CN107793949A - A kind of graphene is except aldehyde sterilization glutinous rice glue - Google Patents
A kind of graphene is except aldehyde sterilization glutinous rice glue Download PDFInfo
- Publication number
- CN107793949A CN107793949A CN201710816367.4A CN201710816367A CN107793949A CN 107793949 A CN107793949 A CN 107793949A CN 201710816367 A CN201710816367 A CN 201710816367A CN 107793949 A CN107793949 A CN 107793949A
- Authority
- CN
- China
- Prior art keywords
- graphene
- glutinous rice
- rice glue
- except aldehyde
- starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 46
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 42
- 235000009566 rice Nutrition 0.000 title claims abstract description 42
- 239000003292 glue Substances 0.000 title claims abstract description 35
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims abstract description 21
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 19
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 19
- 240000007594 Oryza sativa Species 0.000 title claims description 40
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229920002472 Starch Polymers 0.000 claims abstract description 25
- 235000019698 starch Nutrition 0.000 claims abstract description 25
- 239000008107 starch Substances 0.000 claims abstract description 25
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 13
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 11
- 238000012986 modification Methods 0.000 claims abstract description 11
- 230000004048 modification Effects 0.000 claims abstract description 11
- 230000003647 oxidation Effects 0.000 claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 229920000881 Modified starch Polymers 0.000 claims abstract description 6
- 239000004368 Modified starch Substances 0.000 claims abstract description 6
- 235000019426 modified starch Nutrition 0.000 claims abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 244000103152 Eleocharis tuberosa Species 0.000 claims description 6
- 235000014309 Eleocharis tuberosa Nutrition 0.000 claims description 6
- 244000017020 Ipomoea batatas Species 0.000 claims description 6
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 6
- 240000002853 Nelumbo nucifera Species 0.000 claims description 6
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims description 6
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims description 6
- 240000001085 Trapa natans Species 0.000 claims description 6
- 240000004922 Vigna radiata Species 0.000 claims description 6
- 235000010721 Vigna radiata var radiata Nutrition 0.000 claims description 6
- 235000011469 Vigna radiata var sublobata Nutrition 0.000 claims description 6
- 235000009165 saligot Nutrition 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 3
- 235000015110 jellies Nutrition 0.000 claims description 3
- 239000008274 jelly Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- -1 mineral carbon Hydrogen compound Chemical class 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 11
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 5
- 230000002688 persistence Effects 0.000 abstract description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 241000209094 Oryza Species 0.000 abstract 2
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 241000894006 Bacteria Species 0.000 description 6
- 230000003115 biocidal effect Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920002690 Polyoxyl 40 HydrogenatedCastorOil Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to decoration material field, more particularly to a kind of graphene is except aldehyde sterilization glutinous rice glue.By following material composition：Gelatinized starch, carboxymethyl modified starch, oxidation modification starch, anti-Formaldehyde as Additives, antibacterial and mouldproof auxiliary agent, propane diols, defoamer, solubilizer.It is of the invention compared with common glutinous rice glue, the not organic pollution such as removing residue formaldehyde, benzene, and removing formaldehyde can be fundamentally decomposed, simultaneously, the addition of graphene can also improve the decomposing, purifying efficiency of harmful substance, increase the persistence of antibacterial and mouldproof material and improve the cementability of colloid.
Description
Technical field
The invention belongs to decoration material field, more particularly to a kind of graphene is except aldehyde sterilization glutinous rice glue.
Background technology
Wallpaper is a kind of using quite extensive house decorative material.Because wallpaper has, color is various, pattern is abundant, person of outstanding talent
The characteristics of a variety of other house decorative materials institutes such as magnificent style, safety and environmental protection, easy for construction, affordable are incomparable, is disappeared
Expense person accepts extensively.The wallpaper material of safety and environmental protection receives everybody accreditation, but relative to wallpaper, the peace of its auxiliary material
Full property is also the problem of can not be ignored.
