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CN107731934A - A kind of optical-electrical converter and its conversion method - Google Patents

A kind of optical-electrical converter and its conversion method Download PDF

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CN107731934A
CN107731934A CN201711173495.8A CN201711173495A CN107731934A CN 107731934 A CN107731934 A CN 107731934A CN 201711173495 A CN201711173495 A CN 201711173495A CN 107731934 A CN107731934 A CN 107731934A
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substrate
incident beam
carbon nanotubes
aligned carbon
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戴庆
李振军
李驰
白冰
陈科
周圣涵
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National Center for Nanosccience and Technology China
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National Center for Nanosccience and Technology China
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    • HELECTRICITY
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    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/10Semiconductor bodies
    • H10F77/14Shape of semiconductor bodies; Shapes, relative sizes or dispositions of semiconductor regions within semiconductor bodies
    • H10F77/143Shape of semiconductor bodies; Shapes, relative sizes or dispositions of semiconductor regions within semiconductor bodies comprising quantum structures
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Abstract

本发明实施例公开了一种光电转换器及其转换方法,其中,所述光电转换器包括:阴极基板、阳极基板和直立碳纳米管薄膜;其中,所述直立碳纳米管薄膜上的各个碳纳米管与所述阴极基板垂直连接且各个碳纳米管之间平行排布;直立碳纳米管薄膜,用于吸收不同波长的入射光束的能量,在所述入射光束的作用下激发出负电荷;所述阳极基板,用于接收所述直立碳纳米管薄膜激发出的负电荷,在与所述阴极基板相对的表面形成负电势;所述阴极基板,用于接收所述直立碳纳米管薄膜激发出所述负电荷后留下的正电荷,在与所述阳极基板相对的表面形成正电势。本发明实施例提供的技术方案可提高光电转换的效率。

The embodiment of the present invention discloses a photoelectric converter and a conversion method thereof, wherein the photoelectric converter includes: a cathode substrate, an anode substrate and a vertical carbon nanotube film; wherein each carbon on the vertical carbon nanotube film The nanotubes are vertically connected to the cathode substrate and the carbon nanotubes are arranged in parallel; the upright carbon nanotube film is used to absorb the energy of incident light beams of different wavelengths, and excite negative charges under the action of the incident light beams; The anode substrate is used to receive the negative charges excited by the vertical carbon nanotube film, and form a negative potential on the surface opposite to the cathode substrate; the cathode substrate is used to receive the excitation of the vertical carbon nanotube film The positive charges left after the negative charges are discharged form a positive potential on the surface opposite to the anode substrate. The technical solutions provided by the embodiments of the present invention can improve the efficiency of photoelectric conversion.

Description

一种光电转换器及其转换方法A photoelectric converter and conversion method thereof

技术领域technical field

本发明实施例涉及光电能量转化技术领域,尤其涉及一种光电转换器及其转换方法。Embodiments of the present invention relate to the technical field of photoelectric energy conversion, and in particular to a photoelectric converter and a conversion method thereof.

背景技术Background technique

随着社会的发展,人类对能源的需要不断增长,而传统资源的枯竭且引发的环境问题日益严重,使得寻求可持续的清洁能源是当前全球发展中的一个重要问题。而自然界的太阳能量是解决当前人类发展中面临能源问题的有效办法之一。With the development of society, human beings' demand for energy continues to grow, while the depletion of traditional resources and the environmental problems caused by it are becoming more and more serious, making the search for sustainable clean energy an important issue in the current global development. The solar energy in nature is one of the effective ways to solve the energy problems faced by the current human development.

现有技术中,将太阳能的光电转化技术主要有以下两种:In the prior art, there are mainly the following two technologies for photoelectric conversion of solar energy:

方案一,光伏发电过程中主要是利用半导体界面的光生伏特效应将光能直接转变为电能的一种技术,半导体PN结处于平衡状态时,在P区和N区的交界处存在一个内建反向电场,当入射太阳光的能量大于电池材料的能量带隙,使得电池材料中的价带电子吸收能量发生跃迁,使得在价带中出现空穴,光生电子和空穴在内建电场的作用下分别向N区和P区做反向运动,使得在两端造成电势差,由此产生电子-空穴对,但在很短的时间内电子和空穴容易发生复合,因此大大制约了光能转化成电能的效率。Option 1, in the process of photovoltaic power generation, it mainly uses the photovoltaic effect of the semiconductor interface to directly convert light energy into electrical energy. To the electric field, when the energy of the incident sunlight is greater than the energy band gap of the battery material, the valence band electrons in the battery material absorb energy and undergo a transition, so that holes appear in the valence band, and the photogenerated electrons and holes are built into the electric field. Reverse movement to the N region and the P region respectively, causing a potential difference at both ends, thereby generating electron-hole pairs, but electrons and holes are prone to recombination in a short period of time, thus greatly restricting the light energy. conversion efficiency into electricity.

方案二,光热发电技术中,主要是利用聚光系统将太阳能收集到内部的传热媒介内,利用高温蒸汽驱动汽轮机组发电或利用温差电动势效应得到电能。由于需要将太阳能传递到传热媒介内,导致减少部分光能,进而降低光能转化成电能的效率。Option two, in the photothermal power generation technology, mainly uses the concentrating system to collect solar energy into the internal heat transfer medium, uses high-temperature steam to drive the steam turbine unit to generate electricity, or uses the thermoelectromotive force effect to obtain electric energy. Due to the need to transmit solar energy into the heat transfer medium, part of the light energy is reduced, thereby reducing the efficiency of converting light energy into electrical energy.

然而现有技术方案存在以下不足:Yet existing technical scheme has following deficiency:

(1)、方案一制备的PN结在发电过程中存在光生电子和空穴的复合问题,降低光电转换的效率。(1) The PN junction prepared by Scheme 1 has the problem of recombination of photogenerated electrons and holes during the power generation process, which reduces the efficiency of photoelectric conversion.

(2)、方案二光热发电过程中需要向传热媒介传输热量,降低光电转换的效率。(2), Option 2 In the process of photothermal power generation, it is necessary to transfer heat to the heat transfer medium to reduce the efficiency of photoelectric conversion.

