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CN107502832B - A kind of double quenching partition process for high speed tup abrasion-resistant stee steel and preparation method thereof - Google Patents

A kind of double quenching partition process for high speed tup abrasion-resistant stee steel and preparation method thereof Download PDF

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CN107502832B
CN107502832B CN201710609331.9A CN201710609331A CN107502832B CN 107502832 B CN107502832 B CN 107502832B CN 201710609331 A CN201710609331 A CN 201710609331A CN 107502832 B CN107502832 B CN 107502832B
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abrasion
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wear
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steel
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CN107502832A (en
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于浩
康鹏飞
宋成浩
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University of Science and Technology Beijing USTB
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A kind of double quenching partition process for high speed tup abrasion-resistant stees and preparation method thereof, belong to metal material processing technical field.Double quenching partition process for high speed tups in the present invention are designed with abrasion-resistant stee by reasonable alloy system ingredient, again by innovative double quenchings+with division technique, make the tissue more fine uniform of steel, width of sheet obviously becomes smaller, the duplex structure of the proportion-controllable finally obtained, with high rigidity, high intensity, higher toughness, highly anti-fatigue comprehensive mechanical property.The yield strength R of materialp0.2>=1550MPa, tensile strength Rm>=1950MPa, elongation after fracture A >=13%, strength and ductility product >=25GPa%, V-notch ballistic work >=13J, hardness >=55HRC.The membranaceous retained austenite being distributed between martensite lath not only contributes to coordinate the deformation under tissue stress condition, and the effect for hindering microfissure extension is also clearly, improves the anti-fatigue ability of material and the service life of tup.This double quenching partition process for high speed tups are the ideal material of pulverizer hammer steel with abrasion-resistant stee.

Description

A kind of double quenching partition process for high speed tup abrasion-resistant stee steel and preparation method thereof
Technical field
The invention belongs to metal material processing technical fields, and it is difficult to understand for lath martensite and remnants to be related to a kind of room temperature texture Duplex structure's abrasion-resistant stee of family name's body, and the hammer of double quenching partition process for high speed with high rigidity, high-wearing feature and excellent toughness Head abrasion-resistant stee and its manufacturing method.
Background technique
Hammer mill is broadly divided into two kinds of hammerhead crusher and reaction type bar crusher.Due to hammer mill knot Structure is simple, high production efficiency and easy to maintenance, is widely used to mine, metallurgy, building materials, highway, railway, water conservancy and electric power etc. Industry.The material for being commonly used in production tup has potassium steel, abrasion resistant cast steel, high-chromium abrasion-proof cast iron.Hammer mill fragment Tup or bar are main vulnerable parts when material, and since tup working environment is severe, the impact and abrasion of material can all make to hammer into shape It is short-lived, it is prone to wear failure.Materials microstructure and mechanical property are particularly important, service life of the strong influence to it And working efficiency, this requires hammer head materials to have good wearability.
Before about 130 years, British R.A.Hadfield has invented common potassium steel.So far, it is wear-resistant Important status is still occupied in material.Potassium steel has stronger work hardening capacity, as shock loading increases, table Face thin hardened layer is bigger, and hardness is higher, and abrasive resistance is better, and inside workpiece still keeps its original high tenacity, high-ductility. Traditional material of tup is still potassium steel at present.Since the wear form of tup is based on impact wear, and hammer crushing Suffered impact force does not reach the processing hardening claimed range of potassium steel to machine tup during operation, wear-resisting so as to cause its Property it is lower, and lead to tup surface deformation during processing hardening, crushing effect is deteriorated, it is easy to cause because of subsequent abrasion Service life shortens.
It, can when the advantage of potassium steel cannot be brought into play when crusher is worked under the working condition fiercely impacted It is replaced with casting tup using steel alloy.Steel alloy tup is compared with being suitble to operating condition little in broken material granularity and medium stress Under the conditions of use.General middle and high carbon low alloy steel and high-alloy steel this few class abrasion-resistant cast steel material are used to manufacture tup casting. The alloying elements such as nickel, chromium can also be suitably added according to concrete condition to improve the harden ability of material.But under normative heat treatment technique Tup often toughness is poor, easily there is the case where abrasion, fall.