At present, on the market, the glue pasted for wallpaper substantially has rubber powder, rubber cement, wet glue etc., small point of general wallpaper glue
Sub- raw material is formaldehyde, is also compared by the free formaldehyde remained after synthesis technique more.Therefore, there has been proposed various sides
Method, such as the sprinkling of plant absorption method, cleanser, charcoal absorption etc. remove free formaldehyde.Although but above method energy
Formaldehyde is enough cleared up, but still suffers from many deficiencies, for example, plant absorption method purification efficiency is limited, is taken effect too slow, DeGrain；
Cleanser spray effect is not lasting, and some cleansers simply cover smell, can not eliminate formaldehyde；Activated carbon PARA FORMALDEHYDE PRILLS(91,95)
Suction-operated is it is obvious that still according to the of different sizes of space, the amount for placing activated carbon is also different.In addition, activated carbon is inhaled
Be attached to needs to be changed to a certain degree afterwards.Although the effect of activated carbon is pretty good, can not be complete as other method
Remove the formaldehyde in air.And glutinous rice glue, most risen early in Japan, and incoming various countries, it can firmly cling metope wallpaper, and
House is allowed to become comfortable, durable and environmentally friendly.
A kind of glutinous rice glue except aldehyde sterilization how is made, makes itself be free of formaldehyde, and can be with free in decomposition chamber
Formaldehyde and killing harmful bacteria, reach the effect of mould proof, significant to the safe and environment-friendly property of home environment.
The content of the invention
The present invention is directed to the problems such as formaldehyde pollution in above-mentioned hard-cover house fitting-up, it is proposed that a kind of graphene is sterilized except aldehyde
Glutinous rice glue.
In order to achieve the above object, the technical solution adopted by the present invention is that the present invention provides a kind of graphene except aldehyde is sterilized
Glutinous rice glue, it is characterised in that be prepared according to parts by weight by following component：
Preferably, the gelatinized starch carries out gelatinization system for the mixture of glutinous rice, long-grained nonglutinous rice and polished rice by special process
The jelly obtained.
Preferably, the carboxymethyl modified starch is to be entered using sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch as raw material
Row is carboxymethyl modified to be obtained.
Preferably, the oxidation modification starch is carried out by raw material of sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch
Oxidation modification obtains.
Preferably, the anti-Formaldehyde as Additives is the mixture of graphene and nano titanium oxide, the graphene is with receiving
The mass ratio of rice titanium dioxide is 1:10-10:1.
Preferably, the antibacterial and mouldproof auxiliary agent is graphene nano silver dispersion liquid, the graphene nano silver dispersion liquid
The mass ratio of middle graphene and Nano Silver is 1:50-50:1.
Disappear preferably, the defoamer is mineral hydrocarbon defoamer and/or nonionic alkyl copolymer
Infusion.
Preferably, the solubilizer is the table that PEG-40, PEG-60, PEG-80 rilanit special etc. has solubilising power
Face activating agent.
Compared with prior art, the advantages and positive effects of the present invention are,
1st, it is of the invention compared with traditional glutinous rice glue, graphene composition is with the addition of, using the light transmittance of graphene, makes its work
For photocatalysis carrier, light-catalyzed reaction and electronics conduction efficiency are substantially increased.It is improved with the compound of nano titanium oxide
The photocatalytic activity of photocatalyst, add the decomposition efficiency and persistence of formaldehyde.The big specific surface area of graphene and spy simultaneously
Different two-dimensional slice structure, the contact area of anti-biotic material and bacterium can be strengthened, so as to improve antibacterial and mouldproof efficiency, reach efficient
Lasting antibacterial and mouldproof effect.And the addition of graphene, improve the adhesive property of glutinous rice glue.
Embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can
To be mutually combined.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below
The limitation of embodiment.
