CN107793966A - A kind of preparation method of mould proof closestool positioning glue - Google Patents
A kind of preparation method of mould proof closestool positioning glue Download PDFInfo
- Publication number
- CN107793966A CN107793966A CN201711099932.6A CN201711099932A CN107793966A CN 107793966 A CN107793966 A CN 107793966A CN 201711099932 A CN201711099932 A CN 201711099932A CN 107793966 A CN107793966 A CN 107793966A
- Authority
- CN
- China
- Prior art keywords
- mould proof
- preparation
- silicon
- modified resin
- closestool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003292 glue Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- AMMPRZCMKXDUNE-UHFFFAOYSA-N trihexyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(O)(C(=O)OCCCCCC)CC(=O)OCCCCCC AMMPRZCMKXDUNE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 6
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 claims abstract description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 8
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 8
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003729 cation exchange resin Substances 0.000 claims description 8
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 8
- -1 [1,3,5] triazine Thiazolinone Chemical compound 0.000 claims description 6
- BVTLTBONLZSBJC-UHFFFAOYSA-N 2,4,6-tris(ethenyl)-2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O1 BVTLTBONLZSBJC-UHFFFAOYSA-N 0.000 claims description 5
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000004965 Silica aerogel Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- BUBVLQDEIIUIQG-UHFFFAOYSA-N 3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-one Chemical compound C=1C=CC=CC=1COC1C(OCC=2C=CC=CC=2)C(OCC=2C=CC=CC=2)C(=O)OC1COCC1=CC=CC=C1 BUBVLQDEIIUIQG-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- JJRDHFIVAPVZJN-UHFFFAOYSA-N cyclotrisiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]1 JJRDHFIVAPVZJN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910002012 Aerosil® Inorganic materials 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 150000002596 lactones Chemical class 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- 239000011521 glass Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- PHOQVHQSTUBQQK-UHFFFAOYSA-N aldono-1,5-lactone Chemical compound OCC1OC(=O)C(O)C(O)C1O PHOQVHQSTUBQQK-UHFFFAOYSA-N 0.000 description 3
- JTWZVKMWOCBJEV-KLLFFGQPSA-N ethane-1,2-diol (2S,3R,4R,5S,6R)-2-(hydroxymethyl)-6-[(2S,3R,4S,5S,6S)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxane-3,4,5-triol (2S,3S,4R,5S,6S)-2,3,4-trimethoxy-6-(methoxymethyl)-5-[(2R,3S,4R,5S,6S)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane Chemical compound OCCO.OC[C@@H]1O[C@H](O[C@@H]2[C@@H](O)[C@H](O)[C@@H](O)O[C@H]2CO)[C@@H](O)[C@H](O)[C@H]1O.COC[C@@H]1O[C@H](O[C@H]2[C@H](COC)O[C@H](OC)[C@@H](OC)[C@@H]2OC)[C@@H](OC)[C@H](OC)[C@H]1OC JTWZVKMWOCBJEV-KLLFFGQPSA-N 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JWYUFVNJZUSCSM-UHFFFAOYSA-N 2-aminobenzimidazole Chemical compound C1=CC=C2NC(N)=NC2=C1 JWYUFVNJZUSCSM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- ORVGYTXFUWTWDM-UHFFFAOYSA-N silicic acid;sodium Chemical compound [Na].O[Si](O)(O)O ORVGYTXFUWTWDM-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of preparation method of mould proof closestool positioning glue.By weight, the mould proof organic-silicon-modified resin obtained by step 1, Ludox, aerosil, the hydroxyethyl cellulose of methyl 2 are added in stirred tank, citric acid tri-n-hexyl ester, 2,3,4, the lactone of 6 tetrabenzyl D glucopyras saccharic acid 1,5, stirs, that is, obtains positioning glue product.
Description
Technical field
The present invention relates to a kind of preparation method of closestool positioning glue, especially a kind of preparation side of mould proof closestool positioning glue
Method.
Background technology
In the closestool of house ornamentation, generally only hanging closestool just can install (such as C-shaped frame peace using the bolt of high intensity
Fill closestool/or L-shaped frame installation closestool/or wall-hung type closestool), such closestool only could install fixation using bolt；
The use of glue is that can not install that fixed is usual, the price of this type closestool is higher, and the people of selection is less.
For the upper toilet product installation situation of market, the closestool of most of console mode mounting means does not all have generally
There is the anchor (bolt) hole for setting installation, fixed using glass cement or glue for tile to prevent displacement, prevent leak, reinforce closestool.