发明内容Contents of the invention

本发明实施例提供一种光电转换器及其转换方法,能够提高光电转换效率。Embodiments of the present invention provide a photoelectric converter and a conversion method thereof, which can improve photoelectric conversion efficiency.

第一方面,本发明实施例提供了一种光电转换器,所述光电转换器包括:阴极基板、阳极基板和直立碳纳米管薄膜;其中,所述直立碳纳米管薄膜上的各个碳纳米管与所述阴极基板垂直连接且各个碳纳米管之间平行排布;In the first aspect, an embodiment of the present invention provides a photoelectric converter, which includes: a cathode substrate, an anode substrate, and a vertical carbon nanotube film; wherein, each carbon nanotube on the vertical carbon nanotube film vertically connected to the cathode substrate and arranged in parallel between each carbon nanotube;

直立碳纳米管薄膜,用于吸收不同波长的入射光束的能量,在所述入射光束的作用下激发出负电荷;The vertical carbon nanotube film is used to absorb the energy of incident light beams of different wavelengths, and excite negative charges under the action of the incident light beams;

所述阳极基板,用于接收所述直立碳纳米管薄膜激发出的所述负电荷,在与所述阴极基板相对的表面形成负电势;The anode substrate is used to receive the negative charge excited by the vertical carbon nanotube film, and form a negative potential on the surface opposite to the cathode substrate;

所述阴极基板,用于接收所述直立碳纳米管薄膜激发出所述负电荷后留下的正电荷,在与所述阳极基板相对的表面形成正电势。The cathode substrate is used to receive the positive charges left after the negative charges are excited from the vertical carbon nanotube film, and form a positive potential on the surface opposite to the anode substrate.

第二方面,本发明实施例还提供了一种光电转换方法,所述方法包括:In a second aspect, an embodiment of the present invention also provides a photoelectric conversion method, the method comprising:

直立碳纳米管薄膜吸收不同波长的入射光束的能量,在所述入射光束的作用下激发出负电荷;The vertical carbon nanotube film absorbs the energy of incident light beams of different wavelengths, and excites negative charges under the action of the incident light beams;

阳极基板接收所述直立碳纳米管薄膜激发出的所述负电荷,在与阴极基板相对的表面形成负电势;The anode substrate receives the negative charge excited by the vertical carbon nanotube film, and forms a negative potential on the surface opposite to the cathode substrate;

所述阴极基板接收所述直立碳纳米管薄膜激发出所述负电荷后留下的正电荷,在与所述阳极基板相对的表面形成正电势;其中,所述直立碳纳米管薄膜上的各个碳纳米管与所述阴极基板垂直连接且各个碳纳米管之间平行排布。The cathode substrate receives the positive charge left after the negative charge is excited by the vertical carbon nanotube film, and forms a positive potential on the surface opposite to the anode substrate; wherein, each of the vertical carbon nanotube films The carbon nanotubes are vertically connected to the cathode substrate and each carbon nanotube is arranged in parallel.

本发明实施例通过利用直立碳纳米管薄膜可以对入射光束进行高效率的吸收,由于制备的碳纳米管密度较高,较容易被加热到高温发射负电荷,阳极基板接收到负电荷后与阴极基板之间产生电势差,从而驱动负载工作,实现光电能量的转换过程;其中电子激发的过程中只涉及到负电荷的发射,正电荷传递到阴极基板,负电荷发射过程中不会产生正、负电荷复合及载流子平衡等问题,而且在光电转换过程中,避免光能传递给热媒介,使得均提高了光电转换的效率。The embodiment of the present invention can absorb the incident light beam efficiently by using the upright carbon nanotube film. Due to the high density of the prepared carbon nanotubes, it is easier to be heated to a high temperature to emit negative charges. After receiving the negative charges, the anode substrate and the cathode A potential difference is generated between the substrates to drive the load and realize the conversion process of photoelectric energy; the process of electron excitation only involves the emission of negative charges, and the positive charges are transferred to the cathode substrate, and no positive and negative charges are generated during the emission of negative charges. Problems such as charge recombination and carrier balance, and in the process of photoelectric conversion, avoid light energy from being transmitted to the heat medium, so that the efficiency of photoelectric conversion is improved.

附图说明Description of drawings

图1是本发明实施例一提供的光电转换器的第一结构示意图;FIG. 1 is a schematic diagram of a first structure of a photoelectric converter provided by Embodiment 1 of the present invention;

图2是本发明实施例一提供的碳纳米管与阴极基板垂直连接的结构示意图;2 is a schematic structural diagram of the vertical connection of carbon nanotubes and cathode substrates provided by Embodiment 1 of the present invention;

图3是本发明实施例二提供的光电转换器的第二结构示意图;Fig. 3 is a second structural schematic diagram of the photoelectric converter provided by Embodiment 2 of the present invention;

图4是本发明实施例三提供的光电转换器的第三结构示意图;FIG. 4 is a schematic diagram of the third structure of the photoelectric converter provided by Embodiment 3 of the present invention;

图5是本发明实施例四提供的光电转换器的第四结构示意图;Fig. 5 is a fourth structural schematic diagram of the photoelectric converter provided by Embodiment 4 of the present invention;

图6是本发明实施例五提供的光电转换方法的流程图。FIG. 6 is a flowchart of a photoelectric conversion method provided by Embodiment 5 of the present invention.

具体实施方式detailed description

下面结合附图和实施例对本发明作进一步的详细说明。可以理解的是,此处所描述的具体实施例仅仅用于解释本发明,而非对本发明的限定。另外还需要说明的是,为了便于描述,附图中仅示出了与本发明相关的部分而非全部结构。The present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, but not to limit the present invention. In addition, it should be noted that, for the convenience of description, only some structures related to the present invention are shown in the drawings but not all structures.

