CN107417116A - A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity - Google Patents
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity Download PDFInfo
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- CN107417116A CN107417116A CN201710466893.2A CN201710466893A CN107417116A CN 107417116 A CN107417116 A CN 107417116A CN 201710466893 A CN201710466893 A CN 201710466893A CN 107417116 A CN107417116 A CN 107417116A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000000498 ball milling Methods 0.000 claims description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 11
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000011812 mixed powder Substances 0.000 claims description 5
- 229910021532 Calcite Inorganic materials 0.000 claims description 4
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 4
- 239000010436 fluorite Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000010431 corundum Substances 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000005491 wire drawing Methods 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 4
- 229910052796 boron Inorganic materials 0.000 abstract description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 230000009467 reduction Effects 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract 1
- 238000011161 development Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 3
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000003462 bioceramic Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/06—Frit compositions, i.e. in a powdered or comminuted form containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, by scientific and reasonable composition proportion, Li2O, SrO, BaO are not added, reduces cost of material, it is with the obvious advantage compared with the glaze of the high-alkali composition of high boron；It is used for the glazing of household ceramic blank by glaze made of present invention process, by being obtained after glaze firing, hardness is high, glossiness is high, acid and alkali-resistance safe glaze layer, it is and not leaded, it is harmless, environmental protection is attractive in appearance, and external quality is excellent while can ensure the inherent quality of ceramic body, improves the wear-resisting and mechanical strength of domestic ceramics, whole technical process adheres to low-carbon, energy-conservation, the environmentally friendly purpose of emission reduction, is worthy of popularization.
Description
Technical field
The present invention relates to ceramic technology field, more particularly to a kind of system of the unleaded glaze of domestic ceramics of inexpensive high rigidity
Preparation Method.
Background technology
Fritted glaze has the advantages that property of glaze is good, safe, stability is good, temperature of glaze firing scope is wide, in daily pottery
Porcelain, defend and have very extensive application with fields such as ceramics, architectural pottery, the art pottery, bioceramics.According to performance and application
The difference in field, fritted glaze can be divided into leaded fritted glaze, lead-free fritting enamel, clear frit glaze, translucent fritted glaze, milky white molten
Block glaze etc..So far, the development of fritted glaze is highly developed, still, as the development and people of society are to product property
And the increasingly lifting of security performance requirement so that fritted glaze is reducing cost, safety and environmental protection, properties of product raising and novel product
Still there is very big research space in the fields such as research and development.Lead clear frit glaze because melting behaviour is excellent, the transparency is good, glossiness is high,
The many merits such as temperature of glaze firing scope is wide, cost is low, and as the representative products in earliest fritted glaze.But lead glaze product exists
The phenomenon of lead dissolution inevitably occurs during use, and harm is brought to the health of human body of user, this is also limit
The critical defect of lead glaze production development processed.With the development of society, the improvement of people's living standards, people increasingly focus on the person
Health and catering product, the security of living environment.Lead glaze product is gradually abandoned by people, and lead-free fritting enamel arises at the historic moment, generation
The arena of history is climbed up for lead frit glaze.
Lead-free transparent fritted glaze is substituted with oxides such as Bi2O3, Y2O3, B2O3, MgO, ZnO, BaO, SrO, Li2O
Pb O and a kind of fritted glaze prepared, it not only solves the potential safety hazard of lead glaze, and molten with being compared favourably with lead glaze
Melting property, the transparency, glossiness, glaze firing performance, are widely used in architectural pottery, domestic ceramics, defend with fields such as ceramics, especially
It is the domestic ceramics closely related with food, but this glaze uses the high-alkali composition of high boron more, cost is higher, and product is most
In the presence of the transparency it is poor, firing range is narrow, product defects is more the deficiencies of, this just need further to process raw material and technique progress
It is modified.
The content of the invention
The object of the invention be exactly in order to make up prior art the defects of, there is provided a kind of domestic ceramics of inexpensive high rigidity without
The preparation method of lead glaze material.