CN103642399A discloses a kind of glass cement, belongs to chemical technology field, and the glass cement wraps by weight percentage
Include：Phenolic resin 15%, waterglass 50%, silicic acid 20%, acrylic resin 10%, spices 5%.Advantages of the present invention：Use
It is convenient, it is green.
CN106085350A discloses a kind of weather-proof glass cement, is made up of the raw material of following mass fraction：Inclined five water silicic acid
Sodium 10-15 parts, acetone 7-9 parts, dioctyl phthalate 7-10 parts, cumyl peroxide 6-10 parts, zinc oxide 4-6 parts,
Cocoamidopropyl betaine 9-11 parts, polyester fiber 7-8 parts, olive oil 8-10 parts, waterglass 17-19 parts.
Existing closestool positioning glue, waterproof is fixed using simple glass glue mostly, in this environmental wet in toilet
Spend larger, in the environment of easy mould growth, most positioning easily produce mould with glue, it is difficult to clean.
The content of the invention
The purpose of the present invention is：There is provided a kind of manufacture method of closestool positioning glue, it is characterised in that following steps：
Step 1：The preparation of mould proof organic-silicon-modified resin
By weight, tripropylene glycol diacrylate, acrylic trimethoxy silane, 4- are added in a kettle
Simultaneously [1,2-A] benzimidazolyl-2 radicals-amine, 4,5- bis- chloro- 2- are just pungent for [(E) -2- phenyl vinyls]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Base -3- OITs, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane, in polystyrene cation exchange tree
Under the catalysis of fat, 60-70 DEG C is warming up to, reacts 4-8h, styrene type cation exchange resin is removed after terminating, obtain mould proof having
Machine Si modification resin.
Step 2：Position the preparation of glue mixture
By weight, the mould proof organic-silicon-modified resin obtained by step 1, Ludox, dioxy are added in stirred tank
SiClx aeroge, methyl -2- hydroxyethyl celluloses, citric acid tri-n-hexyl ester, 2,3,4,6- tetrabenzyl-D- glucopyras saccharic acids -
1,5- lactone, is warming up to 60-70 DEG C, and 0.5-2.5h is stirred with 150-350rpm rotating speed, that is, obtains positioning glue product.
Described mould proof organic-silicon-modified resin, its material quality amount ratio are tripropylene glycol diacrylate：Acrylic
Trimethoxy silane：4- [(E) -2- phenyl vinyls] -1,4- dihydros [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine：
The chloro- 2- n-octyls -3- OITs of 4,5- bis-：1,3,5- trivinyl -1,3,5- trimethyls cyclotrisiloxane=100:35-
50：0.2-1：0.5-1.5:0.5-2.
Described Ludox, its quality dosage are the 35-50% of mould proof organic-silicon-modified resin.
Described aerosil, its quality dosage are the 4-10% of mould proof organic-silicon-modified resin.
Described methyl -2- hydroxyethyl celluloses, its quality dosage are the 2-5% of mould proof organic-silicon-modified resin.
Described citric acid tri-n-hexyl ester, its quality dosage are the 0.5-1.5% of mould proof organic-silicon-modified resin.
Described 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactones, its quality dosage are that mould proof organosilicon changes
The 0.05-0.2% of property resin.
Described tripropylene glycol diacrylate is commercially available prod, as Beijing Orient subfamily power Chemical Co., Ltd. produces
Product；Acrylic trimethoxy silane is commercially available prod, the product produced such as Henan Kang Qian Co., Ltds；4- [(E) -2- phenyl
Vinyl] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine is commercially available prod to-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine, such as Changzhou Xin Teke chemical industry
The product of Co., Ltd's production；4,5- bis- chloro- 2- n-octyls -3- OITs are commercially available prod, if Hubei is far into Sai Chuan sections
The product of skill Co., Ltd production；Styrene type cation exchange resin is commercially available prod, such as Langfang Jin Nan resins Co., Ltd
The product of production；Methyl -2- hydroxyethyl celluloses are commercially available prod, the product produced such as lark prestige Science and Technology Ltd.；Lemon
Sour three just own esters are commercially available prod, the product produced such as Hubei Ju Sheng scientific ＆ technical corporation；2,3,4,6- tetrabenzyl-D- glucopyranoses
Acid -1,5- lactones are commercially available prod, the product produced such as Shanghai nation into Chemical Co., Ltd..
The beneficial effects of the invention are as follows：The closestool positioning glue that the present invention is produced, its main material resin crosslinks degree is big,
Non-aging flavescence, the good mechanical properties of product, fixed effect is firm, and there have simultaneously for bacteriums such as moulds to be permanent and potent
Bactericidal effect.