实施例一Embodiment one

图1是本发明实施例一提供的光电转换器的第一结构示意图,本发明实施例可适用于真空环境或非真空环境中光电转换的情况,真空环境包括真空腔和外太空,其中当阳极基板与碳纳米管之间的距离小于100nm而并不短路的情况下,可不设置真空腔(非真空)。其中光电转换的可以为自然光(太阳光)的能量,也可以来转换高能量密度的激光束。Figure 1 is a schematic diagram of the first structure of the photoelectric converter provided by the first embodiment of the present invention. The embodiment of the present invention can be applied to the situation of photoelectric conversion in a vacuum environment or a non-vacuum environment. The vacuum environment includes a vacuum chamber and outer space, where the anode If the distance between the substrate and the carbon nanotubes is less than 100 nm and there is no short circuit, the vacuum chamber may not be provided (no vacuum). The photoelectric conversion can be the energy of natural light (sunlight), or it can be converted into a laser beam with high energy density.

如图1所示,该光电转换器的具体结构包括如下:阴极基板1、阳极基板3和直立碳纳米管薄膜;其中,直立碳纳米管薄膜上的各个碳纳米管2与阴极基板1垂直连接且各个碳纳米管2之间平行排布;直立碳纳米管薄膜,用于吸收不同波长的入射光束的能量,在入射光束的作用下激发出负电荷4,碳纳米管2具有近似黑体的光吸收特性,是目前光吸收率最高的材料;在阴极基板1上制备致密的碳纳米管2很容易吸收热量升温到1000℃,实现负电荷4(电子)的激发,在碳纳米管2表面或内部形成正电荷(空穴);阳极基板3,用于接收直立碳纳米管薄膜激发出的负电荷4,在与阴极基板1相对的表面形成负电势;阴极基板1,用于接收直立碳纳米管薄膜激发出负电荷后留下的正电荷,在与阳极基板3相对的表面形成正电势,使得阴极基板1和阳极基板3之间形成正电势和负电势的电势差,形成的电势差可以驱动负载5工作。As shown in Figure 1, the concrete structure of this photoelectric converter comprises as follows: cathode substrate 1, anode substrate 3 and upright carbon nanotube film; Wherein, each carbon nanotube 2 on the upright carbon nanotube film is vertically connected with cathode substrate 1 And each carbon nanotube 2 is arranged in parallel; the upright carbon nanotube film is used to absorb the energy of incident light beams of different wavelengths, and excites negative charges 4 under the action of the incident light beam, and the carbon nanotubes 2 have a light intensity similar to that of a black body. Absorption characteristics, it is the material with the highest light absorption rate at present; the dense carbon nanotubes 2 prepared on the cathode substrate 1 can easily absorb heat and heat up to 1000 ° C, to realize the excitation of negative charges 4 (electrons), on the surface of the carbon nanotubes 2 or Positive charges (holes) are formed inside; the anode substrate 3 is used to receive the negative charges 4 excited by the vertical carbon nanotube film, and forms a negative potential on the surface opposite to the cathode substrate 1; the cathode substrate 1 is used to receive the vertical carbon nanotubes. The positive charge left after the negative charge is excited by the tube film forms a positive potential on the surface opposite to the anode substrate 3, so that a potential difference of positive potential and negative potential is formed between the cathode substrate 1 and the anode substrate 3, and the formed potential difference can drive the load 5 jobs.

本发明实施例提供的技术方案,通过利用碳纳米管接近黑体的光吸收特性,可以对入射光进行高效率的吸收,由于制备的直立碳纳米管薄膜密度较高,容易被加热到高温实现电子的发射,阳极基板接收到负电荷后与阴极基板之间产生电势差形成电流,从而驱动负载工作,实现光电能量的转换;其中电子激发的过程中只涉及到负电荷发射到阳极基板,无正电荷参与,可解决传统PN结电池发电过程中正、负电荷复合及载流子平衡等问题;而且在光电转换过程中,避免光能向传热媒介传输热量,上述过程均提高了光电转换的效率;同时光电转换器及转换方法具有较高的环境适应性。The technical solution provided by the embodiments of the present invention can absorb incident light with high efficiency by utilizing the light absorption characteristics of carbon nanotubes close to black bodies. Since the prepared upright carbon nanotube film has a high density, it is easy to be heated to high temperature to realize electronic When the anode substrate receives negative charges, a potential difference is generated between the cathode substrate and a current is formed, thereby driving the load to work and realizing the conversion of photoelectric energy; the process of electron excitation only involves the emission of negative charges to the anode substrate, without positive charges Participation can solve the problems of positive and negative charge recombination and carrier balance in the power generation process of traditional PN junction cells; and in the process of photoelectric conversion, it avoids the transmission of heat from light energy to the heat transfer medium, and the above processes improve the efficiency of photoelectric conversion; At the same time, the photoelectric converter and the conversion method have high environmental adaptability.

其中,光电转换的过程发生在真空环境中,所需的真空环境是为了排除空气中的气体分子阻挡对负电荷(电子)发射过程,真空环境包括设置真空腔体和外太空环境。真空腔体可以为玻璃封装、金属封装、陶瓷封装或上述材质的复合封装结构,其中真空腔体的适当位置开设有高通透的光学窗口,可以保证入射光束的低损耗传输,光学窗口材料可以选取玻璃、石英、蓝宝石和金刚石等,同时真空腔体为了保持内部的高真空度可以增加适量的吸气剂等。Among them, the process of photoelectric conversion occurs in a vacuum environment. The required vacuum environment is to exclude gas molecules in the air from blocking the negative charge (electron) emission process. The vacuum environment includes setting a vacuum cavity and an outer space environment. The vacuum cavity can be glass package, metal package, ceramic package or a composite package structure of the above materials, wherein a high-transparency optical window is opened at an appropriate position of the vacuum cavity, which can ensure low-loss transmission of the incident beam, and the optical window material can be Choose glass, quartz, sapphire and diamond, etc. At the same time, the vacuum chamber can add an appropriate amount of getter to maintain a high vacuum inside.