The present invention is achieved by the following technical solutions：
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, including step in detail below：
（1）Potassium feldspar, quartz sand, calcite, fluorite, glass dust are subjected to ball milling respectively, it is stand-by to cross 120 mesh sieves, then with oxygen
Change zinc, borax used 20 mesh sieve to be sufficiently mixed for 2-3 times after mixing；
（2）Corundum crucible is put into melting furnace, starts to add above-mentioned mixed powder after being preheated to 1100-1150 DEG C, using point
The mode of secondary dosage is added, and is warming up to 1350-1400 DEG C with 3-5 DEG C/min speed, then temperature control 60-90 minutes, being fused into can
Wire drawing state；
（3）The glass metal melted is poured into rapidly into water quenching in cold water, into small frit, to be dried in vacuo after collection, obtain the small of drying
Frit, small frit is added in the 1.8-2 times of water measured after stirring and be sent into the progress thick ball milling of one-level, ball in intermittent ball mill
Grinding media is zirconium dioxide microballoon, pulp after thick ball milling 40-50 minutes, then is added and continuously run in ball mill by regulating valve,
The two level ball milling 30-40 minutes matched by different ball-milling mediums, three-level ball milling 50-60 minutes, last overflow pulp；
（4）By step（3）0.02-0.03% carboxymethyl cellulose is added in obtained glaze slip, is stirred.
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, step（1）Described in zinc oxide, boron
Sand is chemical pure preparation.
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, step（1）Described in potassium feldspar, stone
Sand, calcite, fluorite, glass dust, zinc oxide, the proportioning of borax account for respectively total glaze 18.06%, 33%, 15.92%,
7.3%、8.72%、7%、10%。
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, step（2）Described in gradation charging
Mode specifically refer to：Divide mixed powder to 5-6 batches, control and added within 50-60 minutes.
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, step（3）Described in the thick ball of one-level
The particle diameter and proportioning of the ball-milling medium of mill are respectively that a diameter of 80mm big ball of zirconium dioxide is accounted in 80%, a diameter of 40mm
Ball accounts for 20%；The ball-milling medium proportioning of described two level ball milling accounts for 80% for ball in a diameter of 40mm zirconium dioxide, is a diameter of
20mm bead accounts for 20%；The ball-milling medium proportioning of described three-level ball milling accounts for 20% for ball in a diameter of 40mm zirconium dioxide,
A diameter of 20mm bead accounts for 80%.
It is an advantage of the invention that：The present invention by scientific and reasonable composition proportion, do not add Li2O, SrO,
BaO, cost of material is reduced, flux and Network former are used as by diboron trioxide, rationally control the addition of borax, energy
Enough so that glaze melts fully and has good glossiness and transparency, and frit temperature of glaze firing is low, has energy-saving low-carbon
Effect, it is with the obvious advantage compared with the glaze of the high-alkali composition of high boron；Grading ball milling is used during grinding glaze, to replace
Intermittent ball mill time processing finished pulp, both ensure that stabilization of the proportioning of glaze before and after ball milling and uniformly, after ball milling
Frit particles are finer and smoother uniformly, specific surface area increase, are advantageous to the uniform and stable and steady quality of follow-up glazing, while have again
There are higher grinding efficiency and relatively low energy consumption.
Be used for the glazing of household ceramic blank by glaze made of present invention process, by obtained after glaze firing hardness it is high,
Glossiness is high, the safe glaze layer of acid and alkali-resistance, and not leaded, harmless, and environmental protection is attractive in appearance, and external quality is excellent while can protect
The inherent quality of ceramic body is demonstrate,proved, improves the wear-resisting and mechanical strength of domestic ceramics, whole technical process adheres to low-carbon, section
Energy, the environmentally friendly purpose of emission reduction, are worthy of popularization.
Embodiment
A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity, including step in detail below：
（1）180.6g potassium feldspars, 330g quartz sands, 159.2g calcites, 73g fluorites, 87.2 glass dust are subjected to ball milling respectively,
It is stand-by to cross 120 mesh sieves, used 20 mesh sieve to be sufficiently mixed for 2 times after then being mixed with 70g zinc oxide, 100g boraxs；
（2）Corundum crucible is put into melting furnace, starts to add above-mentioned mixed powder after being preheated to 1100 DEG C, point 5 secondary controls exist
Added in 50 minutes, be warming up to 1400 DEG C with 5 DEG C/min speed, then temperature control 60 minutes, being fused into can wire drawing state；
（3）The glass metal melted is poured into rapidly into water quenching in cold water, into small frit, to be dried in vacuo after collection, obtain the small of drying
Frit, small frit is added in the water of 1.8 times of amounts after stirring and be sent into the progress thick ball milling of one-level, ball milling in intermittent ball mill
Medium is zirconium dioxide microballoon（The middle ball that the wherein a diameter of 80mm big ball of zirconium dioxide accounts for 80%, a diameter of 40mm accounts for 20%）,
Thick ball milling pulp after 40 minutes, then added and continuously run in ball mill by regulating valve, by the two of different ball-milling mediums proportioning
Level ball milling（Ball accounts for 80%, a diameter of 20mm bead and accounts for 20% in a diameter of 40mm zirconium dioxide）30 minutes, three-level ball milling（Directly
Ball accounts for 20%, a diameter of 20mm bead and accounts for 80% in the zirconium dioxide that footpath is 40mm）50 minutes, last overflow pulp；
（4）By step（3）0.02% carboxymethyl cellulose is added in obtained glaze slip, is stirred.