The present invention is directed to the problems such as formaldehyde pollution in hard-cover house fitting-up, it is proposed that a kind of graphene is except aldehyde sterilization glutinous rice
Glue, it is prepared according to parts by weight by following component：Gelatinized starch 50-70 parts, carboxymethyl modified starch 10-30 parts, oxidation
Modified starch 10-30 parts, anti-Formaldehyde as Additives 1-10 parts, antibacterial and mouldproof auxiliary agent 1-2 parts, propane diols 1-5 parts, defoamer 0.05-1
Part, solubilizer 1-2 parts.Wherein, gelatinized starch by special process be gelatinized and is made for the mixture of glutinous rice, long-grained nonglutinous rice and polished rice
Jelly；Carboxymethyl modified starch is carboxymethyl modified as raw material progress using sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch
Obtain；Oxidation modification starch is to carry out oxidation modification as raw material using sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch to obtain；Graphite
The mass ratio of alkene and nano titanium oxide is 1:10-10:1；The quality of graphene and Nano Silver in graphene nano silver dispersion liquid
Than for 1:50-50:1；Defoamer is mineral hydrocarbon defoamer and/or nonionic alkyl copolymer defoamer；Increase
Solvent is the surfactant that PEG-40, PEG-60, PEG-80 rilanit special etc. has solubilising power.
Gelatinized starch has long viscosity, nontoxic free from extraneous odour and premium properties applied widely after special process is handled,
With the addition of graphene composition, using the light transmittance of graphene, make it as photocatalysis carrier, substantially increase light-catalyzed reaction and
Electronics conduction efficiency.Its compound photocatalytic activity for improving photocatalyst with nano titanium oxide, adds the decomposition of formaldehyde
Efficiency and persistence.The big specific surface area of graphene and special two-dimensional slice structure simultaneously, can strengthen anti-biotic material with it is thin
The contact area of bacterium, so as to improve antibacterial and mouldproof efficiency, reach the antibacterial and mouldproof effect of high-efficient and lasting.And graphene adds
Enter, improve the adhesive property of glutinous rice glue.Inventor draws glutinous rice glue its performance under heterogeneity proportioning by many experiments
Also there is different, illustrate the performance difference of the glutinous rice glue under heterogeneity proportioning with several specific embodiments below.
Embodiment 1
A kind of graphene is except aldehyde sterilization glutinous rice glue, it is characterised in that feed components are grouped into as follows according to weight：Gelatinization
70 parts of starch, carboxymethyl modified 10 parts of starch, 10 parts of oxidation modification starch, the anti-Formaldehyde as Additives (ratio of graphene and nano TiO 2
Example is 2:8) 2 parts, (ratio of graphene and Nano Silver is 1 to antibacterial and mouldproof auxiliary agent:1) 1 part, 4 parts of propane diols, 1 part of defoamer, increase
2 parts of solvent Cremophor RH40.Prepare glutinous rice glue 1.
Embodiment 2
A kind of graphene is except aldehyde sterilization glutinous rice glue, it is characterised in that feed components are grouped into as follows according to weight：Gelatinization
60 parts of starch, carboxymethyl modified 20 parts of starch, 10 parts of oxidation modification starch, the anti-Formaldehyde as Additives (ratio of graphene and nano TiO 2
Example is 1:1) 3 parts, (ratio of graphene and Nano Silver is 1 to antibacterial and mouldproof auxiliary agent:2) 1 part, 3 parts of propane diols, 1 part of defoamer, increase
2 parts of solvent PEG-60 rilanit specials.Prepare glutinous rice glue 2.
Embodiment 3
A kind of graphene is except aldehyde sterilization glutinous rice glue, it is characterised in that feed components are grouped into as follows according to weight：Gelatinization
50 parts of starch, carboxymethyl modified 15 parts of starch, 20 parts of oxidation modification starch, the anti-Formaldehyde as Additives (ratio of graphene and nano TiO 2
Example is 2:5) 5 parts, (ratio of graphene and Nano Silver is 1 to antibacterial and mouldproof auxiliary agent:1) 2 parts, 4 parts of propane diols, 1 part of defoamer, increase
3 parts of solvent PEG-80 rilanit specials.Prepare glutinous rice glue 3.