Since the additive amount of alloying element in low-alloy wear-resistant steel is relatively fewer, carbon content is higher, and hardness is larger, to mention The wear-resisting property of high material need to centainly match its preparation process and the reasonable design of structural state progress with control, acquisition Martensite and retained austenite two-phase fine grain structure steel, it is ensured that material has high rigidity, high intensity, higher toughness, highly resistance tired The good comprehensive performance of labor.Chinese patent application CN200910227804.4 describe a kind of casting obtain hardness 50~ The preparation method of the abrasion-resistant stee of 53HRC, the material composition joined the Re more than 0.1wt%, bring the raising of cost when designing, And it is carbide and ferrite that prolonged lonneal, which easily leads to a small amount of retained austenite tissue breakdown in material, is brought tough Property deterioration, elongation is 2.4~3.0%, and plasticity and toughness are far below double quenching partition process for high speed tups use in the present invention Abrasion-resistant stee.Chinese patent application CN201010575998.X describes a kind of cast and obtains the preparation method of low-alloy wear-resistant steel, The Material cladding adds the microalloy elements such as C, Si, Mn, Cr, B, Ce, is had by obtaining one kind after oil quenchinng+tempering heat treatment Tempered martensite's steel, not under conditions of open gap, ballistic work is only 25~40J, and tensile strength is only 1100~ 1500MPa, mechanical property are poor.Chinese patent application CN201510520418.X describes a kind of hot rolling and obtains inexpensive high-ductility Property super abrasion-resistant stee preparation method, which adds the microalloy elements such as C, Si, Mn, Ti, B, by adding up reduction ratio For 65~80% hot rolling, and after rolling rear section cooling, then heated, salt bath cooling, the complicated heat such as medium temperature+lonneal After treatment process, a kind of surface is obtained based on tempered martensite, high tenacity of the center portion based on bainite and retained austenite Wear-resisting steel plate, the yield strength R of materialp0.2=980~1235MPa, tensile strength Rm=1400~1562MPa, elongation after fracture A=14.2~18.1%, hardness is 412~478HV, after the hot rolling deformation by aximal deformation value, elongation after fracture and this hair Bright middle abrasion-resistant stee differs very little, however its intensity and hardness far below double quenching partition process for high speed tups in the present invention with resistance to Grind steel.
In conclusion double quenching partition process for high speed tups in the present invention with abrasion-resistant stee by reasonable alloy system at Set up meter separately, and innovative double quenchings+match division technique make steel have the duplex structure of proportion-controllable, with high rigidity, high-strength Degree, higher toughness, highly anti-fatigue comprehensive mechanical property, realize the target of high-wearing feature.Heat treatment process technological parameter is adjusted, It after quenching twice, is obviously refined in the crystal grain of material, martensite lath mean breadth is in 200nm hereinafter, having lath-shaped The two-phase structure of martensite and retained austenite.As the result is shown when respectively organized in material shared volume fraction certain When range, especially when retained austenite control in a certain ratio, the toughness of material can be improved, coordinate the change of crystal grain Shape, and the ballistic work of a part can be absorbed under the conditions of severe impact, make retained austenite that the transition process to martensite occur, Improve the hardness of matrix.Mutually coordinated cooperation between respectively organizing during military service, lath martensite tissue can be improved material Intensity, metastable retained austenite undergoes phase transition induced plastic effect, allows the material to bear biggish load and deformation, tool There are good plasticity and shock resistance, yield strength Rp0.2>=1550MPa, tensile strength Rm >=1950MPa, elongation of having no progeny Rate A >=13%.Membranaceous retained austenite effect of the more uniform distribution for obstruction microfissure extension in the base simultaneously Also clearly, the anti-fatigue ability for substantially increasing material improves the service life of tup.Therefore this double quenching partition works The alloying component content of skill high speed tup abrasion-resistant stee is low, and excellent combination property is greatly improved production efficiency, is pulverizer hammer The head ideal material of steel.