Embodiment
Following instance is only to further illustrate the present invention, is not limitation the scope of protection of the invention.
Embodiment 1
Step 1：The preparation of mould proof organic-silicon-modified resin
In a kettle, tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 42.5Kg, 4- are added
[(E) -2- phenyl vinyls]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 0.6Kg, 4,5- bis- chloro- 2-
N-octyl -3- OITs 1Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 1.2Kg, in polystyrene
Under the catalysis of cationic ion-exchange resin, 65 DEG C are warming up to, 6h is reacted, removes styrene type cation exchange resin after terminating, obtain
To mould proof organic-silicon-modified resin.
Step 2：Position the preparation of glue mixture
The mould proof organic-silicon-modified resin 100Kg obtained by step 1, Ludox 50Kg, titanium dioxide are added in stirred tank
Silica aerogel 7Kg, methyl -2- hydroxyethyl cellulose 3.5Kg, citric acid tri-n-hexyl ester 1Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.1Kg, is warming up to 65 DEG C, and 1.5h is stirred with 250rpm rotating speed, that is, obtains positioning glue product.
Embodiment 2
Step 1：The preparation of mould proof organic-silicon-modified resin
In a kettle, add tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 35Kg, 4- [(E)-
2- phenyl vinyls] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 0.2Kg, 4,5- bis- chloro- 2- is just pungent for-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Base -3- OITs 0.5Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 0.5Kg, in polystyrene sun
Under the catalysis of ion exchange resin, 60 DEG C are warming up to, 4h is reacted, removes styrene type cation exchange resin after terminating, obtain
Mould proof organic-silicon-modified resin.
Step 2：Position the preparation of glue mixture
The mould proof organic-silicon-modified resin 100Kg obtained by step 1, Ludox 35Kg, titanium dioxide are added in stirred tank
Silica aerogel 4Kg, methyl -2- hydroxyethyl cellulose 2Kg, citric acid tri-n-hexyl ester 0.5Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.05Kg, is warming up to 60 DEG C, and 0.5h is stirred with 150rpm rotating speed, that is, obtains positioning glue product.
Embodiment 3
Step 1：The preparation of mould proof organic-silicon-modified resin
In a kettle, add tripropylene glycol diacrylate 100Kg, acrylic trimethoxy silane 50Kg, 4- [(E)-
2- phenyl vinyls]-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine 1Kg, 4,5- bis- chloro- 2- n-octyls-
3- OITs 1.5Kg, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane 2Kg, handed in polystyrene cation
Change under the catalysis of resin, be warming up to 70 DEG C, react 8h, styrene type cation exchange resin is removed after terminating, obtain mould proof having
Machine Si modification resin.
Step 2：Position the preparation of glue mixture
The mould proof organic-silicon-modified resin 100Kg obtained by step 1, Ludox 50Kg, titanium dioxide are added in stirred tank
Silica aerogel 10Kg, methyl -2- hydroxyethyl cellulose 5Kg, citric acid tri-n-hexyl ester 1.5Kg, 2,3,4,6- tetrabenzyl-D- pyrans
Gluconic acid -1,5- lactone 0.2Kg, is warming up to 70 DEG C, and 2.5h is stirred with 350rpm rotating speed, that is, obtains positioning glue product.
Comparative example 1
Step 1 be added without 4- [(E) -2- phenyl vinyls] -1,4- dihydros [1,3,5] triazine simultaneously [1,2-A] benzimidazole -
2- amine, other conditions are the same as embodiment 1.
Comparative example 2
Step 1 is added without the chloro- 2- n-octyls -3- OITs of 4,5- bis-, and other conditions are the same as embodiment 1.
Comparative example 3
Step 1 is added without 1,3,5- trivinyls -1,3, and 5- trimethyl cyclotrisiloxane, other conditions are the same as embodiment 1.
Comparative example 4
Step 2 is added without methyl -2- hydroxyethyl celluloses, and other conditions are the same as embodiment 1.
Comparative example 5
Step 2 is added without citric acid tri-n-hexyl ester, and other conditions are the same as embodiment 1.
Comparative example 6
Step 2 is added without 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactones, and other conditions are the same as embodiment 1.
Embodiment 4
The positioning glue product for respectively being produced embodiment 1-3 and comparative example 1-6, its attachment is determined with ASTM D3359
Power, and the method that reference standard QBT2591-2003 is provided examines its antifungi ability and two months later antifungi abilities,
It is shown in Table 1.