图2是本发明实施例一提供的碳纳米管与阴极基板垂直连接的结构示意图,如图2所示,碳纳米管2可以采用化学气相沉积法、电弧放电法或微波等离子法等技术制备。其中生长的碳纳米管2形状包括矩形、圆形、椭圆形或阵列等图案。可选地,以金属钼作为碳纳米管2的生长基底,其中生长基底可作为光电转换器的阴极基板1,并对钼片进行预处理,采用电子束蒸发技术向钼片表面沉积碳纳米管生长催化剂,在通过化学气相沉积技术(MOCVD)生长直立的碳纳米管2。将沉积有碳纳米管生长催化剂的生长基底放入生长设备后,首先通入200-700sccm的氢气作为还原性气体,然后将生长设备快速升温到500-750℃,在通入20-100sccm的乙炔气体后保持10-30min的生长时间,将生长设备冷却降温后得到在金属钼基底表面直立生长的碳纳米管2,其中碳纳米管2的直径为0.1-50nm。Fig. 2 is a schematic structural diagram of the vertical connection of carbon nanotubes and cathode substrates provided by Embodiment 1 of the present invention. As shown in Fig. 2, carbon nanotubes 2 can be prepared by chemical vapor deposition, arc discharge or microwave plasma. The shape of the grown carbon nanotubes 2 includes patterns such as rectangle, circle, ellipse or array. Optionally, metal molybdenum is used as the growth substrate of the carbon nanotubes 2, wherein the growth substrate can be used as the cathode substrate 1 of the photoelectric converter, and the molybdenum sheet is pretreated, and the carbon nanotubes are deposited on the surface of the molybdenum sheet by electron beam evaporation technology Growth catalysts, vertical carbon nanotubes are grown by chemical vapor deposition (MOCVD) 2 . After putting the growth substrate deposited with the carbon nanotube growth catalyst into the growth equipment, first feed 200-700 sccm of hydrogen as a reducing gas, then rapidly heat up the growth equipment to 500-750 °C, and then feed 20-100 sccm of acetylene The growth time is maintained for 10-30 minutes after the gas is released, and the growth equipment is cooled to obtain carbon nanotubes 2 vertically grown on the surface of the metal molybdenum substrate, wherein the diameter of the carbon nanotubes 2 is 0.1-50 nm.

可选地,阳极基板包括:面状透明阳极基板、开孔透明阳极基板、面状不透明阳极基板或者开孔不透明阳极基板;阴极基板包括:面状透明阴极基板或者面状不透明阴极基板。Optionally, the anode substrate includes: planar transparent anode substrate, perforated transparent anode substrate, planar opaque anode substrate or perforated opaque anode substrate; the cathode substrate includes: planar transparent cathode substrate or planar opaque cathode substrate.

其中,选取的阳极基板与阴极基板均具有良好的导电性,根据制作的器件结构需要,阳极基板与阴极基板均可制成透明基板(材料可以为ITO,石墨烯或金属网格等),也可以是不透明的金属基板(材料可以为铜、银、钼、碳布及不锈钢等)或者不透明的重掺杂硅基底等。阴极基板的形状为面状结构,阳极基板形状可以为面状结构或者为了满足光束传输需要,对面状阳极基板进行面内开孔,形成开孔阳极基板。最后,使得阳极基板包括:面状透明阳极基板、开孔透明阳极基板、面状不透明阳极基板或者开孔不透明阳极基板;阴极基板包括:面状透明阴极基板或者面状不透明阴极基板。Among them, the selected anode substrate and cathode substrate all have good conductivity. According to the structural requirements of the device, the anode substrate and the cathode substrate can be made into transparent substrates (materials can be ITO, graphene or metal grids, etc.), or It can be an opaque metal substrate (materials can be copper, silver, molybdenum, carbon cloth, stainless steel, etc.) or an opaque heavily doped silicon substrate. The shape of the cathode substrate is a planar structure, and the shape of the anode substrate can be a planar structure or in order to meet the needs of beam transmission, the planar anode substrate is opened in-plane to form a perforated anode substrate. Finally, the anode substrate includes: planar transparent anode substrate, perforated transparent anode substrate, planar opaque anode substrate or perforated opaque anode substrate; the cathode substrate includes: planar transparent cathode substrate or planar opaque cathode substrate.

实施例二Embodiment two

图3是本发明实施例二提供的光电转换器的第二结构示意图,在实施例一的基础上进行优化,具体是本发明实施例的光电转换器还包括:直立碳纳米管薄膜吸收通过光线汇聚系统汇聚后形成的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从面状透明阴极基板透过。Fig. 3 is a schematic diagram of the second structure of the photoelectric converter provided by Embodiment 2 of the present invention, which is optimized on the basis of Embodiment 1. Specifically, the photoelectric converter according to the embodiment of the present invention also includes: vertical carbon nanotube film absorbing passing light The incident light beam formed by the converging system excites negative charges under the action of the incident light beam; wherein, the incident light beam passes through the planar transparent cathode substrate.

本发明实施例通过在地面环境的真空腔中,通过光线汇聚系统汇聚的自然光可从面状透明阴极基板透过并照射到碳纳米管的表面或内部,碳纳米管会发出稳定的负电荷被阳极基板接收,使得碳纳米管表面或内部形成正电荷传递到阴极基板,避免了正、负电荷的复合,使得阳极基板与阴极基板之间形成电流,提高了光电转换的效率,同时还可用于收集地面太阳光能。In the embodiment of the present invention, in the vacuum chamber of the ground environment, the natural light gathered by the light concentrating system can pass through the planar transparent cathode substrate and irradiate the surface or inside of the carbon nanotubes, and the carbon nanotubes will emit stable negative charges and be absorbed by the carbon nanotubes. The positive charge on the surface or inside of the carbon nanotubes is received by the anode substrate and transferred to the cathode substrate, avoiding the recombination of positive and negative charges, so that a current is formed between the anode substrate and the cathode substrate, which improves the efficiency of photoelectric conversion, and can also be used for Harvesting solar energy from the ground.