Claims (5)
1. the preparation method of the unleaded glaze of domestic ceramics of a kind of inexpensive high rigidity, it is characterised in that including walking in detail below
Suddenly：
（1）Potassium feldspar, quartz sand, calcite, fluorite, glass dust are subjected to ball milling respectively, it is stand-by to cross 120 mesh sieves, then with oxygen
Change zinc, borax used 20 mesh sieve to be sufficiently mixed for 2-3 times after mixing；
（2）Corundum crucible is put into melting furnace, starts to add above-mentioned mixed powder after being preheated to 1100-1150 DEG C, using point
The mode of secondary dosage is added, and is warming up to 1350-1400 DEG C with 3-5 DEG C/min speed, then temperature control 60-90 minutes, being fused into can
Wire drawing state；
（3）The glass metal melted is poured into rapidly into water quenching in cold water, into small frit, to be dried in vacuo after collection, obtain the small of drying
Frit, small frit is added in the 1.8-2 times of water measured after stirring and be sent into the progress thick ball milling of one-level, ball in intermittent ball mill
Grinding media is zirconium dioxide microballoon, pulp after thick ball milling 40-50 minutes, then is added and continuously run in ball mill by regulating valve,
The two level ball milling 30-40 minutes matched by different ball-milling mediums, three-level ball milling 50-60 minutes, last overflow pulp；
（4）By step（3）0.02-0.03% carboxymethyl cellulose is added in obtained glaze slip, is stirred.
2. a kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity according to claim 1, its feature
It is, step（1）Described in zinc oxide, borax be chemical pure preparation.
3. a kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity according to claim 1, its feature
It is, step（1）Described in potassium feldspar, quartz sand, calcite, fluorite, glass dust, zinc oxide, the proportioning of borax account for respectively
18.06%, 33%, 15.92%, 7.3%, 8.72%, 7%, the 10% of total glaze.
4. a kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity according to claim 1, its feature
It is, step（2）Described in gradation charging mode specifically refer to：Divide mixed powder to 5-6 batches, control at 50-60 points
Added in clock.
5. a kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity according to claim 1, its feature
It is, step（3）Described in the thick ball milling of one-level ball-milling medium particle diameter and proportioning be respectively a diameter of 80mm dioxy
The middle ball that the change big ball of zirconium accounts for 80%, a diameter of 40mm accounts for 20%；The ball-milling medium proportioning of described two level ball milling is a diameter of 40mm
Zirconium dioxide in ball account for 80%, a diameter of 20mm bead and account for 20%；The ball-milling medium proportioning of described three-level ball milling is diameter
The bead that 20%, a diameter of 20mm is accounted for for ball in 40mm zirconium dioxide accounts for 80%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710466893.2A CN107417116A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710466893.2A CN107417116A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107417116A true CN107417116A (en) | 2017-12-01 |
Family
ID=60426007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710466893.2A Pending CN107417116A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191239A (en) * | 2018-01-18 | 2018-06-22 | 武汉理工大学 | A kind of unleaded metallic luster gold glaze and preparation method thereof |
| CN109111118A (en) * | 2018-10-25 | 2019-01-01 | 中山市大盛文化传播有限公司 | ceramic glaze and porcelain |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584345A (en) * | 2012-01-19 | 2012-07-18 | 星谊精密陶瓷科技（昆山）有限公司 | High-temperature imitated full-glazed clear frit and production method thereof |
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN106278138A (en) * | 2016-08-05 | 2017-01-04 | 佛山市凯撒大道陶瓷有限公司 | A kind of high rigidity ceramic tile and preparation method thereof |
-
2017
- 2017-06-20 CN CN201710466893.2A patent/CN107417116A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584345A (en) * | 2012-01-19 | 2012-07-18 | 星谊精密陶瓷科技（昆山）有限公司 | High-temperature imitated full-glazed clear frit and production method thereof |
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN106278138A (en) * | 2016-08-05 | 2017-01-04 | 佛山市凯撒大道陶瓷有限公司 | A kind of high rigidity ceramic tile and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191239A (en) * | 2018-01-18 | 2018-06-22 | 武汉理工大学 | A kind of unleaded metallic luster gold glaze and preparation method thereof |
| CN109111118A (en) * | 2018-10-25 | 2019-01-01 | 中山市大盛文化传播有限公司 | ceramic glaze and porcelain |
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Application publication date: 20171201 |
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