Table 1：The tack and Anti-mildew capability for the positioning glue product that different process is produced.
| Production code member | Tack | Antifungi rate/% | Antifungi rate/% after two months |
| Embodiment 1 | 5B | 99 | 98 |
| Embodiment 2 | 5B | 98 | 98 |
| Embodiment 3 | 5B | 99 | 99 |
| Comparative example 1 | 5B | 95 | 91 |
| Comparative example 2 | 4B | 94 | 90 |
| Comparative example 3 | 3B | 97 | 93 |
| Comparative example 4 | 3B | 96 | 90 |
| Comparative example 5 | 3B | 97 | 91 |
| Comparative example 6 | 4B | 96 | 92 |
Claims (7)
1. a kind of preparation method of mould proof closestool positioning glue, it is characterised in that comprise the following steps：
Step 1：The preparation of mould proof organic-silicon-modified resin
By weight, tripropylene glycol diacrylate, acrylic trimethoxy silane, 4- [(E) -2- are added in a kettle
Phenyl vinyl] simultaneously [1,2-A] benzimidazolyl-2 radicals-amine, 4,5- bis- chloro- 2- n-octyls -3- are different for-Isosorbide-5-Nitrae-dihydro [1,3,5] triazine
Thiazolinone, 1,3,5- trivinyl -1,3,5- trimethyl cyclotrisiloxane, in the catalysis of styrene type cation exchange resin
Under, 60-70 DEG C is warming up to, 4-8h is reacted, removes styrene type cation exchange resin after terminating, obtain mould proof organic-silicon-modified
Resin；
Step 2：Position the preparation of glue mixture
By weight, the mould proof organic-silicon-modified resin obtained by step 1, Ludox, silica are added in stirred tank
Aeroge, methyl -2- hydroxyethyl celluloses, citric acid tri-n-hexyl ester, 2,3,4,6- tetrabenzyl-D- glucopyra saccharic acids -1,5-
Lactone, 60-70 DEG C is warming up to, 0.5-2.5h is stirred with 150-350rpm rotating speed, that is, obtain positioning glue product.
A kind of 2. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described mould proof have
Machine Si modification resin, its material quality amount ratio are tripropylene glycol diacrylate：Acrylic trimethoxy silane：4-[(E)-
2- phenyl vinyls] -1,4- dihydros [1,3,5] triazine simultaneously [1,2-A] benzimidazolyl-2 radicals-amine：The chloro- 2- n-octyls -3- of 4,5- bis-
OIT：1,3,5- trivinyl -1,3,5- trimethyls cyclotrisiloxane=100:35-50：0.2-1：0.5-1.5:
0.5-2。
A kind of 3. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described silicon is molten
Glue, its quality dosage are the 30-45% of mould proof organic-silicon-modified resin.
A kind of 4. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described titanium dioxide
Silica aerogel, its quality dosage are the 4-10% of mould proof organic-silicon-modified resin.
A kind of 5. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described methyl-
2- hydroxyethyl celluloses, its quality dosage are the 2-5% of mould proof organic-silicon-modified resin.
A kind of 6. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described citric acid
Three just own esters, its quality dosage are the 0.5-1.5% of mould proof organic-silicon-modified resin.
A kind of 7. preparation method of mould proof closestool positioning glue according to claim 1, it is characterised in that：Described 2,3,4,
6- tetrabenzyl-D- glucopyra saccharic acid -1,5- lactones, its quality dosage are the 0.05-0.2% of mould proof organic-silicon-modified resin.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221756A (en) * | 1997-12-31 | 1999-07-07 | 中国石化齐鲁石油化工公司 | Method for preparing organic silicon modified acrylic resin |
| CN104312525A (en) * | 2014-11-24 | 2015-01-28 | 上海橡胶制品研究所 | Mould-proof organic silicone sealant |
| CN105505296A (en) * | 2015-12-29 | 2016-04-20 | 江苏创景科技有限公司 | Mildew-proof dealcoholization type organic silicon sealant and preparation method thereof |
-
2017
- 2017-11-09 CN CN201711099932.6A patent/CN107793966B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221756A (en) * | 1997-12-31 | 1999-07-07 | 中国石化齐鲁石油化工公司 | Method for preparing organic silicon modified acrylic resin |
| CN104312525A (en) * | 2014-11-24 | 2015-01-28 | 上海橡胶制品研究所 | Mould-proof organic silicone sealant |
| CN105505296A (en) * | 2015-12-29 | 2016-04-20 | 江苏创景科技有限公司 | Mildew-proof dealcoholization type organic silicon sealant and preparation method thereof |
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