如图3所示,本发明实施例提供的光电转换器可适用于地面收集太阳光能,该器件可以在地球表面的真空腔中工作,主要是在阴极基板1的表面制备密度较高的碳纳米管2,通过将辐射源8(太阳)辐射的光束经过光线汇聚系统7形成入射光束9,入射光束9穿过透明阴极基板1照射到生长直立的碳纳米管2的表面,使碳纳米管2表面或内部出现局域高温区,其中局域高温区可以位于碳纳米管2的中心位置或边缘位置,局域高温区的温度在超过600℃后,碳纳米管2会出现稳定的负电荷4(电子)发射,使得阳极基板3接收发射的负电荷(电子)后与阴极基板1之间产生电势差,从而可以驱动负载5工作,实现光电转换的过程。As shown in Figure 3, the photoelectric converter provided by the embodiment of the present invention is suitable for collecting solar light energy on the ground. The nanotube 2 forms the incident beam 9 through the light beam radiated by the radiation source 8 (sun) through the light converging system 7, and the incident beam 9 passes through the transparent cathode substrate 1 and irradiates the surface of the carbon nanotube 2 growing upright, so that the carbon nanotube 2 A local high-temperature area appears on the surface or inside, and the local high-temperature area can be located at the center or edge of the carbon nanotube 2. After the temperature of the local high-temperature area exceeds 600°C, the carbon nanotube 2 will have a stable negative charge 4 (Electron) emission, so that a potential difference is generated between the anode substrate 3 and the cathode substrate 1 after receiving the emitted negative charges (electrons), so as to drive the load 5 to work and realize the process of photoelectric conversion.

实施例三Embodiment three

图4是本发明实施例三提供的光电转换器的第三结构示意图,本实施例中光电转换的为自然光(太阳光)。在实施例一的基础上进行优化,具体是本发明实施例的光电转换器还包括:直立碳纳米管薄膜吸收通过光线汇聚系统汇聚后形成的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从开孔不透明阳极基板的开孔处穿过。FIG. 4 is a schematic diagram of the third structure of the photoelectric converter provided by the third embodiment of the present invention. In this embodiment, natural light (sunlight) is photoelectrically converted. Optimizing on the basis of Embodiment 1, specifically, the photoelectric converter of the embodiment of the present invention also includes: the vertical carbon nanotube film absorbs the incident light beam formed after being converged by the light converging system, and excites negative charges under the action of the incident light beam ; Wherein, the incident light beam passes through the opening of the opaque anode substrate.

本发明实施例在外太空的环境下,通过光线汇聚系统汇聚的太阳光从开孔不透明阳极基板穿过照射到碳纳米管的表面或内部,碳纳米管会发出稳定的负电荷被阳极基板接收,使得碳纳米管表面或内部形成正电荷传递到阴极基板,避免正、负电荷的复合,使得阳极基板与阴极基板之间形成电流,提高了光电转换的效率。In the embodiment of the present invention, in the environment of outer space, the sunlight collected by the light concentrating system passes through the open-hole opaque anode substrate and irradiates the surface or interior of the carbon nanotubes, and the carbon nanotubes will emit stable negative charges and be received by the anode substrate. The positive charges formed on the surface or inside of the carbon nanotubes are transferred to the cathode substrate, avoiding the recombination of positive and negative charges, so that a current is formed between the anode substrate and the cathode substrate, and the photoelectric conversion efficiency is improved.

如图4所示,本发明实施例提供的光电转换器可适用于外太空对太阳光或其它辐射源能量的吸收及转换。本实施例中,将来自辐射源8(太阳光)的辐射光线经光线汇聚系统7汇聚后形成的入射光束9,可从开孔不透明阳极基板3的开孔处穿过,聚焦在碳纳米管2的局部区域形成局域高温区,其中局域高温区可以位于多个碳纳米管2的中心位置或边缘位置,从而使得碳纳米管2接收光能使得局部区域升温,在超过600℃后,碳纳米管2会发出稳定的负电荷4(电子)被阳极基板3接收,使得碳纳米管2表面或内部形成正电荷传递到阴极基板1,使得阳极基板3与阴极基板1之间产生电势差,进而通过驱动负载5来验证光电转换的过程。As shown in FIG. 4 , the photoelectric converter provided by the embodiment of the present invention is suitable for absorbing and converting energy from sunlight or other radiation sources in outer space. In this embodiment, the incident light beam 9 formed after the radiation light from the radiation source 8 (sunlight) is converged by the light converging system 7 can pass through the opening of the opaque anode substrate 3 and focus on the carbon nanotube The local area of 2 forms a local high-temperature area, wherein the local high-temperature area can be located at the center or edge of a plurality of carbon nanotubes 2, so that the carbon nanotubes 2 receive light energy and make the local area heat up. After exceeding 600 ° C, The carbon nanotubes 2 will emit stable negative charges 4 (electrons) and be received by the anode substrate 3, so that the positive charges formed on the surface or inside of the carbon nanotubes 2 are transferred to the cathode substrate 1, so that a potential difference is generated between the anode substrate 3 and the cathode substrate 1, Further, the photoelectric conversion process is verified by driving the load 5 .

实施例四Embodiment four

图5是本发明实施例四提供的光电转换器的第四结构示意图;在实施例一的基础上进行优化,具体是本发明实施例的光电转换器还包括:直立碳纳米管薄膜接收发光器件产生的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从开孔不透明阳极基板的开孔处穿过。Fig. 5 is a schematic diagram of the fourth structure of the photoelectric converter provided by Embodiment 4 of the present invention; it is optimized on the basis of Embodiment 1, specifically, the photoelectric converter of the embodiment of the present invention also includes: vertical carbon nanotube film receiving and emitting devices The generated incident light beam excites negative charges under the action of the incident light beam; wherein, the incident light beam passes through the opening of the perforated opaque anode substrate.

本发明实施例从发光器件产生的入射光束,通过开孔不透光阳极基板的开孔处穿过辐射在碳纳米管的表面和内部,使得碳纳米管激发出负电荷到阳极基板,使得碳纳米管表面或内部形成正电荷传递到阴极基板,避免正、负电荷的复合,使得阳极基板与阴极基板之间形成电流,提高了光电转换的效率,同时此结构还可以用于光电探测领域。In the embodiment of the present invention, the incident light beam generated from the light-emitting device passes through the opening of the opaque anode substrate to radiate on the surface and inside of the carbon nanotube, so that the carbon nanotube excites negative charges to the anode substrate, so that the carbon nanotube The positive charges formed on the surface or inside of the nanotubes are transferred to the cathode substrate to avoid the recombination of positive and negative charges, so that a current is formed between the anode substrate and the cathode substrate, which improves the efficiency of photoelectric conversion. At the same time, this structure can also be used in the field of photodetection.