Summary of the invention
Requirement for pulverizer hammer steel to the strength of materials and plasticity, the present invention provide a kind of double quenching partition techniques High speed tup abrasion-resistant stee steel and preparation method thereof, material have ultra-fine lath martensite+residual austenite body tissue, lath-shaped Mutually coordinated cooperation between martensite and residual austenite body tissue has good intensity and toughness, has high-wearing feature.
The technical scheme is that a kind of double quenching partition process for high speed tup abrasion-resistant stees, chemical component weight Percentage are as follows: C:0.40~0.60%, Si:0.5~1.5%, Mn:1.5~2.5%, Cr:1.5~2.5%, Mo:0.1~ 0.5%, Nb:0.01~0.05%, Ti:0.05~0.25%, surplus are Fe and inevitable impurity.Another mesh of the invention The preparation method for being to provide double quenching partition process for high speed tup abrasion-resistant stees, specifically includes the following steps:
Step 1: weighing raw material according to design ingredient, smelted, cast, obtain ingot casting, forged after ingot casting is heated, forged It makes than being 6~8,;
Step 2: tup blank is prepared in step 1 and is warming up to 980~1080 DEG C, 1~1.5h is kept the temperature, is air-cooled to 400 ~450 DEG C of temperature, then oil are cooled to room temperature;
Step 3: by step 2 treated tup blank is warming up to 850~950 DEG C, keep the temperature 1~1.5h, be air-cooled to 300~ 350 DEG C of temperature, then control and be cooled to 80~140 DEG C, keep the temperature 20~30min;
Step 4: by step 3 treated tup is heated to 350~450 DEG C, keep the temperature 50~80min, water cooling to room temperature, into Row is necessary to be machined to get double quenching partition process for high speed tup abrasion-resistant stee tups are arrived.
Further, the tissue of double quenching partition process for high speed tup abrasion-resistant stees is lath martensite+residual austenite Body, the volume ratio of each tissue are as follows: lath martensite 78%~85%, retained austenite 15%~22%;Double quenchings are matched The martensite lath mean breadth of division technique high speed tup abrasion-resistant stee is less than 200nm.
Further, material room temperature texture of the present invention very fine uniform, lath martensite and two kinds of retained austenite tissues Ratio is controllable, and retained austenite ratio is controlled 15~22%, remaining is lath martensite, is finally quenched in room temperature process It does not undergo phase transition.
Further, the yield strength R of double quenching partition process for high speed tups its material of abrasion-resistant steep0.2≥ 1550MPa, tensile strength Rm>=1950MPa, elongation after fracture A >=13%, strength and ductility product >=25GPa%, V-notch ballistic work >=13J, hardness >=55HRC.
The effect of essential element in material of the present invention are as follows:
The increase of C content can greatly improve intensity, the hardness of material, but will cause the serious evil of moulding and toughness Change.C is the essential element of the important element that austenite is formed and stable austenite, and austenite is to bainite transformation process In the diffusion of C element occurs simultaneously, C element enrichment is so that it can be stabilized at room temperature in retained austenite.
Si can inhibit the precipitation of the carbide such as cementite, reduce the C being dissolved in ferrite, improve C content in austenite, To guarantee obtain enough stable residual austenites at room temperature, in steel Si content 1.3% hereinafter, with Si content increasing Add, intensity, toughness, plasticity increase.
The main function of Mn is enhancing stabilization of austenite, extends it and changes incubation period, improves the intensity and harden ability of steel, Also Ms is promoted to reduce simultaneously, forms the retained austenite of the rich carbon of certain volume.
Cr can increase the intensity of steel, plasticity, toughness.The wearability of material is improved with the increase of chromium content, when chromium is less than When 3%, the effect improved to the wearability of material is more significant.Chromium can increase the harden ability of steel, when additional amount is larger, especially and When Ni, Mo arrange in pairs or groups, the excellent steel grade of harden ability can get.
