Qian Co., Ltd；4- [(E) -2- phenyl
Vinyl] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine is commercial product to-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine, such as Changzhou Xin Teke chemical industry
The product of Co., Ltd's production；4,5- bis- chloro- 2- n-octyl -3- isothiazolinone are commercial product, if Hubei is far at Sai Chuan section
The product of skill Co., Ltd production；Styrene type cation exchange resin is commercial product, such as Langfang Jin Nan resin Co., Ltd
The product of production；Methyl -2- hydroxyethyl cellulose is commercial product, the product produced such as lark prestige Science and Technology Ltd.；Lemon
Sour three just own esters are commercial product, the product produced such as Hubei Ju Sheng scientific & technical corporation；2,3,4,6- tetrabenzyl-D- glucopyranose
Acid -1,5- lactone is commercial product, the product produced such as Shanghai nation at Chemical Co., Ltd..
The beneficial effects of the present invention are: present invention closestool produced positions glue, main material resin crosslinking degree is big,
Non-aging flavescence, the good mechanical properties of product, fixed effect is secured, and there have simultaneously for bacteriums such as moulds to be permanent and potent
Bactericidal effect.
Specific embodiment
Following instance is only to further illustrate the present invention, is not limitation the scope of protection of the invention.
Embodiment 1
Step 1: the preparation of mould proof organic-silicon-modified resin
In a kettle, tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 42.5Kg, 4- is added
[(E) -2- phenyl vinyl]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 0.6Kg, 4,5- bis- chloro- 2-
N-octyl -3- isothiazolinone 1Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 1.2Kg, in polystyrene
Under the catalysis of cation exchange resin, be warming up to 65 DEG C, react 6h, after remove styrene type cation exchange resin, obtain
To mould proof organic-silicon-modified resin.
Step 2: the preparation of positioning glue mixture
Mould proof organic-silicon-modified resin 100Kg obtained by step 1, silica solution 50Kg, titanium dioxide are added in a stirring kettle
Silica aerogel 7Kg, methyl -2- hydroxyethyl cellulose 3.5Kg, citric acid tri-n-hexyl ester 1Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.1Kg, is warming up to 65 DEG C, stirs 1.5h with the revolving speed of 250rpm to get positioning glue product is arrived.
Embodiment 2
Step 1: the preparation of mould proof organic-silicon-modified resin
In a kettle, tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 35Kg, 4- [(E)-is added
2- phenyl vinyl] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 0.2Kg, 4,5- bis- chloro- 2- is just pungent for-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Base -3- isothiazolinone 0.5Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 0.5Kg, in polystyrene sun
Under the catalysis of ion exchange resin, be warming up to 60 DEG C, react 4h, after remove styrene type cation exchange resin, obtain
Mould proof organic-silicon-modified resin.
Step 2: the preparation of positioning glue mixture
Mould proof organic-silicon-modified resin 100Kg obtained by step 1, silica solution 35Kg, titanium dioxide are added in a stirring kettle
Silica aerogel 4Kg, methyl -2- hydroxyethyl cellulose 2Kg, citric acid tri-n-hexyl ester 0.5Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.05Kg, is warming up to 60 DEG C, stirs 0.5h with the revolving speed of 150rpm to get positioning glue product is arrived.
Embodiment 3
Step 1: the preparation of mould proof organic-silicon-modified resin
In a kettle, tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 50Kg, 4- [(E)-is added
2- phenyl vinyl]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 1Kg, 4,5- bis- chloro- 2- n-octyls-
3- isothiazolinone 1.5Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 2Kg are handed in polystyrene cation
Change under the catalysis of resin, be warming up to 70 DEG C, react 8h, after remove styrene type cation exchange resin, obtain mould proof having
Machine Si modification resin.
Step 2: the preparation of positioning glue mixture
Mould proof organic-silicon-modified resin 100Kg obtained by step 1, silica solution 50Kg, titanium dioxide are added in a stirring kettle
Silica aerogel 10Kg, methyl -2- hydroxyethyl cellulose 5Kg, citric acid tri-n-hexyl ester 1.5Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.2Kg, is warming up to 70 DEG C, stirs 2.5h with the revolving speed of 350rpm to get positioning glue product is arrived.
Comparative example 1
Step 1 is added without 4- [(E) -2- phenyl vinyl] -1,4- dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazole -
2- amine, other conditions are the same as embodiment 1.
Comparative example 2
Step 1 is added without the chloro- 2- n-octyl -3- isothiazolinone of 4,5- bis-, and other conditions are the same as embodiment 1.