如图5所示,本发明实施例提供的光电转换器适用于转换高能量密度的激光束或粒子束,主要是将无需汇聚的入射光束9从开孔不透光阳极基板3的开孔处辐射到碳纳米管2的表面或内部形成局域高温区,其中局域高温区可以位于多个碳纳米管2的中心位置或边缘位置,由于碳纳米管2近似黑体的光吸收特性,极易将自身加热到极高的温度,具有极高的光热转换效率,从而激发负电荷4(电子),被阳极基板3接收,提高光电转换效率。选择的开孔不透明阳极基板3可以在保证收集电子的同时可以让入射光束9顺利通过,此外,这种结构除了用于对高能激光束实现光电转换,还可应用于激光能量传输,激光信号传输和激光探测等光电领域。As shown in Figure 5, the photoelectric converter provided by the embodiment of the present invention is suitable for converting laser beams or particle beams with high energy density. Radiation to the surface or inside of the carbon nanotube 2 forms a local high-temperature zone, wherein the local high-temperature zone can be located at the center or edge of a plurality of carbon nanotubes 2. Since the carbon nanotube 2 is similar to the light absorption characteristics of a black body, it is very easy to Heating itself to a very high temperature has a very high photothermal conversion efficiency, thereby exciting negative charges 4 (electrons), which are received by the anode substrate 3 to improve photoelectric conversion efficiency. The selected open-hole opaque anode substrate 3 can allow the incident light beam 9 to pass through while ensuring the collection of electrons. In addition, this structure is not only used for photoelectric conversion of high-energy laser beams, but also can be used for laser energy transmission and laser signal transmission. and laser detection and other optoelectronic fields.

其中无需设置真空腔体包括以下两种情况:其一,当阳极基板与碳纳米管之间的距离小于100nm而并不短路的情况;其二,当光电转换器工作于外太空真空环境时,可以不用设置真空腔体。There are two situations where there is no need to set up a vacuum chamber: first, when the distance between the anode substrate and the carbon nanotube is less than 100nm and there is no short circuit; second, when the photoelectric converter works in the vacuum environment of outer space, A vacuum cavity may not be provided.

实施例五Embodiment five

图6是本发明实施例五提供的光电转换方法的流程图。本发明实施例还提供了一种光电转换方法,具体步骤包括:FIG. 6 is a flowchart of a photoelectric conversion method provided by Embodiment 5 of the present invention. The embodiment of the present invention also provides a photoelectric conversion method, and the specific steps include:

S610、直立碳纳米管薄膜吸收不同波长的入射光束的能量,在入射光束的作用下激发出负电荷。S610, the upright carbon nanotube film absorbs the energy of incident light beams of different wavelengths, and excites negative charges under the action of the incident light beams.

首选需要在生长基底上制备与生长基底垂直连接的直立型碳纳米管,其中生长基底可为光电转换器的阴极基板,制备的高密度直立碳纳米管具有丰富的纳米间隙,质量密度极低,吸收入射光束后极易被加热到1000℃以上,激发负电荷(电子)并生成传输正电荷(空穴)。其中入射光束可以为汇聚的太阳光或高能激光束等。The first choice is to prepare vertical carbon nanotubes vertically connected to the growth substrate on the growth substrate. The growth substrate can be the cathode substrate of the photoelectric converter. The prepared high-density vertical carbon nanotubes have abundant nano-gap and extremely low mass density. After absorbing the incident light beam, it is easily heated to above 1000°C, excites negative charges (electrons) and generates positive charges (holes) for transport. The incident light beam can be concentrated sunlight or high-energy laser beam, etc.

S620、阳极基板接收直立碳纳米管薄膜激发出的负电荷,在与阴极基板相对的表面形成负电势。S620, the anode substrate receives the negative charges excited by the vertical carbon nanotube film, and forms a negative potential on the surface opposite to the cathode substrate.

阳极基板可以接收各个碳纳米管激发出的负电荷(电子),在与阴极基板相对的表面形成负电势,使其与阴极基板之间产生电势差。The anode substrate can receive the negative charges (electrons) excited by each carbon nanotube, and form a negative potential on the surface opposite to the cathode substrate to generate a potential difference between it and the cathode substrate.

其中阳极基板的可以为面状透明阳极基板、开孔透明阳极基板、面状不透明阳极基板或者开孔不透明阳极基板,阳极基板的形状不同,透光性不同则所起的作用也不相同。The anode substrate can be a planar transparent anode substrate, a perforated transparent anode substrate, a planar opaque anode substrate or a perforated opaque anode substrate. The shape of the anode substrate is different, and the role of the different light transmittance is not the same.

S630、阴极基板接收直立碳纳米管薄膜激发出负电荷后留下的正电荷,在与阳极基板相对的表面形成正电势;其中,直立碳纳米管薄膜上的各个碳纳米管与阴极基板垂直连接且各个碳纳米管之间平行排布。S630, the cathode substrate receives the positive charge left after the negative charge is excited by the vertical carbon nanotube film, and forms a positive potential on the surface opposite to the anode substrate; wherein, each carbon nanotube on the vertical carbon nanotube film is vertically connected to the cathode substrate And the carbon nanotubes are arranged in parallel.