Mo can significantly improve the intensity and toughness of steel, in addition it can improve the harden ability and temper resistance of steel.
The present invention matches forged forming and heat treatment process by reasonable element, is prepared a kind of multiple with fine grain The high toughness wear resistant steel of phase constitution, it is partition that uniformly by the diffusion of first time heating alloying component, crystal grain refines significantly after quenching Tiny and uniform matrix is provided.By matching division technique, retained austenite fixing fabric structure 15~22%, guarantee material have compared with High obdurability, during military service, metastable retained austenite induced transformation effect also can be further improved material toughness and Wearability, the complex precipitates that Ti, Nb and C, N are formed can also generate precipitation strength effect, along with refined crystalline strengthening effect can The comprehensive performance of material is improved to varying degrees.
Detailed description of the invention
Fig. 1 is the heat treatment process schematic diagram of abrasion-resistant stee of the invention;
Fig. 2 is the scanning organization chart picture of the abrasion-resistant stee in the embodiment of the present invention 1;
Fig. 3 is the transmission organization chart picture of the abrasion-resistant stee in the embodiment of the present invention 1;
Fig. 4 is the scanning organization chart picture of the abrasion-resistant stee in the embodiment of the present invention 2;
Fig. 5 is the transmission organization chart picture of the abrasion-resistant stee in the embodiment of the present invention 2.
Specific embodiment
Embodiment 1:
It smelted, cast first, in accordance with mentioned component range, then detected the ingredient of slab, be shown in Table 1.
The ingredient (wt.%) of 1 slab of table
Specific heat treatment process parameter is shown in Table 2.
2 heat treatment process parameter of table
3 are shown in Table according to the mechanical property of double quenching partition process for high speed tup abrasion-resistant stees made from Tables 1 and 2.
3 mechanical property of table
The double quenching partition process for high speed tups being prepared according to Tables 1 and 2 measure remaining Austria by XRD with abrasion-resistant stee Family name's body volume fraction, martensitic phase volume fraction subtract retained austenite volume fraction for 100%, the results are shown in Table 4.
4 different tissues content of table
Each mechanical property reaches very high mechanical performance index as can be seen from Table 3, yield strength 1572MPa, Tensile strength is 1993MPa, and elongation 15%, hardness 57HRC, V mouthful ballistic work is 15J.Scanned photograph as shown in Fig. 2, Photo is transmitted as shown in figure 3, tissue is lath martensite+retained austenite, lath martensite and retained austenite difference Zhan are total The 81% of volume and 19%, retained austenite is mainly distributed between martensite lath with film-form, and dislocation density is higher.
Embodiment 2:
It smelted, cast first, in accordance with mentioned component range, then detected the ingredient of slab, be shown in Table 5.
The ingredient (wt.%) of 5 slab of table
Specific heat treatment process parameter is shown in Table 6.
6 heat treatment process parameter of table
7 are shown in Table according to the mechanical property of double quenching partition process for high speed tup abrasion-resistant stees made from table 5 and table 6.
7 mechanical property of table
The double quenching partition process for high speed tups being prepared according to table 5 and table 6 measure remaining Austria by XRD with abrasion-resistant stee Family name's body volume fraction, martensitic phase volume fraction subtract retained austenite volume fraction for 100%, the results are shown in Table 8.
8 different tissues content of table
Each mechanical property reaches very high mechanical performance index as can be seen from Table 7, yield strength 1563MPa, Tensile strength is 1956MPa, and elongation 14%, hardness 55HRC, V mouthful ballistic work is 13.5J.Scanned photograph such as Fig. 4 institute Show, as shown in figure 5, tissue is lath martensite+retained austenite, lath martensite and retained austenite account for transmission photo respectively The 79% of total volume and 21%, retained austenite is mainly distributed between martensite lath with film-form, and dislocation density compares example 1 It is more lower.
It should be noted last that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than limit.Although ginseng It is described the invention in detail according to embodiment, it will be apparent to an ordinarily skilled person in the art that technical side of the invention Case is modified or replaced equivalently, and without departure from the spirit and scope of technical solution of the present invention, should all be covered in the present invention Scope of the claims in.

