CN106957576A - A kind of anti-formaldehyde wallpaper coating - Google Patents
A kind of anti-formaldehyde wallpaper coating Download PDFInfo
- Publication number
- CN106957576A CN106957576A CN201710243314.8A CN201710243314A CN106957576A CN 106957576 A CN106957576 A CN 106957576A CN 201710243314 A CN201710243314 A CN 201710243314A CN 106957576 A CN106957576 A CN 106957576A
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- CN
- China
- Prior art keywords
- formaldehyde
- coating
- defoamer
- thickener
- wallpaper coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to decorative materials technology, and in particular to a kind of anti-formaldehyde wallpaper coating, by following material composition：Deionized water, multifunctional assistant, water-base resin, color stuffing slurry, dispersant, waterproofing agent, defoamer, thickener, bactericide, anti-Formaldehyde as Additives；Wherein, described anti-Formaldehyde as Additives is the mixture of graphene and nano titanium oxide.The present invention does not contain the organic pollutions such as formaldehyde, benzene compared with common wall paper and coating, and can fundamentally remove formaldehyde, meanwhile, the addition of graphene can also improve the decomposing, purifying efficiency of harmful substance and the anti-wear performance of coating.
Description
Technical field
The present invention relates to decorative materials technology, and in particular to a kind of anti-formaldehyde wallpaper coating.
Background technology
Wallpaper is a kind of quite extensive house decorative material of application.Because wallpaper has, color is various, pattern is abundant, person of outstanding talent
The characteristics of a variety of other house decorative materials institutes such as magnificent style, safety and environmental protection, easy construction, affordable are incomparable, therefore
The developed countries and regions such as America and Europe, Southeast Asia, Japan obtain considerable degree of popularization.Because with certain intensity, attractive in appearance
Appearance and good clean-up performance, are widely used in house, office, interior decoration of hotel etc..
The main raw material(s) for making wallpaper at present is fluoropolymer resin, and the inside is contained in higher formaldehyde, finishing in wallpaper
Bonding in terms of used by glue in also contain higher formaldehyde.Therefore, there has been proposed various methods, such as plant
Absorption process, cleanser sprinkling, charcoal absorption etc. remove free formaldehyde.But although the above method can clear up formaldehyde,
But many deficiencies are still suffered from, for example, plant absorption method purification efficiency is limited, are taken effect too slow, DeGrain；Cleanser sprinkling effect
Fruit is not persistently, and some cleansers are to cover smell, can not eliminate formaldehyde；The suction-operated of activated carbon PARA FORMALDEHYDE PRILLS(91,95) is very bright
It is aobvious, but according to the of different sizes of space, the amount for placing activated carbon is also different.In addition, charcoal absorption is to a certain extent
After need to be changed., can not be in fully erased air as other method although the effect of activated carbon is pretty good
Formaldehyde.A kind of anti-formaldehyde wallpaper how is made, makes itself to be free of formaldehyde, and the function with decomposing formaldehyde, and it is simultaneously full
Sufficient home safety, environmental protection, comfortable performance are significant.
The content of the invention
There is provided a kind of anti-formaldehyde wallpaper coating for the problem of present invention is directed to formaldehyde pollution in above-mentioned hard-cover house fitting-up.
In order to achieve the above object, the technical solution adopted by the present invention is,
A kind of anti-formaldehyde wallpaper coating, specifically includes following number by weight：
The anti-Formaldehyde as Additives is the mixture of graphene and nano titanium oxide, and its mass ratio is 1:10-10:1.
Preferably, described multifunctional assistant is multifunction amine analog assistant；Described dispersant be calgon and
Lauryl sodium sulfate is according to mass ratio 1：The mixture of 2 compositions；Described waterproofing agent is organic silicon hydrophobic waterproofing agent；Described
Defoamer is mineral hydrocarbon defoamer and/or nonionic alkyl copolymer defoamer；Described thickener is to form
At least one in mould assembly alkali swollen thickener or polyurethane thickener.
Preferably, described water-base resin be acrylic copolymer, pure third polymer, phenylpropyl alcohol, polyurethane, organosilicon,
Any one or a few in polyflon.
Preferably, described color stuffing slurry is titanium dioxide, powdered whiting slurry, kaolin, talcum powder, ultra-fine calcite
At least one material in powder, diatomite, barium sulfate, mica powder adds in dispersant and disperses stirring with deionized water and forms
Slurry like material.
Compared with prior art, advantages and positive effects of the present invention are,
Graphene composition is with the addition of in the present invention, using the light transmittance of graphene, makes it as photocatalysis carrier, carries significantly
The efficiency of high light-catalyzed reaction；Meanwhile, graphene will be added in Nano titanium dioxide, add visible-light absorptivity, and carry
High electronics conduction efficiency；Furthermore, graphene and the effective of Nano titanium dioxide are combined, and not only improve photo-catalytic nano
Grain is in the dispersiveness of graphenic surface, and by reducing the compound of photo-generate electron-hole, the photocatalysis for improving photocatalyst is lived
Property；At the same time, due to the adjustment of band structure, graphene will also play the effect of sensitising agent, make the absorption region of photocatalyst
Visible region is extended to, utilization rate of the photocatalyst to sunshine is effectively increased；And the addition of graphene, adds wallpaper
The anti-wear performance of coating.
Embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can
To be mutually combined.
Many details are elaborated in the following description in order to fully understand the present invention, and still, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below
The limitation of embodiment.
Embodiment 1
A kind of anti-formaldehyde wallpaper coating, feed components are grouped into as follows according to weight：5 parts of deionized water, multifunction amine
0.3 part of auxiliary agent (AMP-95), 42.5 parts of water-based acrylic resin, color stuffing starches 50 parts, dispersant (calgon and dodecane
Base sodium sulfate quality ratio is 1:2) 0.5 part, 0.5 part of waterproofing agent, nonionic alkyl copolymer defoamer (CHE COAT
DF9000) 0.3 part, 0.1 part of association type alkali swollen thickener (CHE COAT VT-183), polyurethane thickener (CHE COAT
VT-903) 0.1 part, 0.5 part of bactericide (Clariant HF-1), (nano TiO 2 and graphene ratio are 2 to anti-Formaldehyde as Additives:8)0.2
Part.Prepares coating 1.
Embodiment 2
A kind of anti-formaldehyde wallpaper coating, it is characterised in that feed components are grouped into as follows according to weight：Deionized water 8
Part, 0.2 part of multifunction amine auxiliary agent (AMP-95), 49.5 parts of water-based acrylic resin, color stuffing starches 40 parts, dispersant (six inclined phosphorus
Sour sodium and lauryl sodium sulfate mass ratio are 1:2) 0.3 part, 0.8 part of waterproofing agent, nonionic alkyl copolymer defoamer
0.2 part of (CHE COAT DF9000), 0.1 part of association type alkali swollen thickener (CHE COAT VT-183), polyurethane thickener
0.2 part of (CHE COAT VT-903), 0.5 part of bactericide (Clariant HF-1), anti-Formaldehyde as Additives (nano TiO 2 and graphene ratio
Example is 5:5) 0.2 part.Prepares coating 2.
Embodiment 3
A kind of anti-formaldehyde wallpaper coating, it is characterised in that feed components are grouped into as follows according to weight：Deionized water 10
Part, 0.5 part of multifunction amine auxiliary agent (AMP-95), 45 parts of water-based acrylic resin, color stuffing starches 42 parts, dispersant (hexa metaphosphoric acid
Sodium and lauryl sodium sulfate mass ratio are 1:2) 0.8 part, 0.5 part of waterproofing agent, nonionic alkyl copolymer defoamer (CHE
COAT DF9000) 0.3 part, 0.2 part of association type alkali swollen thickener (CHE COAT VT-183), polyurethane thickener (CHE
COAT VT-903) 0.1 part, 0.3 part of bactericide (Clariant HF-1), (nano TiO 2 and graphene ratio are 8 to anti-Formaldehyde as Additives:
2) 0.3 part.Prepares coating 3.
Effect to the embodiment 1-3 anti-formaldehyde wallpaper coatings provided enters detection, and wherein purifying formaldehyde rate method of testing is held
Row JC/T1074-2008《Function of purifying indoor air coating material purification function》Defined Ι classes requirement is tested.
Table 1：The testing result for the anti-formaldehyde wallpaper coating that embodiment 1-3 is provided
The above, is only presently preferred embodiments of the present invention, is not the limitation for making other forms to the present invention, appoints
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Imitate embodiment and be applied to other fields, but every without departing from technical solution of the present invention content, the technical spirit according to the present invention
Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.
Claims (4)
1. a kind of anti-formaldehyde wallpaper coating, it is characterised in that specifically include following number by weight：
The anti-Formaldehyde as Additives is the mixture of graphene and nano titanium oxide, and its mass ratio is 1:10-10:1.
2. a kind of anti-formaldehyde wallpaper coating according to claim 1, it is characterised in that described multifunctional assistant is many work(
Can amine auxiliary agent；Described dispersant is calgon and lauryl sodium sulfate according to mass ratio 1：The mixture of 2 compositions；
Described waterproofing agent is organic silicon hydrophobic waterproofing agent；Described defoamer be mineral hydrocarbon defoamer and/or it is non-from
Subtype alkyl copolymer defoamer；Described thickener is at least one in association type alkali swollen thickener or polyurethane thickener
Kind.
3. a kind of anti-formaldehyde wallpaper coating according to claim 1, it is characterised in that described water-base resin is acrylic acid
Any one or a few in copolymer, pure third polymer, phenylpropyl alcohol, polyurethane, organosilicon, polyflon.