Comparative example 3
Step 1 is added without 1,3,5- trivinyls -1,3, and 5- trimethyl cyclotrisiloxane, other conditions are the same as embodiment 1.
Comparative example 4
Step 2 is added without methyl -2- hydroxyethyl cellulose, and other conditions are the same as embodiment 1.
Comparative example 5
Step 2 is added without citric acid tri-n-hexyl ester, and other conditions are the same as embodiment 1.
Comparative example 6
Step 2 is added without 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactones, and other conditions are the same as embodiment 1.
Embodiment 4
The positioning glue product for respectively being produced embodiment 1-3 and comparative example 1-6, measures its attachment with ASTM D3359
Power, and the method that reference standard QBT2591-2003 is provided examines its antifungi ability and two months later antifungi abilities,
It is shown in Table 1.
Table 1: the adhesion and Anti-mildew capability for the positioning glue product that different process is produced.
| Product number | Adhesion | Antifungi rate/% | Antifungi rate/% after two months |
| Embodiment 1 | 5B | 99 | 98 |
| Embodiment 2 | 5B | 98 | 98 |
| Embodiment 3 | 5B | 99 | 99 |
| Comparative example 1 | 5B | 95 | 91 |
| Comparative example 2 | 4B | 94 | 90 |
| Comparative example 3 | 3B | 97 | 93 |
| Comparative example 4 | 3B | 96 | 90 |
| Comparative example 5 | 3B | 97 | 91 |
| Comparative example 6 | 4B | 96 | 92 |
Claims (1)
1. a kind of preparation method of mould proof closestool positioning glue, it is characterised in that the following steps are included:
Step 1: the preparation of mould proof organic-silicon-modified resin
By weight, tripropylene glycol diacrylate, acrylic trimethoxy silane, 4- [(E) -2- are added in a kettle
Phenyl vinyl] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine, 4,5- bis- chloro- 2- n-octyl -3- are different for-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Thiazolinone, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane, in the catalysis of styrene type cation exchange resin
Under, be warming up to 60-70 DEG C, react 4-8h, after remove styrene type cation exchange resin, obtain mould proof organic-silicon-modified
Resin；
Step 2: the preparation of positioning glue mixture
By weight, mould proof organic-silicon-modified resin obtained by step 1, silica solution, silica are added in a stirring kettle
Aeroge, methyl -2- hydroxyethyl cellulose, citric acid tri-n-hexyl ester, 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acids -1,5-
Lactone is warming up to 60-70 DEG C, stirs 0.5-2.5h with the revolving speed of 150-350rpm to get positioning glue product is arrived；
The mould proof organic-silicon-modified resin, material quality amount ratio are tripropylene glycol diacrylate: acrylic front three
Oxysilane: 4- [(E) -2- phenyl vinyl] -1,4- dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine: 4,5-
Two chloro- 2- n-octyl -3- isothiazolinone: 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane=100:35-50:
0.2-1:0.5-1.5:0.5-2；
The silica solution, quality dosage are the 30-45% of mould proof organic-silicon-modified resin；
The aerosil, quality dosage are the 4-10% of mould proof organic-silicon-modified resin；
Methyl -2- the hydroxyethyl cellulose, quality dosage are the 2-5% of mould proof organic-silicon-modified resin；The lemon
The just own ester of lemon acid three, quality dosage are the 0.5-1.5% of mould proof organic-silicon-modified resin；The 2,3,4,6- tetrabenzyl-
D- glucopyra saccharic acid -1,5- lactone, quality dosage are the 0.05-0.2% of mould proof organic-silicon-modified resin.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221756A (en) * | 1997-12-31 | 1999-07-07 | 中国石化齐鲁石油化工公司 | Method for preparing organic silicon modified acrylic resin |
| CN104312525A (en) * | 2014-11-24 | 2015-01-28 | 上海橡胶制品研究所 | Mould-proof organic silicone sealant |
| CN105505296A (en) * | 2015-12-29 | 2016-04-20 | 江苏创景科技有限公司 | Mildew-proof dealcoholization type organic silicon sealant and preparation method thereof |
-
2017
- 2017-11-09 CN CN201711099932.6A patent/CN107793966B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221756A (en) * | 1997-12-31 | 1999-07-07 | 中国石化齐鲁石油化工公司 | Method for preparing organic silicon modified acrylic resin |
| CN104312525A (en) * | 2014-11-24 | 2015-01-28 | 上海橡胶制品研究所 | Mould-proof organic silicone sealant |
| CN105505296A (en) * | 2015-12-29 | 2016-04-20 | 江苏创景科技有限公司 | Mildew-proof dealcoholization type organic silicon sealant and preparation method thereof |
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