当碳纳米管激发出负电荷(电子)后,会形成正电荷(空穴)沿着碳纳米管传输到阴极基板,在于阳极基板相对的表面形成正电势,这样阳极基板与阴极基板之间形成电势差,从而可以驱动负载工作,验证光电转换过程。其中光电转换方式通常是一种基于高温下的材料发射热电子过程(包括太阳能电池),当入射光子的能量大于碳纳米管的功函数(约4.5eV)使得电子发射。为使碳纳米管表面或内部出现局域高温区,需要照射入射光束,使得局域温度超过600℃,保证碳纳米管发射稳定电子。When the carbon nanotubes excite negative charges (electrons), positive charges (holes) will be formed and transported along the carbon nanotubes to the cathode substrate, forming a positive potential on the opposite surface of the anode substrate, thus forming a positive charge (hole) between the anode substrate and the cathode substrate. Potential difference, so that the load can be driven to verify the photoelectric conversion process. Among them, the photoelectric conversion method is usually a process based on materials emitting thermal electrons at high temperatures (including solar cells), when the energy of the incident photons is greater than the work function of carbon nanotubes (about 4.5eV), electrons are emitted. In order to make a local high-temperature region appear on the surface or inside of the carbon nanotube, it is necessary to irradiate the incident light beam so that the local temperature exceeds 600°C to ensure that the carbon nanotube emits stable electrons.

其中,阴极基板包括面状透明阴极基板或者面状不透明阴极基板。碳纳米管薄膜包括多个碳纳米管,各个碳纳米管与阴极基板垂直连接,且各个碳纳米管之间平行排布,这样可表明制备的为直立平行排布的碳纳米管。碳纳米管是一种优良的电子发射材料,同时也是最接近黑体的材料,具有优良的宽光谱吸收特性,在光电领域具有广泛应用。Wherein, the cathode substrate includes a planar transparent cathode substrate or a planar opaque cathode substrate. The carbon nanotube film includes a plurality of carbon nanotubes, each carbon nanotube is vertically connected to the cathode substrate, and each carbon nanotube is arranged in parallel, which indicates that the prepared carbon nanotubes are vertically arranged in parallel. Carbon nanotubes are an excellent electron emission material, and also the material closest to a black body. They have excellent broad-spectrum absorption characteristics and are widely used in the field of optoelectronics.

本发明实施例提供的技术方案,通过利用碳纳米管接近黑体的光吸收特性,可以对光进行高效率的吸收,由于制备的直立碳纳米管质量密度极低,较容易被加热到高温实现负电荷的发射,阳极基板接收到负电荷后与阴极基板之间产生电势差形成电流,从而驱动负载工作,实现光电能量的转换过程;其中电子激发的过程中只涉及到负电荷的发射,无正电荷参与,可解决传统PN结电池发电过程中正、负电荷复合及载流子平衡等问题,而且在光电转换过程中,避免光能向传热媒介传输热量,上述过程均利于提高光电转换的效率。The technical solution provided by the embodiments of the present invention can absorb light with high efficiency by utilizing the light absorption characteristics of carbon nanotubes close to black bodies. Since the prepared upright carbon nanotubes have extremely low mass density, they are easier to be heated to high temperatures to achieve negative For the emission of charges, a potential difference is generated between the anode substrate and the cathode substrate after receiving negative charges to form a current, thereby driving the load to work and realizing the conversion process of photoelectric energy; the process of electron excitation only involves the emission of negative charges, no positive charges Participation can solve the problems of positive and negative charge recombination and carrier balance in the traditional PN junction battery power generation process, and in the photoelectric conversion process, avoid light energy from transferring heat to the heat transfer medium. The above processes are conducive to improving the efficiency of photoelectric conversion.

可选地,直立碳纳米管薄膜吸收通过光线汇聚系统汇聚后形成的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从面状透明阴极基板透过。Optionally, the vertical carbon nanotube film absorbs the incident light beam formed by the light converging system, and excites negative charges under the action of the incident light beam; wherein, the incident light beam passes through the planar transparent cathode substrate.

示例性地继续参见图3,通过光线汇聚系统7汇聚的太阳光形成入射光束9,并从面状透明阴极基板1透过照射到碳纳米管2的表面或内部,碳纳米管2会发出稳定的负电荷4(电子)被阳极基板3接收,使得碳纳米管2表面或内部形成正电荷传递到阴极基板1,避免正、负电荷的复合,使得阳极基板3与阴极基板1之间形成电流,提高了光电转换的效率,同时还可用于收集地面太阳光能。Continuing to refer to FIG. 3 exemplarily, the sunlight condensed by the light converging system 7 forms an incident beam 9, and penetrates from the planar transparent cathode substrate 1 to the surface or inside of the carbon nanotube 2, and the carbon nanotube 2 emits a stable The negative charges 4 (electrons) are received by the anode substrate 3, so that positive charges are formed on the surface or inside of the carbon nanotube 2 and transferred to the cathode substrate 1, avoiding the recombination of positive and negative charges, so that a current is formed between the anode substrate 3 and the cathode substrate 1 , improve the efficiency of photoelectric conversion, and can also be used to collect solar energy on the ground.

可选地,直立碳纳米管薄膜吸收通过光线汇聚系统汇聚后形成的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从开孔不透明阳极基板的开孔处穿过。Optionally, the erected carbon nanotube film absorbs the incident beam formed by the light converging system, and excites negative charges under the action of the incident beam; wherein, the incident beam passes through the opening of the opaque anode substrate.

示例性地继续参见图4,通过光线汇聚系统7汇聚的太阳光形成入射光束9,并从开孔不透明阳极基板3穿过照射到碳纳米管2的表面或内部,碳纳米管2会发出稳定的负电荷4(电子)被阳极基板3接收,使得碳纳米管2表面或内部形成正电荷传递到阴极基板1,避免正、负电荷的复合,使得阳极基板3与阴极基板1之间形成电流,提高了光电转换的效率。Exemplarily continue to refer to FIG. 4 , the sunlight condensed by the light concentrating system 7 forms an incident light beam 9, and passes through the perforated opaque anode substrate 3 to irradiate the surface or inside of the carbon nanotube 2, and the carbon nanotube 2 emits a stable The negative charges 4 (electrons) are received by the anode substrate 3, so that positive charges are formed on the surface or inside of the carbon nanotube 2 and transferred to the cathode substrate 1, avoiding the recombination of positive and negative charges, so that a current is formed between the anode substrate 3 and the cathode substrate 1 , improving the photoelectric conversion efficiency.