To the graphene that embodiment 1-3 is provided except the effect of aldehyde sterilization glutinous rice glue enters detection, wherein purifying formaldehyde rate is tested
Method performs JC/T1074-2008《Function of purifying indoor air coating material purification function》Defined Ι classes requirement is tested.
Antibiotic property method is with reference to GB/T21866-2008《Antibiotic paint (paint film) antibiotic property determination method and antibacterial effect》Perform.Peel off strong
Degree is tested with reference to GB/T 2790-1995 standards.
Table 1：The graphene that embodiment 1-3 is provided is except the testing result of aldehyde sterilization glutinous rice glue
From upper table, it should be clear that, glutinous rice glue prepared by the present invention is in purifying formaldehyde, purifying formaldehyde
Standardized product performance will be far superior in effect persistence, bacteria resistance, antibacterium persistence and peel strength, especially anti-
Be even more to reach effect very in bacterium property, on the premise of itself is free of formaldehyde, can with the formaldehyde that dissociates in decomposition chamber and
Harmful bacteria is killed, reaches the effect of mould proof, it is significant to the safe and environment-friendly property of home environment.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Effect embodiment is applied to other fields, but every without departing from technical solution of the present invention content, the technical spirit according to the present invention
Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.
Claims (8)
1. a kind of graphene is except aldehyde sterilization glutinous rice glue, it is characterised in that is prepared according to parts by weight by following component：
2. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The gelatinized starch is glutinous
The mixture of rice, long-grained nonglutinous rice and polished rice carries out being gelatinized obtained jelly.
3. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The carboxymethyl modified starch
It is to carry out carboxymethyl modified obtain by raw material of sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch.
4. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The oxidation modification starch is
Oxidation modification is carried out using sweet potato, mung bean, water caltrop, lotus rhizome or Chinese Water Chestnut Starch as raw material to obtain.
5. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The anti-Formaldehyde as Additives is stone
The mixture of black alkene and nano titanium oxide, the mass ratio of the graphene and nano titanium oxide is 1:10-10:1.
6. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The antibacterial and mouldproof auxiliary agent is
Graphene nano silver dispersion liquid, the mass ratio of graphene and Nano Silver is 1 in the graphene nano silver dispersion liquid:50-50:1.
7. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The defoamer is mineral carbon
Hydrogen compound class defoamer and/or nonionic alkyl copolymer defoamer.
8. a kind of graphene is except aldehyde sterilization glutinous rice glue according to claim 1, it is characterised in that：The solubilizer is PEG-
40th, the one or more in PEG-60, PEG-80 rilanit special.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710816367.4A CN107793949A (en) | 2017-09-12 | 2017-09-12 | A kind of graphene is except aldehyde sterilization glutinous rice glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710816367.4A CN107793949A (en) | 2017-09-12 | 2017-09-12 | A kind of graphene is except aldehyde sterilization glutinous rice glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107793949A true CN107793949A (en) | 2018-03-13 |
Family
ID=61531911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710816367.4A Pending CN107793949A (en) | 2017-09-12 | 2017-09-12 | A kind of graphene is except aldehyde sterilization glutinous rice glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107793949A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321144A (en) * | 2018-09-29 | 2019-02-12 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of green wallpaper adhesive |