Claims (2)

1.一种双淬火配分工艺高速锤头用耐磨钢的制备方法,其特征在于,包括以下步骤:1. a preparation method of wear-resistant steel for double quenching and partitioning process high-speed hammer head, is characterized in that, comprises the following steps: 步骤1:按照设计成分称取原料,进行冶炼、铸造,得到铸锭,将铸锭加热后锻造,锻造比为6~8;Step 1: Weigh the raw materials according to the design components, carry out smelting and casting to obtain an ingot, and heat the ingot for forging, with a forging ratio of 6 to 8; 步骤2:将步骤1制备得到锤头坯料升温至980~1080℃,保温1~1.5h,空冷至400~450℃温度,再油冷至室温;Step 2: The hammer head blank prepared in step 1 is heated to 980~1080°C, kept for 1~1.5h, air-cooled to 400~450°C, and then oil-cooled to room temperature; 步骤3:将步骤2处理后的锤头坯料升温至850~950℃,保温1~1.5h,空冷至300~350℃温度,再控制冷却至80~140℃,保温20~30min;Step 3: heating the hammer blank processed in step 2 to 850~950°C, keeping the temperature for 1~1.5h, air-cooling to 300~350°C, and then controlling the cooling to 80~140°C, keeping the temperature for 20~30min; 步骤4:将步骤3处理后的锤头加热至350~450℃,保温50~80min,水冷至室温,进行必要的机械加工,即得到双淬火配分工艺高速锤头用耐磨钢锤头;Step 4: heating the hammer head treated in step 3 to 350~450°C, keeping the temperature for 50~80min, cooling it with water to room temperature, and performing necessary mechanical processing to obtain the wear-resistant steel hammer head for the high-speed hammer head of the double quenching and partitioning process; 耐磨钢的化学成分重量百分比为:C:0.40~0.60%、Si:0.5~1.5%、Mn:1.5~1.95%、Cr:1.5~2.5%、Mo:0.1~0.5%、Nb:0.01~0.05%、Ti:0.05~0.25%,余量为Fe和不可避免的杂质;The chemical composition weight percentage of wear-resistant steel is: C: 0.40~0.60%, Si: 0.5~1.5%, Mn: 1.5~1.95%, Cr: 1.5~2.5%, Mo: 0.1~0.5%, Nb: 0.01~0.05 %, Ti: 0.05~0.25%, the balance is Fe and inevitable impurities; 所述双淬火配分工艺高速锤头用耐磨钢的各个组织的体积比为:板条马氏体78%~85%、残余奥氏体15%~22%;所述双淬火配分工艺高速锤头用耐磨钢的平均马氏体板条宽度小于200nm。The volume ratio of each structure of the wear-resistant steel for the high-speed hammer head of the double quenching and partitioning process is: 78%-85% of lath martensite and 15%-22% of the retained austenite; the high-speed hammer of the double-quenching and partitioning process The average martensitic lath width of the wear-resistant steel for the head is less than 200 nm. 2.根据权利要求1所述的双淬火配分工艺高速锤头用耐磨钢的制备方法,其特征在于,材料的屈服强度Rp0.2≥1550MPa,抗拉强度Rm≥1950MPa,断后伸长率A≥13%,强塑积≥25GPa·%,V形缺口冲击功≥13J,硬度≥55HRC。2. The preparation method of wear-resistant steel for high-speed hammer head with double quenching and partitioning process according to claim 1, characterized in that, the yield strength of the material R p0.2 ≥ 1550MPa, the tensile strength R m ≥ 1950MPa, and the elongation after fracture Rate A ≥ 13%, strong-plastic product ≥ 25GPa·%, V-notch impact energy ≥ 13J, hardness ≥ 55HRC.
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CN106435404A (en) * 2015-08-06 2017-02-22 江苏金源锻造股份有限公司 Low wind speed wind power unit low-carbon alloy steel wind power main shaft manufacturing method

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