4. a kind of anti-formaldehyde wallpaper coating according to claim 1, it is characterised in that described color stuffing slurry is titanium white
At least one thing in powder, powdered whiting slurry, kaolin, talcum powder, ultra-fine calcite in powder, diatomite, barium sulfate, mica powder
Matter adds the slurry like material for disperseing stirring in dispersant and with deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710243314.8A CN106957576A (en) | 2017-04-14 | 2017-04-14 | A kind of anti-formaldehyde wallpaper coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710243314.8A CN106957576A (en) | 2017-04-14 | 2017-04-14 | A kind of anti-formaldehyde wallpaper coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106957576A true CN106957576A (en) | 2017-07-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710243314.8A Pending CN106957576A (en) | 2017-04-14 | 2017-04-14 | A kind of anti-formaldehyde wallpaper coating |
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| Country | Link |
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| CN (1) | CN106957576A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641977A (en) * | 2017-09-12 | 2018-01-30 | 青岛瑞利特新材料科技有限公司 | A kind of graphene glass wall base cloth and preparation method thereof |
| CN107793949A (en) * | 2017-09-12 | 2018-03-13 | 青岛瑞利特新材料科技有限公司 | A kind of graphene is except aldehyde sterilization glutinous rice glue |
| CN107936662A (en) * | 2017-12-02 | 2018-04-20 | 马晓洁 | A kind of graphene-based antibiotic paint and its preparation method and application |
| CN107955482A (en) * | 2017-12-04 | 2018-04-24 | 马晓洁 | A kind of graphene-based antibacterial, wear-resisting dual-component coating and preparation method thereof, application and application method |
| CN108978335A (en) * | 2018-07-25 | 2018-12-11 | 邹德琨 | A kind of photocatalyst is dispelled formaldehyde wallpaper |
| CN109629242A (en) * | 2018-12-12 | 2019-04-16 | 杭州尊尚壁装饰材料有限公司 | A kind of manufacturing method of spunlace non-woven fabric wall paper |
| CN110616040A (en) * | 2019-09-27 | 2019-12-27 | 丹阳市银海镍铬化工有限公司 | Waterproof paint capable of absorbing formaldehyde and preparation method thereof |
| CN110643279A (en) * | 2019-09-27 | 2020-01-03 | 丹阳市银海镍铬化工有限公司 | Wear-resistant paint capable of absorbing formaldehyde and preparation method thereof |
| CN113736295A (en) * | 2021-09-24 | 2021-12-03 | 青岛瑞利特新材料科技有限公司 | Graphene inorganic coating with pearlescent effect and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315814A (en) * | 2015-10-19 | 2016-02-10 | 青岛瑞利特新材料科技有限公司 | Graphene formaldehyde-resisting paint and preparing method thereof |
| CN105542595A (en) * | 2016-01-07 | 2016-05-04 | 青岛瑞利特新材料科技有限公司 | Graphene-diatomaceous-earth anti-formaldehyde coating and preparing method thereof |
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2017
- 2017-04-14 CN CN201710243314.8A patent/CN106957576A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105315814A (en) * | 2015-10-19 | 2016-02-10 | 青岛瑞利特新材料科技有限公司 | Graphene formaldehyde-resisting paint and preparing method thereof |
| CN105542595A (en) * | 2016-01-07 | 2016-05-04 | 青岛瑞利特新材料科技有限公司 | Graphene-diatomaceous-earth anti-formaldehyde coating and preparing method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641977A (en) * | 2017-09-12 | 2018-01-30 | 青岛瑞利特新材料科技有限公司 | A kind of graphene glass wall base cloth and preparation method thereof |
| CN107793949A (en) * | 2017-09-12 | 2018-03-13 | 青岛瑞利特新材料科技有限公司 | A kind of graphene is except aldehyde sterilization glutinous rice glue |
| CN107936662A (en) * | 2017-12-02 | 2018-04-20 | 马晓洁 | A kind of graphene-based antibiotic paint and its preparation method and application |
| CN107955482A (en) * | 2017-12-04 | 2018-04-24 | 马晓洁 | A kind of graphene-based antibacterial, wear-resisting dual-component coating and preparation method thereof, application and application method |
| CN108978335A (en) * | 2018-07-25 | 2018-12-11 | 邹德琨 | A kind of photocatalyst is dispelled formaldehyde wallpaper |
| CN109629242A (en) * | 2018-12-12 | 2019-04-16 | 杭州尊尚壁装饰材料有限公司 | A kind of manufacturing method of spunlace non-woven fabric wall paper |
| CN110616040A (en) * | 2019-09-27 | 2019-12-27 | 丹阳市银海镍铬化工有限公司 | Waterproof paint capable of absorbing formaldehyde and preparation method thereof |
| CN110643279A (en) * | 2019-09-27 | 2020-01-03 | 丹阳市银海镍铬化工有限公司 | Wear-resistant paint capable of absorbing formaldehyde and preparation method thereof |
| CN113736295A (en) * | 2021-09-24 | 2021-12-03 | 青岛瑞利特新材料科技有限公司 | Graphene inorganic coating with pearlescent effect and preparation method thereof |
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Application publication date: 20170718 |
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