| CN115895504A (en) * | 2022-11-22 | 2023-04-04 | 杭州志和新材料有限公司 | A kind of glutinous rice glue that prevents wallpaper from warping and cracking and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2886621A1 (en) * | 2013-12-19 | 2015-06-24 | Grupo Antolin-Ingenieria, S.A. | Adhesive for the manufacture of laminates of cellulose products and manufacturing procedures of laminates of cellulose products |
| CN105419530A (en) * | 2016-01-13 | 2016-03-23 | 青岛瑞利特新材料科技有限公司 | Graphene nano-silver antibacterial coating and preparation method thereof |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106957576A (en) * | 2017-04-14 | 2017-07-18 | 青岛瑞利特新材料科技有限公司 | A kind of anti-formaldehyde wallpaper coating |
-
2017
- 2017-09-12 CN CN201710816367.4A patent/CN107793949A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2886621A1 (en) * | 2013-12-19 | 2015-06-24 | Grupo Antolin-Ingenieria, S.A. | Adhesive for the manufacture of laminates of cellulose products and manufacturing procedures of laminates of cellulose products |
| CN105419530A (en) * | 2016-01-13 | 2016-03-23 | 青岛瑞利特新材料科技有限公司 | Graphene nano-silver antibacterial coating and preparation method thereof |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106957576A (en) * | 2017-04-14 | 2017-07-18 | 青岛瑞利特新材料科技有限公司 | A kind of anti-formaldehyde wallpaper coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321144A (en) * | 2018-09-29 | 2019-02-12 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of green wallpaper adhesive |
| CN115895504A (en) * | 2022-11-22 | 2023-04-04 | 杭州志和新材料有限公司 | A kind of glutinous rice glue that prevents wallpaper from warping and cracking and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102153924B (en) | Inner wall latex paint | |
| WO2008049315A1 (en) | An environment-protecting polyurethane composition used for environment-friendly synthetic leather, a synthetic leather therefrom and its preparation | |
| CN103146267B (en) | The multifunctional coating of deposed polystyrene preparation energy release of trace elements negative ion | |
| CN106731766A (en) | It is a kind of environmentally friendly except formaldehyde spray | |
| CN104387871A (en) | Interior wall latex paint containing sticky rice glue and preparation method of interior wall latex paint | |
| CN106957576A (en) | A kind of anti-formaldehyde wallpaper coating | |
| CN106281112B (en) | A kind of antibacterial glutinous rice glue and preparation method thereof | |
| CN107793949A (en) | A kind of graphene is except aldehyde sterilization glutinous rice glue | |
| CN104817956A (en) | Coral elastic coating and preparation method thereof | |
| CN101823274B (en) | Method for coloring wood by fermenting microorganisms | |
| CN107722700B (en) | A kind of functional paint that indoor air purification is self-cleaning and preparation method | |
| CN106587813A (en) | Multifunctional wall covering material and preparation method thereof | |
| CN107189532A (en) | A kind of graphene formaldehyde-removing wallpaper, wall paper and preparation method | |
| CN106608719B (en) | A kind of Multifunctional diatom ooze decorative material for wall surface compound by modified potato starch | |
| CN106280763A (en) | Kieselguhr photocatalytic spray liquid can be cleaned | |
| CN106675243A (en) | Environment-friendly and healthy white bamboo charcoal functional coating for interior walls | |
| CN106009974A (en) | Scrubbable obsidian photocatalyst spraying solution | |
| CN106221414A (en) | Chlorite photocatalytic spray liquid can be cleaned | |
| CN106221398A (en) | Molecular sieve photocatalytic spray liquid can be cleaned | |
| CN108640121A (en) | Modified manometer silicon dioxide, preparation method and go application in formaldehyde products preparing | |
| CN116510507A (en) | Nano composite formaldehyde-removing spray and preparation method and application thereof | |
| CN106221420A (en) | Erasable whitens white carbon black photocatalytic spray liquid | |
| CN106280769A (en) | Fluorite photocatalytic spray liquid can be cleaned | |
| CN106221401A (en) | Garnet photocatalytic spray liquid can be cleaned | |
| CN106221406A (en) | Attapulgite photocatalytic spray liquid can be cleaned |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180313 |