可选地,直立碳纳米管薄膜接收发光器件产生的入射光束,在入射光束的作用下激发出负电荷;其中,入射光束从开孔不透明阳极基板的开孔处穿过。Optionally, the vertical carbon nanotube film receives incident light beams generated by the light-emitting device, and negative charges are excited under the action of the incident light beams; wherein the incident light beams pass through the openings of the opaque anode substrate with holes.

示例性地继续参见图5,发光器件产生的入射光束9,通过开孔不透光阳极基板3的开孔处穿过辐射在碳纳米管2的表面和内部,使得碳纳米管2激发出负电荷4(电子)到阳极基板3,使得碳纳米管2表面或内部形成正电荷传递到阴极基板1,避免正、负电荷的复合,使得阳极基板3与阴极基板1之间形成电流,提高了光电转换的效率,同时此结构还可以用于光电探测领域。Exemplarily continue to refer to FIG. 5 , the incident light beam 9 generated by the light-emitting device passes through the opening of the opaque anode substrate 3 to radiate on the surface and inside of the carbon nanotube 2, so that the carbon nanotube 2 excites a negative Charge 4 (electrons) to the anode substrate 3, so that positive charges are formed on the surface or inside of the carbon nanotube 2 and transferred to the cathode substrate 1, avoiding the recombination of positive and negative charges, so that a current is formed between the anode substrate 3 and the cathode substrate 1, improving the The efficiency of photoelectric conversion is high, and the structure can also be used in the field of photodetection.

注意,上述仅为本发明的较佳实施例及所运用技术原理。本领域技术人员会理解,本发明不限于这里所述的特定实施例,对本领域技术人员来说能够进行各种明显的变化、重新调整和替代而不会脱离本发明的保护范围。因此,虽然通过以上实施例对本发明进行了较为详细的说明,但是本发明不仅仅限于以上实施例,在不脱离本发明构思的情况下,还可以包括更多其他等效实施例,而本发明的范围由所附的权利要求范围决定。Note that the above are only preferred embodiments of the present invention and applied technical principles. Those skilled in the art will understand that the present invention is not limited to the specific embodiments described herein, and that various obvious changes, readjustments and substitutions can be made by those skilled in the art without departing from the protection scope of the present invention. Therefore, although the present invention has been described in detail through the above embodiments, the present invention is not limited to the above embodiments, and can also include more other equivalent embodiments without departing from the concept of the present invention, and the present invention The scope is determined by the scope of the appended claims.

Claims (10)

  1. A kind of 1. optical-electrical converter, it is characterised in that including:Cathode base, anode grid substrate and Aligned carbon nanotubes film;Its In, each CNT on the Aligned carbon nanotubes film and the cathode base vertical connection and each CNT it Between parallel arrangement;
    Aligned carbon nanotubes film, the energy of the incident beam for absorbing different wave length, in the presence of the incident beam Inspire negative electrical charge;
    The anode grid substrate, the negative electrical charge inspired for receiving the Aligned carbon nanotubes film, with the negative electrode The relative surface of substrate forms negative potential;
    The cathode base, the positive charge left after the negative electrical charge is inspired for receiving the Aligned carbon nanotubes film, Positive potential is formed on the surface relative with the anode grid substrate.
  2. 2. optical-electrical converter according to claim 1, it is characterised in that the anode grid substrate includes:Planar transparent anode Substrate, perforate transparent anode substrate, the opaque anode grid substrate of planar or the opaque anode grid substrate of perforate;The cathode base bag Include:Planar transparent cathode substrate or the opaque cathode base of planar.
  3. 3. optical-electrical converter according to claim 2, it is characterised in that the Aligned carbon nanotubes film absorption passes through light The incident beam formed after the convergence of line collecting system, inspires the negative electrical charge in the presence of the incident beam;Its In, the incident beam passes through from the planar transparent cathode substrate.
  4. 4. optical-electrical converter according to claim 2, it is characterised in that the Aligned carbon nanotubes film absorption passes through light The incident beam formed after the convergence of line collecting system, inspires the negative electrical charge in the presence of the incident beam;Its In, the incident beam passes through from the tapping of the opaque anode grid substrate of the perforate.
  5. 5. optical-electrical converter according to claim 2, it is characterised in that the Aligned carbon nanotubes film receives photophore The incident beam caused by part, inspires the negative electrical charge in the presence of the incident beam;Wherein, the incident beam Passed through from the tapping of the opaque anode grid substrate of the perforate.
  6. A kind of 6. opto-electronic conversion method, it is characterised in that including:
    The energy of the incident beam of Aligned carbon nanotubes film absorption different wave length, is inspired in the presence of the incident beam Negative electrical charge;
    Anode grid substrate receives the negative electrical charge that the Aligned carbon nanotubes film inspires, on the surface relative with cathode base Form negative potential;
    The cathode base receives the Aligned carbon nanotubes film and inspires the positive charge left after the negative electrical charge, with institute State the relative surface of anode grid substrate and form positive potential;Wherein, each CNT on the Aligned carbon nanotubes film and institute State parallel arrangement between cathode base vertical connection and each CNT.
  7. 7. according to the method for claim 6, it is characterised in that the anode grid substrate includes:Planar transparent anode substrate, open Hole transparent anode substrate, the opaque anode grid substrate of planar or the opaque anode grid substrate of perforate;The cathode base includes:Planar Transparent cathode substrate or the opaque cathode base of planar.
  8. 8. according to the method for claim 7, it is characterised in that the Aligned carbon nanotubes film absorption passes through light collection The incident beam formed after system convergence, inspires the negative electrical charge in the presence of the incident beam;Wherein, it is described Incident beam passes through from the planar transparent cathode substrate.
  9. 9. according to the method for claim 7, it is characterised in that the Aligned carbon nanotubes film absorption passes through light collection The incident beam formed after system convergence, inspires the negative electrical charge in the presence of the incident beam;Wherein, it is described Incident beam passes through from the tapping of the opaque anode grid substrate of the perforate.
  10. 10. according to the method for claim 7, it is characterised in that the Aligned carbon nanotubes film receives luminescent device production The raw incident beam, inspires the negative electrical charge in the presence of the incident beam;Wherein, the incident beam is from institute The tapping for stating the opaque anode grid substrate of perforate passes through.
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